Safety Data Sheet

Revision Number: 007.2 Issue date: 04/12/2021

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: LOCTITE 416 INSTANT ADHESIVE IDH num ber: 209589
known as LOCTITE® 416™ INSTANT
ADHESIV
Product type/use: Adhesive Item number: 41661
Restriction of Use: None identified Region: United States
Com pany address: Contact information:
Henkel Corporation Telephone: +1 (860) 571-5100
One Henkel Way MEDICAL EMERGENCY Phone: Poison Control Center
Rocky Hill, Connecticut 06067 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: w ww.henkelna.com

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING: BONDS SKIN IN SECONDS.
COMBUSTIBLE LIQUID.
CAUSES EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.

HAZARD CLASS HAZARD CATEGORY

FLAMMABLE LIQUID 4
EYE IRRITATION 2B
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3

PICTOGRAM(S)

Precautionary Statements

Prevention:
Keep aw ay from heat, sparks, open flames, hot surfaces - no smoking. Avoid breathing vapors,
mist, or spray. Wash affected area thoroughly after handling. Use only outdoors or in a w ell-
ventilated area. Wear protective gloves, eye protection, and face protection.
Response:
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Call a POISON CENTER or physician if you feel unw ell. IF IN EYES: Rinse
cautiously w ith water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical attention. In case of fire: Use foam, dry
chemical or carbon dioxide to extinguish.
Storage:
Store in a w ell-ventilated place. Keep container tightly closed. Store in a w ell-ventilated place.
Keep cool. Store locked up.
Disposal:
Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations.

Classification complies w ith OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of t he
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS

IDH number: 209589 Product name: LOCTITE 416 INSTANT ADHESIVE know n as LOCTITE® 416™ INSTANT ADHESIV
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Hazardous Component(s) CAS Num ber Percentage*
Ethyl 2-cyanoacrylate 7085-85-0 80 - 100

* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate pr otections.

4. FIRST AID MEASURES

Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give
artificial respiration. If symptoms develop and persist, get medical attention.

Skin contact: Do not pull bonded skin apart. Soak in w arm soapy water. Gently peel apart
using a blunt instrument. If skin is burned due to the rapid generation of heat
by a large drop, seek medical attention. If lips are bonded, apply w arm water
to the lips and encourage w etting and pressure from saliva in mouth. Peel or
roll lips apart. Do not pull lips apart w ith direct opposing force.

Eye contact: Immediately flush w ith plenty of w ater for at least 15 minutes. Get medical
attention. If eyelids are bonded closed, release eyelashes with warm water by
covering w ith a w et pad. Do not force eye open. Cyanoacrylate will bond to
eye protein and w ill cause a lachrymatory effect which will help to debond the
adhesive. Keep eye covered until debonding is complete, usually w ithin 1-3
days. Medical attention should be sought in case solid particles of
polymerized cyanoacrylate trapped behind the eyelid caused abrasive
damage.

Ingestion: Ensure breathing passages are not obstructed. The product w ill polymerize
rapidly and bond to the mouth making it almost impossible to sw allow. Saliva
w ill separate any solidified product in several hours. Prevent the patient from
sw allowing any separated mass.

Sym ptoms: See Section 11.

Notes to physician: Surgery is not necessary to separate accidentally bonded tissues. Experience
has show n that bonded tissues are best treated by passive, non-surgical first
aid. If rapid curing has caused thermal burns they should be treated
symptomatically after adhesive is removed.

5. FIRE FIGHTING MEASURES

Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.

Special firefighting procedures: Wear a self-contained breathing apparatus with a full face piece operated in
pressure-demand or other positive pressure mode.

Unusual fire or explosion hazards: None

Hazardous combustion products: Trace amounts of toxic and/or irritating fumes may be released and the use of
breathing apparatus is recommended.

6. ACCIDENTAL RELEASE MEASURES

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and
unprotected personnel.

Environm ental precautions: Ventilate area. Do not allow product to enter sew er or waterways.

Clean-up methods: Do not use cloths for mopping up. Flood w ith w ater to complete polymerization
and scrape off the floor. Cured material can be disposed of as non-hazardous
w aste. Refer to Section 8 "Exposure Controls / Personal Protection" prior to
clean up.

IDH number: 209589 Product name: LOCTITE 416 INSTANT ADHESIVE know n as LOCTITE® 416™ INSTANT ADHESIV
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 7. HANDLING AND STORAGE
Handling: Prevent contact w ith eyes, skin and clothing. Do not breathe vapor and mist.
Wash thoroughly after handling. Avoid contact with fabric or paper goods.
Contact w ith these materials may cause rapid polymerization w hich can
generate smoke and strong irritating vapors, and cause thermal burns.

Storage: Keep in a cool, w ell ventilated area aw ay from heat, sparks and open flame.
Keep container tightly closed until ready for use.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Em ployers should complete an assessment of all w orkplaces to determine the need for, and selection of, proper
exposure controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER

1 ppm STEL
0.2 ppm TWA
Ethyl 2-cyanoacrylate (Respiratory None None None
sensitization)
(Dermal sensitization)

Engineering controls: Use positive dow n-draft exhaust ventilation if general ventilation is insufficient
to maintain vapor concentration below established exposure limits.

Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure
limit(s).

Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should
be used if the potential for splashing or spraying of product exists.

Skin protection: Use nitrile gloves and aprons as necessary to prevent contact. Do not use
PVC, nylon or cotton.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid
Color: Clear
Odor: Irritating
Odor threshold: 1 - 2 ppm
pH: Not applicable
Vapor pressure: < 0.5 mm hg (77 °F (25°C))
Boiling point/range: > 212 °F (> 100°C)
Melting point/ range: Not determined
Specific gravity: 1.1 at 68 °F (20°C)
Vapor density: 3 Approximately
Flash point: 80 - 93 °C (176°F - 199.4 °F) Tagliabue closed cup
Flam m able/Explosive limits - low er: Not determined
Flam m able/Explosive limits - upper: Not determined
Autoignition temperature: 485 °C (905°F)
Flam m ability: Not applicable
Evaporation rate: Not available.
Solubility in w ater: Not available.
Partition coefficient (n-octanol/water): Not determined
VOC content: < 2 %; < 20 g/l (California SCAQMD Method 316B) (Estimated)
Viscosity: Not available.
Decom position temperature: Not available.

IDH number: 209589 Product name: LOCTITE 416 INSTANT ADHESIVE know n as LOCTITE® 416™ INSTANT ADHESIV
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 10. STABILITY AND REACTIVITY
Stability: Stable under recommended storage conditions.

Hazardous reactions: Rapid exothermic polymerization w ill occur in the presence of water, amines, alkalis and
alcohols.

Hazardous decomposition None

products:

Incom patible materials: Water, amines, alkalis and alcohols.

Reactivity: Not available.

Conditions to avoid: Spontaneous polymerization.

11. TOXICOLOGICAL INFORMATION

Relevant routes of exposure: Skin, Inhalation, Eyes

Potential Health Effects/Symptoms

Inhalation: May cause respiratory tract irritation. Exposure to vapors above the established exposure limit
results in respiratory irritation, w hich may lead to difficulty in breathing and tightness in the
chest.
Skin contact: Bonds skin in seconds. May cause skin irritation. Cyanoacrylates have been reported to cause
allergic reaction but due to rapid polymerization at the skin surface, an allergic response is rare.
Cyanoacrylates generate heat on solidification. In rare circumstances a large drop w ill burn the
skin. Cured adhesive does not present a health hazard even if bonded to the skin.
Eye contact: Irritating to eyes. Causes excessive tearing. Eyelids may bond.
Ingestion: Not expected to be harmful by ingestion. Rapidly polymerizes (solidifies) and bonds in mouth. It
is almost impossible to sw allow.

Hazardous Component(s) LD50s and LC50s Im m ediate and Delayed Health Effects
Ethyl 2-cyanoacrylate None Irritant, Allergen, Respiratory

OSHA Carcinogen
Hazardous Component(s) NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
Ethyl 2-cyanoacrylate No No No

12. ECOLOGICAL INFORMATION

Ecological inform ation: Not available.

13. DISPOSAL CONSIDERATIONS

Information provided is for unused product only.

Recom mended method of disposal: Follow all local, state, federal and provincial regulations for disposal.

14. TRANSPORT INFORMATION

The transport information provided in this section only applies to the material/formulation itself, and is not specific to an y
package/configuration.

U.S. Department of Transportation Ground (49 CFR)

Proper shipping name: Combustible liquid, n.o.s. (Cyanoacrylate ester)
Hazard class or division: Combustible Liquid
Identification number: NA 1993
Packing group: III

International Air Transportation (ICAO/IATA)

Proper shipping name: Aviation regulated liquid, n.o.s. (Cyanoacrylate ester)
Hazard class or division: 9
Identification number: UN 3334
Packing group: III

IDH number: 209589 Product name: LOCTITE 416 INSTANT ADHESIVE know n as LOCTITE® 416™ INSTANT ADHESIV
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 Exceptions: Primary packs containing less than 500ml are unregulated by this mode of
transport and may be shipped unrestricted.

Water Transportation (IMO/IMDG)

Proper shipping name: Not regulated

Hazard class or division: None
Identification number: None
Packing group: None

15. REGULATORY INFORMATION

United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed as active or are exempt from listing on the Toxic Substances
Control Act (TSCA) inventory.

TSCA 12 (b) Export Notification: None above reporting de minimis

CERCLA/SARA Section 302 EHS: None above reporting de minimis.

None above reporting de minimis.
CERCLA/SARA Section 311/312: Fire, Reactive, Delayed Health, Immediate Health
CERCLA/SARA Section 313: None above reporting de minimis.

California Proposition 65: No California Proposition 65 listed chemicals are know n to be present.

Canada Regulatory Information

CEPA DSL/NDSL Status: Contains one or more components listed on the Non-Domestic Substances List. All other
components are listed on or are exempt from listing on the Domestic Substances List.
Components listed on the NDSL must be tracked by all Canadian Importers of Record as
required by Environment Canada. They may be imported into Canada in limited quantities.
Please contact Regulatory Affairs for additional details.

16. OTHER INFORMATION

This safety data sheet contains changes from the previous version in sections: 8, 15

Prepared by: Product Safety and Regulatory Affairs

Issue date: 04/12/2021

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. How ever, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property a nd
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all w arranties, express or implied, including w arranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

This Safety Data Sheet has been generated based on OSHA Hazard Communication Standard (29 CFR 1910.1200) and provides
information in accordance with U.S. federal law only. No w arranty or representation of any kind is given w ith respect to the
substantive or export law s of any other jurisdiction or country. Please confirm that the information provided herein conforms to the
substantive export or other law of any other jurisdiction prior to export. Please contact Henkel Product Safety and Regulatory
Affairs for additional assistance.

IDH number: 209589 Product name: LOCTITE 416 INSTANT ADHESIVE know n as LOCTITE® 416™ INSTANT ADHESIV
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