Page 1 of 2 CPP - SANKALP_GS-07-PH-II

CPP
GASEOUS STATE – SHEET: 7
Real gas, Deviation from ideal behaviour

LEVEL - 1

23 –22 3
1. For a gas containing 10 molecules (each having mass 10 g) in a volume of 1 dm , calculate the total
5 –1
kinetic energy of molecules if their root mean square speed is 10 cm s . What will be its temperature?

2. Calculate the total kinetic energy of 0.5 mole of an ideal gas at 273K

3. Calculate the kinetic energy of an Avogadro number of gas molecules at 0°C.

4. Which of the following gases will you consider to be ideal or real?

a) 0.25 mol CO2 at 1200K exerting a pressure of 24.63 atm in 1 L flask.
6
b) 6g of gaseous propanol in100 mL flask exerts a pressure of 2.4956 × 10 pascal at 300K.
c) 1 mol CO2 at 300K occupies volume 22.42 L at 1 atm.

–1
5. For O2 gas, the van der Waals constant b is 0.03182 L mol . Calculate the diameter of O2 molecule.

–3
6. The density of the vapours of a substance at 1 atm pressure and 500 K is 0.36 kg m . The vapour effuses
through a small hole at a rate of 1.33 times faster than oxygen under the same conditions?
a) Determine (i) molecular weight (ii) molar volume, (iii) compression factor (Z) of the vapours and (iv) which
forces among gas molecules are dominating, the attractive or the repulsive?
b) If the vapours behave ideally at 1000 K, determine the average translational kinetic energy of a molecule.

7. Calculate % of the `free volume’ available in 1 mole gaseous water at 1.00 atm and 100°C. Density of liquid
H 2 O at 100°C is 0.958 g/mL.

8. The vander waals constant for O2 are a = 1.36 atm L2 mol–2 and b = 0.0318 L mol–1. Calculate the
temperature at which O2 gas behaves, ideally for longer range of pressure.

9. The compression factor (compressibility factor) for one mole of a van der Waals gas at 0C and 100
atmosphere pressure is found to be 0.5 Assuming that the volume of a gas molecule is negligible, calculate
the van der Waals constant (a).
3
10. The density of water vapour at 327.6 atm and 776.4 K is 133.2 gm/dm .
Determine the molar volume, Vm of water and the compression factor.

LEVEL - 2

11. A graph is plotted between PVm along Y axis and P along X axis where Vm is the molar volume of a real gas.
Find the value of intercept along the Y axis.

12. The compressibility factor for an ideal gas is -

(A) 1.5 (B) 1.0 (C) 2.0 (D) ∞

13. Consider an ideal gas contained in a vessel. If the intermolecular interactions suddenly begins to act, which of
the following will happen?
(A) the observed pressure decreases (B) the observed pressure increases
(C) the observed pressure remains same (D) none of these

14. A real gas obeying Vander Waal equation will resemble ideal gas, if the:
(A) constants a & b are small (B) a is large & b is small
(C) a is small & b is large (D) constant a & b are large

FIITJEE Ltd., ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Terminal), New Delhi - 16, Ph : 6515949 , 6865182, 6854102, Fax : 6513942
Page 2 of 2 CPP - SANKALP_GS-07-PH-II
15. The compressibility factor of real gas is usually greater than one (Z > 1) at high temperature and high
pressure. This is because
(A) the constant a is negligible while b is not (B) the constant b is negligible while a is not
(C) both a and b are negligible (D) both a and b are no negligible

16. Among the four statements given below for real gases, which are incorrect:
(A) The molecules causes attractive interactions.
(B) They show deviation from ideal gas laws.
(C) The molecules are almost volume less points.
(D) The molecules have negligible mass.

17. Which of the following statement is true for Van der waals gas constant ‘a’ and ‘b’?
(A) ‘a’ depends on size and shape, ‘b’ depends only on size of molecule.
(B) ‘b’ depends on size and shape, ‘a’ depends only on size of molecule.
(C) Both ‘a’ and ‘b’ depends on shape and size of molecule.
(D) Both ‘a’ and ‘b’ depends only on size of molecule.

18. Identify the conditions of pressure and temperature at which a real gas shows maximum deviation from ideal
behavior:
(A)10 atm, 273 K (B) 5 atm, 273 K (C) 10 atm, 373 K (D) 5 atm, 373 K

19. Partial pressure are simply additive for ideal gases. For non–ideal gases (such as ammonia and oxygen), if
we tried to consider them as ideal gases, we would
(A) always overestimate the total pressure
(B) always underestimate the total pressure
(C) Underestimate p at low pressure and overestimate p at high pressure
(D) Overestimate p at low pressure and underestimate p at high pressure

20. Which of the following statement is not true?

(A) The pressure of the real gas is equal to the pressure calculated for an ideal gas.
(B) The van der Waals’ equation helps to calculate the pressure and volume of real gases
(C) Real gas molecules do occupy a finite, but small, volume.
(D) None of these
——
ANSWER KEY SHEET : 7

LEVEL – 1
4
1. 0.5 × 10 J, 2414 K
2. 1702 J
3. 3404.6 J
4. (a) ideal (b) non ideal (c) non ideal
-9
5. 2.932 × 10 m
–1
6. (a) (i) 18.1 g mol
(ii)50.25  10 –3 m –3 , (iii) z = 1.225
–20
(b) 2.07  10 J
7. 99.9387%
8. 521 K
2 -2
9. 1.253 atm L mol
10. Molar vol = 0.1353 L/mol, Z = 0.6957
LEVEL – 2
11. RT
12. B
13. A
14. A
15. A
16. C, D
17. A
18. A
19. D
20. A
——
FIITJEE Ltd., ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Terminal), New Delhi - 16, Ph : 6515949 , 6865182, 6854102, Fax : 6513942