Sec: JR.
IIT _*CO-SC(MODEL-A) Date: 28-01-24
Time: 3 Hrs Max. Marks: 198
28-01-24_JR.IIT_STAR CO-SC(MODEL-A) _JEE ADV_WAT-37_SYLLABUS
MATHEMATICS: PRESENT WEEK(80%): Parabola: Equation of Parabola, Equation of
Parabola (Standard from, Foci, Directrix, Eccentricity, Parametric form),
Tangent and its Properties, Chord of contact
PREVIOUS WEEK(20%): Family of Circles, Angle between two Circles,
Common chord, Direct, Transverse, Pair of tangents
PHYSICS: PRESENT WEEK(80%): CAPACITORS: Introduction, types of
capacitors, combination of capacitors in series and in parallel, general
capacitor circuits without involvement of dielectric, Energy stored in a
capacitor (without dielectric), charge flown and heat generated problems
when switch is thrown from one position to other (Exclude: Dielectric)
PREVIOUS WEEK(20%): Gravitation: Complete Gravitation Law of
gravitation; Gravitational potential and field; Acceleration due to gravity;
Motion of planets and satellites in circular orbits; Escape velocity
CHEMISTRY: PRESENT WEEK(80%): Aryl halides: preparation using EAS,
Sandmayer reaction, Mechanism of SNAr reactions (Exclude: Benzyne
mechanism & cine substitution) and EAS Reactions chlorobenzene,
Fittig, Wurtz-Fittig
Grignard reagent: Preparation and properties of Grignard reagent &
Organo lithium
PREVIOUS WEEK(20%): Alkyl halides: Preparation and Reactions of
alkyl halides, Mechanism of Nucleophilic Substitution reactions (SN1,
SN2), Mechanism of Nucleophilic Substitution reactions (SN1 and NGP),
Polyhalogen compounds NCERT(Exclude: haloform reaction)
Narayana IIT Academy 28-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-37_QP
TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 198
PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 6) Questions with Single Correct Options +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 7 – 12) +4 -2 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 13 – 18) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +4 0 6 24
27.30)
Total 18 66
CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 19 – 24) Questions with Single Correct Options +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 25 – 30) +4 -2 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 31 – 36) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +4 0 6 24
127.30)
Total 18 66
MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 37 – 42) Questions with Single Correct Options +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 43 – 48) +4 -2 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 49 – 54) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +4 0 6 24
127.30)
Total 18 66
JR.IIT_*CO-SC Page. No. 2
Narayana IIT Academy 28-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-37_QP
MATHEMATICS MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
1. Equation of the parabola whose axis is y x , distance of vertex from the origin is 2
and the distance of focus from the origin is 2 2 (vertex and focus lie in the 1st quadrant)
is
A) x y 2 x y 2 B) x y 8 x y 2
2 2
C) x y 4 x y 2 D) x y 4 x y 2
2 2
2. PQ is a double ordinate of the parabola y 2 4ax . Then the locus of its point of trisection
is
A) 9 y 2 4ax B) 9 y 2 16ax C) 3 y 2 8ax D) 9 y 2 8ax
3. The focus and directrix of a parabola are (1, 2) and x 2 y 9 0 . Then the equation of
tangent at the vertex is
A) x 2 y 5 B) x 2 y 2 C) x 2 y 5 0 D) x 2 y 2 0
4. Tangents are drawn from the points on the line x 2 y 8 to the circle x 2 y 2 16 . If the
locus of midpoint of chord of contact of the tangents is a circle S, then the radius of S is
A) 3 B) 5 C) 2 D) 2 2
5. The tangent at any point P on the parabola y 2 4ax meets the directrix at the point Q.
Then the angle subtended by PQ at its focus is
A) 300 B) 450 C) 600 D) 900
6. Radius of the largest circle which passes through the focus of the parabola y 2 4x and
contained in it is
A) 16 B) 5 C) 6 D) 4
JR.IIT_*CO-SC Page. No. 3
Narayana IIT Academy 28-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-37_QP
SECTION - 2 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
7. The line x y 2 0 is a tangent to a parabola at A. It intersects the directrix at B and
the tangent at the vertex at C. The focus of the parabola is S (2, 0) and vertex is O (0,0)
then which of the following is (are) true?
A) CS is perpendicular to AB B) AC.BC CS2
C) AC.BC 8 D) CS2 OS.SA
8. Let P and Q be two distinct points on the parabola y 2 4 x . If the axis of the parabola
touches a circle of radius ‘r’, having PQ as its diameter, then the slope of the line joining
P and Q can be
1 1 2 2
A) B) C) D)
r r r r
9. Consider two concentric circles C1 : x 2 y 2 1 0 and C2 : x 2 y 2 4 0 . A parabola is
drawn through the points where C1 meets the x-axis and having arbitrary tangents of C2
as its directrix. Then which of the following is/are not the locus of the focus of the
drawn parabola ?
3 2 3 2 4 2 4 2
A) x y2 3 B) x y2 3 C) x y2 3 D) x y2 3
4 4 3 3
10. Which of the following statement(s) is (are) true?
1
A) If , 2 is one end of a focal chord of the parabola y 2 8x then its length is 12.5
2
units.
B) The length of latusrectum of a parabola whose focal chord is PQ (where S is the
focus and P,Q are points on the parabola) such that SP 3,SQ 2 is 2.4 units.
C) If the distances of two points P and Q are parabola from its focus are 4 and 9 then the
distance of point of intersection of tangents at P and Q from focus is 6 units.
D) The length of focal chord of the parabola y 2 8x which makes an angle of with
6
the axis of the parabola is 32 units.
JR.IIT_*CO-SC Page. No. 4
Narayana IIT Academy 28-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-37_QP
11. Let y 2 5 y 3x k 0 be a parabola then
A) Its latus rectum is least when k = 1
B) Its latus rectum is independent of k
73
C) The line y 2 x 1 will touch the parabola if k
16
5 1
D) The axis of parabola is y if k
2 4
12. Two distinct chords passing through (b, 2b) of parabola y 2 4bx are bisected by the line
x y 1 . Then the length of latus rectum can be
A) 1 B) 2 C) 3 D) 4
SECTION - 3 (Maximum Marks : 24)
This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
13. If P(2, 4) lies on the parabola y 2 8 x and PQ is a focal chord, the co-ordinates of the
mirror image of Q with respect to the tangent at P are (h, k) then h . k
14. The tangents at (1, 4) and (5, 6) drawn to a parabola meet at (6, 8) . If the slope of the
k 3
directrix is then 10 k ______
3
15. Let S be the focus of the parabola y 2 8 x and PQ be the common chord of the circle
x 2 y 2 2 x 4 y 0 and the parabola. Then the area of triangle PQS is _______
16. If L is the length of the chord passing through the origin and having inclination 600 with
x-axis by the parabola y 2 4( x 1) then the value of 3L = ________
17. If two circles are such that each passes through the centre of the other. If the angle
between them is ( is obtuse) then 2 cos 1 _______
18. The radius of the circle touching the parabola y 2 4x 8 0 at (3, 2) and passing
through its focus is r then the value of 5r 4 is equal to
JR.IIT_*CO-SC Page. No. 5
Narayana IIT Academy 28-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-37_QP
PHYSICS MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
19. The plate separation in a parallel plate condenser is d and plate area is A. If it is charged
to V volt & battery is disconnected then the work done in increasing the plate separation
to 2d will be-
3 0 AV 2 0 AV 2 2 0 AV 2 0 AV 2
A) B) C) D)
2 d d d 2d
20. The work done against electric forces in increasing the potential difference of a
condenser from 20V to 40V is W. The work done in increasing its potential difference
from 40V to 50V will be (consider capacitance of capacitor remain constant)
3W W
A) 4W B) C) 2W D)
4 2
21. A parallel plate condenser of capacity C is connected to a battery and is charged to
potential V. Another condenser of capacity 2C is connected to another battery and is
charged to potential 2V. The charging batteries are removed and now the condensers are
connected to form a closed circuit in such a way that the positive plate of one is
connected to negative plate of another. The final energy of this system is___
25CV 2 3CV 2 9CV 2
A) zero B) C) D)
6 2 2
22. A capacitor of capacitance C is charged to a potential difference V0 . The charging
battery is disconnected and the capacitor is connected to a capacitor of unknown
capacitance C x . The potential difference across the combination is V. The value of C x
should be –
C (V0 V ) C (V V0 ) CV CV0
A) B) C) D)
V V V0 V
JR.IIT_*CO-SC Page. No. 6
Narayana IIT Academy 28-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-37_QP
23. Two spherical conductors A1 and A2 of radii r1 and r2 are placed concentrically in air.
The two are connected by a copper wire as shown in figure. Then the equivalent
capacitance of the system is: r1 r2
4 0 k r1r2 4 0 k r22
A) B) 4 0 (r1 r2 ) C) 4 0 r2 D)
r2 r1 r2 r1
24. Consider a spherical gaseous cloud of mass density (r ) in a free space where r is the
radial distance from its centre. The gaseous cloud is made of particles of equal mass m
moving in circular orbits about their common centre with the same kinetic energy K.
The force acting on the particles is their mutual gravitational force. If (r ) is constant in
time. The particle number density n(r ) ( r ) / m is : (G = universal gravitational
constant)
K K 3K K
A) B) C) D)
6 r 2 m 2G r m2G
2
r 2 m2G 2 r 2 m2G
SECTION - 2 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
25. On X-Y plane, the gravitational potential ( v ) of a particle of mass ‘m’ varies with r as
v Kr 2 where
K = a constant
r = distance from the origin
m = mass of particle
JR.IIT_*CO-SC Page. No. 7
Narayana IIT Academy 28-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-37_QP
Two particles A and B of mass ‘m’ and ‘2m’ respectively, rotate about the origin in
concentric coplanar circular path of radius R and 2R. Time taken by them to complete
one round about the origin by them is TA and TB respectively(The two particles are not
interacting with each other).
While the particles are rotating, they are given a very small push radially outward. They
start oscillating (radially inward-and outward) about their original circle with time
period A and B respectively. Choose the correct
A) TA TB B) A B C) 2TA TB D) 2 A B
26. The circuit involves two ideal cells connected to a 1 F capacitor via a key K. Initially
the key K is in position 1 and the capacitor is charged fully by 2V cell. The key is then
pushed to position 2. Due to this change over.
A) The net charge crossing the 4 volt cell is 2 C
B) The net charge crossing the 4 volt cell is 6 C
C) The gain in potential energy of capacitor is 6 J
D) The gain in potential energy of capacitor is 1 J
JR.IIT_*CO-SC Page. No. 8
Narayana IIT Academy 28-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-37_QP
27. In the circuit shown in the figure, each capacitor has a capacitance C. The emf of the cell
is E and circuit already in steady state. If the switch S is closed.
A) some positive charge will flow out of the positive terminal of the cell
B) some positive charge will enter the positive terminal of the cell
C) the amount of charge flowing through the cell will be CE
4
D) the amount of charge flowing through the cell will be CE
3
28. The figure shows a diagonal symmetric arrangement of capacitors and a battery. If the
potential of C is zero, then (All the capacitors are initially uncharged before connected in
the circuit).
A) VA 20V B) 4(VA VB ) 2(VD VB ) 2VB
C) 2(VA VD ) 2(VB VD ) 4VD D) VA VB VD
29. In the circuit shown in the figure, there are two parallel plate capacitors each of
capacitance C. The switch S1 is pressed first to fully charged the capacitor C1 and then
released. The switch S 2 is then pressed to charge the capacitor C2 . After some time, S 2
is released and then S3 is pressed. After some time.
JR.IIT_*CO-SC Page. No. 9
Narayana IIT Academy 28-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-37_QP
A) the charge on the upper plate of C1 is 2CV0
B) the charge on the upper plate of C1 is CV0
C) the charge on the upper plate C2 is 0
D) the charge on the upper plate of C2 is CV0
30. A capacitor of capacitance C0 is charged to a potential V0 and isolated. Another
capacitor C is connected to C0 , and charged to equilibrium. Then it is discharged and
charged again by connecting it C0 . The process being repeated n times. Due to this,
potential of the initial capacitor is decreased to V. Value of C is
V
1/ n V 1/ n V n V
n
A) C0 0 B) C0 0 1 C) C0 0 1 D) C0 0
V V V V
SECTION - 3 (Maximum Marks : 24)
This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
31. Three material points of masses m, m and 2m are at the vertices of an equilateral
triangle of side d . The system is rotating in free space in such a way that under the
mutual gravitational interaction of the three particles, the system is neither expanding
xGm
nor contracting. If angular velocity of this rotation is . Then x
d3
JR.IIT_*CO-SC Page. No. 10
Narayana IIT Academy 28-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-37_QP
32. Two space stations A and B are orbiting the earth with speed v in the same orbit of
radius R. Station B is a distance s ahead of station A. Two astronauts from station A
have to join the station B. For this purpose, they leave station A in a spaceship and move
radially to a slightly lower orbit and stay in that orbit. When the station B comes closest
to them, they immediately move radially to join the station B. If time spend in the lower
sR
orbit is t , then separation between the orbits is . Then x is
xv(t )
33. Three uncharged capacitors of capacitance C1 1 F , C2 2 F and C3 3 F are
connected as shown in the figure. The potential of point A, B and D are 10 volt, 25 volt
and 20 volt respectively. Determine the potential at point O (in volts).
34. Find the capacitance between the point A and B of the given assemblies (in F )
35. Consider the situation shown in the figure. The switch S is open for a long time and then
closed and again steady state reached then
The charge flown through the battery after the switch S is closed is x(C ) . Then x is
36. The particle P shown in the figure has a mass m and a charge –q. Each horizontal plate
mg 0 A
has a surface area A. The potential difference V n should be applied to the
2qc
combination to hold the particle P in equilibrium then find the value of n.
JR.IIT_*CO-SC Page. No. 11
Narayana IIT Academy 28-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-37_QP
CHEMISTRY MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
37. The correct order of the rate constants for the following series of reactions
Z CF CH 3, 3 , OCH 3
Br
N
NO2
NO2
+
N
H z
z
A) CF3 CH 3 OCH 3 B) CF3 OCH 3 CH 3
C) OCH 3 CF3 CH 3 D) CH 3 OCH 3 CF3
38. Which of the following aryl halide will readily undergo nucleophilic substitution
reaction?
Cl
Cl NO2
A) OMe B) C) NO2 D)
39. In which of the following reaction 2 alcohol is obtained as a product?
A) B)
C) D) Both A & B
JR.IIT_*CO-SC Page. No. 12
Narayana IIT Academy 28-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-37_QP
40. When benzene diazonium chloride is treated with cuprous chloride in HCl ,
chlorobenzene is formed. This reaction is called
A) Swart’s reaction B) Etard’s reaction
C) Gattermann reaction D) Sandmeyer’s reaction
41. What function does nitric acid do in the reaction of benzene with I 2 to produce
iodobenzene?
A) HNO3 Converts I to I 2 B) It acts as a catalyst
C) HNO3 converts I 2 to HI D) It oxidises I 2 to I
42.
Cl
Cl HNO3 H 2 SO4 CH 3ONa
A B
Mono nitration
Consider major product in every step and the final product B is
OMe OMe
Cl
OMe Cl
Cl
NO2
A) NO2 B) C) NO2 D) NO2
SECTION - 2 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
43. In which of the following reactions, optically active product is formed.
1. Butan 2one
A) CH 3 MgBr
1. C2 H 5CHO
2. H O
B) C6 H 5 MgBr 2. H O
3 3
MgBr
1. CH 2O
H O
3
C) C2 H 5 MgBr
1. CO2
2. H O
D)
3
JR.IIT_*CO-SC Page. No. 13
Narayana IIT Academy 28-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-37_QP
44. Which of the following reaction(s) give Saytzeff’s alkene as major product?
A) B)
C) D)
45. Consider the following S N Ar reaction
Cl
O
+
F N
+ CH3ONa
O-
(1 equivalent)
The correct statement is (are)
A) Cl will be substituted because it is better leaving group.
B) F will be substituted because nitro from para position facilitates this
C) After substitution of one halogen, substitution of the second halogen
would become further more difficult.
D) First chlorine and then fluorine would be substituted subsequently.
46. Which of the following combinations will yield hydrocarbon as the product
A) CH 3 MgBr C2 H 5 MgCl
B) CH 3 MgBr C2 H 5Cl
C) CH 3 MgBr 1 mole CH 2O
D) CH 3 MgBr 1 mole CH 3CHO
47. The reactivity of compound Z with different halogen under appropriate condition is
given below:
OH
mono halo substituted derivative
when X2 = I2
X2
di halo substituted derivative when
X2 = Br2
C(CH3)3
Z
Tri halo substituted derivative when
X2 = Cl2
JR.IIT_*CO-SC Page. No. 14
Narayana IIT Academy 28-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-37_QP
The observed pattern of electrophilic substitution can be explained by
A) The steric effect of the halogen
B) The steric effect of the tert-butyl group
C) The electronic effect of the phenolic group
D) The electronic effect of the tert-butyl group
48.
CH3 MgBr CH3COCH 2COOC2 H 5 H3O
Re action I
Major product(P1)
(1 eq.)
C6 H 5 MgBr CH3O 2 C O
H3O
Re action II
Major product(P2)
(excess)
Choose the correct statement(s) by studying above reactions.
A) Product P1 is optically inactive ester
B) The Grignard reagent will selectively attack the keto carbon and not the ester carbon.
C) Degree of unsaturation of P2is 12
D) P2 contains only one oxygen.
SECTION - 3 (Maximum Marks : 24)
This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
49.
COOH
NaOH
CaO
A
Cl2
FeCl3
B
HNO3
H 2 SO4
C
Cl2
FeCl3
D
CH3ONa
E
Find the locant number (i.e., position number) of chlorine atom as per IUPAC in final
product E(Consider mono nitration and mono chlorination in respective steps and major
product)
JR.IIT_*CO-SC Page. No. 15
Narayana IIT Academy 28-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-37_QP
50. p-methylbenzonitrileupon treating with one mole of cyclopropyl magnesium bromide
followed by hydrolysis produces an organic compound(X). The molecular weight of X
is____
51. Among the following compounds total number of compounds which are more reactive
than chlorobenzene towards nitration. (Aromatic electrophilic Substitution)
-
O
F
CF3 N+ Cl
O
A B C
Cl
CCl3
D E
52. Number of carbons present in DDT?
53. Volume of CH 4 liberated in the Litre following reaction at STP
(1 GMV=22.4 lit)
OH
HO
CH 3MgBr
2 mole
Product
OH
1 mole
54.
O
CH 3MgBr
1mole
Major product
Locant number of methyl group in the product as per IUPAC
JR.IIT_*CO-SC Page. No. 16
