High Temperature Tensile and Creep Behav
High Temperature Tensile and Creep Behav
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The mechanical behavior of lead free solders is highly The reliability of electronics used in various devices
dependent on the testing temperature. Previous investigations depends on the environmental conditions experienced during
on mechanical characterization of conventional and doped field use. In oil and gas exploration, avionics, automotive,
lead free SAC solders have mainly emphasized stress-strain and defense applications, electronics typically experience very
and creep testing at temperatures from 25 to 125 °C. harsh environments compared to consumer electronics [1-2].
However, solders are exposed to very high temperatures from The electronic systems used in under-the-hood automotive
125-200 °C in several harsh environment applications applications are operated at temperatures over 150 °C [3-4].
including well boring, geothermal energy, and aerospace In addition, engine control modules mounted directly onto the
engines. In the current work, we have extended our previous engine experience high-temperature excursions while in
studies to explore mechanical properties for SAC305, operation.
SAC_Q, SAC_R, and Innolot solders at temperatures from The electronic modules used in oil and gas exploration
125-200 °C at a strain rate of 0.001 (sec-1). The Anand applications experience ambient temperatures above 150 °C,
constitutive model with parameters measured previously using and often up to 200 °C [5]. Wireline logging represents a
test data from 25-125 has been shown to fit the high typical application in oil and gas drilling where the electronic
temperature stress-strain curves reasonably well. In addition, modules are exposed to very high temperatures. During this
high temperature creep behavior of SAC305 was explored. application, the logging tool is lowered into the wellbore, and
Finally, the high temperature tensile properties of the above- the electronics experience extremely low or high temperatures
mentioned solders have been compared. depending on the location and type of the oil well. The
Our results show a significant degradation of mechanical reliability of electronics is an important concern here since the
properties of lead-free solders at higher temperatures. Also, a wireline logging usually lasts 2 to 6 hours. In addition,
noteworthy increase in the secondary creep strain rate has electronic systems used in commercial and defense aircraft,
been observed. Comparison of the results for different solders ground military vehicles, high-speed civil transport, and
has shown that the addition of dopants (e.g. Bi, Ni, and Sb) in supersonic aircraft, can be exposed, most often, to
the traditional SAC alloys improve their properties temperatures up to 200 °C [2]. Also, electric propulsion
significantly. systems in battle tanks and other mobile ground defense
applications can experience ambient temperatures above 200
.(<:25'6Lead-Free Solder, Aging, Stress-Strain °C [6].
Curve, Modulus, Yield Stress, Ultimate Tensile Strength, Thus, electronic products experience very harsh
Anand Model, Constitutive Relations environments, e.g., temperatures up to 200 °C, which are very
close to the melting points of the various Sn-Ag-Cu (SAC)
V
120(1&/$785( solders used by industry. Moreover, longer exposures at such
H
Uniaxial Stress high temperatures can result in extreme aging induced
Uniaxial Strain changes to their properties [7]. In particular, significant
T Temperature degradations have been reported in ball shear strength [8],
s Internal Variable elastic modulus [9], drop reliability [10], fracture behavior
ȟ Multiplier of Stress [11], microstructure [12], creep behavior [13-17], thermal
A Pre-Exponential Factor
cycling reliability [18-24], Anand model parameters [21-22],
Q Activation Energy
R Universal Gas Constant nanoindentation joint modulus and hardness [23-25], high
ho Hardening Constant strain rate mechanical properties [26], uniaxial cyclic stress-
so Internal Variable Initial Value strain curves and fatigue life [27-28], and shear cyclic stress-
ŝ Coefficient for Deformation Saturation Value strain curves and fatigue life [29-30].
m Strain Rate Sensitivity of Stress SAC305 (96.5Sn–3.0Ag–0.5Cu) is one of the most
n Strain Rate Sensitivity of Saturation Process popular lead free solders used in surface mount assembly due
a Strain Rate Sensitivity of the Hardening Process to its relatively high melting point, attractive mechanical
properties, and thermal cycling reliability. Addition of
dopants such as Bi, Ni, In, Mg, Mn, Zn, La, Ce, Co, and Ti to
V C 1 tanh( C 2 H ) C 3 tanh( C 4 H )
SAC solder samples available as a large bars. These were cut
into small pieces. Solid materials were melted into a quartz (1)
crucible. The temperature controller controls the temperature
of the heating system based on the melting point of the This model was used to fit the experimental stress-strain
solders. A vacuum suction method allowed the molten solder curves (usually a set of 10) and an “average” experimental
to be drawn into rectangular glass tubes [13-17]. The samples stress-strain representation was generated.
were solidified using both water quenched (WQ) and reflowed
(RF) solidification profiles. Initially, all the samples were $1$1'9,6&23/$67,&02'(/
solidified with water quenched method. In this study, water The Anand viscoplastic model [48] is one of the most
quenched specimens were used for the creep tests where these popular constitutive models for solder materials. This model
specimens were aged at room temperatures for 10 days before is built into ANSYS and ABAQUS finite element codes and
testing. For tensile tests, some specimens were reflowed in a has been widely adopted to predict solder joint reliability. For
reflow oven where these were re-melted in the glass tube and example, Che, et al. [49] studied multiple constitutive models
then re-solidified in a controlled reflow profile similar to that and used Anand viscoplastic model to predict the fatigue life
used for SMT assembly. Before testing, samples were of lead-free solders accurately. Details of the Anand model
collected by breaking the glass tubes. The final test samples are explained in the literature [e.g., 21-22, 50-51]. The Anand
typically have dimensions of 80 x 3 x 0.5 mm. The gage model provides three equations: (1) stress equation, (2) flow
length of the testing specimen was about 60 mm. The test equation, and (3) evolution equation. There are nine material
samples were preserved in low temperature freezer at -40 °C parameters (constants) in the model that can be determined by
to avoid any unintentional aging effects on their properties. using the stress-strain results obtained at several different
temperatures and strain rates. Finally, a least-squares
Mechanical Testing System and Data Processing regression method is used to extract these parameters [21-22,
The stress-strain testing in this work was performed with a 49, 50-51]. Anand model parameters for SAC305 and
micro-tension/torsion thermo-mechanical test system (MT- SAC_R have previously been measured using stress-strain
200) from Wisdom Technology Inc. (Figure 1). This system data recorded from 25-125 °C [46, 50-51].
offers an axial displacement resolution of 0.1 micron. This
test system includes a universal 6-axis load cell that can (;3(5,0(17$/5(68/76
simultaneously monitor three forces and three moments
during sample mounting and testing. An additional heating Stress-Strain Data for Various Temperatures and Strain Rates
chamber was used (Figure 1), which allowed samples to be The plots in Figure 2 illustrate the recorded high
tested up to +200 °C. temperature stress-strain curves for the SAC305, SAC_R,
SAC_Q, and Innolot alloys (RF microstructures) at a strain
rate of 0.001 sec-1. In each plot, the four different colored
curves represent the 4 testing temperatures (T = 125, 150,
175, and 200 °C). Each curve in these plots is an “average”
H 0 . 001 sec 1
60
experimental stress-strain curve representing the fit of the SAC_Q RF o
125 C
o
150 C
empirical model in eq. (1) to the 10 recorded experimental 50 175 oC
stress-strain curves for the particular strain rate and o
200 C
Stress, V MPa
temperature. In each plot, the top curve represents the 40
average stress-strain curve at T = 125 °C, and the bottom
curve is the average stress-strain curve at T = 200 °C. These 30
results clearly show a significant reduction in the mechanical
properties with increase in temperature. For example, the 20
yield stress and ultimate tensile strength of these alloy
typically drop by 50-60% between T = 125 °C and T = 200 10
°C.
0
Strain, H
0.000 0.005 0.010 0.015 0.020
H 0 .001 sec 1
60
SAC305 RF o
125 C
150 oC (c) SAC_Q
50 o
175 C
o
200 C
Stress, V MPa
40
H 0 . 001 sec 1
60
Innolot RF o
125 C
30 o
150 C
50 175 oC
o
200 C
20
Stress, V MPa 40
10
30
0
20
Strain, H
0.000 0.005 0.010 0.015 0.020
10
(a) SAC305
0
Strain, H
0.000 0.005 0.010 0.015 0.020
0 .001 sec 1
60
İ SAC_R RF o
125 C
o
150 C (d) Innolot
50 175 oC
o
200 C
Figure 2 - Experimental Stress-Strain Curves
Stress, V MPa
40
(RF, No Aging)
30
A comparison of the uniaxial tensile test results for the
four different solder alloys at 125 °C is shown in Figure 3. It
20
can be seen that SAC_Q possesses the best properties whereas
SAC305 shows to have lowest strength which is about 50% of
10
that of SAC_Q. The strength of Innolot is also significantly
higher than SAC305 and very close to SAC_Q. The strength
0
of SAC_R is higher than SAC305, even though SAC_R does
Strain, H
0.000 0.005 0.010 0.015 0.020
not contain any Ag. Analogous results were also obtained at
other testing temperatures.
(b) SAC_R
H 0 .001 sec 1 H 0 .001 sec 1
60 60
T = 125 °C SAC_R RF SAC_Q
40 40
30 30
20 20
10 10
0 0
0.000 0.005 0.010 0.015 0.020
Strain, H
100 120 140 160 180 200 220
o
Temperature, T ( C)
(a) Effective Elastic Modulus
Figure 3 - Comparison of Stress-Strain Curves
(T = 125 °C, Strain Rate = 0.001 sec-1)
H 0 .001 sec 1
60
H 0 .001 sec 1
60
SAC305 o
125 C, Experimental
150 oC, Experimental
50 175 oC, Experimental
200 oC, Experimental
Stress, V(MPa)
20
60
H 0 .001 sec 1 SAC_R o
125 C, Experimental
İ C 0 C1 t C 2 (1 e C 3 t ) (2)
150 oC, Experimental
50 175 oC, Experimental
200 oC, Experimental where C0, C1, C2 and C3 are fitting constants. Note that
constant C1 represents the “steady state” creep strain rate.
Stress, V(MPa)
10 1.8
7.5 2.3
0.003 125
10 3.1
7.5 3.9
150
0.002 10 15.5
100 oC 7.5 7.5
125 oC 175
10 61.0
0.001 150 oC
o
175 C 7.5 18.5
200
200 oC 10 114.0
0.000
0 1000 2000 3000 4000 5000 6000 7000 8000 6800$5<$1'&21&/86,216
Time, t (Sec) In this investigation, we have extended our previous
(a) 7.5 MPa studies to explore the mechanical properties of SAC305,
SAC_R, SAC_Q, and Innolot solders at temperatures from T
= 125-200 °C (e.g. 125, 150, 175, and 200 °C). At each
elevated temperature, stress-strain data were measured at a
0.006
ı = 10 MPa SAC305 strain rate of 0.001 sec-1 for all of the alloys. The variations
of mechanical properties such as effective elastic modulus,
0.005
yield stress, and ultimate tensile strength (UTS) with
temperature were extracted. The stress-strain results of these
0.004
alloys were compared to the predictions of the Anand
Strain, H
10-6
Advanced Vehicle and Extreme Environment Electronics
(CAVE3).
•
10-7
5()(5(1&(6
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