Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Sr.Super60_Elite, Target & LIIT-BTs Paper -2(Adv-2022-P2-Model) Date: 17-04-2024
Time: 02.30Pm to 05.30Pm GTA-25 Max. Marks: 180
17-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P2)_GTA-25_Syllabus

MATHEMATICS : TOTAL SYLLABUS

PHYSICS : TOTAL SYLLABUS

CHEMISTRY : TOTAL SYLLABUS

Name of the Student: ___________________ H.T. NO:

 Sri Chaitanya IIT Academy 17-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P-2)_GTA-25_Q.P

JEE-ADVANCE-2022-P2-Model
Time: 3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 8) Questions with Integer Answer Type +3 -1 8 24
Questions with Multiple Correct
Sec – II(Q.N : 9 – 14) +4 -2 6 24
Choice with partial mark
Sec – III(Q.N : 15 – 18) Questions with Single Correct Choice +3 -1 4 12
Total 18 60

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 19 – 26) Questions with Integer Answer Type +3 -1 8 24
Questions with Multiple Correct
Sec – II(Q.N : 27 – 32) +4 -2 6 24
Choice with partial mark
Sec – III(Q.N : 33 – 36) Questions with Single Correct Choice +3 -1 4 12
Total 18 60

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 37 – 44 Questions with Integer Answer Type +3 -1 8 24
Questions with Multiple Correct
Sec – II(Q.N : 45 – 50) +4 -2 6 24
Choice with partial mark
Sec – III(Q.N : 51 – 54) Questions with Single Correct Choice +3 -1 4 12
Total 18 60

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 2
 Sri Chaitanya IIT Academy 17-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P-2)_GTA-25_Q.P
MATHEMATICS Max Marks: 60
SECTION-I
(INTEGER ANSWER TYPE)
• This section contains EIGHT (08) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual Numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct integer is entered;
Zero Marks: 0 If the question is unanswered;
Negative Marks: -1 In all other cases
x  2 2 y  3 3z  4
1. The distance of the point P  2,3, 4  from the line   measured parallel
3 4 5

to the plane 4 x  12 y  3z  1  0 is d , then the value of  2d  8  .

    
2. Let u , v and w be vectors in three-dimensional space, where u and v are unit vectors
     
which are not perpendicular to each other and u.w  1, v.w  1, w.w  4
If the volume of the parallelepiped, whose adjacent sides are represented by the vectors
    
u, v and w is 2, then the value of 3u  5v is __________.

2 sin 2 sin 
3. Given that f  n   and f    f  2   f  3   ...  f  n   then
cos 2  cos 4 n sin  sin 
the value of    , is ____________.
1 x5
The number of values of x satisfying the equation 1  log9  x  1  log 3   2
4.  is equal to
2  x3
5. Consider the region S of complex numbers a such that z 2  az  1  1, where z  1. Then
area of S in the Argand plane is   k then k  ___________.
6. Let f :  0, 4    0,   be defined by f  x   cos 1  cos x  . The number of points
10  x
x   0, 4  satisfying the equation f  x   is __________
10
7. Let y  f  x  be drawn with f  0   2 and for each real number, the tangent to y  f  x  at
k
 a, f  a  
has x  intercept  a  2  . If f  x  is of the form of ke px , then   has the value
 p
equal to _______.
8. Area bounded by the relation  2 x    y   5, x, y  0 is (Where [.] represents greatest integer

function).

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 3
 Sri Chaitanya IIT Academy 17-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P-2)_GTA-25_Q.P
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
•This section contains SIX (06) questions.
•Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
•For each question, choose the option(s) corresponding to (all) the correct answer(s).
•Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If only (all) the correct option(s) is(are) chosen; Partial Marks +3 If all the four options are correct but ONLY three options are
chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: -2 In all other cases.
9. Which of the following statement is/are correct?
A) Three coins are tossed once. At least two of them must land the same way. No
matter whether they land heads or tails, the third coin is equally likely to land either the
1
same way or oppositely. So, the chance that all the three coins land the same way is .
2

B) Let 0  P  B   1 and P  A / B   P  A / B C  . Then A and B are independent.

C) Suppose an urn contains " w " white and " b " black balls and a ball is drawn from it
and is replaced along with " d " additional balls of the same color. Now a second ball is
drawn from it. The probability that the second drawn ball is white is independent of the
value of " d ".
D) A man alternately tosses a coin and throws a die beginning with the coin. The
3
probability that he gets a head in the coin before he gets a 5 or 6 in the die is .
4

a x e x log e a x2
10. If g  x   a 3 x e3x log a x 4 , then
e

a 5 x e5 x loge a 1

A) graphs of g  x  is symmetrical about the origin

B) graphs of g  x  is symmetrical about the y-axis

d 4g  x
C) 0
dx 4 x  0

ax
D) f  x   g  x  log   is an odd function
ax

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 4
 Sri Chaitanya IIT Academy 17-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P-2)_GTA-25_Q.P
11. If ( a ,0) a is a point on a diameter of the circle x 2  y 2  4, then x 2  4 x  a 2  0 must have
9 1 49
A) Exactly one real root in  ,  B) exactly one real root in 4, 
 10 10   10 

C) Exactly one real root in [0, 2] D) Two distinct real roots in [ -1,5]
C12 C2 C2 C2
12. Consider the expression S  C02   2. 2  3. 3  ...  n. n where Cr  n Cr and n  N . Then
C0 C1 C2 Cn 1

A)  n  2  divides S  n for all n B) 2 n1 divides S  n for all n

C) S is even if n is even D) S is even for all n

13. A rod of length 2 units whose one end is (1, 0, -1) and other end touches the plane
x  2 y  2 z  4  0. then

A) the rod sweeps the figure whose volume is  cubic units.

B) the area of the region which the rod traces on the plane is 2 .
C) the length of projection of the rod on the plane is 3 units.
2 2 5
D) the centre of the region which the rod traces on the plane is  , ,  .
3 3 3 

cos  2 x  cos  2 x  sin  2 x 

14. If f  x    cos x cos x  sin x , then
sin x sin x cos x

A) f '  x   0 at exactly three points in   ,  

B) f '  x   0 at more than three points in   ,  

C) f  x  attains its maximum at x = 0

D) f  x  attains its minimum at x = 0

SECTION – III
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 5
 Sri Chaitanya IIT Academy 17-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P-2)_GTA-25_Q.P
n
 x  cot x
15. Let f  x   nLt  3n 1 sin 3  n  and g  x   x  4 f  x  , then xLt 1  g  x   is equal to

n 1 3  0

A) e B) e2 C) 1 D) 2
16. Consider 4 boxes, where each box contains 3 red balls and 2 blue balls. Assume that all
20 balls are distinct, in how many different ways can 10 balls be chosen from these 4
boxes so that from each box at least one red ball and one blue ball are chosen
A) 21816 B) 85536 C) 12096 D) 156816
20142014 20152015 20162016
17. The remainder when 20172017 20182018 20192019 is divided by 5 is equal to
20202020 20212021 20222022

A) 3 B) 4 C) 9 D) 2
18. A fair coin is tossed repeatedly until two consecutive heads is obtained. If the probability
that two
a
consecutive heads occur on the seventh and eight flips is equal to (where a, b are co
b

b 
primes and a,b  N) then    ________ (where [.] is denoted by greatest integer
 2a 

function)
A) 9 B) 3 C)1 D) 4

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 6
 Sri Chaitanya IIT Academy 17-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P-2)_GTA-25_Q.P
PHYSICS Max Marks: 60
SECTION-I
(INTEGER ANSWER TYPE)
• This section contains EIGHT (08) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual Numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct integer is entered;
Zero Marks: 0 If the question is unanswered;
Negative Marks: -1 In all other cases


19. The period of oscillation of a simple pendulum is T  2 . Measured value of L is 20.0
g

cm known to 1 mm accuracy and time for 100 oscillations of the pendulum is found to be
90 s using a wrist watch of 1 s resolution. The accuracy in the determination of g is
equal to _______% (Round off to nearest integer).
20. Figure shows a ball of mass m connected with two ideal springs of force constant K, kept
in equilibrium on a smooth incline, suddenly right spring is cut. What is the magnitude of
instantaneous acceleration in m  s2  of ball ? (Take g =10 ms -2
)

21. A uniform cylindrical body of radius r has a conical nose. The length of the cylindrical
and conical parts are 4r and 3r respectively. Mass of the conical part is M. The body rests
r
on a horizontal surface as shown A ring of radius is to be tightly fitted on the nose of
2

the body the maximum permissible mass of the ring so that the body does not topple is
 29 
M    m. Find k
 k 

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 7
 Sri Chaitanya IIT Academy 17-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P-2)_GTA-25_Q.P

6
22. Gravitational acceleration on the surface of a planet is g , where g is the gravitational
11
acceleration on the surface of the earth. The average mass density of the planet is 2/3
times that of the earth. If the escape speed on the surface of the earth is taken to be 11
km/s, the escape velocity on the surface of the planet (in km/s) will be …….
23. Two tuning forks produce 4 beats per second when they are sounded together. Now both
the forks are moved towards the observer at same speed  u  . The beat frequency now

becomes 5 Hz. If the observer also begins to run with speed u towards both the forks,
what beat frequency will he hear now ?
24. A uniformly charged hemisphere of radius b and charge density  has a hemispherical
b
cavity of radius a  a   cut from its centre. If the potential at the centre of the cavity is
 2
n b2
, then n= ?
16 0

25. In the circuit shown in the figure, the power dissipated in the circuit is P0 if an ideal cell
is connected across A and B same power is dissipated in the circuit if the same cell is
connected across C and D . when the cell was connected across A and D or across B and
C, the power dissipated in the circuit is found to be 3P0 the power dissipated in the circuit

 15  6 x 
if the cell is connected across A and C is   p0 the value of x is
 16  6 x 

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 8
 Sri Chaitanya IIT Academy 17-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P-2)_GTA-25_Q.P
26. In a photoelectric experiment a metal plate of work function   2.0 eV is irradiated with
beam of monochromatic light. The photoelectric current (i) versus the applied potential
difference (V) graph is as shown in the figure It is known that the efficiency of
photoemission is 103%. Calculate the power of light incident on the metal plate (in
watt)

SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
•This section contains SIX (06) questions.
•Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
•For each question, choose the option(s) corresponding to (all) the correct answer(s).
•Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If only (all) the correct option(s) is(are) chosen; Partial Marks +3 If all the four options are correct but ONLY three options are
chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: -2 In all other cases.
27. The velocity v versus time t graph for the motion of a particle is shown in the figure.
Which of the following statement(s) is (are) correct [One or more option(s) correct]

A) avg  0.50m/s for 0s  t  3s B) avg  0.75m/s for 3s  t  5s

C) avg  0.60m/s for 0s  t  5s D) acceleration is minimum at t  4 s
28. Consider a thin square plate floating on a viscous liquid in large tank. The height h of the
liquid in the tank is much less than the width of the tank. The floating plate is pulled
horizontally with a constant velocity 0 . Which of the following statements is (are) true?
A) The resistive force of liquid on the plate is inversely proportional to h.
B) The resistive force of liquid on the plate is independent of the area of the plate.
C) The tangential (shear) stress on the floor of the tank increases with 0 .
D) The tangential (shear) stress on the plate varies linearly with the viscosity  of the
liquid.

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 9
 Sri Chaitanya IIT Academy 17-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P-2)_GTA-25_Q.P
29. Two bodies A and B have thermal emissivities of 0.01 and 0.81, respectively. The outer
surface area of the two bodies are the same. The two bodies emit total radiant power at
the same rate. The wavelength B corresponding to maximum spectral radiance in the
radiation from B is shifted from the wavelength corresponding to maximum spectral
radiance in the radiation from A by 1.00 µm. If the temperature of A is 5802 K,
A) the temperature of B is 1934 K. B) B  1.5µm.
C) the temperature of B is 11604 K. D) the temperature of B is 2901 K.
30. A plano-convex lens is made of material of refractive index n. When a small object is
placed 30 cm away in front of the curved surface of the lens, an image of double the size
of the object is produced. Due to reflection from the convex surface of the lens. Another
faint image is observed at a distance of 10 cm away from the lens. Which of the
following statement(s) is (are) true?
A) The refractive index of the lens is 2.5.
B) The radius of curvature of the convex surface is 45 cm.
C) The faint image is erect and real.
D) The focal length of the lens is 20 cm.
31. A light source, which emits two wavelengths 1  400 nm and 2  600 nm, is used in
Young’s double site experiment. If recorded fringe widths for 1 and 2 are 1 and  2 and
the number of fringes for them within a distance y on one side of the central maximum
are m1 and m2 , respectively, then
A)  2  1
B) m1  m2
C) From the central maximum, 3rd maximum of 2 overlaps with 5th minimum of 1
D) The angular separation of fringes of 1 is greater than 2
32. In the Bohr’s model of the hydrogen atom
A) the radius of the nth orbit is proportional to n 2 .
B) the total energy of the election in the nth orbit is inversely proportional to n
C) the angular momentum of the electron in an orbit is an integral multiple of h /  .
D) the magnitude of the potential energy of the electron in any orbit is greater than its
kinetic energy.
SECTION – III
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 10
 Sri Chaitanya IIT Academy 17-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P-2)_GTA-25_Q.P
33. A block of mass m is thrown with a velocity v0 towards a spring as shown in figure.
Initially, the block is at a distance L from the spring and the spring is in its natural length.
The coefficient of friction between the block and the ground is   ax , where a is a
constant and x is the distance travelled. Find value of v0 such that the maximum
compression in the spring is L.

1/2 1/2 1/2 1/2

 kL2   kL2   kL2   kL2 
A)   2aL2 g  B)   aL2 g  C)   4aL2 g  D)  2  aL2 g 
 m   m   m   m 
34. Two bodies M and N of equal masses are suspended from two separate massless springs
of spring constants k1 and k 2 respectively. If the two bodies oscillate vertically such that
their maximum velocities are equal, the ratio of the amplitude of vibration of M to that of
N is
A) k1 / k2 B) k2 / k1 C) k2 / k1 D) k1 / k2
35. A conducting square loop of side L and resistance R moves in its plane with a uniform
velocity  perpendicular to one of its sides. A magnetic induction B, constant in time and
space, pointing perpendicular to and into the plane of the loop exists everywhere. The
current induced in the loop is

A) BL / R clockwise B) BL / R anticlockwise

C) 2BL / R anticlockwise D) zero
36. The intensity of X-rays from a Coolidge tube is plotted against wavelength  as shown in
the figure. The minimum wavelength found is c and the wavelength of the K lines is 

k . As the accelerating voltage is increased,

A)  k  c  increases B)  k  c  decreases
C) k increases D) k decreases

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 11
 Sri Chaitanya IIT Academy 17-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P-2)_GTA-25_Q.P
CHEMISTRY Max Marks: 60
SECTION-I
(INTEGER ANSWER TYPE)
• This section contains EIGHT (08) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual Numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct integer is entered;
Zero Marks: 0 If the question is unanswered;
Negative Marks: -1 In all other cases
37. An excited He + ion emits two photons in succession, with wavelengths 108.5 nm and
30.4 nm in making a transition to ground state. The Quantum number n, corresponding to
1240
its initial excited state is_____.[Take E photon  ev ]
 (nm)
38. I .E.1 and I .E.2 of Mg are 178 and 348 kcal mol-1. The enthalpy required for the reaction in
x
kcal/mole Mg  g   Mg 2+  g  +2e- is x. What is value (Rounding to nearest integer
100
value):
39. In how many number of molecule/ions central atom is sp3 hybridized given
PCl3 , NCl3 , XeO3 , ClO3 , POCl3 ,
SF4 , PCl4 , XeO4 , PH 3 , NH 3
40. A saturated solution of a sparingly soluble salt MCl2 has a vapour pressure of 31.78 mm
of Hg at 300 C. While pure water exert a pressure of 31.82 mm of Hg at the same
temperature. Calculate the solubility product of the compound at this temp. is
approximately x×10-5mol3L-3 . Find the value of x.(Rounding to nearest integer value)
41. What are the number of total plane of symmetry in a cube?
42.

At what value of ' n ' the formation of six membered ring take place.
43. Examine the structural formulas of compounds given below and identify number of
compounds which show positive iodoform test.

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 12
 Sri Chaitanya IIT Academy 17-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P-2)_GTA-25_Q.P

44. For oxyacid HClOx , if x  y  z ( x y and z , are natural numbers), then calculate the value

of x  y  z . Where x Number of ‘O’ atoms.

y= Total number of lone pairs at central atom

z= Total number of piπ electrons in the oxyacid
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
•This section contains SIX (06) questions.
•Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
•For each question, choose the option(s) corresponding to (all) the correct answer(s).
•Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If only (all) the correct option(s) is(are) chosen; Partial Marks +3 If all the four options are correct but ONLY three options are
chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: -2 In all other cases.
45. Which of the following have transition metal?
A) Hemoglobin B) Vitamin B12 C) Cis – platin D) Chlorophyll
46. Which one of the following reactions is/are correct?
A) CH 3COOK  CF3COOH 
 CH 3COOH  CF3COOK

B)

C)
D) CH 3CH 2OH  NaHCO3 
 CH 3CH 2 ONa  H 2O  CO2 
Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 13
 Sri Chaitanya IIT Academy 17-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P-2)_GTA-25_Q.P
47. Which of the following carbanions is not resonance stabilized?

A) B) C) D)
48. Which of the following statements is/are correct?
A) The highest probability of finding an electron in 1 s orbital is exactly at the middle
between nucleus and circumference.
B) In the Lyman series as the energy liberated during transition increases then distance
between the spectral lines goes on decreasing.
C) The highest probability of finding an electron in 1s orbital is near the nucleus.
D) The shapes of four d-orbitals are similar to each other.
49. Which of the following statements is / are correct?
A) When lead nitrate is heated to at 400o C only brown gas is released.
B) Complete Hydrolysis of PCl5 gives H3 PO 4 and HCl
C) N 2 O 5  g  +2NaOH  aq.  2NaNO 3 +H 2O

D) CCl 4 can not be hydrolysed but hydrolysis of SiCl 4 can form H4SiO4 +HCl
50. Which of the following statements is (are) correct?
A) Antimony on reaction with conc. HNO3 gives antimonic acid.
B) Manganese on reaction with cold and dilute HNO3 gives NO2 gas.
C) HNO2 disproportionate to give HNO3 and NO
D) HNO3 on reaction with P4 O10 gives N 2O5
SECTION – III
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
51. The necessary condition for a compound to be optically active is:

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 14
 Sri Chaitanya IIT Academy 17-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P-2)_GTA-25_Q.P
A) Presence of chiral carbon atom
B) Presence of atleast one asymmetric atom
C) Non-superimposable mirror image.
D) Absence of plane of symmetry.

52. The H f for CO2 ( g ) and H 2O ( g ) are 395.5 , 110.5 and  241.8 KJ . mole1
respectively. The standard enthalpy change in kJ for the reaction.
CO2 ( g )  H 2 ( g )  CO ( g )  H 2O ( g ) is
A) +524.1 B) +41.2 C) -262.5 D) -41.2
53. Which of the following is weaker base?
A) N  SiH 3 3 B) N  CH3 3 C) NH  CH 3 3 D) All are equally basic

54. Consider the reaction

The rate constant for two parallel reactions were found to be 102 dm3 mol 1 s 1 and
4 10 2 dm3 mol 1s 1. If the corresponding energies of activation of the parallel reaction are

100 and 120 kJ/mol respectively, what is the net energy of activation  Ea  of A?
A) 100 / kJ mol B) 120 / kJ mol C) 116 / kJ mol D) 220 / kJ mol

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 15
 Sri Chaitanya IIT Academy 17-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P-2)_GTA-25_Q.P

Sec: Sr.Super60_Elite, Target & LIIT-BTs Space for rough work Page 16