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Stoichiometry
Mark Scheme 3
Level IGCSE
Subject Chemistry
ExamBoard CIE
Topic Stoichiometry
Sub-Topic
Paper (Extended) Theory
Booklet Mark Scheme 3
TimeAllowed: 71 minutes
Score: / 59
Percentage: /100
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1 (a Avogadro’s Number of particles
or formula mass in grams
or 6 x 1023 particles accept atoms, ions and molecules
or as many particles as there are carbon atoms in 12.00g of 12Ca
ANY one [1]
(b)
b) moles of Mg = 3/24 = 0.125
moles of CH3COOH = 12/60 = 0.200
magnesium is in excess
OR 3.0g of magnesium react with 15g of acid
only 12.0 g of acid present
magnesium is in excess [3]
(ii) Mark conseq to (i) but NOT to any simple integer
moles of H2 = 0.1 [1]
(iii) Mark conseq to (ii) but NOT to any simple integer
Volume of hydrogen = 0.1 x 24
= 2.4 dm3 [2]
(c)
c) moles of NaOH = 25/1000 x 0.4 = 0.01 [1]
(ii) Mark conseq to (i) but NOT to any simple integer
moles of acid = 0.01/2 = 0.005 [1]
(iii) Mark conseq to (ii) max 10M
concentration of acid = 0.005 x 1000/20 [1]
= 0.25 mol/dm3 [1]
TOTAL = [10]
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2 (a filter / centrifuge / decant; [1]
(partially) evaporate / heat / boil; [1]
allow to crystallise / cool / let crystals form; [1]
dry crystals / dry between filter paper / leave in a warm place to dry; [1]
(b)
b) number of moles of HCl used = 0.04 × 2 = 0.08; [1]
number of moles CoCl2 formed = 0.04; [1]
number of moles CoCl2.6H2O formed = 0.04; [1]
maximum yield of CoCl2.6H2O = 9.52; [1]
allow: 9.5
allow: ecf on number of moles of HCl
number of moles of HCl used = 0.08 note: must use their value
allow: ecf
number of moles of CoCO3 in 5.95 g of cobalt(II) carbonate = 5.95/119 = 0.05; [1]
(ii) 0.05 > 0.04 or stated in words;
allow: ecf on number of moles of CoCl2 formed [1]
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Question Answer Marks
3(a)(i) a reaction whose rate is influenced by light / reaction which occurs in presence of light; 1
(a)(ii) CH3CHClCH3; 1
(a)(iii) (both have) same molecular formula; 2
different structural formula or structure;
(b) M1 bonds breaking = (8 × 412) + (2 × 348) + 242 = 4234; 3
M2 bonds forming = (7 × 412) + (2 × 348) + 338 + 431 = 4349;
M3 4234 – 4349 = –115 and exothermic;
(c)(i) CH3CH2CH2Cl + NaOH → CH3CH2CH2Cl + NaCl 2
NaCl as product;
rest of equation;
(c)(ii) propene 2
CH2=CHCH3;
c)(iii) propanoic acid; 1
(d)(i)
(d)( 46; 1
(d)(ii) 60; 1
(d)(iii) moles of CH3CH2CH2OH = 0.1; 2
moles of HCOOH = 0.087 (0.09) and limiting reagent is methanoic acid;
(d)(iv) 88 × (mol of limiting reagent in (d)(iii)); 1
expected answer: 88 × 0.087 = 7.65 g;
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4 (a making fertilisers or pickling metals or making fibres or making phosphoric acid/phosphates
making dyes or making paints/pigments/dyes or making paper making plastics or making
detergents or tanning leather or battery acid. [1]
(b) (i) add water (to yellow solid or to (anhydrous) iron(II) sulfate or to FeSO4 or to products [1]
goes green [1]
(ii) M1 Sulfur trioxide reacts with water to make sulfuric acid or equation [1]
M2 sulfur dioxide reacts with oxygen to form sulfur trioxide or equation [1]
(iii) M1 = 2.07 Allow 2.1 or 2.0666…7
M2 = 62.8.g
M3 =( M2/152 =) 0.41(3)
M4 (=M1/M3) rounded to the nearest whole number × = 5 [4]
(c (i) nitric acid or nitric(V) acid or HNO3 [1]
(ii) 2KNO3 = 2KNO2 + O2 [2]
Species (1)
Balance (1)
[Total: 12]
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5 (a (i) (X(s) ↔) X(l) [1]
(ii) melting point/freezing point (of X) [1]
(iii) gas/gaseous or vapour [1]
(iv) not horizontal or line slopes or line is lower [1]
(b) (i) 14.3 [1]
(ii) 85.7 ÷ 12 and 14.3 ÷ 1 or 7.14 and 14.3 [1]
ratio 1:2 [1]
CH2 [1]
note: Award all 3 marks for correct answer
allow: alternative working e.g.
85.7 × 84 ÷ 100 and 14.3 × 84 ÷ 100 or 71.988/72 and 12/12.012 [1]
6:12 or ratio 1:2 [1]
CH 2 [1]
(iii) C6H12 [1]
[Total: 9]
