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New Science hall TOPPER EXAM New Science hall TOPPER EXAM New Science hall TOPPER EXAM New Science hall
TOPPER EXAM New Science hall TOPPER EXAM New Science hall TOPPER EXAM New Science hall TOPPER EXAM
New Science hall TOPPER EXAM New Science hall TOPPER EXAM New Science hall TOPPER EXAM New Science hall
TOPPER EXAM New Science hall TOPPER EXAM New Science hall TOPPER EXAM New Science hall TOPPER EXAM
NEW
NEW SCIENCE HALL & BEACON
New Science hall
,urhadtpay; -I TOPPER EXAM-20
1 hour 30 min
Chemistry -I 7771119

mfpy thA khwpyp R = 8.314 J K −1 mol−1 gpshq;fpd; khwpyp h = 6.626 × 10−34 Js

mtfhjNuh khwpyp NA = 6.022 × 1023 mol−1 xspapd; Ntfk; 𝑐 = 3 × 108 𝑚𝑠 −1
New Science hall

01. mkpy Clfj;jpy; KMnO4 %yk; vjNdhy; (C2H5OH) MdJ mrw;wpf;fkpyk; (CH3COOH) Mf
xl;rpNaw;wg;gLk; NghJ C2H5OH ,w;Fk; KMnO4 ,w;Fk; ,ilapyhd %y; tpfpjk; ahJ?
(1) 3:2 (2) 1:5 (3) 4:5 (4) 2:5 (5) 5:4

02. xU %y; N2H4 MdH 10 %y; ,yj;jpud;fis mfw;wp Y vDk; NrHit Njhw;Wtpf;fpd;wJ.
Muk;gr; NrHitapy; cs;s vy;yh “N” mZf;fSk; Y vDk; NrHitapy; fhzg;gbd; Y y;
cs;s “N” ,y; cs;s mZnthd;wpd; xl;rpNaw;w vz; ahJ?
(1) -3 (2) -2 (3) +1 (4) +3 (5) + 5

03. gpd;tUk; %yfq;fspy; vJ jiuepiyapYs;s thAepiy mZtpy; ehd;F Nrhbahf;fg;glhj

,yj;jpud;fis cilaJ.
(1) Ti (2) Cr (3) Fe (4) Co (5) Sn

04. Li, K, N, O, Ne , Ar Mfpa %yfq;fspd; Kjyhk; madhf;fr; rf;jpfspd; rupahd khwiyf;

fhl;LtJ gpd;tUtdtw;Ws; vJ?
(1) K < Li < O < N < Ar < Ne (2) Ne < Ar < N < O < Li < K
(3) K < Li < O < N < Ne < Ar (4) K < O < Li < N < Ar < Ne
(5) Li < N < O < K < Ar < Ne

05. gpujhd nrhl;nlz; n=3 ck; fhe;jr; nrhl;nlz; ml = 0 cldhd ,yj;jpundhd;W

,Uf;fj;jf;fjhd mZ xgpw;wy;fs; vj;jid.
(1) 1 (2) 2 (3) 3 (4) 4 (5) 5

06. jpz;kk; A ia xU %ba nfhs;fyj;jpDs; nrYj;jp> xU Fwpj;j ntg;gepiyf;F ng;gNkw;wpa

NghJ gpd;tUk; rkepiy ngwg;gl;lJ.
2A(s) ⇌ B(g) + 2C(g)
ahNjDk; ntg;gepiyapy; Nkw;gb rkdpiyj; njhFjpf;fhd rkepiy khwpyp kp Mapd; B(g)
,d; rkepiyg; gFjpaKf;fj;ijg; gpd;tUk; vf;Nfhitapdhy; tifFwpf;fyhk;.
(2)Kp  2
1
 Kp 
1
 Kp 
3
Kp 1
Kp
2

(1) (3) (4)  (5) 

5 3  4   2 

V.K. |1
07. A →B vd;Dk; Kjy; tupirj; jhf;fj;ijf; fUJf. A apd; njhlf;fr; nrwpT 0.8moldm-3 Mf
,Uf;Fk; mNjNtis 150 nrf;fd;fSf;Fg; gpd;dH mjd; nrwpT 0.1moldm-3 MFk;. ,j;jhf;fj;jpd;
miu MAl;fhyk; ahJ?
(1) 15 nrf;fd; (2) 30 nrf;fd; (3) 40 nrf;fd;
(4) 50 nrf;fd; (5) 120 nrf;fd;

08. jhf;fk; X+Y⇌Z ,w;Fupa rf;jp tupg;glk; fPNo fhzg;gLfpd;wJ.

rf;jp

ΔE1 ΔE
2
X+Y
Z

jhf;f Ms;$W
,j;jhf;fj;jpd; ntg;gTs;Siw khw;wk;
(1) ΔE1 [ (2) ΔE2 (3) ΔE3 (4) ΔE2- ΔE1 (5) ΔE2 + ΔE3

09. mNkhdpah (NH3) gw;wpg; gpd;tUk; $w;Wfspy; vJ ngha;ahdJ

(1) NH3 ,y; N ,d; xl;rpNaw;w epiy -3 MFk;.
(2) NH3 MdJ nerpyH Nrhjidg; nghUSld; ,sQ;rptg;G epwj;ijj; jUfpd;wJ.
(3) NH3 MdJ iej;jpupf;fkpy cw;gj;jpapy; %yg;nghUs;fspy; xd;whfg; gad;gLj;jg;gLfpd;wJ.
(4) NH3 MdJ gz;gLj;jh vz;nzapy; cs;s mkpyf; $Wfis mfw;wg; gad;gLfpwJ.
(5) NaNO3 [ Al J}Sld; NaOH ePHf;fiurYlDk; ntg;gkhf;Fk; NghJ NH3 cz;lhfpd;wJ.

10. X,Y Mfpa cNyhf kpd;tha;fSld; epak epge;jidfspd; fPo; fhzg;gLfpd;w xU kpd;dpurhad
fyj;ijf; fUJf. E 0 y 2 / y  0.14V , E 0 x 2 / x  2.57V Mapd; gpd;tUk; vf;$w;W/ $w;Wfs;
rupahdJ/rupahdit.
1) X kpd;thapypUe;J Y kpd;tha;fF ; ,yj;jpud;fs; nry;Yk;.
2) X ,y; xl;rpNaw;wk; epfOk;
3) Ykpd;tha; fNjhl;lhFk;. .
4) E0cell = 2.43V MFk;.
5) ntg;gepiyapy; kpd;dpaf;ftpir jq;fhJ

Kjyhk; $w;W ,uz;lhk; $w;W

(1) rup rup jFe;j tpsf;fk;
(2) rup rup jFe;j tpsf;fk; my;y
(3) rup gpio
(4) gpio rup
(5) gpio gpio

V.K. |2
 Kjyhk; $w;W ,uz;lhk; $w;W
11 LiF ,Yk; ghHf;f LiI MdJ $Ljyhd fw;wad; rpwpjhf mj;Jld; / my;yJ caH
gq;fPl;L tY ,ay;ig cilaJ Vw;wj;ijf; nfhz;ljhf ,Uf;Fk; NghJ mJ
caH Kidthf;f tYitf; nfhz;bUf;Fk;.
12 ntg;gepiy khwpypahg; Ngzg;gLk; tiuf;Fk; xH Cf;fp Kd;Kfj;jhf;fk;> gpd;Kfj; jhf;fk;
xH Cf;fpiar; NrHg;gjdhy; xH ,urhadr; Mfpa ,uz;bdJk; Vtw; rf;jpia
rkepiyj; njhFjpapd; rkepiy khwpyp Fiwf;fpd;wJ.
khWtjpy;iy
13 CO2 MdJ mkpy kiof;Fg; gq;fspg;Gr; CO2 MdJ ePupy; fiuAk; NghJ fhNghdpf;
nra;tjpy;iy mkpyk; cz;lhfpd;wJ.

14 xH ,urhadj; jhf;fj;jpy; Vtw; rf;jpYk; vy;yh ,urhadj; jhf;fq;fspYk; jhf;fpfs;

ghHf;ff; $ba rf;jpia cila vy;yh mtw;wpd; rf;jpapYk; ghHf;ff; $ba rf;jpia
%yf;$WfSk; tpisnghUs;fis cila xU epiyapD}lhr; nry;y Ntz;Lk;.
cz;lhf;Ffpd;wd.
15 CO2 ,d; nfhjpepiyahdJ Nghky;bifl;bd; CO2 %yf;$WfSf;fpilNa cs;s
nfhjpepiyapYk; ghHf;f caHe;jJ. %yf;$w;wpilf; ftHr;rp tpirfs;
Nghky;bifl;L %yf;$WfSf;fpilNa cs;s
%yf;$w;wpilf; ftHr;rp tpirfspYk; ghHf;f
typikahdit.
16 ntg;gepiyia mjpfupf;fr; nra;jy;; jhf;f ntg;gepiy mjpfupf;Fk; NghJ xU
tPjj;ij mjpfupf;fr; nra;Ak;. jhf;fj;jpd; Vtw; rf;jp Fiwfpd;wJ.
17 ntg;gepiyia mjpfupf;Fk; NghJ khwhf; fdtsT ghj;jpunkhd;wpy; cs;s
CaCO3(s) ⇌ CaO(s) +CO2(g) vDk; CaCO3(s) ⇌ CaO(s) + CO2(g) vDk;
rkepiyf;Fupa Kp ngWkhdk; mjpfupf;Fk;. rkepiyj; njhFjpapd; ntg;gepiyia
mjpfupf;Fk; NghJ mKf;fk; mjpfupf;Fk;.

18 fy;thdpf;fyj;jpy; mNdhl;L kiwahFk; mNdhl;L vg;NghJk; kiwKidthFk;

19 kpd;dpurhadj;njhlupy; NkYs;sit kpd;dpurhadj;njhlupy; Ijurdpw;F

jho;j;jpfs; NkYs;sit mNdhl;lhFk;
20 fiue;j xl;rprdpd; msthdJ ePH khrile;j ePupy; xl;rprdpd; nrwpthdJ
khriljypd; xH mstd;W ntg;gepiy $l FiwAk;

V.K. |3
 Part 2
1) a) khwh mKf;fj;jpYk; ntg;gepiy T apYk; FWf;Fntl;Lg; gug;gsT A MfTk; ePsk; l MfTk;
cs;s xU tpiwj;j milj;j ghj;jpuj;jpy; He, Ne vd;Dk; ,U thAf;fs; cs;sd.
i. mr;re;jg;gj;jpy; njhFjpapd; nkhj;j mKLf;fk; P1 mf ,Uf;Fk; mNj Ntis %y;fspd; nkhj;j
vz;zpf;if n1 ,w;Fupa xU Nfhitiag; ngWf.
ii.tpiwj;j ghj;jpuj;jpd; ntg;gepiyia ,Uklq;fhf;Fk; NghJ Gjpa mKf;fk; P2 MFk; fdtstpy;
khw;wk; Vw;glhnjdpd;> P2 ,w;Fupa xU Nfhitia P1 ,d; rhHgpw; ngWf.
iii.Nkw;Fwpj;j xt;nthU ntg;gepiyapYk; thA He ,w;F Nghy;w;khd; guk;gy; tiugpid tiuf.
xU Fwpj;j rf;jpiaf;
nfhz;l cggpd;dk;

fjp /ms-1

b) A,B,C vd;gd xd;Nwhnlhd;W fyf;Fk; %d;W Mtpg;g ; wg;Gs;s jputq;fshFk;. Xt;nthU $wpdJk;
gFjpaKf;fq;fSk; epuk;gyhtp mKf;fq;fSk; KiwNa PA,PB,PC, P0A, P0B, P0C MFk;. Jput
mtj;ijapy; A,B,C Mfpa $Wfspd; %y; gpd;dq;fs; KiwNa xA, xB, xC MFk;. Xt;nthU fye;j
fiurypd; $wpdJk; Mtpg;gwg;Gj; jd;ik A > B > C vd khWfpd;wJ.
fyitfspy; %yf;$WfSf;fpilNa cs;s ftHr;rp tpirfs;.
𝐴−𝐴
𝐵−𝐵 < 𝐴 − 𝐵
𝐴−𝐴
𝐶−𝐶 < 𝐴 − 𝐶 vd khWfpd;wd.
A iaAk; B iaAk; A iaAk; V iaAk; NtWNtwhf 1.0mol tPjk; vLj;J ,U milj;j
ghj;jpuj;jpy; fye;J rkepiyia mila tplg;gl;lJ.
i. P0A,,P0B,P0C Mfpatw;iwg; gpd;tUk; tupg;glq;fspy; cupa mr;Rfspy; Fwpf;f.
ii. PA,PB,PC mikg;Gld; eilngWk; khwiy mt;tupg;glq;fspy; tiuf.
iii. A,B fyitapd; Mtp mtj;ijapd; nkhj;j mKf;fk; (PAB) khwiy cupa cUtpy; tiuf.
iv. A,C fyitapd; Mtp mtj;ijapd; nkhj;j mKf;fk; (PAC) ,d; khwiy cupa cUtpy; tiuf.
v. gpd;tUk; ntw;wplq;fis epug;Gf.
fyit AB MdJ ,yl;rpa epiyapypUe;J ………… tpyfiyf; fhl;Lk; mNjNtis
fyit AC MdJ ,yl;rpa epiyapypUe;J ………… tpyfiyf; fhl;Lfpd;wJ.
Mtp Mtp Mtp Mtp
mKf;fk; mKf;fk; mKf;fk; mKf;fk;

XA 0 1 XC 0 1
XB 1 cU (1) 0 XB 1 0
cU (2)

V.K. |4
 2) a) ntg;gepiy 700K ,y; fdtsT 2.5dm3 [ cila xH milj;j tpiwg;ghd ghj;jpuj;jpy;
thA X2 ,d; 0.15mol cs;sJ mg;ghj;jpuj;jpDs;Ns ,Wjp mKf;fk; 8,5 x105Nm-2 Mf ,Uf;Fk;
tiuf;Fk; H2 thA GFj;jg;gl;lJ. ,q;F ntg;gepiy my;yJ fdtsT khw;wk; Vw;gLtjpy;iy
milj;j ghj;jpuj;jpDs;Ns xH Cf;fpiag; GFj;jpa gpd;du; rkepiy milag;gl;lJ. rkepiyj;
njhFjpapd; 0.08mol cz;lhf;fg;gl;lJ.
i. rkepiyf;F Kd; X2 ,d; gFjpaKf;fj;ijf; fzpf;f.
ii. rkepiy epiyapy; njhFjpapd; %y;fspd; nkhj;j vz;zpf;ifiaf; fhz;f.
iii. njhFjpf;Fs;Ns GFj;jg;gl;l H2 %y;fspd; vz;zpf;if ahJ?
iv. Nkw;Fwpj;j Kp,Kc Nfhitfis vOJf.
v. 700K ,y; Kc,Kp Mfpatw;wpd; ngWkhdq;fisf; fzpf;Ff.

b) 2FeCl3(aq) + 3KI(aq) → KI3(aq) + 2FeCl2(aq) + 2KCl(aq)

Nkw;gb jhf;fj;jpy; FeCl3 ,w;Fk; KI ,w;Fk; rhHghf tupiriaj; Jzptjw;fhf mtw;wpd; gpd;tUk;
nrwpTfisf; nfhz;l fiury;fisg; gad;gLj;jpg; gupNrhjidnahd;W jpl;lkplg;gl;lJ. mjd;
ngWNgWfs; fPNo fhl;lg;gl;Ls;s ml;ltizapy; jug;gl;Ls;sd.
FeCl3 nrwpT/ moldm-3 KI nrwpT/moldm-3 KI3 Njhd;Wtjw;Fupa jhf;f
tPjk; (R)/Moldm-3s-1
(1) 0.01 0.02 0.08
(2) 0.01 0.04 0.16
(3) 0.02 0.02 0.16

i. KI3 Njhd;Wk; tPjk; R ck; FeCl3 tpuakhFk; tPjk; R ck; Mapd; R ,w;Fk; R,w;Fk;
,ilapyhd njhlHig vOJf.
ii. Nkw;gb (1) re;jHg;gj;jpy; R [f; fzpf;f.
iii. jhf;fj;Jf;Fupa nkhj;jj; jhf;ftupiriaf; fzpf;Ff.
iv. Fwpj;j ntg;gepiyapy; tPj khwpypiaf; fzpf;Ff.

3) a) S2 + B → P
Nkw;gb jhf;fj;jpd; gbKiwfs; gpd;tUkhW ,J xU Gwntg;gj;jhf;fkhFk;.
S2 ⇌ 2S (tpiuthf) → (I)
B + 2S → P(nkJthf ) →(II)
i. jhf;fpfspd; nrwpitg;gad;gLj;jp Nkw;gb jhf;fj;Jf;Fupa tPjr;rkd;ghl;il vOJf.
ii. Nkw;gb gygbKiwj; jhf;fj;jpd; jhf;ftPjj;ij jPHkhdpf;Fk; gbKiw vJ?
iii. S2 jhf;fp rhHghf tupiriaj; Jzpf.
iv. Nkw;gb jhf;fj;jpd; nghwpKiwf;fhd rf;jpg;glj;ij (energy profile) tiuf.

b) xU %y; fhgdPnuhl;irl;L thATk; xU %y; [jurd; thATk; khwhf; fdtsT ghj;jpunkhd;wpy;

fyf;fg;gl;L 250C ntg;gepiyapy; gpd;tUkhW jhf;fKw tplg;gl;ld.
CO2(g) + H2(g) → CO(g) + H2O(g)
250C ,w;Fupa ntg;g ,urhadj; juTfs; rpy fPNo ml;ltizapy; jug;gl;Ls;sd..
gjhHj;jk; ∆Gfθ/ KJ mol-1 Sθ/ J mol-1 K-1
CO(g) -137 197.5
CO2(g) -394 213.7
H2(g) 0 130.6
H2O(g) -229 188.7

V.K. |5
 i. 250C ,y; Nkw;gb jhf;fj;Jf;Fupa ∆Gθ [f; fzpf;Ff.
…………………………………………………………………………………..………………………
…………………………………………………………..……
ii. 250C ,y; Nkw;gb jhf;fj;Jf;Fupa ∆Sθ [f; fzpf;Ff.
…………………………………………………………………………………..
iii. mtw;iwf; nfhz;L Nkw;gb jhf;fj;Jf;Fupa ∆Hθ [f; fzpf;Ff.
…………………………………………………………………………………..………………………
…………………………………………………………..……
iv. Nkw;gb jhf;fkhdJ jug;gl;Ls;s jpirapy; Rakhf epfOkh? Rakhf epfohj jpirapy;
jhf;fj;ij Rakhf epfor; nra;tjw;fhf ahNjDk; T(K) ntg;gepiyia tpl caHthd
ntg;gepiyf;F ntg;gNkw;w Ntz;bAs;sjhapd; T ,dJ ngWkhdj;ijf; fhz;f.
…………………………………………………………………………………..………………………
…………………………………………………………..……

V.K. |6