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P ANSWER KEY & SOLUTION KEY FINAL ROUND - 17 (PCB) Dt.27.04.2024

PHYSICS vnP n 1
dP
dv
 Pn  0

SECTION - A (35 Questions)

dP dp  pn p
01. (3) Magnitude of average velocity is nvP n 1  Pn  n 1

dv dv nVp nV
 displacement
vav  dp dP P
time Bulk modulus =  V 
 dV / V dv n
PQ 2R 05. (3) Volume of first substance, V1 = 1/2
= 
t t Volume of second substance, V2 = 4/3
Here t can be found from 1 4 30
 Relative density = (1 / 2)  (4 / 3)  11  2.73
1 2 
  t 2 or t  , where  
2  2 0 I 2 I
06. (3) B1  , B2  0
2R 2R

2
= 2  2s  0
BR  B12  B22  I 2  (2 I ) 2
/4 2R

 2R 2 2 0 50 I
| vav |   1 m/s  5I 
t 2 2R 2R

1 1 07. (1) Given, v  (3iˆ  5 ˆj ) m/s
02. (2) E  Rhe  2  2  
 n1 n2  B  (6iˆ  4 ˆj )T
E will be maximum for the transition for which   
Magnetic force, F  q (v  B )
1 1
 2  2  is = e[(3iˆ  5 ˆj )  (6iˆ  4 ˆj )]
 n1 n2 
Maximum. Here n2 is the higher energy level. = e[(30kˆ  12kˆ)]  18 ekN
ˆ
Thus, force is along positive Z-axis.
1 1
Clearly,  2  2  is maximum for the third tran- 08. (1) We know in case of parallel plates the charges
 n1 n2  distributed as shown in the figure.
sition,
Q1 –Q2
i.e. 2  1 . I transition represents the absorption
Q1– (–Q2 )
of energy.
Q1 + (–Q2) 2 Q1+ (–Q2)
03. (2) Induced electric field is non conservative in 2
–(Q1 –(– Q2))
2
nature and of circular in shape. 2
P1 P2
d
04. (3) (VP n )  0 09. (4) According to Faraday’s law of electro-mag-
dv
Ldi
netic induction Induced emf, e 
dt

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 52 
50  L  
 0.1 sec 

50  0.1 5 Total elongation =

 L   1.67 H
3 3 mg
L
mgL
10. (3) Work function of aluminium is 4.2 eV. The  dx  
LAY 0
( L  Y ) dy 
2YA
energy of two photons can not be added at the
moment photons collide with electron all its en-
ergy will be dissipated or wasted as this energy is  NiA
not sufficient to knock it out. Hence emission of 16. (3) M (mag×moment / volume)=
A
electron is not possible.
11. (1) Current flowing through the conductor. Ni (500)15
=   30000 Am 1
 25 102
4 nev d1 (1)
2
vd 4  4 16
 or 1   17. (2) Majority carries in an n-type semiconductor
1 nev d2 (2) 2
vd2 1 1 are electrons.
12. (1) According to Stefan’s law 18. (4) F + f = ma ...(i)

E  T 4 mR 2 a
FR – fR = ...(ii)
Heat radiated per unit area in 1 hour (3600s) is 2 R
= 5 × 10–8 × (3000)4 × 3600 = 1.5 × 1010] From equation (i) and (ii)
13. (4) Total charge Q1 + Q2 = Q'1 + Q'2 3ma 4F
= 12µC – 3µC = 9µC 2F  or a 
2 3m
Two isolated conducting spheres S1 and S2 are two
connected by a conducting wire. m4 F
F f 
3m
KQ'1 KQ2
 V1  V2    12  3  9C
2 / 3R R / 3 4 F
F FF 
3 3
Q1  2Q2  2Q2  Q2  9C
1 2
 Q1  6C and Q2  3C 19. (4) Translational KE = mv
2
14. (1) When hot water temperature (T) and surround- Rotational KE =
ing temperature (T0) readings are noted, and log
1 2 1
(T– T0) is plotted versus time, we get a straight I   mR 2 2  For a ring, I = mR 2 
line having a negative slope; as a proof of newton’s 2 2
law of cooling.
1 1
K R  m(R ) 2  mv 2
dT 2 2
  K T
dt So translational KE = rotational KE
T final
dT
t
 T  T0  KT
  1:1

Tinitial
T
  K  dt  ln 
0
   Kt
 Ti  T0 
KR
20. (4) n = n to n = 1, number of transition =
 ln(T  T0 )  ln(Ti  T0 )  kt
n(n  1)
So on comparing y  mx  c  10
2
So option (1) is correct.
n2 – n = 20
15. (1) Mass of section BC m/L (L – y).
n=5
 tension at B = T = m/L (L – y) g.
 elongation of element dy at B
T m dy
 dx  (dy)  (L  y) g
AY L AY
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A r
A 26. (1) 2 [As A = 4r 2 ]
A r
5A

21. (2) V r
4A 3
9A V r
9V V 3 A V 3
22. (1)     
V 2 A V 2
27. (3)   at  b,     a (t  t )  b. Subtrac-
tion gives   at
Average induced emf = ( / t ) = a. The aver--
age induced current is a/R
28. (4) n11  n22

 D1   D 2 
n1    n2  
 d   d 
15V
I   15  103 A  15mA
1 103    5893
n2  n1  1   62   84
The voltage drop across 250  = 20 V – 15 V =  2  4358
5V
29. (3) (KE)max = E – 
The current through 250  is
= 1.8 – 1.2
5V
I  0.02 A  20mA = 0.6 eV
250
i.e., eV0 = (KE)max
The current through the Zener diode is :
= eV0 = 0.6 eV
I Z  I  I   (20  15)mA  5mA  Stopping potential V0 = 0.6 V
23. (1) Let pressure outside be P0 30. (1) A is false and B is true
2T 31. (1) Conceptual
 P1 ( in smaller bubble)=P0  32. (2) By Gauss Law, flux is only by inside charges.
r
33. (1) Ideal ammeter has zero resistance
2T
P2 ( in bigger bubble) = P0  (R  r) 34. (4) U = U1 + U2
R
= n1 Cv1T + n2 Cv2T
 P1  P2
5 3
Hence air moves from smaller bubble to bigger = 3  RT  5  R  T
2 2
bubble.
= 15 RT
24. (1) G  15, ig  4 mA, i  6 A 35. (4) Diffraction effect can be observed in both sound
Required shunt, as well as light waves
SECTION - B (Attempt Any 10 Questions)
 i   4 103 
S  g  G   3 
 15
 i  ig  6  4  10 
 

4  103
 15
5.996
36. (2)
= 10m (in parallel)
25. (1) Kirchoff’s loop rule follows from conserva-
tion of energy.

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will be more pronounced.

We know that y = x tan   1  x 
 R 2
 1 
(3) Z  R   2fL 
2
Now, from figure 43. 
 2fC 
 x  x From above equation at f = 0  z = 
x tan  1   x tan  1  
tan   tan    R   R
1
x ( R  x) When f  (resonate frequency)
2 LC
Z  R
On solving tan   tan   tan 
37. (1) Conceptual 1
For f   Z starts increasing.
2 LC

38. (3) i  i.e., for frequency 0 – fr Z decreases
rR
and for fr to  , Z increases. This is justified by
R  graph (3)
v  iR  v
rR r µMa
1
R

44. (4)
here, r = constant Ma
N
Force of friction will balance
39. (2) Heat given by water, the weight.

Q1  msT  200  1 (25  10)  3000 cal g Mg

So µMa  Mg ; µ =
a
Heat absorbed by m gm of ice at –14°C to convert
into water at 10°C is :
45. (1) The equivalent circuit is shown in figure
Q 2  ( m s  T ) ice  m L ice  ( m s  T ) w ater
0 A
= m(0.5  14  80  1 10]  97 m Thus, Cab = C =
d
Hence, 97 m = 3000 or m = 31 gm.
40. (1) d sin   n C C
for 3rd maxima n = 3 a b
9
n 3  589 10 C C
 sin   
d 0.589
46. (1) Given T/2 = 0.5 s
or   sin 1
 3 10 
6
 T=1s
1 1
A1  Frequency, f    1Hz
41. (1)  , T 1
A2 1
If A is the amplitude, then
amax A1  A2 2A = 50 cm  A = 25 cm

amin A1  A2 47. (3) Both statement I and II are correct
42. (1) When interfering sources have same frequency
1
and their phase difference remains constant with u g (2t1  1)
S 4th 2
time, interference is sustained ( stayed for a finite 48. 
(2) S3rd 1
time interval). u  g (2t2  1)
2
If amplitudes are of nearby values then contrast

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55. (2) XeOF4

1
20  10(2  4  1) O
2
= 1 56. (3) HO P OH it ionizes in three steps because
20  10(2  3  1)
2 OH
three –OH groups are present.
20  5(7) 20  35 55 S3rd 11
= 20  5(5)  20  25  45  S  9 57. (1) E = 0 for isothermal process.
2 nd
58. (2) 2XY  X2 + Y2; Kc = 81
2
GmM mv M
49. (1)   n1  V 1 1
Rn
R R XY  X2 + Y2; K 'c =?
2 2
 n1 n1
2R 2R   K 'c  K c  81  9
T  R 2 
T  R 2
v GM
59. (2) In nitrobenzene –NO2 is strong electron with
16 drawing group decreases the reactivity
50. (4) For 16 g of helium, n1 = =4 60. (2) each double bonded Carbon must be connected
4
to two different group
16 1
For 16 g of oxygen, n2 =  61. (2) The ligands with small value of  0 are called
32 2 weak field ligands whereas those with large value
For mixture of gases, of  0 are called strong field ligands, hence CN–
causes more splitting than H2O and NH3.
n1Cv1  n2CV2 f
CV  where CV  R 62. (1) In F2O, fluorine is more electronegative than
n1  n2 2 oxygen and hence given oxidation number of –1.
n1CP1  n2CP2 63. (1) Conceptual
 f 
CP  where C P    1 R 64. (4) K2Cr2O7, KMnO4 and K2CrO4 are coloured
n1  n2 2 
due to charge transfer.
For helium, f = 3, n1 = 4 65. (1) MnO4– + 8H+ + 5e–  Mn2+ + 4H2O
For oxygen, f = 5, n2 = 1/2 Fe(C2O4)  Fe2+ + C2O42–
Fe2+  Fe3+ + e–, C2O42–  2CO2 + 2e–
 5  1 7 
4 R   R
CP  2   2 2  47 We can see that one mole of KMnO4 accepts 5
    1.62 electrons, whereas one mole of Fe(C2O4) loses 3
CV  3   1 5  29
 4 R    R  electrons.
 2  2 2 
 Number of moles of KMnO4 required to oxidise
CHEMISTRY one mole of Fe(C2O4) = 3/5 = 0.6 mole.
66. (1) Conceptual
SECTION - A (35 Questions) 67. (1) Lanthanoids are 14 elements in the VIth period
51. (2) No. of atoms = N A × No. of moles × 3(atomicity) (atomic number = 58 to 71) that are filling the 4f-
= 6.023 × 1023 × 0.1 × 3 = 1.806 × 1023 sublevel.
52. (4) It is valid for single electron species only w B 1000
68. (1) Molality, m  m  w
COOH B A

1 OH
2 c 1000 c 1000
6 b  ; mB  
53. (3) 3
5 m B (a  c) b (a  c)
4
Br 69. (4) Rate of Reaction α stability of carbocation.
4-Bromo-6-hydroxycyclohex-2-ene-1-carboxylic 70. (2) Assertion is true but Reason is false. The correct
acid form of Reason is :
In NH3, bond angle reduces to 107.5o due to
1 2 3 4
54. (2) H 2C C CH CH3 repulsion between lone pair on N and bond pairs
between N and H.
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71. (3) The given figure is showing positive deviation A-II, B-III, C-IV, D-I
from Raoult’s law.
E ocell can be determined by using this formula.
PA  PAo X A
E ocell  E right  E left  E cathode  E anode
Thus A–B attractive force should be weaker than
A–A and B–B attractive forces.
72. (2) CH3CHO + RMgX

H2O
 CH3–CH(OH)–R 87. (3) N N H – Antiaromatic
N
73. (4) Acetate
88. (3) Due to inert effect the stability of lower oxidation
74. (3) The overall reaction of Daniell cell is
state gradually increases while stability of higher
Zn(s) + Cu2+(aq) 
 Cu(s) + Zn (aq)
2+
oxidation state gradually decreases down the group
So, its cell representation will be as follows : in elements of group 13th to 15th. So correct orders
are :
Zn( s ) | Zn 2 (aq ) || Cu 2 (aq ) | Cu ( s)
(iii) Pb2+ > Pb4+, Bi3+ > Bi5+
75. (3) Conceptual (iv) Sn2+ < Pb2+, Sn4+ > Pb4+
76. (2) Mechanism of reaction as well as relative
concentration of reactants decides that how many 2.303 V
89. (2) k  t
log
V  Vt gives constant value of k.
concentration terms affect the rate of reaction i.e.,
order of reaction. Hence, it is 1st order reaction
77. (2) O 

90. (2) The correct match is as
78. (1) Catalyst catalyse both forward and backward A-III, B-I, C-IV, D-II.
reaction by same extent, without changing ΔG and  
91. (2) NH 2  NH 2 Neutral ligand
Kc .
79. (2) ‘A’ is CH  CH ; ‘B’ is CH3CHO; ‘C’ is It does not act as bidentate because when it acts as
bidentate a three membered ring (chelat complex)
CH3–CH3; ‘D’ is CH3COOH will be formed, that will be highly strained.
CH  CH   CH3–CH3
H2
Ni/150 300o W  96500 22.2  96500
92. (3) E metal    59.5
+ It 2  5  60  60
CH3–CHO 
[Ag(NH3 )2]
H+
 CH3COOH
177
80. (4) Both Assertion and Reason are true and Reason Oxidation number of the metal =  3
is the correct explanation of Assertion 59.5
NaCl dissociates in water and organic acids NO2 NH2
dimerises in benzene. Sn+HCl
93. (3)
81. (2) A = B = pricric acid H2O Br 2
82. (1) Hydrated size of ion  Charge density of NH2
Br
ion  H+ Br Br
a) NaNO2+HCl/278K
Br
83. (3) (I)-(C), (II)-(D), (III)-(A), (IV)-(B) b) H3PO2 + H 2O
Br
84. (1) 4 Br

5F 94. (2) A-II, B-I, C-IV, D-III

1
F F2
95. (3) C(graphite)  C(diamond), H =1.9 kJ
85. (2) S
4
C(graphite) + O2  CO2,........– H1
F F3
6
F C(diamond) + O2  CO2,.......– H 2
F1–S–F3
F2–S–F4’ (– H1 ) – (– H 2 ) = 1.9 kJ or H 2 = H1 +1.9
F5–S–F6, Each = 180o.
For combustion of 6 g, H 2 > H1 by
SECTION - B (Attempt Any 10 Questions)
1.9/2 = 0.95 kJ
86. (4) The correct match is

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COOH 103. (3) [NCERT 11th Page No. 67; Sub-topic 5.1.2]
104. (2) [NCERT 11 th Page No. 70; Sub-topic 5.3]
96. (3) ......Cycloheptanoic acid 105. (3) (NCERT 12th Pg 85 based on polygenic)
106. (3) (NCERT 11 th Pg.237, 2nd line)
Complex ion Hybridization of central atom 107. (2) (NCERT 12th Pg 122, Para 2)
[Fe(CN)6 ]4 d2sp3 (inner) 108. (4) (NCERT 12th Pg 76, based on concept of
[Mn(CN) 6 ]4  d2sp3 (inner) Incomplete Dominance & law of independent
97. (4) [Co(NH 3 )]
3 d2sp3 (inner) assortment)
[Ni(NH3 )6 ]2+ sp3d2 (outer) 109. (3) ( NCERT 11 th Page no.34 to 35,
conceptual.)
N 2(g) + 3H 2(g) 2NH 3(g) 110. (3) (NCERT 12 th Pg 101, Biochemical
98. (1) Initial moles a b Characterisation of Transforming Principle )
At equilibrium a-x b-3x 2x 111. (2) (NCERT 12th Pg 102, based on Figure 6.5 )
Total moles at equilibrium 112. (2) (NCERT 11th, Page no- 26, 2nd Paragraph,
= a – x + b – 3x + 2x = a + b – 2x Line no- 1-12)
113. (3) (NCERT 12th Pg 87, Para 3, Line 16)
 ax  114. (3) (NCERT 12th Pg. 78 , Para 1, Line 4)
p N 2 =Moles fraction of N2 × P =  P
 a  b  2x  115. (3) (NCERT 12th Pg 106, 6.4.2)
 b  3x   2x  116. (1) (NCERT 12th Pg 75, Figure 5.5)
p H2    P; pNH 3   P 117. (3) [NCERT 11th Newly added family]
 a  b  2x   a  b  2x 
2 118. (1) (NCERT 11th, Page no- 27, 2nd Paragraph,
 2x  2
p 2   p Line no- 5-7)
NH 3  a  b  2x 
Kp   119. (1) (NCERT 11th, Page no- 7, 2nd paragraph,
pN2  pH3 2  ax  b  3x  3
3

 P   P line no- 21,22)

 a  b  2 x  a  b  2 x 
120. (1) (NCERT 12th, Page no- 28, 1st, 2 nd and 3rd
4 x 2 (a  b  2 x) 2 paragraph, conceptual)

( a  x)(b  3x)3 P 2 121. (1) (NCERT 11th Para 10.1.1, Page no.163 )
99. (2) (I) Ketones do not give positive Tollen’s and 122. (1) (NCERT 11th Para 8.5.8, Page no.137 )
Fehling’s test. 123. (2) (NCERT 11th Para8.5.3.4 , Page no.134 )
(II) Aromatic aldehydes do not give positive 124. (2) (NCERT 11th Page no. 216, 13.7.2, Page
Fehling’s test no. 218, 13.8 - CONCEPT BASED and Page
(III) HCHO does not give positive haloform test no. 220 1st paragraph)
hc 125. (3) (NCERT 11th Page no. 212 – 19 th line and
100. (1) Energy of photon, E  hυ  Page 13.6 -concept based)
λ
126. (4) [NCERT 11th , Page 248, point 15.4.3.1]
(6.6 1023J s)(3×108 ms  ) 127. (1) [NCERT 11th , Page 248, Point 15.4.3.1]
  3.96 1019 J
5000  10 m 128. (2) (NCERT 12 th Page no. 247 fig.14.3
3.96 1019 J conceptual)
  2.475 eV
1.6×10 J/eV 129. (1) (NCERT 11th Pg.231, 14.4.1 Last para
( 1 ev  1.6  1019 J) 2nd line)
130. (4) (NCERT 12th Page no- 34, 1st paragraph,
Kinetic energy of the emitted photon = h  h0
Concept based)
= 2.475 – 2.20 = 0.275 eV
131. (3) (NCERT 11th Page no.31 fig.3.1, 32 to 33,
= 0.275 × 1.6 × 10–19 J = 4.4 × 10–20 J
name of the plant is fucus and its life cycle
diplontic so diploid is dominant, not
BOTANY gametophyte.)
132. (1) (NCERT 12th Page No 38, Last para)
Section - A (35 Questions) 133. (2) (NCERT 12th Pg 117, based on Figure 6.14)
101. (4) (NCERT 11th Page no.29 last line)
134. (4) (NCERT 12th Pg 85, 5.4)
102. (3) [ NCERT 11 th , Page no. 93 (First
paragraph) and Point no. 6.3.4] 135. (3) (NCERT 11th Para 10.1.1, Page no.163 )

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SECTION - B (Attempt Any 10 Questions) 165. (3) [NCERT 12th P.No.195 2nd and 3rd Line]
136. (4) [NCERT 11th , Page 249, Point 15.4.3.2] 166. (1) (NCERT 12th Page No.- 134 Immunity)
137. (1) [NCERT 11th , Page no. 88, Subpoint 6.2.1] 167. (3) (NCERT 11th Page No. 198)
138. (3) (NCERT 11th Para 10.2, 10.4 conceptual 168. (4) (NCERT 12th Page no.260,last line of 1st
based, Page no.165-170 ) and fig.15.1,based)
139. (3) (NCERT 11th Pg.230, 14.3, 3rd Paragraph, 169. (2) (NCERT 11th Page No. 336; Last line)
1st line) 170. (2) NCERT 11th P.No.309, Fig.20.6]
140. (2) (NCERT 11th Page no. 218, 1st paragraph) 171. (2) [NCERT 11th P.No.312, Disorders]
141. (2) (NCERT 11th, Page no- 23, Paragraph-2nd, 172. (1) [NCERT 11th P.No.321, Line 9th to 12th ]
Line no-9-19) 173. (2) [NCERT 11th P.No.321, 20 th Line]
142. (1) NCERT 12th, Page no- 34, Paragraph- 2.3, 174. (3) (NCERT 11th Page No. 299; 1st line)
Line no- 5-8
175. (1) (NCERT 11th Mixed question)
143. (4) (NCERT 11th, Page no- 11, Table-1.1)
176. (4) (NCERT 11th Page No. 338, 2nd paragraph)
144. (1) (NCERT 11th Para 8.5.8, Page no.137 )
177. (4) (NCERT 12th Page no- 139, Figure 7.10)
145. (4) (NCERT 11th Page no.37 fig.3.3 (d), salvinia
178. (2) (NCERT 11th, Page no- 156, Figure-9.6)
is heterosporous so produces male and female
gametophyte i.e. dioecious gametophyte.) 179. (4) (NCERT 12th page no-129, 1st paragraph,
146. (4) (NCERT 11 th Page no- 24, Paragraph- line no- 11-13)
2.3.3, Line no- 9 and 10) 180. (3) [NCERT 12th P.No.198, 2nd para 3rd Line]
147. (3) (NCERT 12th Page No. 246 2nd Para, 1st 181. (2) [NCERT 12th P.No.312, 208 Last para]
Line) 182. (1) (NCERT 12th Page No.- 155 - Common
148. (2) [NCERT 11th Page No. 79, 80 & Newly Diseases)
added family] 183. (3) (NCERT 11th, Page no- 147, 2nd paragraph,
149. (1) (NCERT 11th Para 8.5.8, Page no.137 ) Line no- 1st line)
150. (2) (NCERT 12th Pg 105, The Experimental 184. (4) (NCERT 12th Para 10.1, 10.2.2, 10.5 Page
Proof; Pg 106, Para 3; Pg 107, Para 2) no.181,182,187 )
185. (3) (NCERT 11th based extra)
SECTION - B (Attempt Any 10 Questions)
ZOOLOGY 186. (4) (NCERT 12th page no-127, 3rd paragraph,
Section - A (35 Questions) line no- 34)
151. (2) (NCERT 12 page no-128, 1 paragraph,
th st 187. (2) (NCERT 11th, Page no- 158, Paragraph-
line no-1 and 2) 9.12.5)
152. (4) [NCERT 11 P.No.310, Last Para]
th 188. (4) (NCERT 12th Para 10.4 Page no.185 )
153. (2) (NCERT 12th page no. 52, factual) 189. (3) [NCERT 12th P.No.213, 2nd and 3rd para]
154. (3) (NCERT 12th page no.62, para1) 190. (3) (NCERT 11th Page No. 339; 8th line of 4th
155. (2) (NCERT 12 page no 43, para1)
th Paragraph)
156. (2) (NCERT 12 page no 44, para1)
th 191. (4) (NCERT 12th Page No. 142-143)
(2) (NCERT 11th page no 112, para1, line 16) 192. (4) [NCERT 11 P.No.304,Last Para]
th
157.
(2) (NCERT 11th Page No. 53; examples of 193. (4) [NCERT 11 P.No.321, Forebrain and
th
158.
arthropoda) Hindbrain para]
159. (4) (NCERT 12 Para 10.2.1Page no.182 )
th 194. (3) (NCERT 12th Page no.264 to 265.)
(3) (NCERT 12th NCERT Page no.260,1st para 195. (4) (NCERT 12 Page no.229 1 para,6
th st th
160.
last line and fig.15.1) LINE)
161. (4) (NCERT 11 Page No.- 183 - Respiratory
th 196. (3) (NCERT 11 th Page No.- 199 - Cardiac
organs) cycle)
162. (3) (NCERT 12 page no.60, last para)
th 197. (1) (NCERT 12th Page No.- 156 - Cancer)
163. (3) (NCERT 12th page no.64, Para 2, line 2) 198. (3) (NCERT 11th page no.104, para2)
(3) (NCERT 11th NCERT - Page No.- 196 - 199. (2) (NCERT 11 page no 102, last para)
th
164.
Coagulation of blood) 200. (2) (NCERT 11th Page No. 297; 4th line)

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