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DPP-05_Thermodynamics_Chemistry (PC)_11th JEE(Gurukul)
1. For a perfectly crystalline solid CP,m = aT2 where 6. Which substance is expected to have highest
'a' is constant, if CP,m is 0.2 JK–1mol–1 at 10K, then molar entropy under standard conditions of
molar entropy at 100 K is : temperature and pressure?
(A) 100 J/K-mol (B) 3.3 × 105 J/K-mol (A) NO2(g)
(C) 10 kJ/K-mol (D) 10 J/K-mol (B) N2O4(g)
(C) I2(s)
2. What is Entropy change when volume of 2.8 gm (D) H2O(l)
of N2 changes from 4 litre to 2 litre at constant
temperature of 27°C? 7. For the reaction:
[ln 2 = 0.7, R = 8.3 J/mole-K] NH4CONH2(s) 2NH3(g) + CO(g)
(A) 0.851 Joule (B) 0.581 Joule
If equilibrium pressure is x bar, then rG° would
(C) –0.581 Joule (D) –0.851 Joule
be:
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3. If Hvaporisation of substance X (l) (molar mass: 30 (A) – 3RT ln x + ln 2 − ln3
3
g/mol) is 300 J/g at it's boiling point 300 K, then
(B) – 3RT [ln x + 2 ln 2 – ln 3]
molar entropy change for reversible condensation
(C) – RT [3 ln x – 2 ln 3]
process is:
(D) – RT[3 ln x]
(A) 30 J/mol K (B) – 300 J/mol K
(C) –30 J/mol K (D) None of these
8. What is rG (kJ/mole) for synthesis of ammonia
at 298 K at following sets of partial pressure:
4. The value of change in enthalpy for 1 mole of
H2O in H2O (l, 1 atm, 373K) → H2O (g, 1 atm, N2(g) + 3H2(g) 2NH3(g); rG° = –33 KJ/mole.
393 K) [Take R = 8.3 J/K mole, log2 = 0.3; log3 = 0.48]
Given: CP(H2O, l) = 75.3 JK–1mol–1 , CP = (H2O, Gas N2 H2 NH3
g) = 35 JK–1mol–1, vapH at 373K = 40 kJ/mol Pressure (atm) 1 3 0.02
(A) 740 kJ (B) 39.3 kJ (A) + 6.5
(C) 40.7 kJ (D) 740 J (B) – 6.5
(C) + 60.5
5. In the caves limestone is formed by following (D) – 60.5
reaction.
Ca2+(aq) + 2CO3– (aq) ⎯⎯⎯ → 9. Calculate log10 {[C]eq [A]eq } where [C] and [A]
CaCO3(s) + CO2(g) + are equilibrium molar concentration of respective
H2O(l) species, when 2 mole each of A and B were
If 1 mol of CaCO3 is formed at 298 K and 1 atm allowed to come to equilibrium at 900 K.
pressure, the reaction performs 2.47 kJ of PV
A+B C + D; G° = 460.6
work, pushing back the atmosphere as the
Calorie
gaseous CO2 form. At the same time 38.95 kJ of
heat is absorbed from environment. Identify the ln X = 2.303logX
Take:
correct value. R = 2Cal / Kmole
(A) H = 38.95 kJ / mol (A) – 5.56 × 10–2
(B) U = 36.48 kJ / mol (B) – 5.57 × 10–3
(C) H – U = 2.47 kJ / mol (C) –1.1 × 10–2
(D) All are correct (D) – 1.1 × 10–3
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10. Diagram shows how G for a hypothetical (C) If rxnG° for a reaction is negative then
reaction changes as temperature changes. equilibrium constant will be greater than one.
Select incorrect statement among following. (D) In spontaneous process Ssurr always
increases.
13. An exothermic reaction is represented by the
graph:
(A) (B)
(A) H > 0
(B) S > 0
(C) process is spontaneous, if T < 250K (C) (D)
(D) system is in equilibrium at T = 250K
11. For a hypothetical reaction: A(g) + B(g) → C(g)
Multiple Correct Questions
Initially all reactants and products are at 1 atm. 14. Two moles of an ideal gas (Cv,m = 3/2R) is
Statement-1: 'x' represents G° subjected to following change of state.
Statement-2: In this reaction all reactant would A (500 K, 5.0 bar) ⎯⎯⎯⎯
Reversible
→ B ⎯⎯⎯⎯
Isochoric
→
isothermal cooling
get converted into product. expansion
Statement-3: At equilibrium partial pressure of Single stage
C will be greater than 1 atm. C (250 K, 1.0 bar) ⎯⎯⎯⎯⎯⎯⎯
adiabatic compression
→ D(3 bar)
Statement-4: At equilibrium total pressure of The correct statement is/are:
mixture will be greater than 3 atm. (A) The pressure at B is 2.0 bar
(B) The temperature at D is 450 K
(C) HCD = 1000 R
(D) UBC = 375 R
15. If one mole monoatomic ideal gas was taken
through process AB as shown in figure, then
select correct option(s).
Given: ln 1.5 = 0.4
(A) Only statement-1 & 4 are incorrect.
(B) Only statement-1 & 3 are correct.
(C) Only statement-2 & 3 are correct.
(D) Only Statement-3 is correct.
(A) wAB = – 1496.52 J
12. Identify the correct statement:
(B) qAB = 5237.82 J
(A) Endothermic reaction are never spontaneous.
(C) HAB = 3741.3 J
(B) During spontaneous process Gibbs free
energy will always decrease. (D) SAB is +ve
*****
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DPP-05_Thermodynamics_Chemistry (PC)_11th JEE(Gurukul)
ANSWER KEY
1. (D) 9. (A)
2. (C) 10. (C)
3. (C) 11. (D)
4. (C) 12. (C)
5. (D) 13. (A)
6. (B) 14. (A,B,C)
7. (A) 15. (A,B,D)
8. (D)
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