SAFETY DATA SHEET

1. Identification
Product name Hydrex 7514
Supplier Veolia Water Solutions & Technologies (SEA) Pte Ltd
Address No. 5 Loyang Way 1
Singapore 508706
Contact Person Hydrex Product Manager
Telephone + 65 6546 1110
Fax + 65 6546 2553
e-mail [email protected]
Global Emergency Contact +1-760-476-3960 (Code: 333239)
Recommended use and Limitations on use
Recommended use Biocide

2. Hazards identification
GHS classification
Physical hazards Not classified.
Health hazards Acute toxicity, oral Category 3
Acute toxicity, dermal Category 3
Acute toxicity, inhalation Category 3
Skin corrosion/irritation Category 1
Serious eye damage/eye irritation Category 1
Sensitization, respiratory Category 1
Sensitization, skin Category 1
Germ cell mutagenicity Category 2
Specific target organ toxicity, single exposure Category 3 narcotic effects
Specific target organ toxicity, single exposure Category 3 respiratory tract irritation
Specific target organ toxicity, single exposure Category 1 (Central Nervous System, Kidney,
Liver)
Specific target organ toxicity, repeated Category 1 (Kidney, Liver, nervous system,
exposure Respiratory system, trachea)
Environmental hazards Hazardous to the aquatic environment, acute Category 1
hazard
Hazardous to the aquatic environment, Category 1
long-term hazard
GHS label elements

Pictograms

Signal word Danger

Hazard statement Toxic if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage. May
cause an allergic skin reaction. Causes serious eye damage. Toxic if inhaled. May cause allergy or
asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause
drowsiness or dizziness. Suspected of causing genetic defects. Causes damage
to organs (Central Nervous System, Kidney, Liver). Causes damage to organs (Kidney, Liver,
nervous system, Respiratory system, trachea) through prolonged or repeated exposure. Very toxic
to aquatic life with long lasting effects.

Material name: Hydrex 7514 SDS

2976 Version #: 02 Revision date: 11-01-2014 Print date: 02-16-2012 1/6

Precautionary statement
Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Use only outdoors or in a well-ventilated area. Do not breathe mist or vapor. In
case of inadequate ventilation wear respiratory protection. Wear protective gloves/protective
clothing/eye protection/face protection. Do not eat, drink or smoke when using this product. Wash
thoroughly after handling. Wash thoroughly after handling. Contaminated work clothing should not
be allowed out of the workplace. Avoid release to the environment.
Response Collect spillage. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF
SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/take off
immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Immediately call a POISON CENTER or doctor/physician. Specific treatment is urgent (see on this
label). Wash contaminated clothing before reuse.
Storage Store locked up. Store in a well-ventilated place. Keep container tightly closed.
Disposal Dispose of contents/container to Dispose of contents/container in accordance with
local/regional/national/international regulations.

3. Composition/information on ingredients
Substance or mixture Mixture
Chemical property
Chemical name CAS Number Concentration (%)
Nitrogeneous Compound * T7803-57-8
rade Secret 40 - < 50

Glutaraldehyde 111-30-8 <5

40 - < 50Formulation
* Proprietary

4. First aid measures

Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or
artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance.
Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other
proper respiratory medical device. Call a physician or poison control center immediately.
Skin contact Take off immediately all contaminated clothing. Wash off with soap and plenty of water. Call a
physician or poison control center immediately. For minor skin contact, avoid spreading material on
unaffected skin.
Eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Call a physician or poison control center immediately.
Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not use
mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid
of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Most important Corrosive effects. Irritation of eyes. May cause allergic respiratory reaction. May cause allergic skin
symptoms/effects, acute and reaction.
delayed
Personal protection for Take off all contaminated clothing immediately. IF exposed or concerned: Get medical
first-aid responders advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take
precautions to protect themselves. Wash contaminated clothing before reuse.
Notes to physician In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation.
Symptoms may be delayed.

5. Fire-fighting measures
Extinguishing media Water spray. Water fog. Foam. Carbon dioxide (CO2). Alcohol resistant foam. Powder.
Extinguishing media to avoid Water. Do not use water jet as an extinguisher, as this will spread the fire.
Specific hazards during fire None.
fighting
Special fire fighting None.
procedures
Protection of fire-fighters Water runoff can cause environmental damage.

Material name: Hydrex 7514 SDS

2976 Version #: 02 Revision date: 11-01-2014 Print date: 02-16-2012 2/6

6. Accidental release measures
Personal precautions, Immediately evacuate personnel to safe areas. Local authorities should be advised if significant
protective equipment and spillages cannot be contained. Wear appropriate protective equipment and clothing during
emergency procedures clean-up. Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no
fire. Do not touch damaged containers or spilled material unless wearing appropriate protective
clothing. Ventilate closed spaces before entering them. Avoid inhalation of vapors or mists.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water.
Spill cleanup methods Remove sources of ignition.

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth
and place into containers. Following product recovery, flush area with water. This material is
classified as a water pollutant under the Clean Water Act and should be prevented from
contaminating soil or from entering sewage and drainage systems which lead to waterways.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.

Never return spills in original containers for re-use. For waste disposal, see section 13 of the
MSDS.

7. Handling and storage

Handling
Precautions Obtain special instructions before use. Do not taste or swallow. In case of insufficient ventilation,
wear suitable respiratory equipment. When using, do not eat, drink or smoke. Wash hands
thoroughly after handling. Avoid release to the environment. Do not empty into drains.
Safe handling advice Do not handle until all safety precautions have been read and understood. Do not breathe mist or
vapor. Do not get this material in contact with skin. Do not get this material in contact with eyes.
Avoid prolonged exposure. Do not get this material on clothing.
Storage
Suitable storage Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep out of the
conditions reach of children.
Incompatible materials Strong oxidizing agents. Amines. Acids.
Safe packaging materials Keep in original container.

8. Exposure controls/personal protection

Control parameters/Occupational exposure limits
Singapore
Components Type Value
Glutaraldehyde (111-30-8) STEL 0.2 ppm
0.82 mg/m3

0.13 mg/m3
Established company exposure guidelines
ACGIH
Components Type Value
Glutaraldehyde (111-30-8) Ceiling 0.05 ppm

Biological limiit values

Singapore
Components Type Value
Glutaraldehyde (111-30-8) STEL 0.2 ppm
0.82 mg/m3

0.13 mg/m3
Appropriate engineering control measures
Personal protective equipment
Respiratory protection Wear positive pressure self-contained breathing apparatus (SCBA).

Material name: Hydrex 7514 SDS

2976 Version #: 02 Revision date: 11-01-2014 Print date: 02-16-2012 3/6

 Skin protection Wear appropriate chemical resistant clothing. It may provide little or no thermal protection.
Eye/face protection Wear eye/face protection.
Thermal hazards Not available.
Hygiene measures When using, do not eat, drink or smoke. Do not get in eyes. Do not get this material in contact
with skin. Do not get this material on clothing. Wash hands before breaks and immediately after
handling the product. Contaminated work clothing should not be allowed out of the workplace.
Handle in accordance with good industrial hygiene and safety practice.

9. Physical and chemical properties

Appearance
Physical state Liquid.
Form Liquid
Color Light yellow to Yellow.
pH 11.9 - 12.9
Melting point/freezing point 30.2 °F (-1 °C)
Boiling point, initial boiling 225 °F (107 °C)
point, and boiling range
Flash point 426.2 °F (219.404456 °C)
Vapor pressure 13.168 hPa estimated
Density 1.03 - 1.07 g/cm3
Other data
Specific gravity 1.03 - 1.07

10. Stability and reactivity

Reactivity None known.
Stability Material is stable under normal conditions.
Conditions to avoid Avoid temperatures exceeding the flash point. Reacts violently with strong acids. This product may
react with oxidizing agents. Do not mix with other chemicals.
Incompatible materials Strong oxidizing agents. Oxidizing agents. Amines. Acids.
Hazardous decomposition Irritants. Nitrogen oxides (NOx).
products
Possibility of hazardous Not available.
reactions

11. Toxicological information

Acute toxicity Causes severe eye burns. Causes severe skin burns and eye damage. Toxic by inhalation. Toxic if
swallowed. Toxic in contact with skin.
Routes of exposure Inhalation. Ingestion. Skin contact. Eye contact.
Symptoms Not available.
Skin corrosion/irritation Causes severe skin burns and eye damage.
Serious eye damage/eye Causes severe eye burns. Causes serious eye damage.
irritation
Respiratory sensitizer May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Skin sensitizer May cause an allergic skin reaction.
Germ cell mutagenicity Suspected of causing genetic defects.
Carcinogenicity Not applicable
Specific target organ Causes damage to organs. Central Nervous System, Kidney, Liver. Respiratory tract irritation.
toxicity - single exposure Narcotic effects.
Specific target organ Kidney, Liver, nervous system, Respiratory system, trachea.
toxicity - repeated
exposure
Chronic effects Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.
Relevant negative data Not available.

Material name: Hydrex 7514 SDS

2976 Version #: 02 Revision date: 11-01-2014 Print date: 02-16-2012 4/6

12. Ecological information
Ecotoxicological data
Product Test Results
Hydrex 7514 (Mixture) EC50 Daphnia: 0.28 mg/l 48.00 hours estimated
Components Test Results
Glutaraldehyde (111-30-8) EC50 Green algae (Selenastrum capricornutum): 1.32 mg/l
72.00 hr
LC50 Daphnia: 0.35 mg/l 48.00 hr
LC50 Fathead minnow (Pimephales promelas): 5.4 mg/l 96.00
hr

* Estimates for product may be based on additional component data not shown.
Ecotoxicity Very toxic to aquatic life with long lasting effects.
Persistence and No data is available on the degradability of this product.
degradability
Bioaccumulation Not available.
Mobility Not available.
Other hazardous effects Not available.

13. Disposal considerations

Disposal Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this
methods/information material to drain into sewers/water supplies. Dispose of contents/container in accordance with
local/regional/national/international regulations.
Special precautions Not available

14. Transport information

ADR
UN number UN1760
Proper shipping name CORROSIVE LIQUID,
TOXIC, N.O.S.
Hazard class 8
Subsidiary hazard class 6.1(PGI, II)
Packing group III
Labels required 8
+6.1
Special transport Not available.
precautions and
conditions
IATA
UN number UN1760
Proper shipping name Corrosive liquid, toxic, n.o.s.
Hazard class 8
Subsidiary hazard class 6.1(PGIII)
Packing group III
Special transport Not available.
precautions and
conditions
IMDG
UN number UN1760
Proper shipping name CORROSIVE LIQUID, TOXIC, N.O.S.
Hazard class 8
Subsidiary hazard class 6.1(PGIII)
Packing group III
EmS No. F-A, S-B
Special transport Not available.
precautions and
conditions

Material name: Hydrex 7514 SDS

2976 Version #: 02 Revision date: 11-01-2014 Print date: 02-16-2012 5/6

 ADR IATA IMDG
SEA (Annex II of MARPOL None.
73/78 and the IBC Code)

15. Regulatory information

Applicable regulations None.
Environmental Protection and Management (Hazardous Substances) Regulations
Not applicable
Environmental Public Health Act
Not applicable
Montreal Protocol
Not applicable.
Rotterdam Convention
Not applicable.
Stockholm Convention
Not applicable.

16. Other information

References Not available.
Issued by
Hydrex Global Platform - Veolia Water Solutions & Technologies
Prepared by
Hydrex Global Platform Authoring Team
Disclaimer The information in the sheet was written based on the best knowledge and experience currently
available.
Issue date 02-16-2012
Revision date 11-01-2014
Key/legend Not applicable.

Material name: Hydrex 7514 SDS

2976 Version #: 02 Revision date: 11-01-2014 Print date: 02-16-2012 6/6