SOME BASIC CONCEPTS

OF ORGANIC CHEMISTRY

1. Out of the following how many are heterocyclic compounds ?

(a) Toluene (b) Cyclohexanol (c) Aniline (d) Pyridine
(e) Furan (f) Thiophene
(1) 2 (2) 3 (3) 4 (4) 5
fuEu esa ls fdrus ;kSfxd fo"kepfØ; gS ?
(a) VkWywbZu (b) lk;DyksgsDlsukWy (c) ,uhyhu (d) fijhMhu

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(e) ¶;wjkWu (f) Fkk;ksQhu
(1) 2 (2) 3 (3) 4 (4) 5
2. Which of the following not correctly matched :-
fuEu esa ls lgh lqesfyr ugh gS \
(1) CH2=CH–OH (Vinyl alcohol)
(2) CH2=CH–CH2–Cl (Allyl chloride)

(3) CH2–OH(Phenyl alcohol)

(4) CH3–CH–NH2 (isopropyl amine)

CH3
3. Incorrect matched IUPAC name is :-

1 1-Chloro-2,4-dinitrobenzene

2 2-Chloro-1-methyl-4-nitrobenzene

3 4-Hydroxy-1,2-dimethylbenzene

4 4-Ethyl-1-fluoro-2-nitrobenzene

(1) 1 (2) 2 (3) 3 (4) 4

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 xyr feyku ;qä IUPAC uke gS :-

1 1&Dyksjks&2]4&MkbukbVªkscsathu

2 2&Dyksjks&1&esfFky&4&ukbVªkscsathu

3 4&gkbMªkWDlh&1]2&MkbesfFkycsathu

4 4&,fFky&1&¶yksjks&2&ukbVªkscsathu

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(1) 1 (2) 2 (3) 3 (4) 4
4. The compound which is not isomeric with diethyl ether is ?
(1) n-propyl methyl ether (2) Butan–1–ol
(3) 2-Methyl propan–2–ol (4) Butanone
fuEu es ls dkSulk ;kSfxd MkbZ,fFky bZFkj dk leko;oh ugh gS \
(1) n-çksfiy esfFky bZFkj (2) C;wVsu&1&vkWy
(3) 2&esfFkyçksisu&2&vkWy (4) C;wVu
s ksu
5. Select the correct option about conformations of ethane :-
(1) It is possible to separate conformational isomers of ethane
(2) Magnitude of torsional strain is independent of dihedral angle
(3) The staggered form has maximum and eclipsed form has minimum torsional strain
(4) In all conformations, bond length and bond angle remain same
,Fksu ds la:i.kksa ds laca/k esa lgh dFku dk p;u djsa %
(1) ,Fksu ds la:i.kksa dks i`Fkd djuk laHko gSA
(2) ejksMh fo—fr dk ifjek.k f}ry dks.k ij fuHkZj ugha djrk gSA
(3) ejksMh fo—fr lkarfjr :i esa vf/kdre rFkk xzflr :i esa U;wure gksrk gSA
(4) lHkh la:i.kksa esa vkca/k dks.k rFkk vkca/k yEckbZ leku jgrh gSA
6. Which is true for the following isomeric forms I and II respectively

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 fuEu I rFkk II leko;oh lajpukvksa ds fy, Øe'k% dkSulk lgh gS \

7. Two possible stereo-structures of CH3CH(OH)COOH, which are optically active, are called :-
(1) Enantiomers (2) mesomers (3) Diastereomers (4) Conformational isomers
CH3CH(OH)COOH, dh nks laHkkfor f=foe lajpuk;s tks fd çdkf'kd lfØ; gS] dgykrh gS %
(1) çfrfcEc :Ik (2) eslksej (3) foofje :Ik (4) la:i.k leko;oh

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8. Which one of the following is not aromatic :&
fuEu esa ls dkSulk ,d ,sjksesfVd ugh gS %&
⊕
(1) (2) (3) (4)
⊕  N
9. Which of the following acidic strength order is not correct :
fuEu esa ls vEyh; lkeFkZ dk dksulk Øe lgh ugh gS :
(1) CHCl2COOH > O2NCH2COOH > NC–CH2COOH > F–CH2COOH
(2) ClCH2COOH > BrCH2COOH > HCOOH > ClCH2CH2COOH
(3) Cl3C–COOH > Cl2CHCOOH > ClCH2–COOH > CH3COOH
(4) ClCH2CH2COOH > HCOOH > C6H5–COOH > CH3COOH
10. Match List – I with List – II.
List-I (Compounds) List-II (pKa-Value)
(a) o-Cresol (i) 10
(b) m-Cresol (ii) 15.9
(c) Ethanol (iii) 10.1
(d) Phenol (iv) 10.2
(1) a-(iv), b-(iii), c-(ii), d-(i) (2) a-(iv), b-(ii), c-(iii), d-(i)
(3) a-(iii), b-(iv), c-(ii), d-(i) (4) a-(ii), b-(iv), c-(i), d-(iii)
lwph–I dk feyku lwph–II ds lkFk dhft,
lwph-I (;kSfxd) lwph-II (pKa- eku)
(a) o-ØhlkWy (i) 10
(b) m-ØhlkWy (ii) 15.9

(c) ,FksukWy (iii) 10.1

(d) QhukWy (iv) 10.2

(1) a-(iv), b-(iii), c-(ii), d-(i) (2) a-(iv), b-(ii), c-(iii), d-(i)
(3) a-(iii), b-(iv), c-(ii), d-(i) (4) a-(ii), b-(iv), c-(i), d-(iii)
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11. Assertion : O-nitrophenol is more acidic than m-nitrophenol.
Reason : Intramolecular H-bonding is present in O-nitrophenol.
(1) Both Assertion and Reason are true but Reason is NOT the correct explanation of Assertion.
(2) Assertion is true but Reason is false.
(3) Assertion is false but Reason is true.
(4) Both Assertion and Reason are true and Reason is the correct explanation of Assertion.
dFku % O&ukbVªksQhuksy] m&ukbVªksQhuksy ls vf/kd vEyh; gSA
dkj.k % O&ukbVªksQhuksy esa vUr% v.kqd H&ca/k mifLFkr gSA
(1) dFku vkSj dkj.k nksuks lR; gS] ijUrq dkj.k] dFku dh lgh O;k[;k ugh gSA
(2) dFku lR; gS ijUrq dkj.k vlR; gSA
(3) dFku vlR; gS ijUrq dkj.k lR; gSA
(4) dFku vkSj dkj.k nksuks lR; gS] vkSj dkj.k] dFku dh lgh O;k[;k gSA

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12. Electrophiles are electron seeking species. Which of the following group contain only electrophiles ?
bysDVªkWuLusgh ,d bysDVªkWu xzkgh lewg gS] rks buesa ls dkSulk lewg dsoy bysDVªkWuLusgh j[krk gS \
⊕ ⊕ ⊕ ·· ⊕ · ⊕
(1) BF3, NH3, H2O (2) AlCl3, SO3, NO2 (3) NO2, CH3 , R–O–H
·· (4) C2H5,C2 H5,CH3–

13. Which of the following reaction is not possible.

fuEu esa ls dkSulh vfHkfØ;k lEHko ugh gS \
+
(1) 2R − COOH + 2Na 
→ 2RCOO N a + H 2
+
(2) R − COOH + NaHCO3 
→ RCOO N a + H 2 O + CO 2

OH ONa
(3) + Na 1
+ H
2 2

OH ONa
(4)
+ NaHCO3 + H2O + CO2

14. Statement-I : Hyperperconjugation involves delocalisation of α C–H bond.

⊕
Statement-II : In C H 3 vaccant P orbital is prependicular to the plane in which C–H bonds lie so it doesn't have
hyper conjugation
(1) Both statements are correct (2) Only statement I is correct
(3) Only statement II is correct (4) Both statements are incorrect
dFku-I % vfrla;qXeu izHkko α C–H cU/k dk foLFkkfudj.k j[krk gSA
⊕
dFku-II % C H3 esa fjä P d{kd] C–H cU/k ds yEcor~ gksrk gS vr% bleas vfrl;qXeu ugh gksrk gSA
(1) nksuks dFku lgh gSA (2) dsoy dFku I lgh gSA
(3) dsoy dFku II lgh gSA (4) nksuks dFku xyr gSA
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15. Statement – I : Energy of resonance hybrid is higher than that of any of the cannonical structure.
Statement – II : The difference in energies between energy of resonance hybrid and lowest energy resonating
structure is called as resonance energy.
(1) Both statements I & II are true. (2) Both statements I & II are false.
(3) Statement I is true but II is false. (4) Statement I is false but II is true.
dFku& I : vuqukn ladj dh ÅtkZ fdlh Hkh vuquknh lajpuk dh rqyuk esa vf/kd gSA
dFku& II : vuqukn ladj dh ÅtkZ vkSj fuEure ÅtkZ vuquknh lajpuk dh ÅtkZ ds chp ds varj dks vuqukn ÅtkZ
dgk tkrk gSA
(1) dFku-I vkSj II nksuksa lR; gSaA (2) dFku-I vkSj II nksuksa vlR; gSaA
(3) dFku-I lR; gS ysfdu II vlR; gSA (4) dFku-I vlR; gS ysfdu II lR; gSA
16. Choose the correct order of basic strength in aqueous solution :
(1) C2H5–NH2>(C2H5)2NH>(C2H5)3N>C6H5–NH2
(2) (C2H5)3N>(C2H5)2NH>C2H5–NH2>C6H5–NH2
(3) (C2H5)2NH>(C2H5)3N>C2H5–NH2>C6H5–NH2

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(4) C6H5–NH2>(C2H5)2NH>(C2H5)3N>C2H5–NH2
tyh; foy;u esa {kkjh; lkeF;Zrk dk lgh Øe igpkfu;s &
(1) C2H5–NH2>(C2H5)2NH>(C2H5)3N>C6H5–NH2
(2) (C2H5)3N>(C2H5)2NH>C2H5–NH2>C6H5–NH2
(3) (C2H5)2NH>(C2H5)3N>C2H5–NH2>C6H5–NH2
(4) C6H5–NH2>(C2H5)2NH>(C2H5)3N>C2H5–NH2
17. Assertion : Pyridine is more basic than aniline.
Reason : Pyridine have resonance.
(1) Both Assertion & Reason are True & the Reason is a correct explanation of the Assertion.
(2) Both Assertion & Reason are True but Reason is not a correct explanation of the Assertion.
(3) Assertion is True but the Reason is False.
(4) Both Assertion & Reason are False.
dFku % fijhMhu] ,uhyhu ls vf/kd {kkjh; gksrh gSA
dkj.k % fijhMhu esa vuqukn gksrk gSA
(1) dFku rFkk dkj.k nksuksa lR; gS rFkk dkj.k] dFku dh lgh O;k[;k gSA
(2) dFku rFkk dkj.k nksuksa lR; gS rFkk dkj.k] dFku dh lgh O;k[;k ugh gSA
(3) dFku lR; gS ijUrq dkj.k xyr gSA
(4) dFku rFkk dkj.k nksuksa xyr gSA
18. Incorrect statement among following is :
(1) Electromeric effect is a temporary effect
(2) In electromeric effect π-bonded electron are completely transfer in presence of reagent
(3) In electromeric effect heterolytic bond breaking takes place is σ bond
(4) When inductive and electromeric effect operates in opposite directions the electromeric effect predominates
fuEu esa ls vlR; dFku gS&
(1) bysDVªksesfjd çHkko ,d vLFkk;h çHkko gSA
(2) bysDVªksesfjd çHkko es π&cfU/kr bysDVªkWu dk vfHkdeZd dh mifLFkfr es iw.kZ LFkkukUrj.k gksrk gSA
(3) bysDVªksesfjd çHkko es σ&cU/k dk fo"keka'k cU/k fonyu gksrk gSA
(4) tc çsjf.kd çHkko vkSj bysDVªksesfjd çHkko foijhr fn'kk es yxrs gS] rc bysDVªksesfjd çHkko dh ojh;rk gksrh gSA
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19. Which is an example of +E effect ?
+E çHkko dk mnkgj.k dkSulk gS %

(1) (2)

(3) (4)

20. Arrange stability of the given carbocations in decreasing order –

fn;s x;s dkcZ/kuk;uksa ds LFkkf;Ro dks ?kVrs Øe esa O;ofLFkr dhft,

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(1) I > II > III > IV (2) III > II > I > IV
(3) IV > I > II > III (4) II > III > I > IV

ANSWER KEY : (SOME BASIC CONCEPTS OF ORGANIC CHEMISTRY)

Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. 2 3 3 4 4 3 1 3 4 1 1 2 4 1 4 3 2 3 1 2
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