PT. ACSET INDONUSA, TBK | OQ COMMISSIONING = oe Somer PROCEDURE REV. DOC. NO. PAGENUMBER | YANTAI-SOMA-MEC-PRC- CHEMICAL CLEANING | | me | ALKALINE ACID CLEANING aaa | AND PASSIVATION * PTSOMA DAYA UTAMA SOMA PT PLN (PERSEROD ae OWNER PT. SOMA DAYA UTA CONTRACTOR —_: PT. ACSET INDONUSA PROJECT NAME. SOMA Karimun CFSPP &31 MW LOCATION ‘Tanjung Balai karimun, Kepulauan Riau INDONESIA. Rev. | Description Prepared ‘Checked Approved PRASADA SAMYA. ACSETINDONUSA | SOMA DAYA UTAMA MUKTI = [ear Wadi Willy Reerarlhana on Mei 2024 02 Mei 2024Procedure Chemical Cleaning Boiler Alkaline Acid Cleaning and Passivation SOMA 2X31MW Coal Fire Power Plant Project ORIGINATED BY REVIEWED BY APPROVED DISTRIBUTION BY Edy Hadi M. Indra $ Makmur CC Dept-Head MR Dir Op REV | IssuED | EFFECTIVE NO. DATE. ATE. a = BRIEF OF REVISION. 30 APR-2024 */36 APR-2024TABLE Of CONTENT No Description Page Cover 1 of 23 Table of Content Lof 23 10 Seope 1 of 23 2.0 Purpose Lof 23 3.0 Reference Document 1 of 23 40 Responsibility Tof 23 5.0 Cleaning Scope 1 of 23 60 Necessary precondition checklist 20f23 70 Major Equipment and tools for Chemical cleaning 3 of 23 80 Checklist the chemical for boiler FoF 23 90 ‘Demin water estimation for chemical cleaning 50F23 10.0 | Waste Water Estimation Sof 23, 11.0 | Chemical Cleaning Sequence 30f23 12.0 | Boiler water flushing and alkali Sof 23, 13.0 | Pre-Heating 6 0f 23 14.0 | Alkali Cleaning (Degreasing) 60f 23 15.0” | Alkali Cleaning Drain Tof23 16.0 | Rinsing after Alkali cleaning. Tof23 17.0__ | Pre-Heating Tof23 18.0 | Boiler Acid Cleaning Tof 23 19.0 | Acid Cleaning Drain 8 of 23 20.0 | Rinsing after acid cleaning 8 of 23 21.0 __| Pre-heating 9 of 23 22.0 __| Passivation Fo 23 23.0 | Quality Control 9 of 2B 24.0 | Requirement of The Concemed Laboratory Test 100f3 25.0 | Work after chemical cleaning. 11 of 3 26.0 | Chemical Cleaning Waste Water Treatment 11 of 23 27.0__| Safety Precaution 11 of 231.0 SCOPE This procedure covers the chemical cleaning of boiler pressure part, Boiler Internal Piping (PLTU SOMA 2X3IMW KARIMUN) Coal-fired Power Plant Project 2.0 PURPOSE The purpose is to clear the impurities from inner surface of the boiler water/steam pipe line, such as metal debris, oxide, oil, dust, and metal oxide produced in inner surface during equipment manufacturing and installation, and to ensure the water and steam quality of boiler water during operation and to apply a foundation to generate protective coating of Fes Os that can prevent further corrosion of inner surface at inner boiler heating surface. 3.0 REFERENCE DOCUMENT Boiler Operation Manual Book (DL-T794 2012) 4.0 RESPONSIBILITIES 4.1 The Boiler Area Manager shall make sure that this instruction is implemented at site. 42 The Boiler Superintendent and engineers are responsible for implementation of this instruction. He has to check that requirement in chemical cleaning is properly adhered to as indicated in this instruction, 4.3 The chemical cleaning Supervisor is responsible for the arrangement of all processes involved in the execution of chemical cleaning work. He has to make sure that standard code practice is applied accordingly. 4.4 The QA/QC personnel in charge of chemical cleaning are responsible in assuring that the requirement in this procedure are properly implemented and followed. 5.0 CLEANING SCOPE. ‘The system will be cleaning are: ‘S:I” Boiler proper: Economizer, Steam Drum, Furnace wall, Furniace Low Header, Fumace Drain line.6.0 Necessary Precondition Check 6.1 The following systems must be normal and can be put be operation separately and have 63 corresponding operation measures. » 2) 3) 4) 5) 6) 0) 8) Demineralized water plant/Water treatment plant is in operation. Auxiliary boiler or auxiliary steam system is ready to supply steam with pressure 1.0 Mpa (temporary auxiliary boiler). Service water system. Industrial waste water system. ‘The unit drainage pit system. Nitrogen protection system for boiler (if needed). Boiler wall temperature measuring point. Make orifice plate for two main down comers put inside of steam drum with diameter @ 50 mm, plate thickness 20 mm (if needed). The Boiler have been Hydro testing, Boiler body have been insulated properly, Furnace wall area is satisfied with the seal ‘Temporary system Requirement. 1) 2) 3) 4) 5) 9) 8) 9) Finish the installation of the all-temporary pipe line and equipment according to the drawing. Finish trial operation of rotary machineries under regulation. The temporary system has been finished heat insulation with correlative steam system (ifneeded). The temporary system has made 5 Bar pressure testing; all the test results are up to standard, The pressure gauge of valves that connected temporary pipe with economizer inlet pipe and the bottom blow down tube should be more than 10 Bar. The copper core valve should do not be installed at the chemical cleaning system. Finish the installation and commission of electrical and control system (permanent system) ‘Valves at the temporary system have been disassembled and checked, all valves are up to standard. The temporary level gauge of drum has been installed; the temporary level indicator of drum is used during acid cleaning stage. Reliable communication equipment and water level monitoring equipment between ddrunt level point and ground level chemical cleaning platform. The cyclone separator inside the drum is not installed during chemical cleaning. 210) Name plates for valves within the scope of cleaning system have been hanged up. 11) Filling demineralized water to superheater + ammonia (PH Control = 9.0~9.5) 12) The laboratory test room at site is prepared ready and could be put in to the operation. All the instrument and chemical analyzers are qualified subject for calibration. 13) Avoid Cleaning liquid corrosion to all the pipes and equipment not take part in the cleaning by closing valves and blinding plates. 14) Discharge facilities for cleaning liquid waste have been fixed. As per project condition 15) Do not install The Check Valve on the feed water pipe of the Economizer, or enforce open the check valve if the check valve has been installed. 16) Close the primary and secondary valves of boiler sampling tube, dosing tube and instrument tubes. 17) The valves in temporary system are checked and qualified subject to disassembled. 6.4 The inside of steam drum shall be inspected before the chemical cleaning started by Client (ACSET, SOMA, & PLN) 6.5 Test plate will be put in the inside of steam drum and at least 3 pes. 6.6 The test plates shall be weighing and measure the dimension witnesses by Client. 6.7 The dimension of test plate is 20x10x3mm the material should be similar with the boiler wall, tube and economizer. 6.8 The acid inhibitor must be checked and tested in the laboratory before acid cleaning. 6.9 Estimation for the effectiveness of corrosion protection. If the corrosion rate is less than 1.0 mg/em?h, the protection effect can be judged as normal. 6.10 Chemical Cleaning Succeed No rust no dust no grease no oil and Clean. And layer Film 7.0 Major Equipment and tools use for chemical cleaning No. Description Specification Qty. Purposed 1} Circulation tank Sm Tunit Mixing tank 2 | Circulation pump: 100m*/h H 80m 75kw 2unit Circulation pump 3 | Temporary valves Various 1 Lot For temporary 4 | Auxiliary Boiler 3ton 1 Lot For heating 5Water Volume in the equipment (Estimation) [No ‘Area Volume [1 | Beonomizer 15,02 [2] Steam Drum ot fet 7 3 | Water wall 32,35 4 | Temporary system 16 TOTAL 95,37 8.0 Check list of Chemical. 8.1 Chemical for boiler chemical cleaning and Quantity volume estimation 90 m3 ‘No. Chemical Purity of | Concentration | Qty kg | Purposed Chemical 1} Tsp (NasPOs) 98% 1% O18 ke 2 | Dsp (NaxHPO.) 98% 0.8% 735kg | Alkali Detergen 100% 0.01 9kg | Cleaning 1 | Inhibitor 100% 0.2-0.3% 180 kg Acid 2 | Citric Acid (CeHisO7) 98% 3-4% 2755 kg | cleaning 4. | Citric Acid (CoHsO7) 98% 0.2% 184 kg se ‘Ammonia (NH,OH) 25% 025% — | 720k | Passivation ‘Sodium Nitrite (NaNO:) 98% 02% 183 kg9.0 Demineralized Water Estimation for Chemical Cleaning [ No. | Cleaning Stage ‘Water Quantity (90 ton) ] [a Water Flushing 2X 90 = 180 ton 2 Alkali 1X90 = 90ton | 3 Water flashing after alkali 2X90 =180 ton 4 ‘Acid Cleaning 1X90= 90 ton 3 ‘Water flashing after acid cleaning 2X 90= 180 ton 6 Citrite acid Rins and passivation 1X90=90 ton I Total (810 m°) | Table 1. Demin Water Estimation 10.0 Waste Water Estimation No. Cleaning Stage ‘Water Quantity (90 ton) ] jr ‘Alkali TX90=90ton 1 2 Water flashing after alkali 2X 90= 180 ton | [3 ‘Acid Cleaning 1X90=90ton 4 Water flushing after acid cleaning 2X 90 =180 ton [5 Citrite acid Rins and passivation 1X90=90ton | Total (630m) Table 2 Waste Water Estimation 11.0 Chemical Cleaning Sequence. Boiler water flushing — Alkali Cleaning — Flushing after alkali — acid cleaning — Flushing after acid cleaning —-Rinsing and Passivation. 12.0 Boiler Water Flushing 12.1 Flushing process flow: Fill Pump-Superheater - boiler drum- Furnace Wall - Furnace Header Furnace Drain Line Temporary pipe- Drain pit. (Estimation 30m) 12.2 Flushing process flow: Cleaning Pump- Economizer - boiler drum- Furnace Wall- ‘Fumace Header- Furnace Drain line Temporary. pipe- Drain pit. 12:3 Fill Demineralized Start filling water pump to fill Boiler, Flush Economizer, Steam Drum and Furnace wall, drain by opening blow down valves. 512.4 Control the drum level until 70%. 12, Continue flushing until the sample from sampling point is visually clean without suspended substance, pH 6 - 8 and then continue circulation (Visually clear water almost same before and after the flushing process and analyst value at ph 6-8 ) and turbidity <20 NTU. 13.0 Pre heating Start Auxiliary boiler — Circulation tank - Continue Circulation 14.0 Alkali Cleaning (DEGREASING) 14.1 Preheat The Boiler Furnace wall before acid cleaning, adjust the level of steam drum level 70%. Raise slowly the boiler Furnace wall temperature. Supervise boiler wall and drum metal temperature. The drum metal temperature difference is no more than 500C between upper part and lower part (bottom part which filled with water and ‘upper part without water). When the boiler Furnace wall tubes metal temperature reaches 60 ~ 700C stop heating. 14.2 Before admitting alkaline to the boiler, check to be sure that all drum vent valves are ‘open elevation vent pipe at least Im above the top of steam drum. 14.3 Filling chemical and Alkali cleaning Acid Cleaning flow chart. 144 Step circulation pump- economizer Steam Drum - Furnace wal Furnace Low Header-Furnace Drain line - circulation pump. And circulation tank 14.5 Start one circulating of water with circulation pump, control water temperature to 60 ~ 700C. Adjust the level of steamdrum until 70%. 14.6 Filling Chemical Material to Circulation Tank TSP 1% and DSP 0.8% and Detergent 0.01%. Continue Circulation after finish adding chemical start taking first time sample to read after one hour. 14,7 Alkali cleaning requirement. The drum level after filling alkaline, Adjust cleaning solution temperature to 60-700C by auxiliary steam heating. Analyzed solution sample for alkaline strength and oil content concentration in return tube Control and record the temperature periodically 14.8 Alkaline cleaning end point estimation. Run the Circulation pump within 6 - 8 hours continuously. End the alkaline cleaning when there is basically stable of oil content, alkaline concentration for 2 times check.15.0 Alkali Cleaning Drain. Stop Circulation Pump. Inject nitrogen (if needed) into the boiler and slowly open the drain valves to the temporary pond, until finish 16.0 Ri 16.1 Flush after alkali cleaning is intended to wash away the ferrous dregs, oxide and ing after Alkali cleaning. remaining acid liquid and is an importance stage of chemical cleaning. To avoid metal surface after acid cleaning from creating staining, the metal surface should be not exposed in the air for a long time. After confirming the alkali cleaning is over, the following work should be done: 16.2 Supply demineralized water to cleaning system, 16.3 Open general drain valve, economizer drain valve, drum emergency drain valve, bank manifold, and temporary valve to discharge the acid cleaning liquid to ‘Temporary pond. 16.4 _ After completely discharging the cleaning liquid in boiler, flush the boiler. 16.5 Fill Demin Water, start cleaning pump to flush boiler. Flushing flow pass, cleaning pump, economizer, Steam Drum. Furnace wall, Furnace low header, Furnace Drain line, temporary pipe, too Temporary Pond 16.6 Control drum and level 70%. And Continue Circulation 16.7 Take sample from sampling valve analyzing pH flushing liquid. The flushing is over when flushing liquid pH = 7 ~ 9 The flushing should be finished within 4 hour in normal condition 17.0 Pre heating. Start Auxiliary boiler — Circulation tank- Continue Circulation 18.0 Boiler Acid Cleaning. 18.1 Preheat Boiler Furnace wall before acid cleaning, adjust the level of steamdrum level 70%. Raise slowly the boiler Furnace wall temperature. Supervise boiler wall and drum metal temperature. The drum metal temperature difference is no more than 500C between upper part and lower part (bottom part which filled with water and upper part without water). When the boiler Fumace wall tubes metal temperature reaches 60 ~ 700C stop heating.19.0 20.0 18.2 Before admitting acid to the boiler, check to be sure that all drum vent valves are open. Elevation vent pipe at least Im above the top of steam drum. 18.3 _ Filling chemical and acid cleaning flow chart. 18.4 Step circulation pump-economizer-Steam Drum - Furnace wall - Furnace Low Header - Furnace Drain line - circulation pump. 18.5 Start one circulating of water with circulation pump, control water temperature to 60 ~ 700C. Adjust the level of steamdrum until 70%. 18.6 Fill 0.2 - 0,3% acid inhibitor to mixing tank, wait for 1 hour and then add Citric Acid 3-4%. Take sample from return tube, Analyzed Citric Acid concentration, the Citric Acid concentration is 3-4%. After finish adding chemical start taking first time sample to read after one hour. 18.7 Acid cleaning requirement. Control the drum level after filling acid, Adjust cleaning solution temperature to 60~70°C by auxiliary steam heating. Analyzed solution sample for acid strength and iron concentration in return tube and record the temperature periodically. 18.8 Acid cleaning end point estimation. Run the Circulation pump within 6 - 8 hours continuously. End the acid cleaning when there is basically stable of ferrous ion, ferric ion and Citric Acid concentration for 2 times check. End the acid cleaning when iron oxide of the monitoring sample tube has been cleaned. Acid Cleaning Drain. Stop Circulation Pump. Inject nitrogen (if needed) into the boiler and slowly open the drain valves to the temporary pond until finish Rinsing after acid cleaning. 20.1 20.2 203 Flush after acid cleaning is intended to wash away the ferrous dregs, oxide and remaining. acid liquid and isan importance stage of chemical cleaning. To avoid ‘metal surface after acid cleaning from creating staining, the metal surface should be not exposed in the air for a long time, After confirming the acid cleaning is over, the following work should be done: Supply demineralized water to cleaning system ‘Open general drain valve, economizer drain valve, drum emergency drain valve, bank manifold, and temporary valve to discharge the acid cleaning liquid to ‘Temporary pond.21.0 22.0 23.0 204 After completely discharging the cleaning liquid in boiler, flush the boiler. 20.5 Fill Demin Water, start cleaning pump to flush boiler. Flushing flow pass, cleaning pump, economizer, Steam Drum. Furnace wall, Furnace low header, Furnace Drain line, temporary pipe, to Temporary Pond 20.6 Control drum and level 70%. And Continue Circulation 20.7 Take sample from sampling valve analyzing pH and iron ion of flushing liquid. The flushing is over when flushing liquid pH = 4.5 ~ 5.0. The flushing should be finished within 4 hours in normal condition. Pre heating. Start Auxiliary boiler — Water tank- Continue Circulation Passivation. 22.1 222 22.3 224 After finish flushing, the cycle way must be as follow: cleaning tank~circulation pump-economizerboiler water wall-boiler drum-circulation pump - cleaning tank. Control drum level until 70%, control the water temperature at 60 ~ 700C by adjusting auxiliary steam pressure. Rinsing: Adding rinsing chemical to cleaning tank to make rinsing liquor add 0.2% Citric Acid. Use Ammonia to adjust pH to 3.5 ~ 4.0, keep the temperature 60~700C for 2 hours. When the ferrous ion is less than 400mg/I this step can end. If the ferrous ion is more than 400mg/I use demineralized water to replace the rinsing liquid until the ferrous ion is less than 400mg/1 Passivation: After rinsing use ammonia to adjust the pH up-to 9.0 ~ 10, add 0.2% sodium nitrite (NaNO2). Keep the temperature at 60~700C for 4-6 hours. Discharge the passivation liquor to unit drainage pit. Open manholes of drum to cool spontaneously, the safety measures must be taken after opening the manholes. Quality Control 23.1 22 ‘Test coupon for chemical cleaning During chemical cleaning process will be installed 3 test coupons to monitor with the same material as Water wall tube, Economizer in temporary pipe line with size 1,5” length 15 - 20cm. Visual check should be done before and after chemical cleaning. ‘Test coupon for pre-cleaning testPrior to Chemical Cleaning of Boiler, the test for corrosion shall be carried out to check and confirm the effectiveness of the corrosion inhibitor. Test coupon with size 20x10x3mm also should be done during chemical cleaning process and placed in ‘Temporary line and test coupon for chemical cleaning in return line. Calculation Using unit mg/m?.h 23.3 wa —w2 (mg) Corrosion Rate raat ie eeencrec aw) Jorrosion Rate (mg/cm?.h) ‘Surface area (cm? ) x Submerge time (h) WI = Weight before process W2 = Weight after process Submerge time = Total timing for acid cleaning The threshold for the corrosion rate are less than 8.0 g/em?.h In addition to the above judgment, the surface of the test coupon shall be visually checked for any pitting. Check Inspection after chemical Cleaning 1. Analys report 2. Test Coupon Report 3. Witness Check Inside Drum 4, Witness Check Inside Pipe Lower Header and Down Commer 24.0 Requirement of The Concerned Laboratory Test No.| Program Trem Standard Interval 1 | Water flushing | Visual & pit Delivery water is clear | 30min without impurity, pH 6-8 2 | Alkali Cleaning | Oil Content & ph Oil Content ppm 60 min 3 | Rinsing After pH pH69 30 min Alkali 4 | Acid cleaning | Citric Acid %, Fe | Citric acid Conc. 3-4%, Fe| 60min Cone. Until stable 3 | Flushing after |~ Appearance No particles basically 30 min acid cleaning pH 45 ~ 5.0 6 Rinsing pH, Fe pH3.0~ 4.0, Cone Fe <400 | 30min 10Mell a ~ Passivation pH pH> 9.5 60 min 25.0 Work after chemical cleaning. 26.0 27.0 25.1 Checking the chemical cleaning quality as the table below: [No Location/Area | Qty Description Remark 1 Around Tank Area | 3 | Test plate 20x10x3mm_| Sample of Economizer, waterwall. Steam Drum 3 | Test plate 20x10x3mm_ | Sample of Economizer, waterwall. 253 25.4 255 25.6 25.7 The test plate should be weighing and measure the dimension and witnessed by Client after chemical cleaning. Cleaning carefully the slag and splashing materials in the drum and lower headers. Remove the temporary system connecting with the permanent system and restore the permanent within 7 days. When the interval is more than 20 days between finishing the chemical cleaning, and blowing out, following corrosion prevention measures to be taken: When freezing is not a problem fill the boiler with demineralized water containing 10 ppm of ammonia and 100 ppm of hydrazine, the pH of the solution should be approximately 9 ~ 10. When freezing is a problem, the water is drainable circuits can be displaced with nitrogen and the unit lay-up under 0.3 ~ 0.5 bar nitrogen pressure. Auxiliary heat ‘may be applied to keep the non — drainable sections from freezing ‘Chemical Cleaning Waste Water Treatment. Acid cleaning and rinsing passivation waste are discharged to unit chemical pond. Waste and Water will be treated by a third party, or released. to sea according to standards PERMENLH 08/2009- Safety Precaution. 271 272 The chemical cleaning personnel must be qualified training. Complete and enough individual guard goods are prepared. The individual guard goods mainly include: rubber gloves, rubber shoes, protective glasses and protective mask. The temporary flush water pump and lime powder should be prepared at site. u273 274 275 276 217 278 279 27.10 27.11 27.12 27.13 Electric welding, fire source and smoking are prohibited on the boiler and in the field during chemical cleaning. High altitude work is prohibited above cleaning panel, temporary laboratory test and duty room to prevent matters dropping from high place. Enough foam and fire extinguishers should be prepared for chemical cleaning in field. The materials and tools for urgent repair and eliminating defect such as steel wire, and acid resistant rubber should be prepared. The lighting is enough in field. Make barricade from color tape around the boiler, pump room and cleaning tank, and the alarming signs with notable writing of “NO SMOKING AND FIRE” “NO ADMITTANCE EXCEPT ON BUSSINUSE” “DANGEROUS ACID LIQUID “ etc. Remove all unnecessary goods remained near the system and in the access or stair after the completion of installation to guarantee unblocks access. The personnel contacting acid and ammonia should be instructed in advand and wear acid resistant clothes with rubber hood, rubber shoes, rubber glove, protective glass, respirator and protective mask. All chemicals are qualified subject to check; the inhibitor is qualified subject to small scale test in field. Eye washer/Safety shower are prepared near the job site. The operation measures of satisfying alkali boiling-out process requirements have been mate. There should have doctors or the medical team with necessary goods and rescuing person on duty in field for first aid treatment. ‘There no open fire and strictly forbidden during acid cleaning. The handling and Storage of chemical materials should be following the requirement and MSDS application. 12Appendix 1 FLOW CHART CHEMICAL CLEANING BOILER EXECUTION STEP INJECT CRITERIA Clear Visual, pH 6-8 ‘Water Flushing Boiler Demin Water Turbidity < 20 NTU - Steam of Auxilary Temperature 60 70°C Pre heating Boiler Duration 3-4 hour ! = ae Duration 6-8 hours, Oil Fal Casing bret = reer Toti POS, pH Demin Water Clear Visual, pH 6-8 Steam of Auxilary “Temperarire 60—70°C Pre heating Boiler Deeaton 34 hour —— ‘Chie Acid 3 % Duration 6 8 hours, ‘Acid Cleaning Inhibier 02-03% ‘Aus couseakatoa se | Fe and ph —— aR Steam of Auxilary “Temperature 60~70°C Boiler aration 2-3 hour 02% Darton 24 hours 035% Phe 9.5 02% All Drained FINISH 13Appendix 2 TEMPORARY CHEMICAL CLEANING 4Appendix 3 REPORT TEST WATER DEMIN FIELD INSPECTION REPORT ‘WATER DEMIN TEST [Prom Date (ene Reported By [400 Wo. Starting Time : Location Sample Point |Oremical Location Concentration, Frequency |ouarntity line No No. Date/Time pH ‘Turbidity (FTU) Prepared by, 15REPORT CHEMICAL CLEANING FIELD INSPECTION REPORT ‘WATER FLUSHING PROCESS Acceptance Crters Vesaby Sample 5 Cear, pH 69 J>miect ‘Date latent ‘Reported By ho. Starting Tine |cocation Sample Pont: crema: Location \concentraton :~ Frequency Quantity lune Ne. Sample No. Date/Time pH ‘Turbidity (FTU) Remarc ao [Peporedby, [Checked [Mowovedby, _ [oprovedlby, __[Anproned by, ry (pr rome 16Appendix 5 REPORT CHEMICAL CLEANING [Prepared by, [checked by, [approved by, [approved by, [Approved by,Appendix 6 REPORT CHEMICAL CLEANING Prepared by, [Checked by, [Approved by, [Approved by, [Approved by, [pr psm 18Appendix 7 REPORT CHEMICAL CLEANING Fre I a]Appendix 8 REPORT CHEMICAL CLEANING Prepared by, [Checked by, [Approved by, [Approved by, [Approved by, 20Appendix 9 REPORT CHEMICAL CLEANING ‘PASSIVATION PROSESS pH 9~ 10, Visual Check of Black Layer OF Pipe fctene Reported By 2‘Appendix 10 REPORT CHEMICAL CLEANING pocmENT PT. PRASADA SAMYA MUR = [cuenta oem pase: [SEUSION: EIELD INSPECTION REPORT RESULT of TEST LABORATORY INHIBITO! 1LINSTALLED LOCATION Stari Temperate Eipored Time: 2Appendix 11 REPORT CHEMICAL CLEANING EIELD INSPECTION REPORT RESULT of COUPON TEST Code of Coupon: = Temperate = — i 20 3A 18 — == —= ————E— 23Appendix 12 oO LOG SHEET MIX BED A & B ACSET Date : Time Mix bed A Mix bed B Remark PH Conductivity SiOz Conductivity | Si02 | f | ‘Shit | Supervisi | Chemist AnalysisAppendix 13 Necessary Precondition Check Description OK/ Not Yet Remark Demineralized water plant/ Water treatment plant is in operation Auxiliary boiler or auxiliary steam system is ready to supply steam with pressure 1.0 Mpa (temporary auxiliary boiler) Service water system Industrial waste water system ‘The unit drainage pit system Nitrogen protection system for boiler (if needed) Boiler wall temperature measuring point 2) x] a} a Make orifice plate for two main down comers put inside of steam drum with diameter © 50 mm, plate thickness 20 mm (if needed) ‘Note: Prepared by, Checked by, Witness by, ‘Approved by, PRASADA SAMYA MUKTI PT. ACSETINDONUSA | PLN PUSERTIF PT SOMA DAYA UTAMA ‘Name: Date = He 25Appendix 14 MATERIAL SAFETY DATA SHEET DISODIUM HYDROGEN PHOSPHATE DIHYDRATE. Revision : 00 ___ Date: 05.03.2019 MSDS Number | 2054 1.1 Product Name _: DISODIUM HYDROGEN PHOSPHATE DIHYDRATE Synonyms + Sodium monohy drogen phosphate, Sodium phosphate dibasic Disodium phosphate CASNo. 10028-24-7 HS Code + 1835 29 90 Molecular Weight: 177.99 g/mol Hill: HINa,0,P *2 130 Chemical Formula: NaHPO,.2 H:0 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Not a hazardous substance or mixture according to Regulation (EC) No, 1272/2008. 2.2 Label elements Not a hazardous substance or mixture according to Regulation (EC) No, 1272/2008 2.3 Other hazards ‘This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPVB) at levels of 0.1% or higher. ‘Synonyms ‘Sodium monohydrogen phosphate, Sodium phosphate dibasic Formula 'NaHPO,.2H;0 Hill HNa;0,P* 2 H,0 Molecular weight: 177.99 g/mol CASNo. 10028-24-7 EC-No. 231-448-7 4.1 Deseription of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. “Iinbated = 7 ‘Af breathed in; move person into fresh’air If not breathing, vive artificial respiration: Consulta physician, {MSDS - DISODIUM HYDROGEN PHOSPHATE DINYDRATE. 4MATERIAL SAFETY DATA SHEET DISODIUM HYDROGEN PHOSPHATE DIHYDRATE Revision : 00 Date: 05.03.2019 MSDS Number : 2054 In case of skin contact Wash off with soap and plenty of water. Consult a physician In case of eye contact Rinse thoroughly with plenty of water for atleast 15 minutes and consult a physician If swallowed ‘Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician 4.2 Most important symptoms and effects, both acute and delayed ‘The most important known symptoms and effects are described in the labelling (see section 22) and/or in section 1] 4.3 Indication of any immediate medical attention and special treatment needed No data available 5.1 Extinguishing media ‘Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Oxides of phosphorus, Sodium oxides 5.3 Advice for firefighters ‘Wear self-contained breathing apparatus for firefighting if necessary ‘Se Further information No data available 6.1 Personal precautions, protective equipment and emergency procedures ‘Avoid dust formation. Avoid breathing vapours, mist or gas. For personal protection see section 8, 62 Environmental precautions ‘No special environmental precautions required 6.3 Methods and materials for containment and cleaning up Sweep up and shovel, Keep in suitable, closed containers for disposal 64 Reference to other sections For disposal see section 13. | ‘Section 7 - Handling and Storage | 7.1 Precautions for safe handling Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 22, [MSDS ~ DISODIUM HYDROGEN PHOSPHATE DHVYORATE 2TY DATA T DISODIUM HYDROGEN PHOSPHATE DIHYDRATE [Revision : 00 Date: 05.03.2019 MSDS Number : 2054 7.2 Conditions for safe storage, including any incompatibilities ‘Keep container tightly closed in a dry and well-ventilated place. Store in cool place. 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated ‘Section & - Exposure Controls, Personal Protection 8.1 Control parameters 8.2 Exposure controls Appropriat engineering controls General industrial hygiene practice Personal protective equipment Eye/face protection Use equipment for eye protection tested and approved under appropriate govemment standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves Gloves must be inspected prior o use. Use proper glove removal ‘technique (wathout touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. ‘The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it Full contact ‘Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested: Dermatril® ‘Splash contact Material: Nitile rubber Minimum layer thickness: 0,11 mm. Break through time: 480 min Material tested:Dermatril® Body Protection Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place., The type of protective equipment must be ‘selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection ‘Respiratory protection is not required. Where protection from nuisance levels of dusts are desired, use type N95 (US) or type PI (EN 143) dust masks. Use respirators and components tested and approved under appropriate government standards such as NIOSH. (US) or CEN (EU). ‘Control of environmental exposure [No special environmental precautions required. an nN ann RIRInaGaateeanaiasiaiaEEaeEaEeEEEEEeEEEEEEEEmenemeeE -MSDS~ DISODIUM HYDROGEN PHOSPHATE DIHYDRATEMATERIAL SAFETY DATA SHEET DISODIUM HYDROGEN PHOSPHATE DIHYDRATE Revision : 00 Date: 05.03.2019 MSDS Number 2054 ‘Section 9 - Physical and Chemical Properties 9.1 Information on basic physical and chemical properties Appearance Form: solid Colour: white Odour codourless Odour Threshold Not applicable pH 9,-9.4 at 50 gf 20°C Melting point/reezingpoint 92,5 °C Elimination of water of crystallisation. Inital boiling point and boiling range No data available Flash point Not applicable Evaporation rate No data available Flammability (solid, gas) ‘The product is not flammable Upper/lower flammability or Not applicable explosive limits Vapour pressure ‘No data available ‘Vapour density ‘No data available Relative density 2,1 glem’ at 20°C Water solubility 93 g/l at 20°C Partition coefficient: noctanolwater No data available ‘Auto-ignition temperature ‘No data available ‘Decomposition temperature 295°C Viscosity ‘No data available Explosive properties No data available ‘Onidizing properties none 9.2 Other safety information Ignition temperature not combustible Bulk density ca 850 = 1,000 kg/m 10.1 Reactivity No data available 10.2 Chemical stability ‘Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions ‘No data available 104 Conditions to avoid ‘No data available 105 Incompatible materials ‘Strong oxidizing agents 10.6 Hazardous decomposition products ‘Hazardous decomposition products formed under fire conditions. ~ Oxides of phosphorus, Sodium oxides ‘Other decomposition products - No data available In the eventof fire: see section 5 ee nn epee |MSOS ~ DISODIUM HYDROGEN PHOSPHATE DIHYDRATE.MATERIAL SAFETY DATA SHEET DISODIUM HYDROGEN PHOSPHATE DIHYDRATE Revision : 00 Date: 05.03.2019 MSDS Number 2054 | Section 11 - Toxicological Information 11.1 Information on toxicological effects ‘Acute toxicity No data available Skin corrosion/irritation No data available Serious eye damageleye irritation No data available Respiratory or skin sensitisation No data available Germ cell mutagenicity No data available Carcinogenicity TARC No component of this product present at levels greater than or equal 10 0.1% is ‘identified as probable, possible or confirmed human carcinogen by LARC. Reproductive toxicity No data available Specific target organ toxicity - single exposure No data available ‘Specific target organ toxicity - repeated exposure ‘No data available Aspiration hazard ‘No data available ‘Additional Information RTECS: Not available To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. 12.1 Toxicity "No data available 12.2 Persistence and degradability ‘No data available 12.3 Bioaccumulative potential No data available 12.4 Mobility in soil No data avsilable a 'MSDS~ DISODIUM HYDROGEN PHOSPHATE DIHVORATE.MATERIAL SAFETY DATA SHEET DISODIUM HYDROGEN PHOSPHATE DIHYDRATE Revision : 00 Date: 05.03.2019 MSDS Number | 2054 12.5 Results of PBT and yPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPVB) at levels of 0.1% or higher. 12.6 Other adverse effects No data available 13.1 Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. 14.1 UN number ADRIRID: - IMDG: TATA: - 14.2 UN proper shipping name ADRIRID: Not dangerous goods IMDG: Not dangerous goods TATA: Not dangerous goods 14.3 Transport hazard class(es) ADRIRID: - IMDG:- IATA: 144 Packaging group ADRIRID: - IMDG:- TATA: - 145 Environmental hazards ADRIRID: no IMDG Marine pollutant: no TATA: no 114.6 Special precautions for user “Further information - — ‘No data available 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture ‘This safety datasheet complies with the requirements of Regulation (EC) No, 1907/2006, 15.2 Chemical safety assessment “For this product « chemical safety assessment Was not Carried outTY DATA DISODIUM HYDROGEN PHOSPHATE DIHYDRATE Revision : 00 Date: 05.03.2019 MSDS Number : 2054 National Fire Protection Association (US.A.): Health: | Flammability: 0 Reactivity: 0 Farther information ‘The above information is Believed to be correct but does not purport to be all inclusive and shall be used only as 4 guide. The information in this document is based on the present state of our knowledge and is applicable 10 the product with regard to appropriate safety precautions. It does not represent any guarantee ofthe properties of the product Corporation and its Affliates shall not be held liable for any damage resulting from handling cor from contact with the above product. See www.sigmaaldrich com andor the reverse side of invoice or packing slip for additional terms and conditions of sale. [MSDS ~ D/SOD1UM HYDROGEN PHOSPHATE OINYDRATE‘No: F/QCL/008 Rev.01 LEMBAR DATA KESELAMATAN BAHAN ‘Menurut peraturan ( UE ) no.1907/2006 TRI SODIUM PHOSPHATE (dodecahydrate) Revisi:00 [ : 1.1 Mengidentifikasi Produk Nama ‘TRI SODIUM PHOSPHATE (dodecahydrate) Produk tri-sodium orthophosphate dedecahydrate, Trisodium phosphate Sinonim : ‘SODIUM PHOSPHATE tnibasic (dodecahyarate) No. CAS : 10101-89-0 Kode HS : 2835 29 30 2.1 Klasifikasi bahan atau campuran Klasifikasi menurut Peraturan (EC) No 1272/2008 ‘Toksisitas akut, Oral (Kategori 3), H301 ‘Korosi kulit (Kategori 1B), H314 ‘Teks pernyataan-H penuh yang disebutkan dalam Bagian ini, baca Bagian 16. 2.2, Elemen label Pelabelan menurut Peraturan (EC) No 1272/2008 Piktogram bahaya BOL Beracun jika tertelan. B14 ‘Menyebabkan Juka bakar kulit yang parah dan kerusakan mata. Jangan menghirup debu / asap / gas /kabut /uap / semprotan, Pakailah sarung tangan pelindung / pakaian pelindung / pelindung mata / ‘Pelindung wajah, - eae = ‘PSO1-+P330+P331-+ P30 JIKA TERTELAN: Bilas mulut. JANGAN memaksakan muntah Segera ro rr {LEMBAR DATA KESELAMATAN BAVLAN — SODIUM PHOSPHATE ibaa (decay) 7No: F/QCL/008 Rev.01 LEMBAR DATA KESELAMATAN BAHAN Menurut peraturan ( UE ) no.1907/2006 ‘TRI SODIUM PHOSPHATE (dodecahydrate) | Revisi: 00 I Tanggal : 06.05.2019 I No. MSDS :275 | 303 + P361 + P3S3 304 + P340+ P310 305 ~P351 + P338 JIKA TERKENA KULIT (stan rambut): Tanggalkan segera semua pakaian ‘yang terkontaminasi. Bilas kult dengan air / pancuran. JIKA TERHIRUP: Pindahkan orang ke udara segar dan tetap nyaman untuk ‘bemnafas. Segera hubungi PUSAT RACUN / dokter. JIKA TERKENA MATA: Bilas secara hati-hati dengan air selama beberape ‘menit. Lepaskan lensa kontak, jika ada dan mudah dilakukan. Lanjutkan membilas Pemyataan Bahaya Tambahan tidak ada 23° Bahaya lain Zat / campuran ini tidak mengandung Komponen yang diangeap persisten, bioakumulasi dan beracun (PBT), atau sangat persisten dan sangat bioakumulatif (vPvB) pada level 0,1% atau lebih tingsi Sinonim tri-sodium orthophosphate dodecahydrate Rumws Kimia __: Na;PO,.12 #0 Hill: Na,O,P.12H;0 ‘Berat Molekul 380.12 g/mol No. CAS 10101-89-0 EC-No, 231-509-8 ‘Untuk teks pernyataan -H penuh dari yang disebutkan dalam Bagian ini, lihat Bagian 16, 4.1 Penjelasan mengenai tindakan pertolongan pertama ‘Setelah menghirup: Bila terjadi kontak kulit: Setelah Kontak pada mata : Setelah tertelan: Jka menarik napas, pindahkan orang ke udara segar. Jka tidak bbemafas, berikan ‘pemapasan buatan. Konsultasikan dengan dokter CCuci dengan sabun dan banyak air. Bawa korban segera ke rumah sekit, Konsultasikan dengan dokter. Bilas bersih dengan banyak air selama minimal 15 menit dan berkonsultasilah dengan dokter JANGAN memaksakan muntah. Jangan_pemah memberikan apapun melalui mulut kepada orang yang tidak sadar. Bilas mulut -dengan sir. Konsultasikan dengan dokter 42 Kumpulan gejalaiefek terpenting, baik akut maupun tertunda. Gejala yang berhubungan dengan penggunaan 4.3 Indikasi pertolongan medis Perlaukan berdasargojala. ‘Gejala / cedere: Menyebabkan Juka bakar kulit yang parah dan Kerusakan mata. pertama dan perawatan khusus yang dipertukan LEMBAR DATA KESELAMATAN BAVLAN — SODIUM PHOSEHATE hbass(dodcay cats) 2No: FiQCL/008 Rev.01 LEMBAR DATA KESELAMATAN BAHAN ‘Menurut peraturan ( UE ) no.1907/2006 ‘TRI SODIUM PHOSPHATE (dodecahydrate) | Revisi: 00 Tanggal : 06.05.2019 No. MSDS -275 | 5.1 Media pemadaman api ‘Media pemadam yang sesuai Dbubuk kimia kering, busa tahan-alkohol, karbon dioksida (CO,) ‘Media pemadam yang tidak sesuai Jangan gunakan aliran air yang deras, 52. Bahaya khusus yang muncal dari bahan atau campuran ‘Tidak ada data yang tersedia 5.3. Saran bagi petugas pemadam kebakaran Perlindungan selama pemadam kebakaran: Jangan berusaha mengambiltindakantanpa peralatan pelindung yang sesuat S4 Informasi lebih lanjut ‘Tidak ada data yang tersecia 6.1 Langkah-langkah pencegahan diri,alat pelindung dan prosedur tanggap darurat ‘Gunakan alat pelindung dir Hindari pembentukan debu. Hindari menghirup uap, kabut, atau gas. Pastikan ventilasi yang memadai. Evakuasi personel ke area yang aman. Hindari menghirup debu. Untuk perlindungan pribadi lihat bagian 8 62 Tindakan pencegahan Linghungan Jangan biarkan produk masuk ke saluran pembuangan {6.3 Metode dan bahan untuk penyimpanan dan pembersihan ‘Angkat dan atur pembuangan tanpa membuat debu. Sapu dan sekop. Simpan dalam wadah yang cocok dan ‘ertutup untuk pembuangan. 64 Rujukan ke bagian lainnya ‘Untuk pembuangan, lihat bagian 13, 7. Kehati-hatian dalam menangani secara aman, - Hindari_ Kontak dengan kulit dan mata. Hindari pembentukan debu dan aerosol. Berikan ventilasi EEE YE ep TSG EBV, UGE HOS PENCSADT, TER EAE 72 Kondisi penyimpanan yang aman termasuk adanya inkompatibilitas Simpan di tempat yang dingin. Simpan wadah tertutup rapat di tempat yang Kering dan berventilasi baik ‘Kelas penyimpanan (TRGS 510): Pedatan yang mudah torbakar,beracun.No: F/QCL/008 Rev.01 LEMBAR DATA KESELAMATAN BAHAN ‘Menurut peraturan ( UE ) no.1907/2006 TRI SODIUM PHOSPHATE (dodecahydrate) [Revisi:00 I Tanggal : 06.05.2019 I No MSDS 275 | 8.1 Parameter Pengendalian Tidak mengandung bahan-bahan yang mempunyai nilai batas eksposur pekerjaan, 8.2 Pengendalian Pemaparan Pengendalian teknik/tindakan rekayasa yang sesuai untuk mengurangi paparan. Hindari kontak dengan kulit, mata dan pakaian. Cuci tangan sebelum istirahat dan segera setelah menangani produk ‘Tindakan perlindungan individual Pakaian pelindung harus diplih secara spesifik untuk tempat bekerja, tergantung konsentrasi dan jumish bbahan berbahaya yang ditangani. Daya tahan pakaian pelindung kimia harus dipastikan dari masing-masing suplier Pertindungan mataiwajah Pelindung wajah dan kacamata keselamatan Gunakan peralatan untuk pelindung mata yang diuji dan disetuju! berdasarkan standar pemerintah yang sesuai seperti NIOSH (AS) atau EN 166 (UE). perlindungan kulit ‘Menangani dengan sarmng tangan, Sarung tangan harus diperiksa sebelum digunakan. Gunakan teknik Penghapusan sarung tangan yang tepat (Tanpa menyentuh permukaan luar sarung tangan) untuk menghindari ‘kontak kulit dengan produk ini. Buang sarung tangan yang terkontaminasi setelah digunakan sesuai dengan Jnulcum yang berlaku dan praktek laboratorium yang baik. Cuci dan keringkan tangan, Sarung tangan pelindung yang dipilih harus memenuhi spesifikasi dari EU Directive 89/686 / EEC dan standar EN 374 berasal dari itu Kontak penuh Bahan Karetnitril ketebalanlapisan minimal 0,11 mm Menembus walt: > 480 menit ‘Kontak percikan 7 Bahan Karetnitril etebalanlapisan minimal: O11 mm “Menembus waktu: > 480 menit Peralatan pelindung lainaya ‘Sarung tangan pelindung perlindungan pernapasan ‘Untuk eksposur gangguan gunakan tipe P95 (AS) atau tipe Pl (EU EN 143) partikel r (AS) atau ketik sespirator cartridge ABEKP2.(EU_EN 143)..Gunakan. respirator. dan. komponen_ yang. diuji.dan.disetujui berdasarkan standar pemerintah yang sesuai seperti NIOSH (AS) atau CEN (UE), Kontrol eksposur lingkungan Jangan biarkan produk masuk ke saluran pembuangan. ‘LEMBAR DATA KESELAMATAN BAHAN— SCOIUM PHOSPHITE titi (dadectydate)No: FiQCL/008 Rev.01 LEMBAR DATA KESELAMATAN BAHAN Menurut peraturan ( UE ) no.1907/2006 TRI SODIUM PHOSPHATE (dodecahydrate) i Revisi: 00 I Tanggal : 06.05.2019 No. MSDS = 275 9.1 Informasi tentang sfat fisika dan kimia Bentuk krista Wama pth Bau Tek berbau ‘Ambang Bau Tidak berlaku pH 13 at 190.1 gf at 25°C Titik lebur 75°C Titik didib/rentang diih Tidak tersedia informasi Titik nyala Tidak berlaku ‘Laju penguapan Tidak tersedia informa. Flamabilitas (padatan, gas) Tidak tersedia informasi ‘Terendah batas ledakan Tidak tersedia informasi ‘Tertingg: batas ledakan Tidak tersedia informasi, Tekanan wap Tidak tersedia informasi ‘Kerapatan (densitas) wap relatif Tidak tersedia informasi, Densitas 1.62 g/m at 25 °C ‘Kerapatan (den-sitas)relatif ‘Tidak tersedia informasi ‘Kelarutan dalam air 285 gl at 20°C Koefisien parts (n-oktanol/ir) Tidak tersedia informasi Suihu dapat membakar seni Tidak tersedia informasi (auto ignition temperature) ‘Suu penguraian ea 75°C Viskositas, dinamis Tidak tersedia informasi. Sifat peledak Tidak modah meledak Sifat oksidator Tidak tersedia informasi 92 Data lain ‘Tidak tersedia informasi, 10.1 Reakeificas Tidak tersedia informasi, 10.3 Reaksi berbahaya yang mungkin di bawah kondisi spesifil/khusus ‘Tidak tersedia informasi, 10.4 Kondisi yang harus dihindari Tidak tersedia informasi 10.5 Bahan yang harus dihindari Asam kuat 10 Produk berbahaya hasil penguraian ‘Hazardous decomposition products formed under fire conditions. - Oxides of phosphorus, Sodium oxides Other decomposition products - No data available In the event of fire: see section $No: F/QCL/008 Rev.01 LEMBAR DATA KESELAMATAN BAHAN ‘Menurut peraturan ( UE ) no.1907/2006 ‘TRI SODIUM PHOSPHATE (dodecahydrate) Revisi: 00 Tanggal : 06.05.2019 No. MSDS 275 | 11.1 Informasi tentang efek toksikologis Toksisitas oral akut LDS0 Oral - Tikus -> 2.000 mg / kg (Sodium phosphate tribasic dodecahydrate) (Pedoman Tes OECD 420) [ritasi kalit “Mengiritasi kulit (Sodium phosphate tribasic dodecahydrate) Initasi mata Trtasi mata (Sodium phosphate tribasic dodecahydrate) Sensitisasi Tidak ada data yang tersedia (Sodium phosphate tribasic dodecahydrate) Mutagenisitas pada sel mutfai ‘Tes Ames (Sodium phosphate tribasic dodecahydrate) ‘asil: Tidak mutagenik dalam Tes Ames Karsinogenisitas ‘Karsinogen manusia yang dicurigai (Hydroxylamine hydrochloride) (Fydroxylamine hydrochloride) TARC. ‘Tidak ada komponen dari produk ini yang hadir pada level yang lebih. besar atau ‘sama dengan 0,1% diidentifikasi sebagai karsinogen manusia yang memungkinkan, ‘mungkin atau dikonfirmasi oleh TARC. ‘Toksisitas terhadap Reproduksi ‘Tidak ada data yang tersedia (Sodium phosphate tribasic dodecahydrate) ‘Teratogenisitas Tidak ada data yang tersedia (Sodium phosphate tribasic dodecahydrate) ‘Toksisitas pada organ sasaran spesifik - paparan tunggal ‘Dapat menyebabkan irtasi pernafasan. (Sodium phosphate tribasic dodecahydrate) ‘Toksisitas pada organ sasaran spesifik - paparan berulang Tidak ada data tersedia Bahaya aspirasi ‘Tidak ada data yang tersedia (Sodium phosphate tribasic dodecahydrate) 11.2 Informasi lebih lanjut RTECS: TC9575000 12.1 Toksisitas ‘Keracunan untuk ikan ‘L.CO = Leuciseus idus (Golden orf) - 2.400 mg / 1 - 48 jam (Sodium phosphate tribasic dodecahydrate) 12.2 Persistensi dan penguraian oleh lingkungan Tidak tersedia informasi 12:3 Potensi bioakumulasi ‘Tidak tersedia informasi re ‘LEMBAR DATA NESELAMATAN BAHAN ~ SODIUM PHOSPHATE tani (Andee) eNo: F/QCL/008 Rev.01 TA (AN | ‘Menurut peraturan ( UE ) no.1907/2006 ‘TRI SODIUM PHOSPHATE (dodecahydrate) | Revisi: 00 ‘Tanggal : 06.05.2019 No. MSDS :275 | 12.4 Mobilitas dalam tanah Tidak ada data yang tersedia (Sodium phosphate tnbasic dodecahydrate) 12.5 Hasil dar asesmen PBT dan vPvB Zat / campuran ini tidak mengandung komponen yang dianggap persisten, bioakumulasi dan toksik (PBT), ‘tau sangat persisten dan sangat bioakumulatf(vPVB) pada level 0,1% atau lebih tinggi 12.6 Bfek merugikan lainnya Tidak tersedia informasi, 13.1 Metode pengolahan limbab Produk Menawarkan solusi surplus dan tidak dapat didaur ulang ke perusahaan pembuangan berlisensi. Larutkan ‘atau campur bahan dengan pelarut yang mudah terbakar dan bakar di scrubber kimi Kemasan terkontaminasi Buang sebagai produk yang tidak digunakan ‘Transpor jalan (ADR/RID) 14.1 Nomar PBB UN 3262 14.2 Nama pengapalan yang CORROSIVE SOLID, BASIC, INORGANIC, NOS sesuai berdasarkan PBB 143 Kelas 8 144 Kelompok pengemasan ig 14.5 Environmentally hazardous = 146 Tindakan kehati-hatian Ya ‘chusus bagi pengguna ‘Kode pembatasan terowongan E ‘Transportasi air sungai(ADN) Tidak bersangkut paut ‘Transpor udara (IATA) 14.1 Nomor PBB UN 3262 14.2 Nama pengapalan yang CORROSIVE SOLID, BASIC, INORGANIC, NOS sesuai berdssarkan PBB 143 Kelas 8 +144 Kelompok pengemasan, a. 14.8 Environmentally hazardous = 14.6 Tindakan kebati-hatian Tidak ‘khusus bagi pengguna ‘Transpor laut (IMDG) 14.1 Nomor PBB UN 3262 14.2 Nama pengapalan yang CORROSIVE SOLID, BASIC, INORGANIC, NOS sesuai berdasarkan PBB 143 Kelas — + |——14.4 Relompok pengemasan TE a 14.5 Environmentally hazardous — oe ra nanan ‘LEMGAR DATA KESELAMATAN BAAN ~ SODIUM PHOSPHATE tase (Sdeahycate) 7No: F/QCL/008 Rev.01 | LEMBAR DATA KESELAMATAN BAHAN. | Menurut peraturan ( UE )no.1907/2006 LTRI SODIUM PHOSPHATE (dodecahydrate) | [Revisi: 00 ‘Tanggal : 06.05.2019 l No. MSDS = 275 | 14.6 Tindakan kehat-hatian Ya ‘knusus bagi pengguna 15.1 Peraturan / perundang-undangan keselamatan, kesehatan, dan lingkungan khusus untuk ‘bahan atan campuran LLembar data keselamatan ini mematuhi persyaratan Peraturan (EC) No, 1907/2006, 152 Penilaian keamanan bahan kimia (Untuk produk ini penilaian keamanan bahan kimia tidak dilakukan Teks Pernyataan-H{ penuh mengacu pada bagian 2 dan 3. Koreksi Kulit 1B Koresi/ irtasi uli, Kategori 1B BIG ‘Menyebabkan luke bekar kulit yang parah dan kerusakan mata R34 “Menyebabkar tuka bakar c Korosif ‘National Fire Protection Association (U.S.A.): Informasi lebih lanjut Informasi di atas diyakini benar tetapi tidak dimaksudkan untuk menjadi semua inklusif dan harus hanya digunakan sebagai panduan. Informasi dalam dokumen ini didasarkan pada pengetahuan terkini ‘kami dan berlaku untuk produk yang berkaitan dengan tindakan pencegahan dan keselamatan. It tidak ‘mewakili menjamin sifat dari produk dan AVliasinya tidak berangeung jawab atas segala kerusakan akibat penanganan atau dari Kontak dengan produk di atas. dan / atau sisi sebaliknya dari faktur atau slip Kemasan untuk syara dan kefentuan penjualantambahanMaterial Safety Data Sheet IC WETTING AGENT- 4055 REV: 001-102015 1. GENERAL INFORMATION Generic Description Alkaline Degreaser, Alkaline cleaner Physical Form: Liguid Color. Colorless to yellowish liquid NFPA Profi: Health 2 Flammability 0 Instabiity/Reactivity 0 Note NFPA-= National Fire Protection Association 2. COMPOSITION NAME CAS WEIGHT Chelating agent mixed 37.5% Alkaline builder mixed 315% Proprietary Surfactant - 75-15% 3. OSHA HAZARDOUS COMPONENTS None present. This is not a hazardous material as defined in the OSHA Hazard Communication Standard. 4. EFFECTS OF OVEREXPOSURE Acute Effects Eye Direct contact may cause heavy iritation. Skin Imitation expected from a single long-term exposure. Inhalation: No Significant effects expected from a single short-term exposure. Oral: Medium ingestion hazard in normal use, Prolonged/Repeated Exposure Effects Skin Iritation Inhalation: "No known applicable information Oral: No known applicable information ‘Signs and Symptoms of Overexposure: No known applicable information ‘Medical Conditions Aggravated by Exposure: No knowrr applicable information:Material Safety Data Sheet IC WETTING AGENT- 4055 REV: 001-102015 The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar compositions, component data andor expert review of the product. Please refer to Section 11 for the etaled toxcealogy information 5, FIRST AID MEASURES Eye: Immediately flush with water for 15 minutes. Skin: Immediately flush with water for 15 minutes Inhalation: 'No first aid should be needed. Oral: No first ald should be needed, 6. FIRE FIGHTING MEASURES Flash Point: Not determined Autoignition Temperature: Not determined, Flammability Limits in Air: ‘Not determined. Extinguishing Media: (On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide (C2), dry chemical or water spray. Water can be used to cool fire exposed containers, Fire Fighting Measures Setf-contained breathing apparatus and protective clothing ould be worn in fighting large fires involving chemicals. Use water spray to keep fire exposed containers cool. Determine the need to evacuate or isolate the area according to your local emergency plan. Unusual Fire Hazardstion Products: Not determined, 7. ACCIDENTAL RELEASE MEASURES ContainmentiClean up: Determine whether to evacuate or isolate the erea according to your local emergency plan. Observe all_personal protection equipment recommendations described in Sections 5 and 8. For large spills, provide diking or other ‘appropriate containment to Keep material from spreading. If diked material can be pumped, store recovered material in ‘appropriate container. Clean up remaining materials from spill with suitable absorbant. Final cleaning may require use of water and detergents. 8. HANDLING AND STORAGE Use with adequate ventilation. Avoid eye contact. Use reasonable care and store away from acidic materials. 9. EXPOSURE CONTROLS / PERSONAL PROTECTIONMaterial Safety Data Sheet IC WETTING AGENT- 4055 REV: 001-102015 Component Exposure Limits ‘There are no components with workplace exposure limits. Engineering Controls Local Ventilation: Not should be needed General Ventilation: Recommended, Personal Protective Equipment for Routine Handling Eyes: Use proper protection - safety glasses as a minimum. Skin: ‘Washing at mealtime and end of shift is adequate. Suitable Gloves Protection needed, Inhalation No respiratory protection should be needed. Suitable Respirator: None should be needed. Personal Protective Equipment for Spills Eyes: Use proper protection - safety glasses as a minimum. Skin Washing at mealtime and end of shift is adequate. Inhalation/Sutabe Respirator: 'No respiratory protection should be needed. Precautionary Measures: ‘Avoid eye contact: Use reasonable cere: Note: ‘These precautions are for room temperature handling. Use at elevated temperature or aerosolspray applications may require ‘added precautions 10. PHYSICAL AND CHEMICAL PROPERTIES + Appearance: Clear colortess to yellowish liquid + Sp. Gravity 25°C: 4.00-1.10 + pH >10 * Solubility ‘Completely soluble in water 11. STABILITY AND REACTIVITY Chemical Stability Stable. Hazardous Polymerization’ Hazardous polymerization will not occur. Conditions to Avoid: None. Materials to Avoid: Acidic material can cause @ reaction. 12, TOXICOLOGICAL INFORMATION ‘Acute Toxicology Data for Product ‘Complete information is not yet available. ‘Component Toxicology Information No known applicable information. ‘Special Hazard Information on Components ‘No known applicable information.Material Safety Data Sheet IC WETTING AGENT- 4055 REY: 001-102015 13. ECOLOGICAL INFORMATION Environmental Fate and Distribution No specific information is available, 14. DISPOSAL CONSIDERATION D0 NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator 15. TRANSPORT INFORMATION DOT Non-Bulk NOT REGULATED DOT Bulk NOT REGULATED IMDG NOT REGULATED ICAONATA NOT REGULATED This information is not intended to convey all specifi regulatory or operational requirementsfinformation relating fo this product. Adtiional transportation system information can be obtained through an authorized sales or customer service representative. it is the responsibilty of the transporting organization to follow all applicable Jaws, regulations and rules relating tothe transportation of the material 16. OTHER INFORMATION ‘These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate.Material Safety Data Sheet HCS Cl 3140 REV: 007.102015 1. GENERAL INFORMATION Generic Description: Physical Form: Color: NFPA Profile: Note: ‘Acid Corrosion inhibitor Liquid Yellow to Brown Health 2 Flammabilty 1 Instability/Reactivity 0 NFPA = National Fire Protection Association Section 2. Hazards Identification Physical State Color ‘Odor Hazard statements Precautionary statements R Phrases 'S Phrases Liquid Yeliow to Brown Characteristic 1319 Causes serious eye initation. 264 Wash with water Thoroughly after handling, 280 Wear protective glovesiprotective clothingleye protectioniiace protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 if eye imitation persists: Get medical advice/attention. Rat Risk of serious damage to eyes. ‘S26 In case of contact with eyes, rinse immediately with plenty of water land seek medical advice. ‘$39 Wear eye/face protection. Section 3. Composition/ Information on Ingredients NAME CAS WEIGHT ‘Thiourea, N,N‘-dibutyl- mixed 15.0 - 25.0% Proprietary Akyiphenal ethoxyate moes 75-95% Propiertary moxed 60- 120% Section 4. First Aid Measures Eye Contact ‘Afier contact with the eyes, rinse with waier with the eyelids open for a sufficient length of time, then consult an opthaimologist immediately.Protect uninjured eye. ‘Skin Contact Immediately take off all contaminated clothing. Areas of the body that have - co are only even suspected of having - come into contact with the product must be rinsed immediately with. plenty of running water and possibly with soap. Wash thoroughly the body (shower or bath). Remove contaminated clothing immediatley and dispose off safely.Material Safety Data Sheet HCS Cl 3140 REV: 001-102015, Inhalation Remove casualty to fresh air and keep warm and at rest. If breathing is irregular or stopped, administer artificial respiration. In case of inhalation, consult a doctor immediately and show him packing or label Ingestion Do NOT induce voriting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this Material are swallowed, call a physician immediately. Loosen tight ciothing such as a collar, tie, belt or waistband, Medical Conditions In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). Section 5. Fire Fighting Measures Extinguishing media Water. Carbon dioxide (CO2) Extinguishing media which must not be used for safety reasons. ‘None in particular. ‘Special hazards arising from the Do not inhale explosion and combustion gases. substance or mixture Buming produces heavy smoke. Advice for fire-fighters Use suitable breathing apparatus. Collect contaminated fre extinguishing water separately. This must not be discharged into drains Move undamaged containers from immediate hazard _area if it can be done safely Section 6. Accidental Release Measures Personal precautions, protective ‘Wear personal protection equipment. equipment and emergency procedures Remove persons to safety. ‘See protective measures under point 7 and 8, Environmental precautions Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains. Retain contaminated washing water and dispose it. In case of gas escape or of entty into waterways, Soil oF drains, inform the responsible authorities. Suitable material for taking up: absorbing material, ‘organic, sand ‘Methods and material for containment ‘Wash with plenty of water. and cleaning up Reference to other sections See also section 8 and 13,Material Safety Data Sheet HCS Cl 3140 REV: 001-102015 Section 7. Handling and Storage Precautions for safe handling Avoid contact with skin and eyes, inhaltion of vapours and mists. Dont use empty container before they nave been cleaned. Before making transfer operations, assure that there aren't any incompatible material residuals in the containers, Contamined clothing should be changed before entering eating areas. Do not eat or drink while working. See also section 8 for recomended protective equipment. Conditions for safe storage, Keep away from food, drink and feed ‘Specific end use(s) \cluding any incompatibilities Incompatible materials: None in particular. Instructions as regards storage premises: Adequately ventilated ‘premises. The current legislation ofthe storage of the chemical products must be respected. ‘None in particular Section 8. Exposure Controls/ Personal Protection Eye protection Protection for skin Protection for hands Respiratory protection ‘Thermal Hazards. Use close filling safely goggles, don't use eye lens. No special precaution must be adopted for normal use. Use protective gloves that provides comprehensive protection, €.9. P.V.C., neoprene or rubber. Penetration time of glove material ‘The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. The determined Penetration time according to EN 374-3 are not performed under Practical conditions. Therefore a maximum wearing time which corresponds to 50% of the penetration time is recommended. Not needed for normal use. ‘None Environmental exposure None Controls. Section 9. Physical and Chemical Properties Appearance pH Relative density Solubility in water Yellow to brown Liquid 3.00-6,00 0.95 = 1.00.g/mL. Dispersibie Section 10. Stability and Reactivity Reactivity ‘Chemical stability Stable under normal conditions. ‘Stable under normal conditions.Material Safety Data Sheet HCS CI 3140 REV: 001-102015, Possibility of hazardous reactions not determined Conditions to avoid Stable under normal conditions. Incompatible materiats None in particular Hazardous decomposition products None. Section 11. Toxicological Information Information on toxicological effects There is no toxicological data available on the mixture. Consider the individual concentration of each component to ‘assess toxicological effects resulting from exposure to the mixture. Section 12. Ecological Information Toxicity “Adopt good working practices, so thatthe product is not released into the environment. Do not use when plants are in flower: the product is toxic for bees. Persistence and degradability None Bioaccumulative potential NA Mobility in soit NA Other adverse effects None Section 13. Disposal Considerations Waste treatment methods Recover if possible. in so doing, comply with the local and national regulations currently in force. Packaging: disposal must be made according to current legislation. Section 14. Transport Information DOT Non-Bulk NOT REGULATED DOT Bulk NOT REGULATED IMDG NOT REGULATED ICAONATA NOT REGULATEDMaterial Safety Data Sheet HCS Ci 3140 REV: 001-102015, This information is nat intended to convey all specific regulatory or operational requirements/nformation relating to this product. Additional transportation system information can be obtained through an authorized sales or customer ‘service representative. i is the responsibilty of the transporting organization to follow all applicable laws, ‘regulations and rules relating to the transportation ofthe material Section 15. Regulatory Information Safety, health and environmental Dir. 6/548/I:LC (Classtfication, packaging and labeling of dangerous (Classification, packaging and labelling of dangerous preparations). Dir. 98/24/EC (Risks related to chemical agents at work). Dir. 2000/39/EC. (Occupational ‘exposure limit values); Dir. 2006/8/CE. Regulations/legislation specific ‘Regulation (CE) n. 1907/2006 (REACH), Regulation (CE) for the substance or mixture 1127212008 (CLP), Regulation (CE) n.790/2008. Where applicable, refer tothe folowing regulatory provisions Directive 82/501/EEC (‘Activites linked to risks of serious accidents’) and subsequent amendments. Regulation (EC) nr £648/2004 (detergents). 1998/13/EC (VOC directive) Chemical Safety Assessment No Section 16. Other Information Full text of phrases referred to in Section 3 R22 Harmful if swallowed, RQ5 Causes severe bums. Rai Risk of serious damage to eyes. 11302 Harmful if swallowed, 1319 Causes serious eye irritation H314 Causes severe skin bums and eye damage. +228 Flammable sold 1317 May cause an allergic skin reaction. This safety data sheet has been completely updated in compliance to Regulation 463/201 0/EU. This document was prepared by a competent person who has received appropriate training, Main bibliographic sources: ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, ‘Commission of the European Communities SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition ~ Van ‘Nostrand Reinold CCNL - Appencix 1 Insert further consulted bibliography The information contained herein is based on our state of knowledge at the above-specified date. it ‘efers solely to the product indicated and constitutes no guarantee of particular quality. {tis the duty of the user to ensure that this information is appropriate and complete with respect to the ‘specific use intended. ‘This MSDS cancels and replaces any preceding releaseF-AENSIGN Page 1/7 Safety data sheet according to 1907/2006/EC, Article 31 Revision: 15.06.2017 Version number 3 ‘Superseded version: No 2/22.03.2014 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier ‘Trade name: Citric Acid Monohydrate CAS number: 5949-29-1 EC number: 201-069-1 1.2 Relevant identified uses of the substance or mixture and uses advised against Application of the substance / the preparation: Intermediate Formutation Photography products Laboratory reagents Water treatment Treatment of metal surfaces Medical devices 1.3 Details of the supplier of the safety data sheet Manufacturer/Supplier: ‘Weifang Ensign Industry Co., Ltd 1.4 Emergency telephone number(s): 0086-536-6296125 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Eye Init. 2, H319 Causes serious eye itation. 2.2 Label elements Jabali seconsina to Regulation (EG) Ne. 12722008: ‘The substance is classified and labelled according to the CLP regulation. Hazard pictograms: Q GHSO7 Signal word: WarningVAENSIGN io Safety data sheet according to 1907/2006/EC, Article 31 a Teaees si eee ae ‘Trade name: Citric Acid Monohydrate Hazard statements: H319 Causes serious eye irritation. Precautionary statements: 264 ‘Wash thoroughly after handling, 280 ‘Wear eye protection / face protection. P305+P351+P336 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if resent and easy to do. Continue rinsing. P337+P313_Ifeye irritation persists: Get medical advice/attention 2.3 Other hazards Results of PBT and vPVB assessment PBT: No PBT. vPvB: No vPvB. [SECTION 3: Compositionfinformation on ingredients 3.1 Substances ‘CAS Number. Description. ‘5949-29-1 Citric Acid Monohydrate Identification number(s) EC number: 201-069-1 (USECTIONG: Firstaid’ measures e 4.1 Description of first aid measures ne Shade oe gelato Sea, repenmn poh comm 2 tee. ‘er cate eaten Imes rinse wth water. If skin irritation continues, consult a doctor. After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: Rinse out mouth and then drink plenty of water. Do not induce voriting; call for medical help immediately. 4.2 Most important symptoms and effects, both acute and delayed Serious eye damageleye irritation: Eye Irit. 2 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. [SSECTIONS: Firefighting measures sama nia oars] 5.1 Extinguishing media Suitable extinguishing agents: ‘C02, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. 5.2 Special hazards arising from the substance or mixture Carbon dioxide (CO2) ‘Carbon monoxide (CO) 5.3 Advice for firefighters Protective equipment: Wear fully protective suit.V-AENSIGN Page 3/7 Safety data sheet according to 1907/2006/EC, Article 31 Revision: 15.06.2017 Version number 3 ‘Superseded version: No 2/22.03.2014 ‘Trade name: Citric Acid Monohydrate Wear self-contained respiratory protective device. SECTION 6: Accidental 6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Ensure adequate ventilation. 6.2 Environmental precautions Do not allow to enter sewers! surface or ground water. 6.3 Methods and material for containment and cleaning up ‘Send for recovery or disposal in suitable receptacles. Retrieve the product by mechanical means. Dispose contaminated material as waste according to item 13. 6.4 Reference to other sections ‘See Section 7 for information on safe handing. ‘See Section 8 for information on personal protection equipment. See Section 13 for disposal information, 7.1 Precautions for safe handling Use only in well ventilated areas. Provide suction extractors if dust is formed. Do not inhale dust / smoke / mist. Avoid contact with the eyes and skin Information about fire - and explosion protection: No special measures required. 7.2 Conditions for safe storage, including any incompatibilities Requirements to be met by storerooms and receptacles: ‘Store in a cool, dry location in well sealed receptactes. Provide ventilation for receptacies. ‘Store only in the original receptacle. Information about storage in one common storage facility: Store away from oxidising agents. 7.3 Specific end use(s): No further relevant information available. 8.1 Control parameters Ingredients with limit values that require monitoring at the workplace: Not required. [PNECs 7-829 Citric Acid Anhydrous. | PNECTO.44 mg/l. (Water (Freshwater) [0.044 mg/L (Water (Marine Water)) >1000 mg/l. (Sewage Treatment Piant (STP)) PNEC|3.46 mg/kg sedim. dw (Sediment (Marine Water)) 34.6 mg/kg sedim. dw (Sediment (Freshwater)) __PNEC|33.1 mgikg soil dw (Soil) ‘Additional information: The lists valid during the making were used as basis.V-AENSIGN Page 47 Safety data sheet according to 1907/2006/EC, Article 31 Revision: 15.06.2017 Version number 3 ‘Superseded version: No 2/22.03.2014 Trade name: Citric Acid Monohydrate 8.2 Exposure controls Personal protective equipment General protective and hygienic measures: Do not inhale dust / smoke / mist ‘Avoid contact with the eyes and skin Wash hands before breaks and at the end of work Do noteat, drink, smoke or sniff while working Respiratory protection: Suitable respiratory protective device recommended. Protection of hands: @ Protective gloves. Material of gloves: Rubber, PVC or neoprene gloves recommended. Eye protection: © Tightly sealed goggles (EN 166). Body protection: Protective work clothing. 9.1 Information on basic physical and chemical properties General information Appearance: Form: Colour: Odour: ‘Odour threshold: Not determined. pH-value (100 git): 47 Matting pointifreezing point: 1530 Initial boiling point and boiling range: Not determined. Decomposes before boiling Flash point: Not applicable. Flammability (solid, gas): Product is not flammable. {Ignition temperature: Not applicable. Decomposition temperature: Not determined. Explosive properties: Product does not present an expiosion hazard. Explosion limits: tow Not determined: Upper: Not determined. Oxidising properties Not oxidising. ‘Vapour pressure at 25: 2.21106 PaV-AENSIGN Page 5/7 Safety data sheet according to 1907/2006/EC, Article 31 Revision: 16.08.2017 Version number ‘Superseded version: No 22.03.2014 ‘Trade name: Citric Acid Monohydrate Density: Not determined. Relative density at 20 1.985 Vapour density ‘Not applicable. Evaporation rate Not applicable. ‘Solubility in / Miscibility with Water at 20 T: 590 g/l Alcohols: Partly soluble. Partition coefficient: n-octanoliwater: -0.2 - -1.8 log Pow Viscosity: Dynamlc: Not applicable Kinematic: Not applicable. 9.2 Other information ‘No further relevant information available. 10.1 Reactivity No data available. 10.2 Chemical stability Thermal decomposition / conditions to be avoided: Stable at environment temperature. 10.3 Possibility of hazardous reactions Reacts with alkali (iyes). 10.4 Conditions to avoid Keep away from heat and direct sunlight. 10.5 Incompatible materials Protect from moisture. ‘Avoid strong oxidants, strong alkalis and strong acids, 10.6 Hazardous decomposition products Carbon dioxide Carbon monoxide [ “SECTION 14: Toxicological information 11.1 Information on toxicological effects ‘Acute toxicity Based on available data, the classification criteria are not met. TDILC5O values: 77-829 Citric Acid Anhydrous i Ora maiKg bw (Mouse) (OECD 401) | Dermal L050|>2000 mg/Kg bw (Rat) (OECD 402) Primary iritant effect: Skin corrosion/iritation: Based on available data, the classification criteria are not met. Serious eye damagelirritation: Causes serious eye iritation. Respiratory or skin sensitisation: Based on available data, the classification criteria are not met. CMR effects (carcinogenity, mutagenicity and toxicity for reproduction): ‘Germ cell mutagenicity: Based on available data, the classification criteria are not met. Carcinogenicity: Based on available data, the classification criteria are not met, Reproductive toxicity: Based on available data, the classification erteria are not met. 'STOT-single exposure: Based on available data, the classification criteria are not met. 'STOT-repeated exposure: Based on available data, the classification criteria are not met.V-AENSIGN We Safety data sheet according to 1907/2006/EC, Article 31 Revision: 15.06.2017 ‘Version number 3 ‘Superseded version: No 2/22.03.2014 ‘Trade name: Citric Acid Monohydrate Aspiration hazard: Based on available data, the classification criteria are not met. “SECTION 12: Ecological information aoe Baz 12.1 Toxicity ‘Rquatic toxicity: 77-82-9 Citric Acid Anhydrous TCSO/48h 1440 mg/L (Fish) (OECD 203) Pot ee NOEC [425 mg/L (Algae) LC50/24h | 1535 mg/L (Daphnia Magna) 12.2 Persistence and degradability Readily biodegradable 12.3 Bioaccumulative potential Does not accumulate in organisms. 12.4 Mobillity in soil pka: 3.13, 4.76 and 64 at 25 °C 12.5 Results of PBT and vPVB assessment PBT: No PBT. \PVB: No vPVB, 12.6 Other adverse effects No further relevant information available. “SECTION 13: Disposal considerations a a 13.1 Waste treatment methods Recommendation: Do not allow product to reach sewage system. Uncleaned packaging: Recommendation: Disposal must be made according to official regutations. Packaging that may not be cleansed must be disposed of in the same manner as the product. "SECTION 14: Transport information 14.1 UN Number (ADR, ADN, IMDG, IATA Not applicable. 14.2 UN proper shipping name ADR, ADN, IMDG, IATA Not applicable. 14.3 Transport hazard class(es) ADR, ADN, IMDG, IATA Class Not applicable. 14.4 Packing group ADR, IMDG, IATA Not applicable. 14.5 Environmental hazards Marine pollutant: No 14.6 Special precautions for user Not applicable, 14,7 Transport in bulk according to Annex I of MARPOL 73/78 and the IBC Code Not applicable.V-AENSIGN Page 7/7 Safety data sheet according to 1907/2006/EC, Article 31 Revision: 15.06.2017 Version number 3 ‘Superseded version: No 2/22.03.2014 ‘Trade name: Citric Acid Monohydrate __ SECTION 15: Regulatory information a 15.4 Safety, health and environmental regulations/legislation specific for the substance or mixture This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.2 Chemical safety assessment A Chemical Safety Assessment has been carried out. _ SECTION 46: Other information = pe eed This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Abbreviations and acronyms: ‘ADR: Accord europten sure transport des marchandises cangereuses par Route (European Agreement concerning the Eye It 2: Serious eye damage/eye imitation ~ Category 2 * Data compared to the previous version altered. Classification and labelling according to Directive 67/548/EEC in section 2 has been removed.@ PT PUPUK KUJANG LEMBAR DATA KESELAMATAN BAHAN AMMONIUM HYDROXIDE 25 % Tanggal revs: 02.06.2019 Versi: 10.01 “Tanga penerbitan: 8 Juni 2019 1. Identifikasi Produk dan Perusahaan Nama produk: AMMNOIUM HYDROXIDE 25% Sinonim: AMMONIA LIQUID Pemasok: PT. AGHEO LANGGENG CHEMINDO ‘Alamat : JI. Warung Gantung Kp. Rawa Lele RT 004.RW O10 Blok B No. 24 Kalideres . Kec, Kalideres, Jakarta Barat 11840 Pabrikan : PT. Pupuk Kujang, Jl. Jend A . Yani No. 39 Cikampek 41373, Kabupaten Karawang - Jawa Barat Nomor telepon: + 62-21- 22585412 Nomor faks: + 62-21- 22585412 Panggilan darurat: + 62-21- 22526352 Telp: (0264) 316141, 317007 TOLL FREE : 0800-100-3001 (0264) 314235, 314335, 2. Identifikasi Bahaya Piktogram bahaya: OO Kata sinyal: Bahaya Pernyataan bahaya: H302 Berbahaya jika tertelan 1314 Menyebabkan luka bakar kulit yang parah dan kerusakan mata. 400 Sangat toksik bagi kehidupan air. Pernyataan pencegahar 260: Jangan menghirup gas / uap / semprotan. 273: Hindari melepaskan ke lingkungan. 280: Kenakan sarung tangan pelindung / pakaian pelindung / pelindung mata / pelindung wajah. 'P403.+ P233: Simpan di tempat yang berventilasi baik. Simpan wadah tertutup rapat. 3. Komposisi / Informasi tentang Bahan Nama Bahan Berbahaya Komposisi nomor CAS Ammonium Hydroxide (NH40H) 1336-21-6 24 - 26% 4. Tindakan Pertolongan Pertama ‘DOC LOKS AMON 25 COPY 2018A @ PT PUPUK KUJANG JIKA TERTELAN: * bilas mulut dan keluarkan cairannya + membaringkan korban dan melindungi dari hipotermia, « jika pasien tetap sadar memberikan korban perlahan-lahan minum segelas air, + melakukan tindakan lebih lanjut seperti inhalasi. KONTAK KULIT: + lepaskan pakaian yang terkontaminasi sambil melindungi diri Anda sendiri * bilas area kulit yang terkena selama 10 menit dengan air mengalir, '* mencari perawatan medis. KONTAK MATA: + segera bilas mata yang terkena dengan kelopak mata yang tersebar luas selama 10 menit saat berlari air sambil melindungi mata yang tidak rusak. Alirkan air yang lembut ke mata untuk melarutkan atau menghilangkan larutan alkali secepat mungkin. Segera membilas dapat mencegah kerusakan mata yang serius, ‘ segera membawa korban ke dokter mata atau ke rumah sakit. Lanjutkan membilas selama transportasi. INHALASI: + meletakkan korban dan melindunginya terhadap hipotermia, + berulang kali minta korban menghirup atau menghirup semprot inhalasi glukokortikoid dalam- dalam kasus kesulitan bernapas memiliki korban menghirup oksigen dan mengambil semiupright posisi * jika korban tidak sadarkan diri tetapi pernapasan membuatnya stabil di sisinya, « jike korban berhenti bernapas berikan resusitasi dari mulut ke hidung atau jika tidak ‘mungkin menggunakan resusitasi mulut ke mulut, + dalam kasus henti jantung (kekurangan denyut jantung atau denyut jantung) segera oleskan paru- aru jantung resusitasi, * perlindungan fungsi vital (detak jantung dan pernapasan tanpa bantuan) dibutuhkan prioritas di atas setiap kegiatan lainnya. ‘SARAN UNTUK RESPONDER AID PERTAMA: ‘amonia menyentuh mata, perawatan khusus diperlukan setelahnya pertolongan pertama awal (pembilasan, pengobatan terhadap rasa nyeri) selesai, * air adalah media yang disukai untuk membilas mata karena ketersediaan langsung adalah menentukan kriteria. Jike tersedia, larutan garam fisiologis atau - lebih baik - dering laktat larutan atau - bahkan lebih baik - BSS (Solusi Garam Seimbang/Larutan garam) dapat digunakan untuk pembiasan lebih lanjut ‘Solust pembilasan isotonik hipertonik alr mata int dianggap efektif dalam ‘mencegah edema dan kerusakan epitel. Namun, untuk tujuan ini mereka harus digunakan segera dan dalam bentuk steril yang andal (perhatikan tanggal kedaluwarsa), * dalam kebanyakan kasus pengobatan efek inhalasi akan menjadi sangat penting, * setelah menghirup masif, pemberian glukokortikoid (inhalasi, yaitu) dan oksigen diindikasikan, + kodein dapat diberikan untuk mengobati batuk iritasi, + dalam keadaan apa pun muntah tidak boleh diinduksi, DOC LOK AMMONA 25 COPY 2018AGHEO + jangan memberikan arang aktif. 5, Tindakan Pemadaman Kebakaran PETUNJUK PEMADAMAN KEBAKARAN: Petugas pemadam kebakaran harus menggunakan pernafasan mandiri dengan tekanan positif aparatur (tipe potongan wajah penuh). MEDIA PEMADAMAN: bahan kimia kering, karbon dioksida, busa atau air PRODUK DEKOMPOSISI YANG BERBAHAYA: Dekomposisi termal (kebakaran destruktif) menghasilkan oksida unsur. Jangan biarkan limpasan masuk ke sistem pembuangan kotoran 6. Tindakan Pelepasan Terkadang PERLINDUNGAN DAN KONTAINEMEN Tumpahan: Area ventilasi. Gunakan peralatan pelindung yang ditentukan. Mengandung dan menyerap bahan penyerap. ‘Tempatkan dalam wadah pembuangan limbah. Basuh area dengan air. INSTRUKS! PEMBUANGAN: Air yang terkontaminasi dengan produk ini dapat dikirim ke pengolahan saluran pembuangan sanitasi fasilitas, sesuai dengan perjanjian setempat, fasilitas pengolahan limbah yang diijinkan atau habis dengan izin. Produk apa adanya - Membakar atau membuang tanh ke tempat yang disetujui TPA 7. Penanganan dan Penyimpanan ‘PENANGANAN: Lantai harus tahan alkali. PENYIMPANAN: Simpan dalam wadah asli dan tutup saat tidak digunakan. Letakkan wadah di area yang berventilasi baik dan pada suhu kamar 8. Kontrol Paparan / Perlindungan Pribadi Perlindungan kulit: kenakan sarung tangan pelindung (EN: 388, EN: 374). + kenakan celemek dan sepatu ketat yang panjang atau pakaian pelindung kimia yang cocok. itu pakaian pelindung harus tahan alkali. Perlindungan pernapasan: + Dalam keadaan darurat (mis.: Pelepasan zat yang tidak disengaja, melebihi nila batas pajanan kerja) perlindungan pernapasan harus dipakat. Pertimbangkan periode maksimuny untuk dipakel. DOC LoKS AMMONIA 25 COPY 2019AGHEO @ PT PUPUK KUJANG * filter gas K (EN: 14387), kode warna hijau. ‘* menggunakan perangkat isolasi untuk konsentrasi di atas batas penggunaan untuk perangkat filter, (EN: 145), untuk konsentrasi oksigen di bawah 17% volume, atau dalam keadaan seperti itu tidak jelas. Perlindungan mata: + pakai kacamata pengaman bahan kimia, (EN: 166), * Jika uap atau aerosol yang dapat melukai mata muncul, pakailah masker penuh (EN: 136) 9. Sifat Fisika dan Kimia Penampilan: Cairan tidak berwarna Bau Pedas pH> 11,00 Kepadatan pada 250C: 0,85 -0,95 g /cm3 Titik lebur: Tidak ada data Massa molar: 35,05 g / mol Titik nyala: Tidak ada data Kemudahan terbakar: Tidak mudah terbakar Kelarutan: larut 10. Stabilitas dan Reaktivitas Stabilitas: Termal stabil, mudah larut dalam air, alkali, Polimerisasi Berbahaya: Tidak akan terjadi Ketidakcocokan: Akan menyebabkan ledakan dengan tambahan yang kuat asam dan yodium Produk Penguraian: Nitrogen & hidrogen 11. Informasi Toksikologi “400 ppn(=278 mg/m. iit) =ImmodiatcTbrQal irritation 709 Respiratory } Human, pai 487 min in ai Eyeimitation inhalation data} 1700 ppax (~ 1182 mg/m. at) = Coug hing co view ff 200,650 pm 38-4519 might) = Life Ureatening ater 0.5 hour 5000 «10000 ppm (= 348-@953 main sr) = Mortality Seah female ‘un ust ified 12. Informasi Ekologis TOKSIKOLOGI AKUATIK. Daphnia magna Bioassay Pembaruan Statis 48 Jam irritating ‘DOC LOKB AMMONIA 25 COPY 2018AGHEO @ PT PUPUK KUJANG Lc50 = 101. mg/L BIODEGRADAS| Mudah terurai secara hayati dalam air dan tanah 13, Pertimbangan pembuangan Limbah berbahaya menurut Katalog Limbah. Jika tidak ada cara daur ulang, maka harus demikian dibuang sesuai dengan peraturan nasional dan lokal masing-masing. Limbah kode / penunjukan limbah menurut LoW: 06 02 03 * Ammonia (Limbah alkali solusi) 14. Informasi Transportasi 14.1. Nomor PBB: 2672 14.2. Kelas bahaya transportasi ADR / RID / ADN / ICAO / IATA: 8 IMDG: 8 14.3. Kelompok pengemasan ADR / RID / DAN / IMDG / ICAO / IATA: Ii 14.4, Bahaya lingkungan ADR, RID, ADN, ICAO / IATA: Berbahaya bagi lingkungan akuatik. IMDG: Polutan laut. 15. Informasi Peraturan 15.1. Peraturan / legislasi keselamatan, kesehatan, dan lingkungan khusus untuk zat ateu campuran Peraturan (EC) No 1907/2006; Peraturan Komisi (UE) No 453/2010, Lampiran |, amandemen Peraturan (EC) No 1907/2006; Petunjuk Dewan 67/548 / EEC; Peraturan (EC) No 1272/2008; ‘Arahan Komisi 2006/15 / EC, Arahan Dewan ‘91/689 / EEC; Arahan 2008/98 / EC; Petunjuk 98/24 / EC; Rekomendasi tentang pengangkutan barang berbahaya, Model Peraturan; ADR, ADN, RID, IMDG, ICAO / IATA. 15.2. Penilaian keamanan bahan kimia ‘Sesuai dengan Pasal 14 Peraturan EC No 1907/2006 Keselamatan Kimia Penilaian telah dilakukan untuk amonia anhidrat. 16. Informasi Lainnya Komentar: informasi. yang. dijelaskan. dalam MSDS. didasarkan_pada_pengetahuan. terbaik kami. saat- ini. ‘Bagaimanapun-kami-tidak-dapat-menjamin”-kerena-hasit-dari-aptikasi-dan~ penanganan” dapat bervariast sesual dengan Kondist yang diadopst. Mengacu pada pengetahuan praktis Anda dalam (DOC LOKE AMMONIA 25 COPY 2018