B. Homologous Series Mordanic Compounds 2% ND ve - Organic Compounds 1. Complete the table pertaining to ‘homologous series’ by placing the correct word/s in the respective blank in each sentence. are a family of organic compounds following a regular a] Homologous se mula. fx pattern, all members of the series sharing a b] Methane and ethane are members of the homologous series of A) K AWE G They differ in molecular formula by a group and in vapour density by a Shy cc] Members of the alkene series have the elements and functional group. d] The boiling point of butene [CyHg] is yAG RE than that of ethene [Hy] 2. Give reasons for the following: a] ‘Homologous series’ are prevalent for organic compounds and not for inorganic compounds. b] Methane, ethane and propane have similar chemical properties but differ in physical properties. ¢]_ Hydrocarbons of the same homologous series have the same general formula. 3. Match the hydrocarbon in Column-I with its correct - a] Homologous series b] LU.P.A.C. name c] General formula: ‘Column I Homologous Series | Name[LUP.A.C] | General Formula : GH 1. Alkanes Butane i] CyHop : GH, 2. Alkenes Ethene ii) Cyn + CoH, 3. Alkynes Propene iii] Cygne : CyHio Propyne : CGHy Ethane : CoHy Methane : CHy Ethyne 101 @ scanned with OKEN ScannerCc. Structure~ Organic Compounds 1. Match the sentences in Column I with the c ‘orrect answers in Column II. Column T ‘Column IL 1. ‘The formula indicating the actual no. of | At Condensed , atoms in a molecule of an organic compound. structural formula 2. The formula which shows a full B: Electronic 1 branched arrangement of various atoms structural formula in an organic compound 3. A short hand method of representing |: Molecular formula the structural formula. 14. The formula which represents the D: Branched structural formula depicting valence electrons structural formula The molecular formula of: A: Gy H. Methane B: C3Hg 2, Ethane C: HyC-CH)—CH—CH3 3, Ethene [ethylene] D: H-C=C-H 4. Ethyne [acetylene] E: CqHio 5. Propane HyC=CHg 6. 1-Butene [1-butylene] # # 7. Butane G: H-¢-¢-H HH The condensed structural formula of: Ho 18. Ethane H: Sc=cZ H H 9. Ethene [ethylene] I: H3C—CH3 10. Ethyne [acetylene] HjC—CH=CH), 111. Propyne [methyl acetylene] CoH ii 2. Propane L: H-C I H 13. Butane M: CH, 114. Propene N: H,C-C=CH IThe branched structural formula of: 115. Ethane O: 116. Ethene P: 17. Propyne Q: /18. 1-Butyne [ethyl acetylene] R: 102 @ scanned with OKEN ScannerE. Nomenclature — Organic Compounds 1. Complete the sentences by selecting the correct word/s from the brackets. a] The system of assignment of names to organic compounds is termed . [isomerism / nomenclature / trivial system] D]_ The name assigned to an organic compound on basis of IUPAC rules is its name & on basis of trivial system its _ name. [common / systematic] 2. Complete the table given below by filling in each blank correctly. Formula IUPAC Name Common Name 1. H-CH3 2 Ethane ag LLLELEREAHEEEAASREEHAPEEAATE Propane 4. H3C- CH) - CH, - CH3| 5. Pentane 6. Hexane 7. HyC=CH Ethylene 8. Propene 9. 1-butene 10. 2-butylene 1. 1-pentene 12, Ethyne 13. H3C- C=CH U4. 2-butyne 15. Methanol 16. H3C - CH) - OH 17. Propan-1-ol 18. Propan-2-ol 19. Butan-1-ol 20. Formaldehyde 21. HyC - CHO 2. Propanal 23, Formic acid 24. Ethanoic acid 2. Propanoic acid 26. HC - CH - CH, - COOH] 27. iso-butynic acid 28. Hy - CHp - Cl 29. fo ite ab) ae Acetone 30. Methoxy methane nc aac Scanned with OKEN Scanner3. Match the organic compounds in Column A with their IUPAC name in Column B ‘Column A Column A a A. Pentan-3-ol H,C-CHy-CHyCH-CH, 13. CHCh, B, 2-chloro propanal ae CH HyC-C-CH, . Hyc-C-chhy CH3 Br C. 3:methyl but-1-yne D. Trichloromethane CH, E, 2,2,dimethyl propane 1 HjC-CH-CH=CH, (Chis - CH) - CH, - COOH F, 2+bromo-2-methyl propane Hy G. Methoxy ethane HyC- CH-C=CH CH - CH) - C= C-CH; H. 2-methyl propan- os 1. 2-methyl pentane H,C- CH-CH,OH CHCl - CHCl, J. Bromoethane OH CH; HyC-Cliy CH-CHpCH, 18. CH C-CH,OH K. 3-methyl butanal Sd L. 3-methyl but-1-ene t H,C-CH,-C=CH, CH ~ CH ~ CH ~ CHy - Cll M. 1,1,2,2,tetrachloroethane N. Butan-2- a jutan-2-ol HyC-CH,-CH-CH, |. CH - O- CH O. 1-chloro-butane P. 2,2,dimethyl propan-1-ol CH3CH,Br CH - CH, - COOH Q 2-methyl but-l-ene CH; OH CH, R. 3-methyl butan-2-ol |. CH;-CH -CH-CH, .. CH3-CHy-CH-CH,OH : S. Butanoic acid H CH; oH T. 2-methyl-butan-1-ol 1 + CHy-CH-C=0 . CHy- CH-CHy-C= U, 2-methyl propanoic acid V. 3bromo-2:methyl butanoic acid W.Propanoic acid X. Pent-2-yne 106 @ scanned with OKEN ScannerF. Hydrocarbons 1. Complete the table pertaining to hydrocarbons in general by selecting the correct terns in each case. nic compounds containing, 1. Hydrocarbons are aliphatic, open-chain org nitrogen.} and ______ only. [carbon, sulphur, oxygen, hydrogen, The general molecular formula of hydrocarbons is IQ, CQHyO2, CyHyI Aliphatic hydrocarbons are divided into two main grou! and unsaturated hydrocarbons of which alkanes are ——— hydrocarbons while alkenes and alkynes are __ hydrocarbons. [saturated, unsaturated]. 4. Alkanes have the general formula alkynes - [CaHan2 + CaHane2 + CaHon 5. Methane and ethane are examples of an , ethene [ethylene] an example of an |, while acetylene an example of an [alkyne, alkene, alkane] [availability / non-availability] of electrons in the Dp ps i.e. saturated » alkenes and 6. The [single, double, triple] covalent bond/s, makes saturated organic compounds [less, more] reactive and therefore they undergo characteristic [substitution, addition] reactions. G. ALKANES - METHANE AND ETHANE Introduction, Sources and Nomenclature of alkanes 1. Name the following : i. A saturated aliphatic gaseous paraffin. . The main natural source of alkanes. 3, The second member of the homologous alkane series. 4. The type of bond between the two carbon atoms in methane. I5, An alkane containing one carbon atom only. 2. Complete the table given below representing the formula of alkanes. ‘Common. Molecular Structural Electronic name formula formula structure 1. Methane 2. Ethane 107 @ scanned with OKEN Scanner