Matrix CHEMISTRY

JEE Academy Daily Practice Problems (DPP)

Agile Topic : Gaseous State DPP # 1
1. Calculate the pressure of the gas in cm of Hg in each case (liquid used is Hg)

(i) (ii)

(iii)

2. Calculate the pressure at the point A in :

3
152m  = 6.8 g/cm
A
(A) N/m2 (B) mm of Hg
(C) m of H2O (D) torr (E) atm
3. The liquids shown in the fig. in the two arms are mercury (specific gravity = 13.6) and water. If the
difference of heights of the mercury columns is 2 cm. Find the height h of the water column.

4. In the following arrangement find the pressure of the confined gas in cm of Hg.

of Hg


Hg

5. A chamber of constant volume contains hydrogen gas. When the chamber is immersed in a bath of melting
ice (0ºC) the pressure of the gas is 800 torr. What pressure will be indicated when the chamber is brought
to 100ºC ?

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6. Give a one meter long glass tube closed at one end having a uniform cross-section containing a mercury column
of 10 cm length. At a distance of 39 cm from the closed end. By what distance would this column move down
if the tube is held vertical with the open end downwards. [Take atmospheric pressure to be 78 cm of Hg.]

7. For gaseous state, which of the following is correct ?

(A) Thermal energy = Molecular attraction
(B) Thermal energy >> Molecular attraction
(C) Thermal energy << Molecular attraction
(D) Molecular force >> attraction in liquid
8. A thin balloon filled with air at 47ºC has a volume of 3 litre. If on placing it in a cooled room its volume becomes
2.7 litre , the temperature of room is :
(A) 42ºC (B) 100ºC
(C) 15ºC (D) 200ºC

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 Matrix CHEMISTRY
JEE Academy Daily Practice Problems (DPP)
Agile Topic : Gaseous State DPP # 2
1. A balloon blown up with 1 mole of gas has a volume of 480 mL at 7ºC. the balloon is filled to (7/8)th of
its maximum capacity suggest,
(a) Will the balloon burst at 30ºC ?
(b) The minimum temperature at which it will burst.
2. A gas cylinder containing cooking gas can withstand a pressure of 15 atmosphere. The pressure gauge of
the cylinder indicates 12 atmosphere at 27ºC. Due to a sudden fire in the building the temperature starts
rising. At what temperature will the cylinder explode ?
3. If V0 is the volume of a given mass of gas at 273 K at a constant pressure, then according to Charles' law, the
volume at 10ºC will be :
(A) 10 V0
1
(B) 273
(V0 + 10)
10
(C) V0 + 273
283
(D) 273
V0

4. At what temperature in centrigrade, will the volume of a gas at 0ºC double itself, pressure remaining constant?
5. A flask is of a capacity of one litre. What volume of air will escape from the flask, if it is heated from 27°C to
57°C ? Assume pressure to be constant.
6. A gas occupies 300 mL at 27°C and 380 mm pressure. What would be its volume at STP ?
7. A bottle is heated with mouth open to have a final temperature as five times its original value of 25°C. The
percentage of expelled air is :
(A) 50%
(B) 25%
(C) 33%
(D) 40%
8. Calculate volume occupied by 8.8 g CO2 gas, if 5.6 g CO gas occupies 6.24 L at same Temperature and
pressure.
(A) 22.4 L
(B) 1.12 L
(C) 4.48 L
(D) 6.24 L
9. 4.2 gm of a gas at 27ºC occupied the same volume as 0.84 gm of hydrogen at 17°C and at the same pressure.
What is the molecular mass of the gas ?
10. An under water bubble with a radius of 0.5 cm at the bottom of tank, where the temperature is 27ºC and
pressure is 9 atm rises to the surface, where temperature is 627ºC and pressure is 1 atm. What will be the
radius of bubble when it reaches to surface ?
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11. The product of PV is plotted against P at two temperatures T1 and T2 and the result is shown in figure.
What is correct about T1 and T2?

(A) T1 > T2
(B) T2 > T1
(C) T1 = T2
(D) T1 + T2 = 1
12. A vertical cylinder of total length 100 cm is closed at the lower end and is fitted with a movable frictionless
gas tight disc at the other end . An ideal gas is trapped under the disc . Initially the height of the gas column
is 90 cm when the disc is in equilibrium between the gas and the atmosphere. Mercury is then slowly
poured on the top of the disc and it just starts overflowing when the disc has descended through 32cm.
Find the atmospheric pressure . Assume that the temperature of the gas to remain constant and neglect
the thickness and weight of the disc

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 Matrix CHEMISTRY
JEE Academy Daily Practice Problems (DPP)
Agile Topic : Gaseous State DPP # 3
1. 2 g of a gas A is introduced into an evacuated flask kept at 25°C. The pressure is found to be 1 atm. If 3 g of
another gas B is added to the same flask, the total pressure becomes 1.5 atm. Assuming ideal gas behavior,
calculate :
(a) the ratio of mol. weight of gases, MA and MB
(b) the volume of the vessel, if gas A is O2
2. A mixture of helium and methane at 1.4 bar pressure contains 20% by weight of helium. Partial pressure of
helium will be :
(A) 0.7 bar (B) 0.9 bar
(C) 0.6 bar (D) 0.8 bar
3. Two gases A and B having molecular weights 60 and 45 respectively are enclosed in a vessel. The weight of A
is 0.5 g and that of B is 0.2g . The total pressure of the mixture is 750 mm. Calculate the partial pressure of the
two gases
4. One mole of N2O4(g) at 300 K is kept in a closed rigid container at 1 atm. It is heated to 900 K when 20% by
mass of N2O4 decomposes to NO2(g). The resultant pressure is
(A) 1.2 atm (B) 3.6 atm
(C) 2.4 atm (D) none of these
5. The density of a mixture of O2 and N2 at NTP is 1.3 g litre–1. Calculate partial pressure of O2
6. The density of gas A is twice that of a gas B at the same temperature. The molecular weight of gas B is thrice
that of A.The ratio of the pressure acting on A and B will be :
(A) 6 : 1 (B) 7 : 8
(C) 2 : 5 (D) 1 : 4
7. 1.0 litre of N2 and 7/8 litre of O2 at the same temperature and pressure were mixed together. What is the
relation between the masses of the gases in the mixture ?
(A) mN2 = 3 mO2 (B) mN2 = 8 mO2
(C) mN2 = mO2 (D) mN2 = 16 mO2
8. Two glass bulbs of equal volume and filled with a gas at 0°C and pressure of 76 cm of Hg, are connected by
a narrow tube. One of the bulb is then placed in a water bath maintained at 62°C and the other bulb is
maintained at 0ºC. What is the new value of the pressure inside the bulbs? The volume of the connecting tube
is negligible.
9. Consider the arrangement of bulbs shown below:

1.0 L 1.0 L 0.5 L

N2 Ne H2
635 mm 212 mm 418 mm

What is the pressure of the system when all the stopcocks are opened?

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10. Two glass bulbs A (of 100 mL capacity), and B (of 150 mL capacity) containing same gas are connected
by a small tube of negligible volume. At a particular temperature, the pressure in A was found to be 20
times more than that in bulb B. The stopcock is opened without changing the temperature. The pressure
in A will :
(A) drop by 75% (B) drop by 57%
(C) drop by 25% (D) will remain same
11. A dry air sample has the composition
% by mol of N2 = 80%
% by mol of O2 = 20%
Choose the correct option(s) about this air sample.
(A) Average molecular weight of this air sample is 28.8 g/mol
(B) % by weight of O2 in this air sample is 22.22%
(C) % by weight of O2 is this air sample is 20%
(D) Average molecular weight of this air sample is 30 g/mol

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 Matrix CHEMISTRY
JEE Academy Daily Practice Problems (DPP)
Agile Topic : Gaseous State DPP # 4
1. Calculate the temperature at which the R.M.S. velocity of sulphur dioxide molecules is the same as that of
oxygen at 300 K :
(A) 600°C (B) 600 K
(C) 300 K (D) 300°C
2. Which of the following statements is not true?
(A) The ratio of the mean speed to the rms speed is independent of the temperature.
(B) The square of the mean speed of the molecules is equal to the mean squared speed at a certain
temperature.
(C) Mean kinetic energy of the gas molecules at any given temperature is independent of the mean speed.
(D) The difference between rms speed and mean speed at any temperature for different gases diminishes
as larger and yet larger molar masses are considered.
3. Suppose that we change the rms speed (vrms) of the gas molecules in closed container of fixed volume
from 5 × 104 cm sec1 to 10 × 104 cm sec1. Which one of the following statements might correctly
explain how this change was accomplished?
(A) By heating the gas, we double the temperature.
(B) By pumping out 75% of the gas at constant temperature, we decreased the pressure to one quarter
of its original value.
(C) By heating the gas, we quadrupled the pressure.
(D) By pumping in more gas at constant temperature, we quadrupled the pressure.
(E) None of the above.
4. If a gas is allowed to expand at constant tempeature, then :
(A) the kinetic energy of the gas molecules decreases
(B) the kinetic energy of the gas molecules increases
(C) the kinetic energy of the gas molecules remains the same
(D) None of these
5. A helium atom is two times heavier than a hydrogen molecule at 298 K. The average translational kinetic
energy of helium is :
(A) two times that of hydrogen molecules
(B) same as that of hydrogen molecules
(C) four time that of hydrogen molecules
(D) half that of hydrogen molecules
6. At what temperature, will hydrogen molecules have the same kinetic energy as nitrogen molecules have, at
35°C?
 28  35   2  35   2  28 
(A)   °C (B)  28  °C (C)  35  °C (D) 35 °C
 2     

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7. K.E. of one mole of helium at 273 K in Calories is :
(A) 819 Cal (B) 81.9 Cal
(C) 8.19 Cal (D) None of these
8. The translational kinetic energy for 14 grams of nitrogen gas at 127°C is nearly : (mol. mass of nitrogen = 28
and gas constant = 8.31 J/mol/K.
(A) 1.0 J (B) 4.15 J
(C) 2494.2 J (D) 3.3 J
9. At the same T and P, which of the following gases will have the highest average translational kinetic energy
per mole?
(at. wt: H = 1, C = 12, O = 16, S = 32, F = 19)
(A) H2 (B) O2 (C) CH4
(D) SF6 (E) All the same.
10. Two bulbs A and B of equal capacity are filled with He and SO2 respectively at same temperature.
(i) How will the URMS be affected if volume of B becomes 4 times that of A at constant temperature.
(ii) How will the URMS be affected if half of the molecules of SO2 are removed at constant temperature.

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 Matrix CHEMISTRY
JEE Academy Daily Practice Problems (DPP)
Agile Topic : Gaseous State DPP # 5
1. Let the most probable velocity of hydrogen molecules at a temperature t0C is V0. Suppose all the molecules
dissociate into atoms when temperature is raised to (2t + 273)0C then the new r.m.s velocity is
(A) 2 / 3 V0
(B) 3(2  273 / t ) V0
(C) 2 3 V0
(D) 6 V0
2. With the increase in temperature of a gas, the fraction of molecules having velocities within a given range around
the most probable velocity, would
(A) increase
(B) decrease
(C) remain unchanged
(D) initially increase and then decrease
3. Express the kinetic energy per mole of a monoatomic gas of molar mass M, at temperature T K in terms
of the mean speed of the molecules ( c ) :
8M
(A) ( c )2
3
3M
(B) ( c )2
16

 2M 
(C)   ( c )2
  

 3M 
(D)   ( c )2
 16 

4. The ratio of rates of diffusion of SO2, O2 and CH4 under identical conditions is :
(A) 1 : 2 : 2 (B) 1 : 2 : 4
(C) 2 : 2 : 1 (D) 1 : 2 : 2
5. The rate of effusion of helium gas at a pressure of 1000 torr is 10 torr min–1. What will be the rate of
effusion of hydrogen gas at a pressure of 2000 torr at the same temperature ?
(A) 20 torr min–1
(B) 40 torr min–1
(C) 20 2 torr min–1
(D) 10 torr min–1
6. Pressure in a bulb dropped from 2000 to 1500 mm in 50 minute, when the contained oxygen leaked
through a small hole. The bulb was then completely evacuated. A mixture of oxygen and another gas of
molecular weight 72 in molar ratio 1 : 1 at a total pressure of 6000 mm was introduced. Find the molar
ratio of two gases remaining in the bulb after a period of 70 minute

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7. 180 mL of a hydrocarbon diffuses through a porous membrane in 15 minutes while 120 mL of SO2 under
identical conditions diffuses in 20 minutes. What is the molecular mass of the hydrocarbon ?
8. At room temperature, ammonia gas at one atmospheric pressure and hydrogen chloride at P atmospheric
pressure are allowed to effuse through identical pinholes from opposite ends of a glass tube of one metre
length and of uniform cross section. NH4Cl is first formed at a distance of 60 cm from the end through
which HCl gas is sent in. What is the value of P ?
Passage : [Read the following passage carefully and answer the questions. (Q.9 to Q.11)]
The speed of a molecule of a gas changes continuously as a result of collisions with other molecules and
with the walls of the container. The speeds of individual molecules therefore change, but it is expected
that the distribution of molecular speeds does not change with time.
A direct consequence of the distribution of speeds is that the average kinetic energy is constant for a
given temperature.
The average K.E, is defined as
1  1 mv 2  1 mv 2  ....  1 mv 2  1 1
KE =  1 2 N = m(v12 + v22 + ..... + vN2) = m V2
N 2 2 2  2N 2

1 1   dNi 2 
Alternatively it may be defined as KE =  m
 dNi v 12  = 1 m 
  v1
N 2  2  N 
 i   i 
dNi
where is the fraction of molecules having speeds between vi and vi + dv and as proposed by Maxwell
N
3/2
dN  m 
= 4  2KT  exp (–mv2/2kT).v2.dv
N  

 1 dN 
The plot of  N dv  is plotted for a particular gas at two different
 

temperatures against ‘v’ as shown.

The majority of molecules have speeds which cluster around vMPS in the middle of the range of v. There
area under the curve between any two speeds v1 and v2 is the fraction of molecules having speeds between
v1 and v2.
The speed distribution also depends on the mass of the molecule. As the area under the curve is the same
(equal to unity) for all gas samples, samples which have the same vMPS will have identical Maxwellian
plots. On the basis of the above passage answer the questions that follow.
9. If a gas sample contains a total of ‘N’ molecules, the area under any given maxwellian plot is equal to:
(A) infinite (B) N
N
 dN 
(C) 1 (D)   dv   dv
0

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10. For the above graph, drawn for two different samples of gases at two different temperatures T1 and T2,
which of the following statements is necessarily true :

(A) If T2 > T1, MA is necessarily greater than MB

(B) If T1 > T2, MB is necessarily greater than MA
T2 T1
(C) M > M
B A

(D) Nothing can be predicted

11. If two gases ‘A’ and ‘B’ and at temperature TA and TB respectively have identical Maxwellian plots, then
which of the following statements are true :
T
A B T
(A) TB = TA (B) MB = MA (C) M  M
A B

(D) Gases A and B may be O2 and SO2 at 27ºC and 327ºC respectively.

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 Matrix CHEMISTRY
JEE Academy Daily Practice Problems (DPP)
Agile Topic : Gaseous State DPP # 6
1. Choose the correct alternative (more than one may be correct) (B.M.C.= Bimolecular collision)
(at constant P) (n- is constant throughout)
(A)  is constant
(B) BMC made by 1 molecule per second is directly proportional to T.
(C) BMC for all the molecules per unit volume is directly proportional to T2.
(D) None of these
2. Choose the correct alternative (more than one may be correct) (B.M.C.= Bimolecular collision)
(at constant V) (n- is constant throughout)
(A)  is constant
(B) BMC made by 1 molecule per second is directly proportional to P .
(C) BMC for all the molecules per unit volume is directly proportional to T 3/2.
(D) none of these
3. 10 ml of CO is mixed with 25 ml air having 20% O2 by volume. What would be the final volume if none of CO
and O2 is left after the reaction?
4. Calculate the volume of CO2 evolved by the combustion of 50 ml of a mixture containing 40% C2H4 and 60%
CH4 (by volume)
5. 10 mL of gaseous organic compound contain C, H and O only was mixed with 100 mL of O2 and exploded
under identical conditions and then cooled. The volume left after cooling was 90 mL. On treatment with KOH
a contraction of 20 mL was observed. If vapour density of compound is 23, derive molecular formula of the
compound.
6. 200 ml of a gaseous mixture containing CO, CO2 and N2 on complete combustion in just sufficient amount of
O2 showed contraction of 40 ml. When the resulting gases were passed through KOH solution it reduces by
50 % then calculate the volume ratio of VCO : VCO : VN in original mixture.
2 2

(A) 4 : 1 : 5
(B) 2 : 3 : 5
(C) 1 : 4 : 5
(D) 1 : 3 : 5
7. When 20 ml of mixture of O2 and O3 is heated, the volume becomes 29 ml and disappears in alkaline pyragallol
solution. What is the volume precent of O2 in the original mixture?
(A) 90%
(B) 10%
(C) 18%
(D) 2%

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8. A mixture of C3H8 (g) & O2 having total volume 100 ml in an Eudiometry tube is sparked & it is observed that
a contraction of 45 ml is observed what can be the composition of reacting mixture.
(A) 15 ml C3H8 & 85 ml O2
(B) 25 ml C3H8 & 75 ml O2
(C) 45 ml C3H8 & 55 ml O2
(D) 55 ml C3H8 & 45 ml O2
9. A balloon with volume 4200 m3 is filled with helium gas at 27°C, 1 bar pressure and is found to weigh 700
kg. If density of air is 1.2 kg m–3, the payload of balloon is :
(A) 5040 kg
(B) 4340 kg
(C) 3500 kg
(D) 5740 kg.
10. 500 ml of a hydrocarbon gas burnt in excess of oxygen yields 2500 ml of CO2 and 3 lts of water vapours. All
volume being measured at the same temperature and pressure. The formula of the hydrocarbon is
(A) C5H10
(B) C5H12
(C) C4H10
(D) C4H8

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 Matrix CHEMISTRY
JEE Academy Daily Practice Problems (DPP)
Agile Topic : Gaseous State DPP # 7
1. Vander waal’s equation for :
(a) high pressure and low temp (i) PV = RT + Pb
(b) low pressure (ii) PV = RT – a/V
(c) force of attraction is negligible (iii) PV = RT + a/V
(c) volume of molecule is negligible (iv) [P – (a/V2)] (V – b) = RT.
(A) (a)-(i), (b)-(ii), (c)-(i), (d)-(ii)
(B) (a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)
(C) (a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)
(D) (a)-(iv), (b)-(ii), (c)-(iii). (d)-(i).

2.

If the above plot is replotted at 373 K, then which of the following plots may show the correct behaviour at 373 K.

(A) (B) (C) (D)

3. Four different identical vessels at same temperature contains one mole each of C2H6, CO2, C2 and H2S
at pressures P1, P2, P3 and P4 respectively. The value of Vander waals constant ‘a‘ for C2H6, CO2, Cl2
and H2S is 5.562, 3.640, 6.579 and 4.490 atm.L2.mol–2 respectively. Then
(A) P3 < P1 < P4 < P2 (B) P1 < P3 < P2 < P4
(C) P2 < P4 < P1 < P3 (D) P1 = P2 = P3 = P4
4. Consider the following statements :
1. (a)NH3 > (a)H2O [(a) is Vander waal's constant]
2. Pressure of the real gas is more than the ideal gas for same temperature and volume of the container.
3. Compresssibilty factor for H2 (g) is never less than unity at any temperature
The above statements 1, 2, 3 respectively are : (T = True, F = False)
(A) T F F (B) F F F (C) F T F (D) T T F
5. Compressibility factor (Z) for N2 at – 50°C and 800 atm pressure is 1.95. The mole of N2 gas required
to fill a gas cylinder of 100 L capacity under the given conditions is _____________.
6. Graph depicting correct behaviour of ideal gas & H2 gas will be (neglect a)

(A) (B) (C) (D)

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7. Which of the following statement(s) are true about Z vs P graph for a real gas at a given temperature.

(A) dZ dP  0 as P  0 for most real gases

(B) dZ dP = –ive as P  0 for most real gases
(C) dZ dP  0 at a pressure where repulsive and attractive forces are comparable.
(D) dZ dP = +ive for real gases at extremely high pressure.
8. For the four gases A, B, E and D the value of the excluded volume per mole is same. If the order of the critical
temperature is TB > TD > TA > TE then the order of their liquefaction pressure at a temperature T (T < TE) will be :
(A) PA < PB < PE < PD (B) PB < PD < PA < PE (C) PE < PA < PD < PB (D) PD < PE < PA < PB
9. At the critical point for H2 gas, value of z = 3/8, then the value of z for the similar condition of CO2, O2, SO2 at
their respective critical points will be :
(A) greater than 3/8 (B) smaller than 3/8 (C) equal to 3/8 (D) nothing can be said
10. Consider the following statements: If the van der Waal’s parameters of two gases are given as
a (atm lit2 mol–2) b (lit mol–1)
Gas X: 6.5 0.056
Gas Y: 8.0 0.011
then i : VC (X) < VC (Y); ii : PC (X) < PC (Y); iii : TC (X) < TC(Y)
Select correct alternate:
(A) i alone (B) i and ii (C) i, ii and iii (D) ii and iii
11. Critical temperature of a gas is ______ Boyle temperature.
(A) higher than (B) equal to (C) lower than (D) no relation
12. The vander waal gas constant ‘a’ is given by
2 2
1 1 RTC 27 R TC
(A) VC (B) 3 PC VC2 (C) 8 P (D) PC
3 C 64

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 ANSWER KEY
DPP # 1
1. (i) 10 cm of Hg (ii) 66 cm of Hg (iii) 86 cm of Hg
2. (A) 10132500 , (B) 76000 , (C) 1033.6 , (D) 76000 , (E) 100
3. 27.2 cm
30  6.8 10  27.2
4. Pgas = 76 – 15 – – = 76 – 15 – 15 – 20 = 26 cm of Hg
13.6 13 .6
5. 1093 torr 6. x = 5.7 cm 7. B 8. C

DPP # 2
1. (a) it will not burst (b) 47°C 2. 102ºC 3. D 4. 273ºC

5. 100 mL. 6. 136.5 mL 7. B 8. D

9. 10.34 10. 1.5 cm 11. B 12. 76.125 cm of Hg

DPP # 3
1. (a) 1 : 3 (b) 1.527 litre 2. A
3. pA = 490 mm, pB = 260 mm. 4. B 5. 0.28 atm
6. A 7. C 8. 83.75 cm of Hg
9. 506 mm Hg 10. B 11. AB

DPP # 4
1. B 2. B 3. C 4. C 5. B 6. D 7. A
8. C 9. E 10. No change in both

DPP # 5
1. D 2. B 3. D 4. A 5. C 6. 39/46 7. M = 16
8. 2.198 atm 9. C 10. C 11. CD

DPP # 6
1. D 2. AB 3. 30 ml 4. 70 ml 5. C 2H 6 O
6. C 7. B 8. AB 9. B 10. B

DPP # 7
1. A 2. C 3. A 4. B 5. 2243.56 6. A
7. BD 8. B 9. C 10. D 11. C 12. B

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