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PLATINUM-NICKEL-
CHROMIUM DEPOSITS
GEOLOGY, EXPLORATION
AND RESERVE BASE
S.K. Haldar
Emeritus Scientist, Presidency University
Formerly Hindustan Zinc Limited,
Hindustan Copper Limited,
IMX Resources Limited, Perth
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This book and the individual contributions contained in it are protected under copyright by the Publisher
(other than as may be noted herein).
Notices
Knowledge and best practice in this field are constantly changing. As new research and experience broaden our
understanding, changes in research methods, professional practices, or medical treatment may become necessary.
Practitioners and researchers must always rely on their own experience and knowledge in evaluating and using any
information, methods, compounds, or experiments described herein. In using such information or methods they should
be mindful of their own safety and the safety of others, including parties for whom they have a professional
responsibility.
To the fullest extent of the law, neither the Publisher nor the authors, contributors, or editors, assume any liability for any
injury and/or damage to persons or property as a matter of products liability, negligence or otherwise, or from any use
or operation of any methods, products, instructions, or ideas contained in the material herein.
ISBN: 978-0-12-802041-8
Hindustan Zinc Limited, where he has under- Dr. Haldar has a unique professional blend
taken various technical roles and managerial of mineral exploration, evaluation, and mineral
responsibilities. Since 2003, he has been Emeri- economics with an essence of classroom teach-
tus Scientist with the Department of Applied ing of postgraduate students of three celebrated
Geology, Presidency University, K olkata, and universities over the past decade.
ix
Preface
I have no special talents, I am only passionately the processes of the Universe, and to understand
curious - Albert Einstein. how the mystic mother Earth hosts minerals and
metals from the core to the crust for the bene-
When I was a postgraduate student at fit of birds, animals, and human beings. When
alcutta University in the mid-1960s, I did
C I first visited Sukinda chromite belt in 1964, it
my thesis on the Sukinda chromite deposits was a sleeping hamlet, gifted by nature’s love,
of Orissa, India. Mining for chromite had just with dense forests, mineral wealth, and peace-
begun in the country. The chromite belt was loving tribal people. There were three small
located in a valley between the Mahagiri and mines separated by kilometers and supported
the Daitari hill ranges. I was put up in a small by fewer than 100 employees. The economic
hut inside the boundary of the mining camp. interest in the area was only for small-scale
The area was a dense forest, populated by wild production of chromite ore for the indigenous
animals and a few tribal villages. I used to do market. M/s Ferro Alloys Corporation Limited
geological studies in the forest from early morn- (FACOR Ltd.), a few kilometers away in the
ing to late afternoon. No one was allowed to Nausahi chromium belt, produced a few tons.
step outside the mine’s fenced area once twilight I recently revisited the area, nearly after 50 years,
set in. No one could open the hut door at night. to bring my knowledge up-to-date about the pres-
Elephants regularly visited the villages for food ent chromium–nickel–platinum resources in the
and would destroy green banana plants. We wit- world. The present status of the project confirmed
nessed bear families fading away into the forest. my belief that lateritic nickel could not be econom-
Once, I experienced the smell of a tiger and saw ically extracted due to metallurgical complexities,
leftover food in a small cave. Lateritic nickel was and was happy to learn that platinum–palladium
discovered in the area by the Geological Survey do exist at Sukinda–Nausahi Belt. However, what
of India while I was there. My three months of I saw saddened me. There are more than 25 surface
fieldwork in the deep forest amid nature deci- and underground working mines separated by
sively influenced me forever. Back at the common boundaries. The forests have totally dis-
University, my thesis was highly acclaimed. appeared. The majestic Mahagiri range had been
Thereafter, I joined metal-mining corporate com- reduced greatly by bulldozing. Series of newly
panies (copper–zinc–lead). Nevertheless, I could born hills appear parallel to Mahagiri range due
never forget that short stay in a remote mining to mine-waste dumping. Unpaved roads serve
camp with inadequate facilities and very few the movement of more than 1000 trucks daily for
modern comforts. I promised myself that I would transporting ore to distant ferrochrome factories
return to the platinum–nickel–chromite industry and seaports. The sky is gloomy throughout the
at an opportune phase and share my knowledge day due to the mine and road dust. Social evils,
with students and fellow professionals. crime, alcoholism, and other such abuses have
This first experience made a permanent and increased. This is the other side of the coin. We
passionate impact on me, to love nature, to learn have to balance between good and evil through
xi
xii Preface
proper self-protective education, counseling, and mission. I am deeply indebted to Finn for help-
training. Making stringent mine-safety rules is not ing me with information and innumerable pub-
the solution—it has to be implemented in the right lications throughout the writing of this book.
spirit. Otherwise, what will we leave for future Dr. Tom Evans, Executive Manager Explora-
generations? tion at Lonmin Plc, United Kingdom, Avinash
Five decades have passed between the two Sarin from Washington, D.C., and Soumi Haldar
visits. The demand and supply for chromite from Los Angeles enriched the pages with won-
has increased manyfold to cater to the needs of derful mineral images. I am delighted to work
domestic and international markets. The later- with Marisa LaFleur and Frank Tasha, Elsevier,
itic nickel resources are still under scientific and and thankful for their very positive attitude in
technological research and development without this journey.
any commercial breakthroughs. The presence of My heartfelt thanks to Mr. R. Venkatesan, Paul
platinum–palladium has been reported. This was Prasad Chandramohan and team of Elsevier for
how the present project was conceived. I was unique support to shape the book awesome.
interested in comparing with world-class depos- I am thankful to Presidency University, fac-
its like Bushveld chromite–platinum group met- ulty, and students for providing an academically
als (PGMs), South Africa, Sudbury nickel–copper, enriching environment. I extend my sincere
Canada, and a few new discoveries in Australia. thanks to all the mining camps: FACOR India
The project was initially supported by the Gov- Ltd., Orissa Mining Corporation Ltd., Tata Steel,
ernment of India’s Department of Science and and Department of Mines and Geology, and the
Technology (DST) under its Utilization of Scien- states of Tamil Nadu and Karnataka for extend-
tific Expertise of Retired Scientists Scheme HR/ ing support during my field visits to Sukinda–
UR/29/2007. The book has been partially funded Nausahi, Sittampundi, and Byrapur. All figures
by the financial support of DST, New Delhi. are drafted by my dear students: Subham Sarkar,
The book is primarily intended for academic Bidisha Dey, and Promita Bhar.
students of Applied Geology, faculty members, My humble gratitude to all the past and pres-
and researchers, geoscientists of exploration ent monks of Ramakrishna Math, Barisha, Kol-
companies, and investors. It is divided into 11 kata for their blessings in this journey.
chapters. Chapter 1 is a general introduction to I am short of words in expressing my emo-
precious metals including the PGMs–Nickel– tions for my wife, Swapna, for her continuous
Chromium. Chapter 2 deals with the host affin- inspiration, particularly at times of mental dis-
ity of these metals. Chapters 3–8 describe the tress, and for bringing me back to a working
occurrences/deposits/mines of six continents: mode. My family team—Srishti and Srishta
Africa, North America, South America, Asia, (grandchildren), Soumi (daughter), and Surat-
Oceania (including Australia), and Europe. The want (son-in-law) are always my source of moti-
remaining Chapters 9–11 give an overview of vation and happiness.
genetic aspects, exploration approach, and sta-
tus of in situ reserves and resource base includ- I shall be telling this with a sigh
Somewhere ages and ages hence:
ing characteristics of global deposits.
Two roads diverged in a wood, and I–
I visited all possible platinum group of ele- I took the one less traveled by,
ments (PGEs)–Ni–Cr-bearing areas in India for And that has made all the difference.
reconnaissance studies with Mr. Finn Barrett, Robert Frost, 1920
Exploration Geologist, IMX Resources Ltd.,
Perth. It is my privilege and pleasure to acknowl-
Presidency University
edge my academic association with Finn over
Kolkta, April 19, 2016 S.K. Haldar
a decade that has inspired me to complete this
List of Acronyms
xiii
C H A P T E R
1
Introduction
O U T L I N E
Platinum-Nickel-Chromium Deposits
http://dx.doi.org/10.1016/B978-0-12-802041-8.00001-8 1 Copyright © 2017 Elsevier Inc. All rights reserved.
2 1. INTRODUCTION
FIGURE 1.1 Position of platinum group of elements, nickel, chromium, copper, gold, silver, and cobalt in the periodic table.
1.2 The Metals 3
All six members of the platinum group share affinity places them in the “chalcophile” (copper-
affinity to Fe, Co, and Ni with consequential loving) group of elements (Mungall, 2005a).
formation of metallic bonds over ionic bonds. The PGMs are naturally occurring rare metals,
This preferential tendency sets them in the sparsely distributed, and relatively costlier than
“siderophile” (iron-loving) group in the geo- gold and silver. The elements have similar phys-
chemical classification of elements (Box 1.1) ical properties and tend to occur together in an
(Ertel et al., 2008). The PGE, in addition, tends identical metallogenic environment.
to associate with copper (Cu), silver (Ag), and The metals gold, iridium, osmium, palladium,
gold (Au) to form covalent bonds with sulfur in platinum, rhodium, ruthenium, and silver are
preference to ionized bonds with oxygen. This most commonly considered the group of noble
B O X 1 . 1 G E O C H E M I C A L C L A S S I F I C AT I O N O F
ELEMENTS
Geochemical classification is the subdivision or Cobaltite (CoAsS), and Loellingite (FeAs2)],
grouping of elements according to their joint con- sulfur {e.g., [Pentlandite (FeNi)9S8], and Molyb-
centration in preferred host phases in a particular denite (MoS2)}, carbon, phosphorus, and nitro-
natural system: gen. In nature, platinum occurs mainly in the
Lithophile (rock-loving): The lithophile elemental state. Siderophile elements often bond
elements are the fundamental source of rock- with chalcophile elements.
forming minerals of the Earth’s crust. The litho- The elements are bound through a metallic
phile elements include aluminum, astatine, boron, bond with iron in the Earth’s solid inner core.
barium, beryllium, bromine, calcium, c hlorine, Most of them are known for their rarity in the
chromium, cesium, fluorine, iodine, hafnium, Earth’s crust and recognized as precious metals.
potassium, l ithium, magnesium, sodium, Chalcophile (ore/copper/bronze-loving): The
niobium, oxygen, phosphorus, rubidium, scan- chalcophile elements predominantly represent
dium, silicon, strontium, tantalum, technetium, sulfide ores. The elements include antimony, arse-
thorium, titanium, uranium, vanadium, yttrium, nic, bismuth, cadmium, copper, gallium, germa-
zirconium, tungsten, and the lanthanides. The nium, indium, lead, mercury, polonium, selenium,
lithophile elements occur naturally as stable ions silver, sulfur, tellurium, thallium, tin, and zinc.
in the forms of silicates, oxides, halides, phos- Chalcophile elements have low affinity for oxygen
phates, sulfates, and carbonates. except for tin [e.g., Cassiterite (SnO2)]. The natural
Siderophile (iron-loving): The siderophile ele- form of the occurrences of chalcophile elements is
ments include cobalt, gold, iridium, iron, manga- as sulfides, selenides, and tellurides. The elements
nese, molybdenum, nickel, osmium, palladium, silver, copper, arsenic, sulfur, and bismuth often
platinum, rhenium, rhodium, and ruthenium. occur in the elemental state.
The elements are high-density ferromagnetic and Atmophile (gas/volatile-loving): Atmophile
paramagnetic transition metals that readily dis- elements occur as liquid or gaseous state and
solve in iron as a solid solution or in the molten mostly remain on or above the surface or in
state. The elements have no affinity with oxygen. atmosphere. The elements include all the inert
They exhibit strong chemical bonds with arse- gases from helium to radon, nitrogen, and
nic [e.g., Sperrylite (PtAs2), Chloanthite (NiAs2), hydrogen.
4 1. INTRODUCTION
metals. These noble metals are largely resistant and/or chromium. The value-added secondary
to oxidation and corrosion in moist air, unlike metals are copper, gold, silver, and cobalt.
most base metals such as iron, nickel, lead, zinc,
and copper. They are considered precious due
to their rarity in the Earth’s crust. The most 1.2.1 Platinum Group of Metals
common primary metals that are generally asso- Platinum with symbol (Pt) and an atomic
ciated with platinum group are copper, nickel, number of 78 in the Periodic Table is considered
“rich man’s gold.” The metal was discovered
by Antonio de Ulloa, a Spanish explorer, in
1735. The name “platinum” is derived from the
Spanish word “platina,” which literally means
tiny form of “plata” or “little silver.” The new
metal (Fig. 1.2) was found as large placer deposits
during the 16th century Spanish conquest of
South America. It was called “platina del Pinto”
after the Rio Pinto of Columbia. Platinum is
silver-white to steel-gray or dark-gray in color
and is lustrous. It is the most ductile among the
pure metals. It is a malleable transition metal
(Box 1.2) with a melting point at 1768°C. Pure
platinum is a little harder (4–4.5) on the Mohs
scale of hardness than pure iron (4). Platinum
is one of the rarest elements in the Earth’s crust
(0.005 g/t), precious with high specific gravity
between 14 and 22. It is generally nonreactive
FIGURE 1.2 Native metals occur in their metallic forms, to oxidation, wear, and tarnish. This property
either as pure or as an alloy in nature—singly and/or in alloy makes it well suitable for fine jewelry. A famous
with lead, copper, gold, platinum, nickel, and cobalt. Native native platinum nugget was recovered from
platinum is one of the rarest and most precious metals in the the perfect circular, 8-km diameter Kondyor
Earth’s crust, and was discovered in the 18th century. The
platinum–palladium metals immensely contribute in pollution
Massif intrusion in Russia. Platinum is often
control of automobiles and marks the “Day of Love in Couple’s found in mining of secondary alluvial deposits
journey in life.” Avinash Sarin. in Colombia and the Ural Mountains, Russia.
B O X 1 . 2 T R A N S I T I O N M E TA L S
An explicit set of metallic elements within elements are present in more than one shell and
Groups 3 to 12 in the Periodic Table contains an often exhibit several common oxidation states. Iron,
incomplete inner electron shell and serves as cobalt, and nickel are the most significant members
transition links between the most and the least in the transition-metal family and are the only
electropositive series of elements. These metals common elements known to produce a magnetic
are characterized by multiple valence, colored field. The other metallic elements include platinum
compounds, and an ability to form stable complex group, chromium, copper, gold, silver, lead, zinc,
ions. The electrons they use to combine with other tungsten, manganese, mercury, etc.
1.2 The Metals 5
Platiniridium is a rare naturally occurring native extremely hard and brittle metal, silvery-white
platinum/iridium alloy (Ir,Pt). in color and considered a transition element of
Palladium, the second significant member the platinum family. It is the second-densest
in the PGMs, has a chemical symbol of (Pd) (22.56 g/cm3) element after osmium (22.59 g/
and an atomic number of 46 in the Periodic cm3). It is the most corrosion-resistant metal,
Table. Palladium was discovered by William even at high temperatures. It has a melting point
Hyde Wollaston in 1803 and named after the at 2410°C. Iridium is one of the least abundant
asteroid Pallas (goddess of wisdom) which was elements in the Earth’s crust, having an average
discovered at about the same time. It is a soft, mass fraction of 0.001 g/t in crustal rock. Metallic
malleable, ductile, silvery-white metal that iridium is closely associated with platinum and
resists oxidation and corrosion. Palladium other PGMs in alluvial deposits. Iridium is found
has the lowest melting point at 1,555°C and in nature as free element or as natural alloys of
lowest density (11.3–11.8 g/cm3) among the iridium–osmium that include “osmiridium” and
group. Its metal dust is flammable. Palladium is “iridosmine.” These alloys are mixtures of irid-
usually associated with platinum, nickel, copper, ium and osmium. The rare metals are recovered
and mercury ores. Palladium is commercially commercially as a byproduct from nickel min-
produced from nickel–copper deposits of South ing and processing. Significant primary sources
Africa and the Province of Ontario, Canada. The of iridium are in the Bushveld igneous complex
processing of large volumes of nickel–copper in South Africa, the large copper–nickel deposits
ore technically makes this extraction profitable near Noril’sk in Russia, and the Sudbury Basin
despite its low concentration in these ores. in Canada. Iron meteorites (Box 1.3), derived
Iridium is a rarely occurring natural element from small celestial bodies, are composed mostly
with chemical symbol of (Ir) and atomic number of iron, nickel, gallium, germanium, and iridium
of 77 in the Periodic Table. Iridium was discov- (Fig. 1.3). The impact of falling on the Earth’s
ered by the British chemist Smithson Tennani crust causes partial melting and concentration of
in 1803 and named from the Greek word “iris” valuable metals.
meaning “Goddess of rainbow” for the brilliant Osmium is the least-abundant transition metal
color of many of its compounds. Iridium is an in the Earth’s crust with chemical symbol (Os) and
FIGURE 1.4 Polymetallic nodules collected from the FIGURE 1.5 Native copper from polymetallic sulfide
Indian Ocean bed containing 1.5% Ni, 1.4% Cu, 0.25% Co, deposit at Neves-Corvo mine, Portugal. Haldar, S.K., 2013.
30% Mn, and 6% Fe. Haldar, S.K., 2013. Mineral Exploration – Mineral Exploration – Principles and Applications. Elsevier
Principles and Applications. Elsevier Publication, p. 374. Publication, p. 374.
8 1. INTRODUCTION
1.2.5 Gold and Silver 961.8°C. Silver occurs in native form (Fig. 1.7) and
an alloy with gold ores containing arsenic, sul-
Gold is noble and precious, and documented fur, and antimony. The common silver-bearing
as one of the first metals used during prehistoric minerals are Argentite (Ag2S), Chlorargyrite
culture. The Latin name for this noble metal is (AgCl), and Pyrargyrite (Ag2SbS3). The primary
“aurum” with chemical symbol (Au) and atomic sources of silver include ores of copper, copper–
number 79. It is a dense, soft, malleable, and nickel, lead, and lead–zinc.
ductile transition metal with melting point at
1064°C. The color is bright yellow with metal-
lic luster. A property of pure gold is remaining
1.2.6 Cobalt
untarnished on exposure to air or water. Gold Cobalt is one of the least-abundant elements
occurs mainly in native form (Fig. 1.6). in the Earth’s crust with chemical symbol (Co)
Magmatic gold–copper and gold–PGE depo and atomic number 27. Cobalt is hard, lustrous
sits, and combined with tellurium-bearing min- gray metal with attractive appearance and
erals are Sylvanite [(Ag, Au) Te2], Calaverite, or resistance to oxidation. It is a transition metal
gold telluride (AuTe2), Krennerite (Au3AgTe8) crystallizing in the hexagonal crystal system.
(Fig. 1.7), and Petzite (Ag3AuTe2). The name was derived from the German word
Silver is a precious metal with chemical symbol “Kobold” meaning “evil spirits.” The metal
(Ag) and atomic number 47. Silver is a soft, white, was used by Egyptian artisans as a coloring
lustrous transition metal used for thousands of agent during 3000 to 2000 BC. Cobalt is one of
years. It possesses the highest electrical conduc- the essential alloying elements in the Earth’s
tivity of any element and the highest thermal crust. It has many strategic and irreplaceable
conductivity of any metal. The melting point is at industrial uses and is a central component
FIGURE 1.6 Native gold from Al Amar volcanogenic FIGURE 1.7 Native silver occurs in various forms and
gold–zinc–copper deposit in volcaniclastic host rocks, sizes. Silver mining in the United States began on a major
∼180 km southwest of Riyadh, Saudi Arabia. The average scale with the discovery of the Comstock Lode in 1858; 36
grades are 7 g/t Au, 14 g/t Ag, 3.7% Zn, and 0.5% Cu. Haldar, mines from 18 states continue silver production today in
S.K., 2013. Mineral Exploration – Principles and Applications. the United States. Haldar, S.K., 2013. Mineral Exploration –
Elsevier Publication, p. 374. Principles and Applications. Elsevier Publication, p. 374.
1.3 The Minerals 9
of Vitamin B12. It has a high melting point
(1495°C) and retains its strength to high
temperature. Cobalt is frequently associated
with nickel, and both are characteristic compo-
nents of meteoric iron. The common cobalt
bearing minerals include Cobaltite (CoAsS),
Skutterudite (CoAs3), Safflorite (CoAs2) and
Glaucodot [(Co,Fe)AsS].
Russia, The Great Dyke in Zimbabwe, and as North San Juan, Stillwater, Montana, United
platinum–iron nuggets in Madagascar. States, Mechanic Pluton, Canada, Skaergaard
Intrusion, East Greenland, Talnakh Cu-Ni deposit,
1.3.1.3 Cooperite Noril’sk, Putoran plateau, Taimyr Peninsula, and
Cooperite is a sulfide mineral composed of Taymvrskiy, Eastern Siberia, Russia.
platinum, palladium, and nickel ± copper with
chemical formula [(Pt, Pd, Ni)S]. The mineral was 1.3.1.6 Merenskyite
first characterized in 1928 at Bushveld Igneous Merenskyite is a rare telluride–bismuthinide-
Complex by Richard A. Cooper, a South African bearing platinum–palladium mineral with
metallurgist, and named after him. The color, chemical formula [(Pd,Pt)(Te,Bi)2]. The mineral
streak, and luster are gray, brownish-yellow, and was first described in 1966 for its occurrence at
metallic, respectively. It is moderately hard (4.5 on Merensky Reef in the Western Bushveld Igneous
the Mohs scale) with high specific gravity of 9.5. Complex, and named after Hans Merensky, a
The mineral in purest form contains 62.62% Pt, German–South African geologist. It is an opaque
17.08% Pd, 3.14% Ni, 17.18% S, ±0.5–0.8% Cu. white to light gray metallic mineral. The hard-
Cooperite is mined in sizable quantity at the ness is medium at 3.5 on the Mohs scale with a
Bushveld Complex, South Africa. moderately high specific gravity of 8.55. The
average content of elements at purest form is
1.3.1.4 Laurite 24.76% Pd, 5.04% Pt, 59.39% Te, and 10.81% Bi.
Laurite is an opaque black metallic ruthenium The mineral usually occurs as inclusion in Chal-
sulfide mineral with chemical formula (RuS2). copyrite. It is a source of platinum, palladium,
The mineral was discovered in 1866 in Borneo tellurium, and bismuth.
and named for Laurie, wife of an American
chemist. The color ranges between iron-black, 1.3.1.7 Michenerite
white-gray, and bluish. The streak and luster are Michenerite is a rare telluride–bismuthinide
dark-gray and metallic, respectively. It is hard bearing platinum–palladium mineral with
(7.5 on the Mohs scale) with moderate specific chemical formula [(Pd,Pt)BiTe]. The mineral
gravity (6.4). It occurs in ultramafic magmatic was named after its discoverer Charles Edward
cumulate deposits and as placer types derived Michener, a Canadian exploration geologist.
from the former. Laurite in pure form contains The color is silver-white with black streak and
61.18% Ru, and 38.82% S. metallic luster. The hardness is low at 2.5 on
the Mohs scale, and the average specific grav-
1.3.1.5 Vysotskite ity is high at 9.5. The mineral in the purest form
Vysotskite is a palladium–nickel sulfide contains 17.16% Pd, 10.48% Pt, 44.93% Bi and
mineral with chemical formula [(Pd,Ni)S], and 27.43% Te. The mineral occurs at Frood mine,
crystallizes in the tetragonal system. The mineral McKim Township and Capre deposit (Fig. 1.9),
was named after Nikolai Konstantinovich Vysotskii, Sudbury Camp.
a geologist who found the platinum ore deposit at
Noril’sk, Russia. The color ranges between silver- 1.3.1.8 Moncheite
gray and white with a green streak. The mineral Moncheite is a rare telluride–bismuthinide
is soft (1.5 on the Mohs scale of hardness) with bearing platinum–palladium mineral with chemi-
an average moderate specific gravity of 6.69. The cal formula [(Pt,Pd)(Te,Bi)2]. It is named after the
average contents of elements in purest form of the locality at Monche Tundra in Russia. The mineral
mineral are 63.07% Pd, 11.59% Ni, and 25.34% S. is steel-gray to gray color. It has low hardness of
The mineral reported from Mutoshi mine, Zaire, 2–3 and moderately high specific gravity at 10. The
1.3 The Minerals 11
The Skaergaard mafic–ultramafic intrusion is
the only known source of Skaergaardite, the
most common mineraland sufficiently abundant
to be mined. It is the most common source of the
metal palladium.
and smelter can handle with acceptable recov- igneous intrusive in South Africa, the Voisey’s
ery. The prime locations include Sudbury basin, Bay mafic troctolite (olivine, calcic-plagioclase,
Canada, Widgiemooltha Dome and Kambalda and pyroxene rock) intrusive complex in Can-
areas, Western Australia. ada, and Duluth gabbro intrusive in the United
States. The other examples of Pentlandite
1.3.2.3 Pentlandite deposits are Kambalda-type komatiitic ore
Pentlandite is an iron nickel sulfide with in Western Australia, Noril’sk Ni–Cu–PGE
chemical formula of [(Fe,Ni)9S8]. The mineral in trans-Siberian Russia, and a few others in
was discovered by and named after the Irish Namibia and Brazil, The supergiant Sudbury
scientist Joseph Barclay Pentland. The color
nickel deposit in Canada was formed by a large
is yellow-bronze with light bronze-brown meteorite impact crater.
streak and metallic luster. The hardness varies
between 3.5 and 4.0 on the Mohs scale with 1.3.2.4 Pyrrhotite
moderate specific gravity between 4.6 and
Pyrrhotite (Fig. 1.11) is an unusual iron sul-
5.0. The m ineral in purest form contains 22% fide with variable iron content [Fe(1−x) S(x=0–0.2)].
Ni, 42% Fe, and 36% S. Pentlandite is the most The color ranges between bronze yellow and
common terrestrial nickel sulfide; it typically copper-red with black streak and metallic lus-
forms during cooling of magmatic sulfide melts ter. The hardness varies between 3.5 and 4.5 on
during the evolution of parent silicate melt.
the Mohs scale and an average specific gravity
Pentlandite typically concentrates within the of 4.6. Pyrrhotite is naturally magnetic with the
lower margin of a mineralized layered intrusive. increase of iron content. Pyrrhotite is a com-
The best examples include the Sudbury mon and important constituent in mafic igne-
(Fig. 1.10) deposits, Canada, Bushveld layered ous intrusive rocks such as norites. It occurs
1.3.3.2 Crocoite
Crocoite is a rare lead chromate mineral hav-
ing the chemical formula of (PbCrO4). The min-
eral in the purest form contains 64.11% Pb and
16.09% Cr. It has a brilliant vivid yellow color
FIGURE 1.12 Crystalline brownish-black chromite from
Kathpal mine, Sukinda Layered Igneous Complex, Orissa, for its best use in paints. The mineral was first
India. reported at Berezovsk gold mines in the Urals
region in 1766, and named “Crocoise” in 1832
as segregation in layered intrusions associated from the Greek “Kpókoç” (“krokos” meaning
with Pentlandite, Chalcopyrite, and other sul- “saffron”). The mineral is found in gold-bearing
fides. The Pentlandite–Chalcopyrite–Pyrrhotite quartz veins traversing granite or gneisses in the
ore around the Sudbury structure formed from presence of ultramafic rocks serving as source of
sulfide melts that segregated from the melt sheet chromium. The type areas include Russia, South
produced by the meteoritic impact. Africa, Brazil, North America, Germany, Austra-
lia, and the Red Lead, West Comet, Platt, and a
few other mines at Dundas, Tasmania.
1.3.3 Minerals of Chromium
1.3.3.1 Chromite 1.3.4 Minerals of Copper
Chromite (Fig. 1.12) is an iron chromium Copper-bearing minerals occur in nature by
oxide (FeO,Cr2O3 or FeCr2O4 ± Mg). In its pur- various chemical forms (carbonate, oxide, and
est form, chromite ore contains 68% Cr2O3, sulfide), metal content (% Cu), and name for
and Cr:Fe ratio of 1.8:1. Louis Nicolas Vau- identification. The most important, common,
quelin was the discoverer of the element and abundant copper mineral is Chalcopyrite.
“chromium,” and named the mineral “ferrous-
chromate-alumine” in 1798. Later, Wilhelm 1.3.4.1 Azurite
Haidinger named it “chromite” in 1845 with ref- Azurite is a soft deep-blue (azure-blue)
erence to its extremely high chromium content. color copper carbonate hydroxide mineral
Chromite occurs in mafic–ultramafic intrusives [Cu3(CO3)2(OH)2]formed by weathering of
and as a process of early magmatic differentia- copper orebodies (Fig. 1.13). The hardness var-
tion usually in layered form. The common host ies between 3.5 and 4.0 on the Mohs scale with
component is ultramafic igneous intrusive rocks. average specific gravity of 3.8. The mineral in
The typical host rocks are peridotite, pyroxenite, the purest form contains 55.31% Cu. Azurite is
dunite, serpentinite, chromitite cumulate, and seldom used as copper ore, but its presence is an
komatiite. The characteristic mineral assem- excellent surface indicator and guide for explo-
blages are Olivine, Serpentine, Magnetite with ration targeting in the vicinity and at depth. The
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Language: English
SWISS BOY
BY
JOHANNA SPYRI
Translated by
CLEMENT W. COUMBE
Illustrated by
FRANCES BRUNDAGE
THE
Made in U. S. A.
Copyright, 1926
By
CONTENTS
Chapter
I. IN LEUK
V. IN EXILE
SWISS BOY
CHAPTER I
IN LEUK
"I tell you, Marianne," said the more talkative one, "if
you could furnish a couple of rooms as I did, you would find
it very profitable. You would soon get boarders, for many of
the people coming to the baths do not wish to live there, or
they should not, like the three I have. Of course you live
rather far down and most people prefer the higher localities.
If only you lived over there where those people do! They
have the best location on the slope, and own the best
meadow land too. But I do not like them," glancing at the
house with an unfriendly look. "They are eaten up with
pride. The man is not so bad, but you should see the
woman!"
"The little girl can't help it if her nose turns up, and the
boy isn't really to blame for his curly hair," Marianne replied.
"Doesn't the woman speak pleasantly when you meet her?"
"It is the same house, and the change shows how proud
they are," answered Magdalen warmly. "Farmer Lesa lived
there more than fifty years with his old housekeeper, and in
all those years never drove so much as a nail in the house.
What was good enough for father and grandfather before
him was good enough for him. When his heir came from
over the Gemmi, there started such a tearing down and
rebuilding and such a cleaning up one might suppose a
count was moving in. Of course the wife was the cause of it
all."
"But I should think it would be necessary to clean up
and renew things if nothing had been done for fifty years,"
said Marianne. "The old house was no pretty sight, I must
say! But why do you say the heir came from across the
Gemmi? Don't the Lesas belong to our section of the
country?"
"She died shortly after he did. She was his cousin and
had lived with him fully fifty years. She was over seventy,
so she could not undertake anything new. Look, look!"
continued Magdalen eagerly. "There they come across the
meadow! Now you can see the Lesa woman and her
dressed-up children too."
Marianne did not need much persuasion to tarry, for she
was very curious to see the people they had been talking
about. The three came nearer, and the children must have
had a great deal to tell their mother for they were so
engrossed in conversation they had neither eyes nor ears
for anything else.
"Can you believe it, mother?" the lad said. "The child
isn't much taller than Stefeli. When we passed Mrs. Troll's
house last evening, she stood at the front door, and she
went inside and suddenly we heard lovely music through
the open window. Her brother still sat outside reading a
book, so I asked what it was and he said, 'Alida is playing
the piano.' Think of it, such a little girl! I would have liked to
have listened, but Stefeli said we must go on home for it
was getting late."
"What are you staring at? And why don't you answer
your sister?" asked his mother.
"I do not know. If only I could sing the tune that still
rings in my ears!"
"She will not let Alida talk with us; did you hear that,
mother?" said Stefeli.
"Yes," replied Mrs. Lesa. "I am glad you did not run in to
see them, and you must not do so, Stefeli, do you hear?"
"A man can never tell what his wife will think of next!"
he exclaimed with rising anger. "But I know what you are
aiming at, and I say, let it alone. I want to live by myself,
and as to these strange gentlefolk, our children are not to
have anything to do with them, or our girl will be as spoilt
as our boy. I am glad to say she is quite different from him.
The young heifer runs after her and eats out of her hand.
When she is told something, she pays attention, but the boy
—he knows nothing."
CHAPTER II
IN THE PASTURE
ONE Monday morning, so early that the sun was just
reddening the tops of the mountains, Stefeli rushed into
Vinzi's room.
Now the two set off, and the father called after them,
"Look out, Vinzi, that none of the cows gets across the
stream," and the mother followed with her warning, "Take
care not to go too near the stream where the rapids are!"
"Most of all, I love to hear the bells peal and hear them
resound through the branches of the trees and down from
the mountain heights. Do you hear the soft notes around us
—do you hear?" and his eyes grew larger and brighter as he
listened.
Sitting up, Vinzi said, "I wish the dog had been on the
other side, where the path leads up to the pasture. I saw a
fiery red flower there, and it looked tremendously big, even
from where I was—bigger than any I ever saw. If it were
not so far, I'd go and fetch it, but it is too hot."
The cows had been so busy grazing that now they were
ready to rest a bit. Even Schwarzeli had settled down
peacefully, though she tossed her little black head from
time to time, showing she could not be trusted altogether.
"Yes," agreed Stefeli. "The big ones will rest for a while
and if Schwarzeli starts to run to the stream, I'll entice her
back. I have kept all the salt mother gave us for the eggs.
You did not ask for any, and Schwarzeli loves it."
Taking the scarf which Stefeli had folded, Vinzi ran off,
but it took a good quarter of an hour for him to reach Mrs.
Troll's house. The front door stood open and all was quiet
inside.
"If it pleases you, say yes quickly, that you really wish
it," said Alida a little impatiently. "Then you must come here
every day at two o'clock, like today, because then Miss
Landrat takes a walk with Hugo and I have to practise until
three o'clock or sometimes even later, until they return. So
we will be quite alone and I will teach you everything."