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Aquaflow Nms-450 Drum 200l 000000000000432597 Dominican Republic (GHS) - English

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0% found this document useful (0 votes)
115 views13 pages

Aquaflow Nms-450 Drum 200l 000000000000432597 Dominican Republic (GHS) - English

Uploaded by

cristi
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 13

Page: 1

SAFETY DATA SHEET Revision Date: 01/11/2019


Print Date: 8/29/2023
SDS Number: R0703759
Aquaflow™ NMS-450 LIQUID SYNTHETIC Version: 1.1
RHEOLOGY MODIFIER
™ Trademark, Ashland or its subsidiaries, registered
in various countries
432597

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product identifier
Trade name : Aquaflow™ NMS-450
LIQUID SYNTHETIC RHEOLOGY MODIFIER
™ Trademark, Ashland or its subsidiaries, registered in
various countries

Relevant identified uses of the substance or mixture and uses advised against
Recommended use : Rheology modifier
in Paint

Details of the supplier of the safety data Emergency telephone number


sheet 1-606-329-5006 (international)
Ashland 1-800-ASHLAND (1-800-274-5263)
P.O. Box 2219
Columbus, OH 43216 Regulatory Information Number
United States of America (USA) 1-800-325-3751
+1-614-790-3333
Product Information
+1-614-790-3333
ASHLAND ARGENTINA S.R.L.
Paraguay 610 piso 8
1057 - Buenos Aires - Argentina
Tel.: + 54 11 4314-8971/3293/0659

[email protected]

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Short-term (acute) aquatic : Category 3
hazard

GHS label elements


Hazard pictograms : None

Signal word : None

Hazard statements : H402 Harmful to aquatic life.

Precautionary statements : Prevention:


P273 Avoid release to the environment.

1 / 13
Page: 2

SAFETY DATA SHEET Revision Date: 01/11/2019


Print Date: 8/29/2023
SDS Number: R0703759
Aquaflow™ NMS-450 LIQUID SYNTHETIC Version: 1.1
RHEOLOGY MODIFIER
™ Trademark, Ashland or its subsidiaries, registered
in various countries
432597

Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

Other hazards which do not result in classification


No information available.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Hazardous components
Chemical name CAS-No. Classification Concentration (%)
ISODECYL ALCOHOL 61827-42-7 Acute Tox. 4; H302 >= 1.00 - < 10.00
POLYETHOXYLATE
Eye Dam. 2A; H319

Aquatic Acute 3; H402

POLY(HEXAMETHYLENEBIGUA Acute Tox. 4; H302 0.00 - < 0.10


NIDE) HYDROCHLORIDE
Acute Tox. 2; H330

Skin Corr. 2; H315

Eye Dam. 1; H318

Skin Sens. 1B; H317

Carc. 2; H351

STOT RE 1; H372

Aquatic Acute 1; H400

Aquatic Chronic 1;
H410

2 / 13
Page: 3

SAFETY DATA SHEET Revision Date: 01/11/2019


Print Date: 8/29/2023
SDS Number: R0703759
Aquaflow™ NMS-450 LIQUID SYNTHETIC Version: 1.1
RHEOLOGY MODIFIER
™ Trademark, Ashland or its subsidiaries, registered
in various countries
432597

SECTION 4. FIRST AID MEASURES

General advice : No hazards which require special first aid measures.

If inhaled : If breathed in, move person into fresh air.


If unconscious, place in recovery position and seek medical
advice.
If symptoms persist, call a physician.

In case of skin contact : First aid is not normally required. However, it is


recommended that exposed areas be cleaned by washing
with soap and water.

In case of eye contact : Remove contact lenses.


Protect unharmed eye.

If swallowed : Do not give milk or alcoholic beverages.


Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.

Most important symptoms : The most important known symptoms and effects are
and effects, both acute and described in the labelling (see Section 2.2) and/or Section 11.
delayed

Notes to physician : No hazards which require special first aid measures.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Water spray
Foam
Carbon dioxide (CO2)
Dry chemical

Specific hazards during : Do not allow run-off from fire fighting to enter drains or water
firefighting courses.

Hazardous combustion : No hazardous combustion products are known


products

Specific extinguishing : Fire residues and contaminated fire extinguishing water must
methods be disposed of in accordance with local regulations.

3 / 13
Page: 4

SAFETY DATA SHEET Revision Date: 01/11/2019


Print Date: 8/29/2023
SDS Number: R0703759
Aquaflow™ NMS-450 LIQUID SYNTHETIC Version: 1.1
RHEOLOGY MODIFIER
™ Trademark, Ashland or its subsidiaries, registered
in various countries
432597

Product is compatible with standard fire-fighting agents.

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Persons not wearing protective equipment should be excluded


protective equipment and from area of spill until clean-up has been completed.
emergency procedures Comply with all applicable federal, state, and local regulations.

Environmental precautions : Prevent product from entering drains.


Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for : Keep in suitable, closed containers for disposal.
containment and cleaning up

SECTION 7. HANDLING AND STORAGE

Advice on protection against : Normal measures for preventive fire protection.


fire and explosion

Advice on safe handling : Smoking, eating and drinking should be prohibited in the
application area.
For personal protection see section 8.

Hygiene measures : General industrial hygiene practice.

Conditions for safe storage : Product shipped or stored in other containers (totes, drums,
pails, etc) must be maintained between 59 degrees F (15
degrees C) and 77 degrees F (25 degrees C).

Containers which are opened must be carefully resealed and


kept upright to prevent leakage.

Materials to avoid : No materials to be especially mentioned.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters


Contains no substances with occupational exposure limit values.

4 / 13
Page: 5

SAFETY DATA SHEET Revision Date: 01/11/2019


Print Date: 8/29/2023
SDS Number: R0703759
Aquaflow™ NMS-450 LIQUID SYNTHETIC Version: 1.1
RHEOLOGY MODIFIER
™ Trademark, Ashland or its subsidiaries, registered
in various countries
432597

Contains no substances with occupational exposure limit values.


Engineering measures : General room ventilation should be adequate for normal
conditions of use. However, if unusual operating conditions
exist, provide sufficient mechanical (general and/or local
exhaust) ventilation to maintain exposure below exposure
guidelines (if applicable) or below levels that cause known,
suspected or apparent adverse effects.

Personal protective equipment


Respiratory protection : In the case of vapour formation use a respirator with an
approved filter within the capabilities of the respirator/filter
combination.
Where concentrations are above recommended limits or are
unknown, or a cartridge type respirator is not adequate, wear
a positive-pressure supplied-air respirator.

Hand protection
Material : butyl-rubber
Break through time : 480 min
Glove thickness : > 0.5 mm

Remarks : The exact break through time can be obtained from the
protective glove producer and this has to be observed. Gloves
should be discarded and replaced if there is any indication of
degradation or chemical breakthrough.

Eye protection : Not required under normal conditions of use. Wear splash-
proof safety goggles if material could be misted or splashed
into eyes.

Skin and body protection : Wear as appropriate:


Safety shoes

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state : liquid

Colour : colourless

Odour : odourless

Odour Threshold : No data available

pH : 6.5 - 7.5

5 / 13
Page: 6

SAFETY DATA SHEET Revision Date: 01/11/2019


Print Date: 8/29/2023
SDS Number: R0703759
Aquaflow™ NMS-450 LIQUID SYNTHETIC Version: 1.1
RHEOLOGY MODIFIER
™ Trademark, Ashland or its subsidiaries, registered
in various countries
432597

Melting point/freezing point : ca.0 °C

Boiling point/boiling range : > 100 °C

Flash point : Not applicable

Evaporation rate : <1


Water

Flammability (solid, gas) : No data available

Upper explosion limit : No data available

Lower explosion limit : No data available

Vapour pressure : similar to water

Relative vapour density : > 1(Air = 1.0)

Relative density : No data available

Density : No data available

Solubility(ies)
Water solubility : completely miscible

Solubility in other solvents : No data available

Partition coefficient: n- : No data available


octanol/water

Thermal decomposition : No data available

Viscosity
Viscosity, dynamic : < 6,500 mPa.s (25 °C)

Viscosity, kinematic : No data available

Oxidizing properties : No data available

Solids in Solution : 27 - 29 %(m)

6 / 13
Page: 7

SAFETY DATA SHEET Revision Date: 01/11/2019


Print Date: 8/29/2023
SDS Number: R0703759
Aquaflow™ NMS-450 LIQUID SYNTHETIC Version: 1.1
RHEOLOGY MODIFIER
™ Trademark, Ashland or its subsidiaries, registered
in various countries
432597

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No decomposition if stored and applied as directed.

Chemical stability : Stable under recommended storage conditions.

Possibility of hazardous : Product will not undergo hazardous polymerization.


reactions

Conditions to avoid : None known.

Incompatible materials : Reducing agents


Strong acids
Strong oxidizing agents

Hazardous decomposition : No hazardous decomposition products are known.


products

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Not classified based on available information.
Components:
ISODECYL ALCOHOL POLYETHOXYLATE:
Acute oral toxicity : LD50 (Rat): 1,940 mg/kg
Method: OECD Test Guideline 401
Remarks: Information given is based on data obtained from
similar substances.

POLY(HEXAMETHYLENEBIGUANIDE) HYDROCHLORIDE:
Acute oral toxicity : LD50 (Rat, female): 501 mg/kg

LD50 (Rat, male): 549 mg/kg

Acute inhalation toxicity : Assessment: The component/mixture is classified as acute


inhalation toxicity, category 2.

Acute dermal toxicity : LD50 (Rat): > 5,000 mg/kg


Method: OECD Test Guideline 402

Skin corrosion/irritation
Not classified based on available information.
Components:
ISODECYL ALCOHOL POLYETHOXYLATE:
Result: No skin irritation

7 / 13
Page: 8

SAFETY DATA SHEET Revision Date: 01/11/2019


Print Date: 8/29/2023
SDS Number: R0703759
Aquaflow™ NMS-450 LIQUID SYNTHETIC Version: 1.1
RHEOLOGY MODIFIER
™ Trademark, Ashland or its subsidiaries, registered
in various countries
432597

POLY(HEXAMETHYLENEBIGUANIDE) HYDROCHLORIDE:
Result: Irritating to skin.

Serious eye damage/eye irritation


Not classified based on available information.
Product:
Remarks: Unlikely to cause eye irritation or injury.

Components:
ISODECYL ALCOHOL POLYETHOXYLATE:
Result: Irritating to eyes.

POLY(HEXAMETHYLENEBIGUANIDE) HYDROCHLORIDE:
Result: Corrosive

Respiratory or skin sensitisation


Skin sensitisation: Not classified based on available information.
Respiratory sensitisation: Not classified based on available information.
Components:
POLY(HEXAMETHYLENEBIGUANIDE) HYDROCHLORIDE:
Assessment: The product is a skin sensitiser, sub-category 1B.

Germ cell mutagenicity


Not classified based on available information.
Carcinogenicity
Not classified based on available information.
Components:
POLY(HEXAMETHYLENEBIGUANIDE) HYDROCHLORIDE:
Carcinogenicity - : Limited evidence of carcinogenicity in animal studies
Assessment

Reproductive toxicity
Not classified based on available information.
STOT - single exposure
Not classified based on available information.
STOT - repeated exposure
Not classified based on available information.
Components:
POLY(HEXAMETHYLENEBIGUANIDE) HYDROCHLORIDE:
Exposure routes: Inhalation
Target Organs: Respiratory Tract
Assessment: Causes damage to organs through prolonged or repeated exposure.

Aspiration toxicity
Not classified based on available information.
Further information

8 / 13
Page: 9

SAFETY DATA SHEET Revision Date: 01/11/2019


Print Date: 8/29/2023
SDS Number: R0703759
Aquaflow™ NMS-450 LIQUID SYNTHETIC Version: 1.1
RHEOLOGY MODIFIER
™ Trademark, Ashland or its subsidiaries, registered
in various countries
432597

Product:
Remarks: No data available

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Components:
ISODECYL ALCOHOL POLYETHOXYLATE:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 56 mg/l
Exposure time: 96 h
Test Type: semi-static test

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 57.4 mg/l
aquatic invertebrates Exposure time: 48 h
Test Type: static test

POLY(HEXAMETHYLENEBIGUANIDE) HYDROCHLORIDE:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 0.026 mg/l
Exposure time: 96 h

LC50 (Pimephales promelas (fathead minnow)): 0.11 mg/l


Exposure time: 96 h

M-Factor (Short-term (acute) : 10


aquatic hazard)

M-Factor (Long-term : 10
(chronic) aquatic hazard)

No data available
Persistence and degradability
Product:
Biodegradability : Remarks: No data available

Components:
ISODECYL ALCOHOL POLYETHOXYLATE:
Biodegradability : Result: Readily biodegradable.
Biodegradation: > 60 %
Exposure time: 28 d

POLY(HEXAMETHYLENEBIGUANIDE) HYDROCHLORIDE:
Biodegradability : Result: Not readily biodegradable.
Method: OECD Test Guideline 301B

No data available

9 / 13
Page: 10

SAFETY DATA SHEET Revision Date: 01/11/2019


Print Date: 8/29/2023
SDS Number: R0703759
Aquaflow™ NMS-450 LIQUID SYNTHETIC Version: 1.1
RHEOLOGY MODIFIER
™ Trademark, Ashland or its subsidiaries, registered
in various countries
432597

Bioaccumulative potential
Components:
POLY(HEXAMETHYLENEBIGUANIDE) HYDROCHLORIDE:
Partition coefficient: n- : log Pow: -2.3
octanol/water

No data available
Mobility in soil
Components:
No data available
Other adverse effects
No data available
Product:
Additional ecological : An environmental hazard cannot be excluded in the event of
information unprofessional handling or disposal., Harmful to aquatic life.

Components:

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
General advice : The product should not be allowed to enter drains, water
courses or the soil.

Contaminated packaging : Empty remaining contents.


Dispose of as unused product.
Empty containers should be taken to an approved waste
handling site for recycling or disposal.

SECTION 14. TRANSPORT INFORMATION

International transport regulations


REGULATION
ID NUMBER PROPER SHIPPING NAME *HAZARD SUBSIDIARY PACKING MARINE
CLASS HAZARDS GROUP POLLUTANT /
LTD. QTY.

INTERNATIONAL MARITIME DANGEROUS GOODS


Not dangerous goods

INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER


Not dangerous goods

10 / 13
Page: 11

SAFETY DATA SHEET Revision Date: 01/11/2019


Print Date: 8/29/2023
SDS Number: R0703759
Aquaflow™ NMS-450 LIQUID SYNTHETIC Version: 1.1
RHEOLOGY MODIFIER
™ Trademark, Ashland or its subsidiaries, registered
in various countries
432597

INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO


Not dangerous goods

MERCOSUR
Not dangerous goods

*ORM = ORM-D, CBL = COMBUSTIBLE LIQUID

Marine pollutant no

Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific
exceptions that can be applied. Consult shipping documents for descriptions that are specific to the
shipment.

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or


mixture

Control of precursors and essential chemicals for the : Not applicable


preparation of drugs.

The components of this product are reported in the following inventories:


DSL : All components of this product are on the Canadian DSL

AICS : On the inventory, or in compliance with the inventory

ENCS : On the inventory, or in compliance with the inventory

KECI : On the inventory, or in compliance with the inventory

PICCS : On the inventory, or in compliance with the inventory

IECSC : On the inventory, or in compliance with the inventory

TCSI : Not in compliance with the inventory

TSCA : On TSCA Inventory

11 / 13
Page: 12

SAFETY DATA SHEET Revision Date: 01/11/2019


Print Date: 8/29/2023
SDS Number: R0703759
Aquaflow™ NMS-450 LIQUID SYNTHETIC Version: 1.1
RHEOLOGY MODIFIER
™ Trademark, Ashland or its subsidiaries, registered
in various countries
432597

Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)

SECTION 16. OTHER INFORMATION

Further information
Revision Date: 01/11/2019

Full text of H-Statements


H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H351 Suspected of causing cancer.
H372 Causes damage to organs through prolonged or repeated exposure if
inhaled.
H400 Very toxic to aquatic life.
H402 Harmful to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

Other information : The information accumulated herein is believed to be accurate


but is not warranted to be whether originating with the
company or not. Recipients are advised to confirm in advance
of need that the information is current, applicable, and suitable
to their circumstances. This SDS has been prepared by
Ashland's Environmental Health and Safety Department (1-
800-325-3751).

Sources of key data used to compile the Safety Data Sheet


Ashland internal data including own and sponsored test reports
The UNECE administers regional agreements implementing harmonised classification for
labelling (GHS) and transport.

12 / 13
Page: 13

SAFETY DATA SHEET Revision Date: 01/11/2019


Print Date: 8/29/2023
SDS Number: R0703759
Aquaflow™ NMS-450 LIQUID SYNTHETIC Version: 1.1
RHEOLOGY MODIFIER
™ Trademark, Ashland or its subsidiaries, registered
in various countries
432597

List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data
sheet :
ACGIH : American Conference of Industrial Hygienists
BEI : Biological Exposure Index
CAS : Chemical Abstracts Service (Division of the American Chemical Society).
CMR : Carcinogenic, Mutagenic or Toxic for Reproduction
FG : Food grade
GHS : Globally Harmonized System of Classification and Labeling of Chemicals.
H-statement : Hazard Statement
IATA : International Air Transport Association.
IATA-DGR : Dangerous Goods Regulation by the “International Air Transport Association” (IATA).

ICAO : International Civil Aviation Organization


ICAO-TI (ICAO) : Technical Instructions by the “International Civil Aviation Organization”
IMDG : International Maritime Code for Dangerous Goods
ISO : International Organization for Standardization
logPow : octanol-water partition coefficient
LCxx : Lethal Concentration, for xx percent of test population
LDxx : Lethal Dose, for xx percent of test population.
ICxx : Inhibitory Concentration for xx of a substance
Ecxx : Effective Concentration of xx
N.O.S.: Not Otherwise Specified
OECD : Organization for Economic Co-operation and Development
OEL : Occupational Exposure Limit
P-Statement : Precautionary Statement
PBT : Persistent , Bioaccumulative and Toxic
PPE : Personal Protective Equipment
STEL : Short-term exposure limit
STOT : Specific Target Organ Toxicity
TLV : Threshold Limit Value
TWA : Time-weighted average
vPvB : Very Persistent and Very Bioaccumulative
WEL : Workplace Exposure Level

13 / 13

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