DSE CHEMISTRY

F.5 SUPER MOCK

50 NORMAL 60m

重點課題

§ 6. Microscopic World II II
§ 7. Redox Reactions
§ 8. Chemical Reactions & Energy
§ 9. Rate of Reaction

考生資料

你的表現

MCQ LQ

15 35 50

LV 5**: 45 LV 5*: 41 -44 LV 5: 36 40 LV 4: 31 35 LV 3 : <40

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Multiple Choice Questions
Choose the best answer for each question. Select your answer at the space provided below.

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1. Chlorine is bubbled into an aqueous solution X for some time. The colour of X gradually changes to brown. X could
be

(1) Calcium hydroxide solution

(2) Ammonium iodide solution
(3) Sodium sulphate solution

A. (1) only
B. (2) only
C. (1) and (3) only
D. (2) and (3) only

2. Which of the following statements concerning sulphur dioxide is INCORRECT?

A. It can be prepared by heating copper turnings with concentrated sulphuric acid

B. It can turn limewater milky
C. It can be absorbed by sodium hydroxide solution
D. It can reduce potassium iodide solution

3. Which of the following would occur when copper(II) sulphate solution is electrolyzed using carbon electrodes?

(1) The cathode dissolves

(2) The pH of the solution decreases
(3) The concentration of copper(II) ions in the solution increases

A. (1) only
B. (2) only
C. (1) and (3) only
D. (2) and (3) only

4. In an acidic solution, zinc is oxidized to zinc ions. The net ionic equation for the reaction is given below.
Zn(s) + 2H! (aq) → Zn"! (aq) + H" (g)

In an experiment, 5.0 g of Zn(s) were added to 100 cm3 of 1.0 mol dm-3 HCl(aq). Which of the following changes to
the procedure would NOT affect the initial rate of the reaction?

A. Warming the acid before adding the zinc

B. Using zinc powder instead of zinc granules
C. Using 50 cm3 of 1.0 mol dm-3 HCl(aq)
D. Using 100 cm3 of 1.0 mol dm-3 H2SO4(aq)

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5. Consider the following reaction:
2MnO$ "$ ! "!
# (aq) + 5C" O# (aq) + 16H (aq) → 2Mn (aq) + 10CO" (g) + 8H" O(l)

Which of the following instruments can be used to monitor the progress of the reaction in an open system?

(1) Electronic balance

(2) Colourimeter
(3) pH meter

A. (1) and (2) only

B. (1) and (3) only
C. (2) and (3) only
D. (1), (2) and (3)

6. In an experiment, 12.5 cm3 of liquid hexene (C6H12) (density = 0.673 g cm-3) were treated with 2.70 dm3 of HBr(g),
measured at room temperature and pressure. What mass of C6H13Br would be produced in the reaction?
(Molar masses: C6H12 = 84.0 g mol-1, C6H13Br = 164.9 g mol-1; molar volume of gas at room temperature and pressure
= 24.0 dm3 mol-1)

A. 16.5 g
B. 18.6 g
C. 20.2 g
D. 22.7 g

7. The standard enthalpy changes of formation of carbon dioxide and of methanoic acid are −394 kJ mol-1 and −409
kJ mol-1 respectively. Calculate the enthalpy change for the reaction:
H" (g) + CO"(g) → HCOOH(l)

A. 803 kJ mol-1
B. 15 kJ mol-1
C. +803 kJ mol-1
D. + 15 kJ mol-1

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8. Consider the enthalpy changes of the following reactions:
N" (g) + 2O" (g) → 2NO" (g) Δ𝐻 = +68 kJ

N" (g) + 2O" (g) → N" O# (g) Δ𝐻 = +10 kJ

What is the enthalpy change of the following reaction?

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NO" (g) → N" O# (g)
2

A. + 58 kJ
B. + 29 kJ
C. 29 kJ
D. 58 kJ

9. Consider the following two compounds, X and Y.

Which of the following statements is INCORRECT?

A. X is more volatile than Y.

B. Both X and Y contain polar bond.
C. X has a higher boiling point than Y.
D. Both X and Y contains van der Waals force between their molecules.

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10. Which of the following species has/have a shape similar to that of an ammonia molecule?

(1) PCl%
(2) BH%
(3) SO%

A. (1) only
B. (2) only
C. (1) and (3) only
D. (2) and (3) only

11. In which of the following steps the sulphur is not undergoing any redox reaction?
&'() + &'() " &'() % &'() #
H" S A⎯⎯C S, A⎯⎯C SO" A⎯⎯C H" SO% A⎯⎯C H" SO#

A. Step 1
B. Step 2
C. Step 3
D. Step 4

12. Consider the following equation:

Zn(s) + pMnO2(s) + qNH4+(aq) → Zn2+(aq) + xMn2O3(s) + yNH3(g) + zH2O(l)

Which of the following combinations is correct?

x y z

A 1 2 1

B 1 3 2

C 2 3 2

D 2 2 3

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13. Results of some reactions of the metals Q, R, S and T are given below.

Metal Reaction in air Reaction with steam Reaction with dilute HCl

Q Burns to form an oxide Reacts to form hydrogen gas Hydrogen is given off

Reacts slowly to form an oxide on

R No reaction No reaction
surface

S No reaction No reaction No reaction

T Burns to form an oxide No reaction Hydrogen is given off

Which of the following chemical cells would produce the highest voltage?

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14. Consider the following chemical cell, the voltmeter gives a positive reading.

Which of the following statements are correct?

(1) The position of X in the electrochemical series is lower than that of Y

(2) Metal X is the anode.
(3) A current flow from Y to X in the external circuit

A. (1) and (2) only

B. (1) and (3) only
C. (2) and (3) only
D. (1), (2) and (3)

15. Consider the following electrolytic cells:

What would happen during electrolysis?

A. Sodium amalgam forms around A.

B. Chlorine forms around B.
C. Oxygen gas forms around C.
D. Hydrogen gas forms around D.

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Long Questions
1. Consider the following experimental set-up of a chemical cell.

When the circuit is closed, a current flow in the external circuit. After some time, silver deposits on carbon
electrode B.

(a) What is the direction of current flow in the external circuit? Explain your answer.

(2 marks)

(b) Suggest and explain what metal M might be.

(2 marks)

(c) Suggest an adjustment to the experimental set-up in order to generate higher voltage.

(1 mark)

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(d) After the circuit has been closed for some time, state any change in the following with the aid of ionic half-
equation.

(i) Colour of the solution around electrode A (with a few drops of universal indicator)

(ii) Mass of copper electrode

(4 marks)

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2. Two different impure samples of calcium carbonate (A and B), each weighing 12.5 g, were allowed to react with
excess dilute hydrochloric acid at room temperature. The following curve showed the loss in mass of the contents
of the reaction flask against time.

(a) Draw a labelled diagram to show how the above experiment can be conducted in the laboratory.

(3 marks)

(b) Consider the curve for sample A. Explain why the tangent to curve at X is steeper than that at Y.

(1 mark)

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(c) Consider the curve above. State TWO differences between samples A and B with explanations.

(4 marks)

(d) Calculate the percentage by mass of calcium carbonate in sample B.

(Relative atomic masses: C = 12.0, O = 16.0, Ca = 40.1)

(3 marks)

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3. A student used the set-up shown below to determine the enthalpy change of combustion of propan-1-ol.

Mass of water in beaker = 250.0 g

Mass of spirit lamp + propan-1-ol before combustion = 143.50 g

Mass of spirit lamp + propan-1-ol after combustion = 142.18 g

Water before heating = 25.0℃

Water after heating = 58.5℃

(a) Calculate the enthalpy change of combustion of propan-1-ol from the experimental results.

(Relative atomic masses: H = 1.0, C = 12.0, O = 16.0; specific heat capacity of water = 4.18 J g-1 K-1; you may
assume the container has negligible heat capacity.)

(3 marks)

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(b) Suggest a possible source of error other than heat loss.

(1 mark)

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4.

(a) Draw electron diagrams of ammonia and water molecules, showing the outermost shell electrons only.

(2 marks)

(b) Explain why the boiling point of water is higher than that of ammonia.

(2 marks)

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5. The relative oxidizing power of three chemical species is in the following order:

SO"$ $
# < Br" < MnO#

You are provided with the following substances and apparatus:

sodium bromide solution, aqueous bromine, acidifies potassium permanganate solution, sodium sulphite
solution and test tubes

Design an experiment to verify the order. You should state and explain the expected observations of the tests.

(7 marks)

End of the paper

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