Shield disinfecting fogger air conditioner odour

treatment
Safety Data Sheet
According to SANS 10234:2008 and SANS 11014:2010
Issue date:27/05/2020 Revision date: 27/05/2022 : Version: 1.0

SECTION 1: Identification
1.1. Product identifier
Product form : Mixture
Trade name : Shield disinfecting fogger air conditioner odour treatment
Type of product : Automotive airconditioning system cleaner and disinfectant
Product code : SH755
Product group : Trade product
1.2. Relevant identified uses of the substance or mixture and uses advised against
No additional information available
1.3. Supplier's details

Manufacturer
Shield Chemicals (Pty) Ltd
9 London Rd
Apex
P.O. Box 1939
1501 Benoni - South Africa
T (011) 421 7111
[email protected]
1.4. Emergency telephone number
Emergency number : (011) 421 7111

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to the United Nations GHS
Aerosol, Category 1 H222;H229
Serious eye damage/eye irritation, Category 2A H319
Hazardous to the aquatic environment — Acute Hazard, Category 2 H401
Full text of H statements : see section 16
2.2. Label elements
Labelling according to the United Nations GHS
Hazard pictograms (GHS-ZA) :

GHS02 GHS07
Signal word (GHS-ZA) : Danger
Hazardous ingredients : propane; butane, liquefied, under pressure; Ethanol
Hazard statements (GHS-ZA) : H222 - Extremely flammable aerosol.
H229 - Pressurised container: May burst if heated.
H319 - Causes serious eye irritation.
H401 - Toxic to aquatic life
Precautionary statements (GHS-ZA) : P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P211 - Do not spray on an open flame or other ignition source.
P251 - Do not pierce or burn, even after use.
P264 - Wash hands, forearms and face thoroughly after handling.
P273 - Avoid release to the environment.
P280 - Wear eye protection, protective clothing, protective gloves.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P337+P313 - If eye irritation persists: Get medical advice.
P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 °C.
P501 - Dispose of contents and container to an approved waste disposal plant.
2.3. Other hazards
Adverse physicochemical, human health and : Pressurised container: May burst if heated,Extremely flammable aerosol,Causes serious eye
environmental effects irritation,Toxic to aquatic life

13/10/2020 EN (English) 1/7

Shield disinfecting fogger air conditioner odour treatment
Safety Data Sheet
According to SANS 10234:2008 and SANS 11014:2010

SECTION 3: Composition/information on ingredients

3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % Classification according to
the United Nations GHS
Ethanol >80% of Flam. Liq. 2, H225
concentrate Acute Tox. Not classified (Oral)
Acute Tox. Not classified (Dermal)
Acute Tox. Not classified
(Inhalation:dust,mist)
Eye Irrit. 2A, H319
Aquatic Acute Not classified
butane, liquefied, under pressure (CAS-No.) 106-97-8 20.0 - 30.0% Pyr. Gas Not classified
of aerosol Flam. Gas 1, H220
Aquatic Acute 2, H401
propane (CAS-No.) 74-98-6 10.0 - 20.0% Pyr. Gas Not classified
of aerosol Flam. Gas 1, H220
Aquatic Acute Not classified

Full text of H-statements: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing.
First-aid measures after skin contact : Wash skin with plenty of water.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Call a poison center or a doctor if you feel unwell.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after eye contact : Eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Extremely flammable aerosol.
Explosion hazard : Pressurised container: May burst if heated.
5.3. Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
No additional information available
6.1.1. For non-emergency personnel
Emergency procedures : Ventilate spillage area. No open flames, no sparks, and no smoking. Avoid contact with skin
and eyes.
6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. For further information
refer to section 8: "Exposure controls/personal protection".
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
For containment : Collect spillage.
Methods for cleaning up : Mechanically recover the product.
Other information : Dispose of materials or solid residues at an authorized site.

13/10/2020 EN (English) 2/7

Shield disinfecting fogger air conditioner odour treatment
Safety Data Sheet
According to SANS 10234:2008 and SANS 11014:2010

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Ensure good ventilation of the work station. Keep away from heat, hot surfaces, sparks, open
flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition
source. Do not pierce or burn, even after use. Avoid contact with skin and eyes. Wear personal
protective equipment.
Hygiene measures : Do not eat, drink or smoke when using this product. Always wash hands after handling the
product.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F. Store in a well-
ventilated place. Keep cool.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

propane (74-98-6)
South Africa - Occupational Exposure Limits (Airborne Pollutants)
Local name Propane
OEL TWA (mg/m³) 1800 mg/m³
OEL TWA (ppm) 1000 ppm
Regulatory reference Government Notice No. R 904
butane, liquefied, under pressure (106-97-8)
South Africa - Occupational Exposure Limits (Recommended Limits)
Local name Butane
OEL TWA (mg/m³) 1430 mg/m³
OEL TWA (ppm) 600 ppm
OEL STEL (mg/m³) 1780 mg/m³
OEL STEL (ppm) 750 ppm
Regulatory reference Government Notice. R: 1179
South Africa - Occupational Exposure Limits (Airborne Pollutants)
Local name n-Butane
OEL TWA (mg/m³) 1430 mg/m³
OEL TWA (ppm) 600 ppm
OEL STEL (mg/m³) 1780 mg/m³
OEL STEL (ppm) 750 ppm
Regulatory reference Government Notice No. R 904

8.2. Appropriate engineering controls

Appropriate engineering controls : Ensure good ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures, such as personal protective equipment (PPE)
Hand protection : Protective gloves
Eye protection : Safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment

8.4. Exposure limit values for the other components

No additional information available

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Liquid.
Colour : clear.
Odour : characteristic.
Odour threshold : No data available
pH : No data available
pH solution : No data available
Relative evaporation rate (butylacetate=1) : No data available

13/10/2020 EN (English) 3/7

Shield disinfecting fogger air conditioner odour treatment
Safety Data Sheet
According to SANS 10234:2008 and SANS 11014:2010

Relative evaporation rate (ether=1) : No data available

Melting point : Not applicable
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Extremely flammable aerosol.
Vapour pressure : No data available
Vapour pressure at 50 °C : No data available
Relative vapour density at 20 °C : No data available
Relative density : No data available
Relative density of saturated gas/air mixture : No data available
Density : No data available
Relative gas density : No data available
Solubility : No data available
Log Pow : No data available
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : Pressurised container: May burst if heated.
Oxidising properties : No data available
Explosive limits : No data available
Lower explosive limit (LEL) : No data available
Upper explosive limit (UEL) : No data available
9.2. Other information
No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity
Extremely flammable aerosol. Pressurised container: May burst if heated.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4. Conditions to avoid
Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity (oral) : Not classified

Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified

propane (74-98-6)
LC50 inhalation rat (ppm) > 800000 ppm (15 minutes, Rat, Male / female, Experimental value, Inhalation (gases))
butane, liquefied, under pressure (106-97-8)
LC50 inhalation rat (mg/l) 1442.738 - 1443 mg/l 15 MIN
LC50 inhalation rat (ppm) 800000 ppm 15 MIN
Ethanol
LD50 oral rat 10470 mg/kg
LD50 dermal rabbit > 15800 mg/kg
LC50 inhalation rat (mg/l) 51 mg/l/4h

13/10/2020 EN (English) 4/7

Shield disinfecting fogger air conditioner odour treatment
Safety Data Sheet
According to SANS 10234:2008 and SANS 11014:2010

Skin corrosion/irritation : Not classified

Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified

Shield disinfecting fogger air conditioner odour treatment

Vaporizer Aerosol

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : Toxic to aquatic life.
Hazardous to the aquatic environment, short- : Toxic to aquatic life.
term (acute)
Hazardous to the aquatic environment, long- : Not classified
term (chronic)

propane (74-98-6)
LC50 fish 1 24 mg/l (96 h, Pisces, Literature study)
LC50 fish 2 49.9 mg/l (96 h, Pisces, Fresh water, QSAR)
EC50 Daphnia 1 7 mg/l (48 h, Daphnia magna, Literature study)
BCF fish 1 9 - 25 (Pisces, QSAR)
Log Pow 1.09 - 2.8 (Experimental value, 20 °C)
butane, liquefied, under pressure (106-97-8)
LC50 fish 1 > 1000 mg/l (96 h, Pimephales promelas, QSAR)
EC50 72h algae (1) 5.3 - 5.5 mg/l (Algae, QSAR)
Log Pow 2.89 (Experimental value)
Ethanol
LC50 fish 1 11.2 mg/l
EC50 Daphnia 1 5012 mg/l
Bioconcentration factor (BCF REACH) < 10
12.2. Persistence and degradability
Shield disinfecting fogger air conditioner odour treatment
Persistence and degradability No additional information available

propane (74-98-6)
Persistence and degradability Readily biodegradable in water.
butane, liquefied, under pressure (106-97-8)
Persistence and degradability Readily biodegradable in water.
Ethanol
Chemical oxygen demand (COD) 2.04 g O₂/g substance
12.3. Bioaccumulative potential
Shield disinfecting fogger air conditioner odour treatment
Bioaccumulative potential No additional information available

propane (74-98-6)
BCF fish 1 See section 12.1 on ecotoxicology 9 - 25 (Pisces, QSAR)

Log Pow See section 12.1 on ecotoxicology 1. 09 - 2.8 (Expe rim ental value , 20 °C )

Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
butane, liquefied, under pressure (106-97-8)
Log Pow See section 12.1 on ecotoxicology 2. 89 (Ex peri men tal val ue)

Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
Ethanol
Bioconcentration factor (BCF REACH) See section 12.1 on ecotoxicology < 10

13/10/2020 EN (English) 5/7

Shield disinfecting fogger air conditioner odour treatment
Safety Data Sheet
According to SANS 10234:2008 and SANS 11014:2010

12.4. Mobility in soil

Shield disinfecting fogger air conditioner odour treatment
Mobility in soil No additional information available

propane (74-98-6)
Surface tension 0.016 N/m (-47 °C)
Log Pow See section 12.1 on ecotoxicology 1. 09 - 2.8 (Expe rim ental value , 20 °C )

Ecology - soil Not applicable (gas).

butane, liquefied, under pressure (106-97-8)
Surface tension < 0.1 N/m (0 °C)
Log Pow See section 12.1 on ecotoxicology 2. 89 (Ex peri men tal val ue)

Ecology - soil Not applicable (gas).

Ethanol
Mobility in soil 1
12.5. Other adverse effects
Ozone : Not classified
Other adverse effects : No additional information available

SECTION 13: Disposal considerations

13.1. Disposal methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.

SECTION 14: Transport information

In accordance with SANS / IMDG / IATA

SANS IMDG IATA

14.1. UN number
1950 1950 1950
14.2. Proper Shipping Name
AEROSOLS AEROSOLS Aerosols, flammable
14.3. Transport hazard class(es)
2.1 2.1 2.1

Not applicable
14.4. Packing group
Not applicable Not applicable Not applicable

14.5. Environmental hazards

Dangerous for the environment : No Dangerous for the environment : No Dangerous for the environment : No
:
No supplementary information available

14.6. Special precautions for user

- SANS
Special provisions (SANS) : 63, 190
Limited quantities (SANS) : See SP277
Limited quantities (SANS) : See SP277
Packagings, large packagings and IBCs : P003
Packing instructions (SANS)
Packagings, large packagings and IBCs Special : PP17, PP87
packing instructions (SANS)

- IMDG
Special provisions (IMDG) : 63, 190, 277, 327, 344, 381, 959
Packing instructions (IMDG) : P207, LP200
Special packing provisions (IMDG) : PP87, L2
EmS-No. (Fire) : F-D - FIRE SCHEDULE Delta - FLAMMABLE GASES

13/10/2020 EN (English) 6/7

Shield disinfecting fogger air conditioner odour treatment
Safety Data Sheet
According to SANS 10234:2008 and SANS 11014:2010

EmS-No. (Spillage) : S-U - SPILLAGE SCHEDULE Uniform - GASES (FLAMMABLE, TOXIC OR CORROSIVE)
Stowage category (IMDG) : None

- IATA
PCA Excepted quantities (IATA) : E0
PCA Limited quantities (IATA) : Y203
PCA limited quantity max net quantity (IATA) : 30kgG
PCA packing instructions (IATA) : 203
PCA max net quantity (IATA) : 75kg
CAO packing instructions (IATA) : 203
CAO max net quantity (IATA) : 150kg
Special provisions (IATA) : A145, A167, A802
ERG code (IATA) : 10L
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1. Safety, health, and environmental national regulations specific for the product
No additional information available

SECTION 16: Other information

Issue date : 27/05/2020
Revision date : 27/05/2022

Full text of H-statements:

H220 Extremely flammable gas.
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H227 Combustible liquid
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H303 May be harmful if swallowed
H305 May be harmful if swallowed and enters airways
H311 Toxic in contact with skin.
H313 May be harmful in contact with skin
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H371 May cause damage to organs.
H400 Very toxic to aquatic life.
H401 Toxic to aquatic life
H402 Harmful to aquatic life
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

SDS South Africa

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements o nly. It should not therefore be
construed as guaranteeing any specific property of the product.

13/10/2020 EN (English) 7/7