Sec: SR_*CO-SC(MODEL-B) Date07-07-2024

Time: 3 Hrs CTM-47 Max. Marks: 300

PHYSICS MAX.MARKS: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
1. A glass sphere (   1.5) of radius 20 cm has a small air bubble 4 cm below its centre. The
sphere is viewed from outside and along a vertical line through the bubble. The apparent
depth of the bubble below the surface of sphere is (in cm)
A) 13.33 B) 26.67 C) 15 D) 30
2. A ray of light is incident on a glass sphere of refractive index 3/2. What should be the
angle of incidence so that the ray which enters the sphere does not come out of the
sphere is
A) tan 1 (2 / 3) B) sin 1 (2 / 3) C) 900 D)
cos 1 (1/ 3)

3. There is a small air bubble inside a glass sphere (   1.5) of radius 10 cm. The bubble is 4
cm below the surface and is viewed normally from the outside. The apparent depth of
the bubble is
A) 3 cm below the surface B) 5 cm below the surface

C) 8 cm below the surface D) 10 cm below the surface

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4. A spherical convex surface of radius of curvature R separates air (  a  1) from glass

 a  g  1.5 . The centre of curvature is in the glass. A point object P placed in air is found

to have a real image Q in the glass. The line PQ cuts the surface at a point O and
PO  OQ. The distance PO is equal to

A) 5 R B) 3 R C) 2 R D) 1.5 R
5. A denser medium of refractive index 1.5 has a concave surace with respect to air of
radius of curvature 12 cm. An object is situated in the denser medium at a distance of 9
cm from the pole locate the image due to refraction in air
A) A real image at 8 cm B) A virtual image at 8 cm
C) A real image at 4.8 cm D) A virtual image at 4.8 cm
6. Yellow light is used in a single slit diffraction experiment with slit width of 0.6 mm. If
yellow light is replaced by red light X – rays, then the observed pattern will reveal:
A) That the central maximum is narrower B) More number of fringes
C) Less number of fringes D) No diffraction pattern
7. In the Young’s double – slit experiment, the interference pattern is found to have an
intensity ratio between the bright and dark fringes as 9. This implies that :
A) the ratio of intensities of two slits are 4 units and amplitudes 2 unit respectively
B) the ratio of intensities of two slits are 9 units and amplitudes 3 unit respectively
C) the ratio of intensities of two slits are 2 units and amplitudes 4 unit respectively
D) the ratio of intensities of two slits are 3 units and amplitudes 9 unit respectively
8. The angle of polarisation for any medium is 60o, what will be critical angle for this
1
A) sin 1 3 B) tan 1 3 C) cos 1 3 D) sin 1
3

9. Plane polarized light is passed through a polaroid. On viewing through the polaroid we
find that when the polaroid is given one complete rotation about the direction of the
light, one of the following is observed
A) The intensity of light gradually decreases to zero and remains at zero
B) The intensity of light gradually increases to a maximum and remains at maximu
C) There is no change in intensity
D) The intensity of light is twice maximum and twice zero

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10. A beam of light AO is incident on a glass slab (  1 . 54 ) in a direction as shown in figure.
The reflected ray OB is passed through a Nicol prism on viewing through a Nicole
prism, we find on rotating the prism that

A) The intensity is reduced down to zero and remains zero

B) The intensity reduces down some what and rises again
C) There is no change in intensity
D) The intensity gradually reduces to zero and then again increases
11. If a minima in Young’s double slit experiment occurs directly infront of one of the slits
(distance between slit and screen D = 12 cm and distance between slits d = 5 cm) then
the wavelength of the radiation used can be
A) 2 cm only B) 4 cm only
2 2 4 4
C) 2cm or cm or cm D) 4cm or cm or cm
3 5 3 5
12. Two polaroids are placed in the path of unpolarized beam of intensity I0 such that no
light is emitted from the second polaroid. If a third polaroid whose polarization axis
makes an angle  with the polarization axis of first polaroid, is placed between these
polaroids then the intensity of light emerging from the last polaroid will be
I0  2 I I
A)   sin 2 B)  0  sin 2 2 C)  0  cos 4  D) I 0 cos 4 
8 4 2
13. Young’s double slit experiment is performed in a liquid. The 10th bright fringe in liquid
lies at the point on the screen, where 6th dark fringe lies if the experiment was performed
in vacuum. The refractive index of the liquid is approximately [the source used is same
for both the experiments in liquid and vacuum]
A) 1.8 B) 1.5 C) 1.67 D) 1.2

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14. In double – slit experiment, monochromatic light of wavelength  is used. When a sheet
of thickness t is introduced in the path of one wave, the fringe pattern shift by the same
amount by which distance between successive maxima is observed by doubling the
distance between slit and screen. Find the refractive index of the sheet:
2 2 2 2t   
A) 1   B) C)  2   D)  
 t  t  t   2t 
15. In Young’s double – slit experiment, the separation between the slits is halved and the
distance between the slits and screen is doubled and finally the setup is dipped in the
liquid of R.I. ( = 4). Then the fringe width is:
A) Unchanged B) halved C) doubled D) quadrupled
16. In a Young’s double – slit experiment instead of taking slits of equal width, one slit is
made twice as wide as other, then in the interference pattern:
A) The intensities of both the maxima and the minima increases
B) The intensity of the maxima increases and minima has zero intensity
C) The intensity of maxima decreases and that of minima increases
D) The intensity of maxima decreases and the minima has zero intensity
17. Two polaroids are oriented with their transmission axes making angle of 30 with each
other. The fraction of incident unpolarised light is transmitted
A) 37% B) 37.5% C) 3.36% D) 36.5%
18. In YDSE light containing wavelength 400 nm and 560 nm is used. The distance between
slits is 0.1 mm and distance between the plane of the slits and the screen is 1.0 m. The
minimum distance between two successive regions of complete darkness is :
A) 24 mm B) 56 mm C) 14 mm D) 28 mm
19. A ray incident at an angle of incidence 600 enters a glass sphere of refractive index
  3. This ray is reflected and refracted at the farther surface of the sphere. The angle

between reflected and refracted rays at the surface is

A) 900 B) 600 C) 700 D) 400

20. In Young’s double slit interference experiment the wavelength of light used is 6000 A . If
the path difference between waves reaching a point P on the screen is 1.5 microns, then
at that point P

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A) Second bright band occurs B) Second dark band occur
C) Third dark band occur D) Third bright band occur
SECTION-II

(NUMERICAL VALUE ANSWER TYPE)

This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.

21. In Young’s double – slit experiment, the separation between two slits d and wavelength
of light  . The intensity of light falling on slit 1 is four times of light falling on slit 2.
If d=  the number of local maxima that the screen will contain will be:
22. Unpolarized light of intensity 32Wm–2 passes through three polarizers such that
transmission axes of the first and second polarizer makes and angle 30° with each other
and the transmission axis of the last polarizer is crossed with that of the first. The
intensity of final emerging light will be (Wm –2)
23. In a single slit diffraction, the width of slit is 0.5 cm, focal length of lens is 40 cm and

wave length of light is 4890 A . The distance of first dark fringe is P 105 m , then the
value of P _______
24. Two identical coherent sources are placed on a diameter of a circle of radius R at
separation x (<<R) symmetrically about the centre of the circle. The sources emit
identical wavelength  each. The number of points on the circle with maximum
intensity is  x  5 
25. A parallel beam of wavelength   4500 A0 passes through a long slit of width 2 104 m .
n
The angular divergence for which most of the light is diffracted is 10 5 rad , then the
4
value of n is____
26. The distance between the first and the sixth minima in the diffraction pattern of a single
slit is 0.5 mm. The screen is 0.5 m away from the slit. If the wavelength of light used is

5000 A . Then the slit width will be P  101 mm , then the value of P _______

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10
27. Light of wavelength 5000  10 m is incident normally on a slit. The first minimum of the
diffraction pattern is observed to lie at a distance of 5mm from the central maximum on
a screen placed at a distance of 3 m from the slit. Then the width of the slit is P  102 cm ,
then the value of P _______
28. In a Young’s doubles slit experiment, 12 fringes are observed to be formed in a certain
segment of the screen, when light of wavelength 600 nm is used. If the wavelength of
light is changed to 400 nm, number of fringes observed in the same segment of screen is
given by:
29. The yellow component of light from a helium discharge tube (  = 587.5 nm) is allowed
to fall on a plane containing parallel slits that are 0.2 mm apart. A screen is located so
that the second bright band in the interference pattern is at a distance equal to 10 slit
spacings from the central maximum. The distance between the source plane and the
screen is (in cm)

30. A screen is placed 50 cm from a single slit, which is illuminated with 6000 A light. If
distance between the first and third minima in the diffraction pattern is 3.0 mm, then the
width of the slit is P  101 mm , then the value of P _______
CHEMISTRY MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

31. Fe4 [Fe(CN)6 ]3 a blue coloured complex. Average oxidation number of Fe in Fe4 [Fe(CN)6 ]3
is ‘a’, oxidation state of central iron atom ‘b’, oxidation state of counter iron atom ‘c’;
a,b,c are respectively:
5 5 18 18
(A)  , 2, 3 (B)  , 3, 2 (C)  , 2, 3 (D)  , 3, 2
2 2 7 7
32. Which of the following ligands does not form metal-nitrogen bond when bonded with
metal?
(A) EDTA 4 (B) en (C) Gly1 (D) acac1

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33. Which of the following complexes is example of strongest reducing reagent?
(A) [Co(CN) 6 ]4 (B) [Co(CN) 6 ]3 (C) [Ag(CN) 2 ]1 (D) [Cu(CN) 4 ]3
34. Which of the following complexes would not show stereoisomerism?
(A) Bis Gly  Platinum (II) (B) Bis  en  Pt  II  ion

(C) Tris Gly  Pt  IV  ion (D) Tris en  Pt  IV  ion

35. A solution is prepared containing a 2 : 1 mol ratio of dibromoethane  C2 H 4 Br2  and
dibromopropane  C3 H 6 Br2  . What is total vapour pressure of the solution assuming ideal
behaviour?
Vapor pressure  mm Hg 

C2 H 4 Br2 173
C3 H 6 Br2 127
(A) 300 mm Hg (B) 142 mm Hg (C) 150 mm Hg (D) 158 mm Hg
36. Which of the following is a correct Irving – Williams order? (Tendency of complex
formation)
(A) Mn 2  Fe2  Co 2  Ni 2 (B) Ni 2  Co 2  Fe 2  Mn 2
(C) Fe 2  Mn 2  Ni 2  Co 2 (D) Co 2  Mn 2  Fe2  Ni 2
37. Select most stable complex?
3 3
(A) Co  NH 3 6  (B) Co  NH 3 2  en 2 
3 3
(C) Co  NH 3  4  en   (D) Co  en 3 

38. Among the following metal carbonyls, the C – O bond is strongest in

  2
(A)  Mn  CO 6  (B) Cr  CO 6  (C) V  CO 6  (D) Ti  CO 6 

39. The V – C distance in V  CO 6  and V  CO 6  are respectively (in pm) are:

(A) 200, 200 (B) 200, 193 (C) 193, 193 (D) 193, 200
40. For a complex ( d 6 - configuration) having  0  25000cm 1 and P  15000cm 1 , the crystal
field stabilization energy is
(A) 30, 000cm 1 (B) 60, 000cm 1 (C) 30, 000cm 1 (D) 60, 000cm 1

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41. For an octahedral complex, which of the following d electron configuration will give
maximum crystal – field stabilization energy ?
(A) High spin d 6 (B) Low- spin d 4 (C) Low spin d 5 (D) High – spin d 7
2
42. If the formation constant of Cu  NH 3 4  is 2 103 , then its dissociation constant is

(A) 5 104 (B) 2 103 (C) 5 102 (D) 0.2 103


43. The number of geometrical isomers for octahedral CoCl4  NH 3 2  , square planar

 AuBr2Cl2  and  PtCl2  en   are

(A) 2, 2, 2 (B) 2, 2, no isomerism

(C) 3, 2, 2 (D) 2, 3, no isomerism
44. Which of the following statements is correct ?
(A) Geometrical isomerism is not observed in complexes of C.N.4 having tetrahedral
geometry
(B) Square planar complexes generally do not show geometrical isomerism
(C) The square planar complex of general formulae Ma3b or Mab3 exhibits cis – trans
isomerism
(D) The platinum glycinato complex,  Pt  Gly 2  does not show geometrical isomerism

45. Select correct about PtCl 4 .4NH3 complex salt :

(I) All the chlorides are bonded by primary valency
(II) All the chlorides are bonded by secondary valency
(III) All the NH 3 are bounded by secondary valency
(IV) Half of the chlorides are bonded with secondary valency
(A) I, III (B) III, IV (C) II, III (D) only III
46. Which of the following has the highest molar conductivity under similar conditions?
(A) Diamminedichloroplatinum (II) (B) Tetraaminedichlorocobalt (III) chloride
(C) Potassium hexacyanoferrate (II) (D) Hexaaquachromium (III) chloride
47. If excess of AgNO 3 solution is added to 100 mL of a 0.024M solution of dichloro
bis(ethylene diamine) cobalt (III) chloride, how many mole of AgCl be precipitated?
(A) 0.0012 (B) 0.0016 (C) 0.0024 (D) 0.0048

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48. A complex K n [MnF6 ] has magnetic moment 4.9 B.M. what will be the oxidation state of
Mn and the value of n?
(A) Mn(II); n=4 (B) Mn(III);n=3 (C) Mn(IV);n=2 (D) Mn(V);n=1
49. Which of the following do not obey 18 e rule?
4
(A) Fe  CO 5 (B)  Ni  CO  4  (C) V  CO 6  (D)  Fe  CN 6 

50. Percent of ‘P’ character of the hybrid orbital’s of Ni 2 used in the formation of the
2
complex  Ni  CN 4  is

(A) 50 (B) 33 (C) 25 (D) 100

SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.

51. The relative lowering of vapour pressure casued by dissolved 71.3 g of a substance in
1000 g of water is 7.13  103. The molecular mass of the substance is:
52. The ratio of the value of any colligative property for K 4  Fe  CN 6  to that of
Fe4  Fe  CN 6 
3
solution is ‘x’ then 100 x  ____

53. Compound pbCl4 .6 H 2 O is a hydrated complex; 1 m aqueous solution of it has freezing point
269.28 K.Assuming 100% ionization of complex, calculate the number of ions furnished
by complex in the solution.
54. Osmotic pressure of a solution is 1.5 atm. The density of solution is 1.1g / cm3 . osmotic rise
is_________. 1 atm  76 cm Hg , d Hg  13.6 g / cm 3 

55. For the complex ML2 , stepwise formation constants for M  L  ML and ML  L  ML2 are
4 and 3 respectively. Hence, overall stability constant for M  2 L  ML2 ,is
56. The number of bridged carbonyl groups in Mn2  CO 10 is :

57. The number of unpaired electrons in eg orbitals of iron in K 4  Fe  CN 6  is_______


58. How many geometrical isomers are possible for  Pt  NO 2   NH 3  NH 2OH  Py  ?

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59. One molal aqueous solution of urea freezes at 1.86 0 C Aqueous solution of Cn H 2 n On 36% by

mass of water freezes at 3.720 C. what is the value of n?

60. The number of stereoisomers possible in Ma2b2 c2 are
MATHEMATICS MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

61. The number of ways of permuting the letter of the word DEVIL so that neither D is the
first letter nor L is the last letter is
1)36 2)114 3)4 4)78
62. In the word ‘ENGINEERING’ if all ‘E’s are not together and N’s come together then
number of permutations is
9! 7! 9! 7! 9! 7! 9! 7!
1)  2)  3)  4) 
2!2! 2!2! 3!2! 2!2! 3!2!2! 2!2!2! 3!2!2! 2!2!
63. I. The number of ways in which 4 letters can be posted in 5 letter boxes is 45 ways.
II. If words are formed by taking only 4 at a time out of the letters of the word
PHYSICS, then the number of words in which Y occur is 288. Which of the above
statements is correct
1)only I 2)only II 3)Both I and II 4)Neither I nor II
64. Assertion (A) : The number of ways of arranging 6 boys and 5 girls alternately at
circular table is 0
Reason (R) : To arrange boys and girls alternately at a circular table, they should be
equal in number.
1)A is true, R is true and R is the correct explanation for A
2)A is true, R is false and R is the not correct explanation for A
3)A is true, R is false
4)A is false, R is true.
65. The number of ways that all the letters of the word SWORD can be arranged such that
no letter is in its original position is
1)44 2)32 3)28 4)20
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66. If the set {1, 2, 3, …….., 12} is to be partitioned into three sets A, B, C of equal size
such that A  B  C  S , A  B  B  C  A  C   then the number of ways of partitioning
S is
12! 12! 12! 12!
1) 2) 3) 4)
(3!)4 3!(4!)3 3!(3!)4 (4!)3

67. The number of non-negative integral solutions of x1  x2  x3  x4  n (where n is a non

negative integer) is
1) ( n 3) C3 2) ( n 5) C5 3) ( n 4) C4 4) ( n 6) C6
68. The number of integral solution to the system of equations x1  x2  x3  x4  x5  20 and
x1  x2  15 when xk  0( k  1, 2,3, 4,5) is

1)300 2)350 3)336 4)316

69. Given that ‘n’ is odd, the number of ways in which three numbers in A.P can be selected
from 1,2,3,……,n is
(n  1)2 (n  1)2 (n  1)2 (n  1)2
1) 2) 3) 4)
2 4 2 4
70. A1 , A2 , A3 , A4 , A5 lie on L1 . B1 , B2 , B3 , B4 , B5 lie on L2 is parallel to L2 . If these points are

joined and lines are formed, the maximum number of points of intersection that will
form between the lines is
1)80 2)100 3)120 4)240
71. Nine points lie in a plane forming a square as shown

If N is the number of triangles with positive area, having three of these points as
vertices, then the last digit of N is
1)6 2)7 3)8 4)9

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72. Let x1 x2 x3 x4 x5 x4 x3 x2 x1 be in nine digit palindrome such that either the sequence

( x1 , x2 , x3 , x4 , x5 ) is a strictly ascending or strictly descending. Then the number of such

palindromes is
1) 9 9 P4 2) 3 9 P5 3) 9 9 C5 4) 3 9 C5
73. 7 boys be seated at a round table. X is the number of ways in which two particular boys
are next to each other, Y is number of ways in which they are separated, then X  Y is
1)500 2)600 3)700 4)720
2
4
 k .Ck 
74. If Ck denotes 4 Ck , then the value of 2   is
k 1  C k  C 4  k 

1)12 2)13 3)14 4)15

75. The number of integral solution of the equation x1 x2 x3 x4  210 is
1) 44 2) 6.4 4 3) 8.44 4) 10.4 4
76. Eight persons are to be transported from city A to city B in the three cars of different
makes. If each car can accommodate at most three persons, then the number of ways, in
which they can be transported, is
1)1120 2)3360 3)1680 4)560
77. If the number of 5 digit numbers with distinct digits and 2 at the 10th place is 336K,
then K=
1)8 2)6 3)4 4)7
78. Team A consider of 7 boys and n girls and Team B has 4 boys and 6 girls. If a total of 52
single matches can be arranged between these two teams when a boy plays against a boy
and a girl plays against a girl, then n is equal to
1)5 2)6 3)2 4)4
79. If the sides AB, BC and CA of triangle ABC have 3,5 and 6 interior points respectively,
then the total number of triangles that can be constructed using these points as vertices is
equal to
1)240 2)364 3)360 4)333

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80. Two families with these members each and one family with four members are to be
seated in a row. In how many ways can they be seated so that the same family members
are not separated ?
1) 2!3!4! 2) (3!)3 (4!) 3) (3!)2 (4!) 4) 3!(4!)3
SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.s

81. If all the six digit numbers x1 , x2 , x3 , x4 , x5 , x6 with 0  x1  x2  x3  x4  x5  x6 are arranged in

the increasing order, then the sum of the digits in the 72th number is
82. Let x and y be distinct integers where 1  x  25 and 1  y  25 . Then, the number of ways
of choosing x and y such that x  y is divisible by 5 is
83. The number of 5-digit natural numbers, such that the product of their digits is 36 is
84. The total number of 3-digit numbers, whose greatest common divisor with 36 is 2 is
85. The number of six letter words (with or without meaning) formed using all the letters of
the word VOWELS so that all the consonants never come together is
86. All the arrangements, with or without meaning of the word FARMER are written
excluding any word what has two R appearing together. The arrangements are listed
serially in the alphabetic order as in the English dictionary. Then the serial number of
the word FARMER in this list is
87. If a & b are non co linear vector and a  b  3 then (2 a  5b ).(3a  b) 

88. If A is ( x1 , y1 ) where x1  1 on the curve y  x 2  x  10 . The tangent at A cuts the x-axis at

B, The negative value of OA . AB is
89. Let u  i  j, v  i  j , w  i  2 j  3k . If n is a unit vector such that u.n  0, v.n  0, then

w .n 
90. If a & b are unit vectors and c satisfies 2  a  b   c  b  c, then the max. value of a  c . b is

SR.IIT_*CO-SC Page. No. 13