sc fa se (by 1085" C (asec 10s 20. Wiyst are the solid phases in the di é HAlghs Only (b) Alpha « L fing of 60% o ARIE an alloy consisting of 60% Ni snd 40% state. tb) Solid fe (23. When the phase diagram fora substance hes 3 sol ‘has a negative slope (leans to the lef) the substance fof can vo irom solid to liquid, within smalt ofpressure (b) sublimes rather than melts under ordinary coricivr {e) cannot go trom solid to liquid by application of pressure at any temperature 4) eacinat be liquefied above its tripte point 34 Liquid <-rgas phasis involved in the following: ne ic gs gpsora solution i ‘\aporizatien curve of Si(4) se mi sil ag bec er itaches © ond F je, adndna begs be Farm ald reaches. (@) h mase of Solid Lan} will wien and thet. ob Ure methe: ‘acases solid 8 Separcbed Eeledic atid wtrhve 6UPb Sn] As dened and ceded down, ure le eer ae rose | aie, Reser te ebony thos wad agent When ava se pois G (sas °C) . 4. Solid bison is hess dense shan liquid bisnth, How would this change the ep plain, ceof (b)Cateuate the dezeecs of freedom af each of the following wsfems: answer only? 2-142.F An aqueous solution of NaNOs tnd KCLENaw3 « KCI HO Sy Kwey Heel PHO <4 ¢.2, Mixture of Cl, Onand He gasess3 C2 Sen | G28 Hel v2 eX? Piienol and water C-2 Pa Pat Sete FocPae Xue | 1hO W225 HMO, $9 Ong) rage W MPO3+ 11:9 7 Bry dissolved in CCh 4. Fe(S) + Hyg) «FeO (S) + Hg) 9, etlylolcohwl #HO teeuo dn uonr2e0s sajquua vy puns" ees ee seg aa pute" secptny 4 BAH 1 sere Tpagits 2oet suioysds ap ain> aTKHS >‘werst0D Poy 10 payeA dq Z0UH19 wo adn DOUASQNS atp JO soee Cee {agai ere ooueisqns oip awasaad 9 aouersns ahese OF Le is never in equines oven a 2 xery few semi, (1X) Decmie. macade of Ge SCAN” any Mae Se ge ANETS Tam Change inle Soll 35 very. Wwpestelh, even ervey oo a eine + Aluminium & Capper have face cantercd cubie structure yet NTS soluble in rer ere A Fass ag oy tap nh SS Mee BLAS, alferenE atomic. weight serene yaad kaw. Fok ‘Solid ana was (b) Complete the fattowing: 3 1 swer 10 only Witer his one of its Hite points ot .2,00....°Cand 2.096. sim, besides this one, water has at least 8. move gle poi : 2 tern means the sypiem.anakas Idegiee af Freedom only Tax P 3. Types solid salutinns are. Substbabtonad, , anterskiat 44, Please diagram engbles wsto wodie.t90. aB-pnese, phases presenk, amount of Hans Saget gral preter : », hast ag Sermons on syle ets sie om st em SN 6 Romber of components inthe phase ply is detiged 3 ma, AS ‘specs Haak ste soma adic seals is desl mesg Jolt tem (Use egininyym nach fnkersive. yaxibies Yak conf Chala Rae We ER gakeF oe gee we 4 & SOs used int any. eeceria ond Pool a dry clening ond defntgy 9, Solids curve isthe cyrve which .oeloun ik. a8 Sad, tolaion Voie Sofie 2. Univacieny BP Sil pine oats tv sd pane Eins ren teaetion up on celine i [c) ln the apposite plvase diagram | iy What isthe phase assembly oe Aaqaid & sot ine a compition of Givtatouloe the selnive am sats ot phases that east ailibeiv®) fea coanpesition a 35% Bot Temporatire aC TE? Where Mae 38508, C7 WY Q casts Liquid Phase amount = fake = M235 y 190 ba” So aNs = Sulid ghase omountamps piste sopuns © Reowpbou apaya soars © Rawdon soars @ per Wwr9q doViug su rgypuoa Curmoyoy yaou aeyy, oye puryysans py uuoy Bay 9 FPS Pinks pue PUPS OY B]AVSIA BO WA pus FO LORS pes IN py npaie amoung pha parton Son be steed ws MGyPhase rule pf beset vibe Ties cauilioiuin berwean te FSS ee Hhageam 13.0 the phase diagram shown above, segment psa te conditions of iniperaite an pressive under shite soll nd the was oF the GAB (av (acd MA. On the phase diagram s ove, the covrdin: toe emticaltempergore and pres : wr wo wre wp 35. the eral temperature ad pressure of C3. ar2 279 Cand 8 ates, tape. \emperatures above 279 °C and oes ove 78 aim, CS, cin only 9s (a) solid fb) liguid 16,0n a phase diagram, the critical pressure is _ (ohthe pressure requircd to melt a solid the pressure above which a substance is u liquid at all temperatures (@) the pressure at which a liquid changes to 2 gas 2 pressure required to liquefy a gas at its critical temperature Vi80r all. one-component phase diagrams, choose the correct statement from the 7 following Hist. (0) The line separating the ges from the liquid phase may have a positive ota ihe ine Separating the solid from the oF negative liquid phase may have a positive or negative! e engi is ne same OW the Feezing point @ the vapor-] pressure eSy. the figure provided is a phase i fer foie. (1) lndieme resent in the portions af the diag on ants. (2) U Tue eaters t9 ent dhe tske point (A), the ne Inciting point «B). the nosnal boiling p (Cand the eritical point «BS. ciively (Design the phase diagrams for three compensa ston Question (8) {) The fetowing isa sin composition and temperature and lead, iied phase diagray you that 8 pFOSUITEN Hy HIN tb ark ‘ ms {OSA ater Tard at 4.) Gelid Po 4 molten, dm) Selidon ¢ melien &<) Solid Pl 4 Selid Sms molten ZW hat woul be pre 2. Ifyou coo 300°C to at points 2, bande? suuce of tin and lead containing 62% Sa ard 3 0°C, sketch the cooling curve which sou would expect to go Z. What name is given to the mixture of 62% Sr and 38% Pb? Bulecke mixture “4. Explain what is happening at each siagé of your ewaling curve in (ls od a molte Ph fiom by figure int. Suppose you cooled a crucible containing a mixture of tin and tead with composition What would there bg in the crucible al each of the points froma € t0 h? ak day fine cyptds of Phand Sa ke» G3 4 4 4 af ge, rg cgshs br Sn) rimaty cryshesoFntvarlbles — OAfadcpendent variates ons 21 and 22 (©)eonsiants eter wo the following dingranis” 2A. ALLO atmoxphere of peessure and 130 we 20 What phases of water an: presont sta temporature of .01°C and 0.006 a of pressure? des fal {@) solid and Figad (by solid 2H The boundary Fine borvean (liquid ant (liquid soi) regions must be part of C. shat is ke phase of water? bY Figuig (6) solid (anoles )Sotidus (Sinuies wre 1fPick the odd one in the fon — {ay tsemomntious alloy 1 Femina soi station {Ghistemediae sola station Corned 2G.Liquid c>gas phase is involved in the following (a) Eutectic (b) Solid solution (c) Sublimation curve of HO ‘aporization curve of Sulphur 24Not a solid solution conditions : (a) Crystal structure of each element of solid solution must be the same (b) Size of atoms of each two elements mustnot differ by more than lements should form compounds with each other (d) Elements should have the same valence .“Faculty of Seienee ‘Cheanistry Depaatment evel second “The ueson paper esits OF 6 PAB tremistry students Question (6) Choase the correct swener: answer only 20 UF Condansation aceurs by Release ofcuesey (bo) Absorption afencrey (€)! 2. Gibbs phase re fi reece © (Gy Pr (a) PHECl : 3. Ina two-component condensed system, if degree! fieedam is zero, maximuen | 3 number of phases that eat co-cNist TOs (ao (o) 2 4. The degree of treecom ai triple point in a phase diagram for sulphur . ho, wt 13 “Above the following Tins liquid p () Solus conditions {Ib indicates the temperature at which different phases star to melt : (d) Solid solubility limits are depicted by it 7. Asan example, consider the sysiem of tivo completely miscible liquids seh ‘as toluene and . in equilibrium with their vapors. bbenzene (a) ethylene br of degre ‘of intensive properties suct int ah ciablesoanyxyu Buyzoasd so anno JopOU-gl -f Tra ‘ afar ‘Susy Ur S139 sypods sop snde Jo propo ¢ aonpoud or pasn 9q ue9 “9.9 pyjos Sy two wows (A “Zo. 20 wacaeip ase ai AS) “pos Bor pundy E wwH} Dy 1 anja uy sioenoa 6O.) s9Te98 NY] WE GTN POL WSL WOM Jea4AD aeH UE UNE Ys “LIZ TESORO. soy aud ajdian uy, (9) vn en apm toss o wessep aseq mp yaIaAS. 2 © ofits poate > (yay (oat Os (SPA riyguepasqossin “8 yO spud 7% peu? puns eye ps 6 pas anes els sunsiu 2 pue (OS “OS “OSUL (WUE'SUZ ss0de aus AUER MIS OI cee SMUT SSIN, PSION BS ze (OK 7 pe oi ges ONL FHS e2 JO smuodieoy coe “apenvip oe “anus “awe. * WENCH SUEY NUE NOTT ( 9) Sea HATHOT ry TAD cng go 290 sayeglisnid EGY pos Jo Wade SAne|aL ay aIE|AITELT swoge 18 woHnins a0 snag ¢ p36 5 Fo oid am was “SEU VIX PllE Y OTE I suNaDO gHADINE HN 15 paw 9 BE sue AL PHE Y SpHOS and a4 Jo stutod Funist AHL pu ssjanygodsal 0 neu supa Tu woo} 9 ANH UNE ep’ asuyd py«amount af ras eer 4 feere ol parts of sy Pca ve amounts 0) Fohases tha eget MpOStion ot Petature op yy“ype syuyo pus RayrypoReu creer’ Ruan Warp soy wy su-8 qstodusy, aomgotuny 01 fash gp uana aspstedees St pues oaut Bum wou Bunrow saprandwe YBa Reo Spm sayoiagyn soB ayy saDa~H BMH BTMIAG, my AD go rye Bagi aus ayy. oye sn st oe 2 C18 fod Sagres nas ot aol oR ‘UY spay FeO ampXus Jyama UE uuos Rouy asimraq, -9 -ayeys: pad pur PUPS Ut aq DSuN ake spyos omy 344 29n2039,"S vamssand Ry pajpagge you ate PEP _PUPS PA’ uMqymbe sy “iysye BEE OU Slay, sIIMDAG -—h pio Burgaw pensBusy © spaas puo quouenus s} voupoay Me aime,“ vaysissodwy, Sy StL + PY AMIDA Can) aq yen CY WPT YP aalep ayy ao 4. asm7ag-z aug’ aU sauorad anim Ruyoog ayy 08 PRM BE P aPURSS “su suo samppied wag, SUL amgxyu Buy gp Beakypers POMP asmmag - 7 =«) Ch) yes V's FF: C-P42 c rnin Fax eT a a 113 3 14 ZA K possible if the compesdion of She alley to the euhche Campesitien binary pure metal / Eutectic mitlure composition cooling Curve. RW)you st up tn De OY|. NaNog +Kel + Rad <= rach + kNog +420 Ce gene 3-1-4 Pel Fe C-P42 Zul422 5 a. C23, Pal —e Fe t# 3_Phend + waker 5 at criticad bemnperabure “-P=1 c-2 Pl Fe c-P42- 2-142 =3 Ye Ether 4120 C22 Par FoC-Pi2- 2242-22 BMG Orgh Magy C28 P22 Fe B-242=3 6- HyPOy 4 20 Car Pal Fa C-P42= 214253 F- Pa\ C22 Fe agen 8 Se4, P23 CeoSmi4l-3 F-C-P 42 =3-34222 Vicor, Vel Fe C-Pyo 2 a-l4223ays yd sion nnetay anh aqgegyy | eideador chiro ew a) quioposty yo aanGap Jo s7qure sayy ante pas ind ea ters ft 207 Koge Jap cle 7, pede parquuns mbt (ng J ump fo si Tee toa og 3 me SN SMU RE ua yeh Pearse amps poe” pee2nge m y:F 7 waregaebo w satay a PaypoadseD au YE aque aut shoo ilo slpsurtal4. The triple pointin a one component phase: idgiam has Unee degrees of freedom. + (YX) ~ Thetemstriple pointis Used only for pure substances. The system'at the, biple poink as, “no deguee of freedom. ~ cannatbe fuer or more phises ine rumiberef conponentst2 x ey vy < graph paper conesponds tea fixed ree “ , onesie rns ounsterof phases (2 maximuen when he variance ig, A» “ equals tne density of solid and 9 i rina es wy) “ we ba egy x» 3. Ona ph: 4+ The lowest temper ‘System has Goqmplete solid sotuup Bu Buoys youn pee : NSU RUYE A “CU LUMI 50 Pou, pp st SO pauy PP ae ark uy ee P eopnasy Pp saaBaq -¢, ARquinn - 9uinuuxeu 9 pos set sou nnn wanes SmeNE tak ees vou (0) ARs 40 wordiosqy (4) ‘iano yo 090)J say go gue Guyiau yp omg Prpnsn ra APS PACS PHS uouMPS {mS 22, waamyaq _uanciq yin Wo sq pus ammyxius ayoyrs Uo sey Fase areneg, SO: APPS JO HMNUINE pm ats Spy sty ata ey daw QDS sw spyoe omy ayy 2ME2ID meter sel ye aon RMS MLE aunsaaid Ba, paq22yyo you aye, 4a> 9 ot Gata) BEM, aie pinky, pus preg gratameyets ager yao 98 ou sas See ALS") sans 128-84 PNY PURE pH|DS LHI pred Poyaws Fombas wv spasu pus quoMAUl Sh UDYDVOL Sy IW9MEIEq = saprstodus, $1 Sty Pe MPA Ih-_3q, yy LHOPINY fo cara oyk FAKE fE BHMEDAE aoe npn soe lig omy MN NPD UR SE ‘ums 34 stioong_ some Coyond ay, of aut nd Se ag en au fo CauRyepanes Gump asm qyeqeury sumusar smpisdulay my (eu see Cukpenes, Tanne, osmooq, ‘saan Sige sqpuomtEovktns 3A 9S Peay A Ue YAN AME I |PO MES 99 | 18) Freres Totten uve grees Bewesed Tt TOT 104s} gin OMT SAE Egg ur pososip ag ST Ott rog FT s = “Oo az OL age“Answer the following questions: Question {1 5 aye c a 1. Me wile point ina one eomponenphese diagram has nee degrees of feed x) Jag system at the triple point hes “A sue tu oF enone phases in gquiibvivim, The Ms v wv 2, “The teem tripte point is used only’ For pure substance no degree of freedom, J. tn one-compirent spstem, there € maxima number of phases ~qoals the number of “em 44. Paso tee point is found in He- phase diawyam, Tnhase diagram drawn on atangle yroph 3 rained presse, snug Ish od to devgh 7. Vor given mamber of eoimpanent. mums zero $. Monodline sulphus will Raat on motien soll per cornesponds toa fixed (K) and solid phases. (x) ngsinnu when the variance is wv) wW J the caunpasiine af fiqu hisses is 9. Aka critical pow tive loneess ceimpersature © whic! sung tigaic to, Sid fen si 9 i Fo Phang A hranstion ASE Os iv v pevnazcruie lea quaitive ss of aregensr yen xlibourn, Ox yf the fae is bys 1- Ateniperst siglo phase ofa givea eanysiton im ghane eqeilibiuns i diet a ems ol pe Cmelking ‘Poink.....) cern chapernis seus el separating the bon, cps ad hero a es eB (Trensition curve» one at 1 Gna phase diugrar the inter cetion.of the solid gui ne ytseaus ines. THe pata cho lamest enapursaureat wbishany Thyosdaistses ovis: Eabeckie Teoperekure ho tue eompernents Hts iw the Ftd ab 8 (Prnorplrous. $yshem 5 we stom has amplete solid $0eM pole s 9p You we amssoid pene aan ; Wegner ee soa eae 19) Pom BUI oH S954 SOUS aU: © seaad ‘eam de0n (p) su0N (7) “yepnunsod peseioep (5 saaugo, 4929 HHS —saaseniene sienna9 dn wonseoa ‘Buunp sase\ ie pouyjap sy ayn asec sojqeuo yy pues -pisnézodiuay oy Soa @ 7 wo 24.01 poppe st es Jo Hee “suoysAe wonmy ogthe number af phase: on cequilibsiom, fo Sostare mininun and maximum ay r be umber of prases ag w - sv a POMEN en tines ete? Erin [Fes Fria] Prax | Pha Bip oe) 3 [Faery WTS ]e [ge frees 114 [eo] S [ewes © 4 2 3 4 aide (4) Coating ese oF binary alloy looks exoatly sina to hat oF pure met Js is possible” — ges, is “possible WF the Composition of the binary, allay io the eutiche composition [pat merc in \ eating care > Question answer only 20 1 Lor any system, why sninimum munnber of degrees of freedom? 2 las wo (out w 2 on be expresset te)P— CHEER bAfall ofthe 2, Mathematigally, the phase eel C12 ke works 3. ne psec was it dssevsie by (an Sormst wfGivos (e) Arehenivs (a) Le Cha 4p pve marti yases Op Naand COki8 vee MBEAN whone fine fo) twee yt suds vor aivures @ sustens havin the umber of pk $A mminnaite of your nmisetbie eeu 1) one Sow sa nee way zeeleat cy we e)2 wa 9. - oa cant he degree ov ligedom a1 triple-point ia a ay - ile pointing yhase ram fr sulphur im 2 8, Followi : ” {i yives information on transl hy Relative amount af diflirent phases con be found under given equilbriunn cov (c) It indicates the tegpperature at whieh eifferent phases stan to melt 1a) Solid solubility thts ane depicted by it sysicm of ase eom squitibriven sith their vapors, feYbeavene ie leduced using letely imimseitle fiquids suely Se, vamsicter th tsar ex (a) ethylene tavalkane 1W.Relative amounts oF pases inp (4) Phase rile WM escrrute fe) Kiuher Te cquillvium betwoen ts 6 phases oth substanes is represented by (A) Nos a phase iayvar fe) atea tine called om left sie ofan invariant reaction Fi Aityro concetic Faby Hs pememtects (6) None YA (an (wien Bo 1 wn ahve __correepond tothe eical tempest and reser, we ou vnuoi{icoduson Ups + Pas 3 ui uy, aswaizap ee satdde y pics 9 p97 04 garys oqo ~~gga me god 2 30 puconygortuun qu: peay pure wp je 21s yquao ag 32 40 jyuytan 244004 199 nk 350 (a) sep wy aaans Buyo9 os yo bos yous ea aa EY yes" Hie yews Ey, minis woyseaeey apes of 28 | nays 2.051 8130 to o1 roads ypioss mod yore: 23189 r Casa # pajowa HOS ALT ony gd 48 HE US 50 SEAUON Poo} PAE AIO uoyous Suspes Hig PIS ened ie sep ajo + oe SS PAS | pens poy nls my saponin : os ord f ‘xiuiad fq parweseidas eamvereds Hass iva fg pani, amuse von sensed sj wigbaip ont payee Bory ou (6) ipo aimpou vous © se water on ee avr € PEG ADK H PEE PUL2g) Fares Sin pitows ayy uneIG pony fo ofeyy cap 2 ome posta ap SE USI 2940 1 jps) oy ed on of tited eng, sje Rade fh USNTE| “WHE | PRE 2c) APE Weta SIMS eB oa soe sopun % dejoo sn 9 Pinos 1eap SB pues wots 2Puvys pur uerqounene 1 weitios i paseasouys sumercis: yp aged ie 950 qua! onsale sg *T Md ayo ata elena, I iy Proge EL 1 . sso) samt Te woe 28 1290 Sti ose) tuoneés iauoduuoa-cue e jay wuedoip aveagl jeD0 141 NOS 3 prides prs qd beeen iis syapareiiop po uray ig go mous (9 | @ enpoot qr yyun avadd 69 suGaq Cus pars ga? Afa sayooe 48 [0 19 ay pes aire m8 i aye ope, “YE Count usted inst ~ ep « wera phe mt