Page 1 of 2 CPP-SANKALP_LS-1.
-PH-VI
CPP
SHEET – 1 (LIQUID SOLUTION)
Solutions, Types of Solutions, Concentration Terms i.e., Mole Fraction/Molarity/Molality etc.
LEVEL - 1
1. Which of the two, molarity or molality, is a better way to express the concentration of a solution and why?
2. Under what condition, moality = molarity? Explain your answer with reason.
3. A solution is prepared by adding 2 g of glucose into 18g of water. Calculate the mass per cent of the glucose.
–1
4. What is the concentration of glucose in mol L , if 40 g of it is dissolved in enough water to make a final
volume upto 2L?
5. A solution contains 25 per cent water, 25 per cent ethanol and 50 pe cent acetic acid by mass. Calculate the
mole fraction of each component.
6. 2.82g of glucose (mol. mass = 180 are dissolved in 30g of water. Calculate the:
i) molality of solution
ii) mole fraction of (a) glucose (b) water.
7. Find the molarity and molality of a 15% solution of H2SO4 (density = 1.02 g/cc).
8. Calculate the masses of cane sugar and water required to prepare 250g of 25% cane sugar solution.
9. Calculate the molarity of the following solutions:
i) 4g of caustic soda is dissolve din 200 mL of the solution
ii) 5.3g of anhydrous sodium carbonate is dissolved in 100 mL of solution.
iii) 0.365 g of pure HCl gas is dissolved in 50 mL of solution.
10. Calculate the molarity of pure water (d = 1 g/L).
LEVEL – 2
11. What volume of 95% sulphuric acid (density = 1.85 g/cc) and what mass of water must be taken to prepare
100 cc of 15% solution of sulphuric acid? (density 1.10 g/cc)
12. If the density of methanol is 0.793 g/mL, what is its volume needed for making 2.5 L of its 0.25 M solution?
13. Molarity of H2SO4 is 0.8 and its density is 1.06 g/mL. What will be its concentration in terms of molality and
mole fraction.
14. A 6.9 M solution of KOH in water contains 30% by mass of KOH. Calculate the density of the KOH solution.
(Molar mass of KOH = 56 g mol–1)
–1
15. Calculate the moles of methanol is 5 litre of its 2 m solution, if the density of the solution is 0.981 kg L .
(Molar mass of methanol = 32 g mol–1).
16. 2.46 g of sodium hydroxide (molar mass = 40) are dissolved in water and the solution is made to 100 cm3 in a
volumetric flask. Calculate the molarity of the solution.
17. The density of a solution containing 13% by mass of sulphuric acid is 1.09 g/mL. Calculate the molarity and
normality of the solution.
18. Calculate molality (m) of 3M solution of NaCl whose density is 1.25gm/ml.
MM2 1
19. Prove the formula d = M where d = density of the solution. M = molarity of the solution,
1000 m
m = molality of the solution, MM2 = molar mass of solution.
20. 20 mg of K+ ions are present in 1L of aqueous solution. Density of solution is 0.8 gm mL–1 What is the
+
concentration of K ion in ppm.
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Page 2 of 2 CPP-SANKALP_LS-1.-PH-VI
ANSWER KEY LIQUID SOLUTION – SHEET – 1
Level - 1
1. Molarity of a solution is the number of mole of the solute dissolved per litre of the solution. The volume
changes with the change of temperature, i.e., molarity changes with change in temperature. However, molality
is indepdent of change in temperature as it is the number of moles of the solute dissolved in 1 kg of the
solvent (mass does not vary with temperature). It is, thus better to express concentration in terms of molality.
2. The molality can be equal to molarity if the solution is solution 1000 g of solution 1000 g of solvent.
3. 10%
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4. 0.11 mol L
5. Mole fraction of water : 0.5
Mole fraction of ethyl alcohol : 0.197
Mole fraction of acetic acid: 0.302
6. i) 0.52
ii) 0.9907
7. 1.56 M, 1.79 m
8. Wcanesugar = 62.5gm. WH2O 187.5g
9. i) 0.5 M
ii) 0.5 M
iii) 0.2 M
10. 55.5 M
Level - 2
11. WH2O 90.62g, VH2SO4 9.38cc
12. 25.22 mL
13. 0.814 m, mole fraction = 0.014
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14. 1.288 g mL
15. 9.682
16. 0.615
17. 1.44m, 2.88 N
18. 2.79 m
20. 25 ppm
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FIITJEE Ltd., ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Terminal), New Delhi - 16, Ph : 6515949 , 6865182, 6854102, Fax : 6513942
