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CHEMISTRY BY S.K.Y. SIR
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NEET : Chemistry
AIPMT 2009 6. Mole fraction of the solute in a 1.00 molal
1. A 0.0020 m aqueous solution of an ionic aqueous solution is :
compound [Co(NH3)5(NO2)]Cl freezes at (1) 0.1770 (2) 0.0177
–0.00732°C. Number of moles of ions which (3) 0.0344 (4) 1.7700
1mol of ionic compound produces on being
dissolved in water will be(Kf = 1.86°C m–1) :- AIPMT Mains 2011
(1) 1 (2) 2 (3) 3 (4) 4 7. 200 mL of an aqueous solution of a protein
contain its 1.26 g. The Osmotic pressure of this
AIPMT 2010 solution at 300 K is found to be 2.57 × 10–3 bar.
2. An aqueous solution of KI is 1.00 molal. Which The molar mass of protein will be :-
change will cause increase in vapour pressure (R = 0.083 L bar mol–1 K–1)
of the solution ? (1) 61038 g mol–1 (2) 51022 g mol–1
(1) Addition of water (3) 122044 g mol–1 (4) 31011 g mol–1
(2) Addition of NaCl
(3) Addition of Na2SO4 AIPMT Pre 2012
(4) Addition of 100 molal KI 8. pA and pB are the vapour pressure of pure
3. A solution of sucrose (molar mass = 342 g mol-1) liquid components, A and B, respectively of an
has been prepared by dissolving 68.5 g of sucrose ideal binary solution. If xA represents the mole
in 1000 g of water. The freezing point of the fraction of component A, the total pressure of
solution obtained will be :- the solution will be.
(Kf for water = 1.86 K kg mol–1) (1) pB + xA (pB – pA) (2) pB + xA (pA – pB)
(1) –0.570°C (2) –0.372°C (3) pA + xA (pB – pA) (4) pA + xA (pA – pB)
(3) –0.520°C (4) +0.372°C
AIPMT Mains 2012
AIPMT Pre. 2011 9. Which of the following compounds can be
4. The freezing point depression constant for used as antifreeze in automobile radiators ?
water is –1.86°C m–1. If 5 g Na2SO4 is dissolved (1) Nitrophenol (2) Ethyl alcohol
in 45.0 g H2O, the freezing point is changed by (3) Methyl alcohol (4) Glycol
–3.82°C. Calculate the Van't Hoff factor for 10. Vapour pressure of chloroform (CHCl3) and
Na2SO4 dichloro methane (CH2Cl2) at 25°C are
(1) 2.05 (2) 2.63 (3) 3.11 (4) 0.381 200 mmHg and 415 mmHg respectively.
5. The Van't Hoff factor i for a compound which Vapour pressure of the solution obtained by
undergoes dissociation in one solvent and mixing 25.5 g of CHCl3 and 40g of CH2Cl2 at the
association in other solvent is respectively : same temperature will be: (Molecular mass of
(1) Less than one and greater than one CHCl3 = 119.5 u and molecular mass of
(2) Less than one and less than one CH2Cl2 = 85 u)
(3) Greater than one and less than one (1) 347.9 mmHg (2) 280.5 mmHg
(4) Greater than one and greater than one (3) 173.9 mmHg (4) 615 mmHg
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Solutions
NEET-UG 2013 NEET-I 2016
11. 6.02 × 1020 molecules of urea are present in 17. Which of the following statement about the
100mL of its solution. The concentration of composition of the vapour over an ideal a 1 : 1
solution is :- molar mixture of benzene and toluene is
(1) 0.1 M (2) 0.02 M (3) 0.01 M (4) 0.001M correct? Assume that the temperature is
constant at (25°C). (Given : Vapour Pressure
AIPMT 2014
Data at 25°C, benzene = 12.8 kPa, Toluene =
12. Of the following 0.10m aqueous solutions,
3.85 kPa)
which one will exhibit the largest freezing
(1) The vapour will contain a higher percentage
point depression?
of benzene
(1) KCl (2) C6H12O6
(2) The vapour will contain a higher percentage
(3) Al2(SO4)3 (4) K2SO4
of toluene
AIPMT 2015 (3) The vapour will contain equal amounts of
13. The boiling point of 0.2 mol kg–1 solution of X benezene and toluene
in water is greater than equimolal solution of (4) Not enough information is given to make a
Y in water. Which one of the following predication
statements is true in this case? 18. At 100°C the vapour pressure of a solution of
(1) Molecular mass of X is greater than the 6.5g of a solute in 100 g water is 732 mm. If
molecular mass of Y. Kb = 0.52°C m–1, the boiling point of this
(2) Molecular mass of X is less than the solution will be :-
molecular mass of Y. (1) 101°C (2) 100°C (3) 102°C (4) 103°C
(3) Y is undergoing dissociation in water 19. Consider the following liquid - vapour
while X undergoes no change.
equilibrium.
(4) X is undergoing dissociation in water
Liquid Vapour
while Y undergoes no change.
14. Which one is not equal to zero for an ideal Which of the following relations is correct ?
solution:- d nG Hv d nP −Hv
(1) 2
= 2
(2) =
(1) Smix dT RT dT RT
(2) Vmix d nP −Hv d nP Hv
(3) = 2 (4) =
(3) P = Pobserved - PRaoult dT2 T dT RT2
(4) Hmix
15. Which one of the following electrolytes has NEET-II 2016
the same value of van't Hoff's factor (i) as that 20. The van't Hoff factor (i) for a dilute aqueous
of the Al2(SO4)3 (if all are 100% ionised) ? solution of the strong electrolyte barium
(1) K3[Fe(CN)6] (2) Al(NO3)3 hydroxide is
(3) K4[Fe(CN)6] (4) K2SO4 (1) 2 (2) 3 (3) 0 (4) 1
21. Which one of the following is incorrect for
Re-AIPMT 2015 ideal solution ?
16. What is the mole fraction of the solute in a (1) P = Pobs – Pcalculated by Raoult's law = 0
1.00 m aqueous solution ? (2) Gmix = 0
(1) 0.0354 (2) 0.0177 (3) Hmix = 0
(3) 0.177 (4) 1.770 (4) Umix = 0
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NEET : Chemistry
NEET(UG) 2017 28. The mixture which shows positive deviation
22. If molality of a dilute solution is doubled, the from Raoult's law is :-
value of molal depression constant (Kf) will be:- (1) Chloroethane + Bromoethane
(1) Halved (2) Tripled (2) Ethanol + Acetone
(3) Unchanged (4) Doubled (3) Benzene + Toluene
23. Which of the following is dependent on (4) Acetone + Chloroform
temperature?
NEET (UG) 2020 (COVID-19)
(1) Molarity (2) Mole fraction
29. If 8g of a non-electrolyte solute is dissolved in
(3) Weight percentage (4) Molality
114 g of n-octane to reduce its vapour
pressure to 80%, the molar mass (in g mol–1)
NEET(UG) 2019
of the solute is
24. For an ideal solution, the correct option is :-
[Given that molar mass of n-octane is 114 g
(1) mix S = 0 at constant T and P mol–1]
(2) mix V 0 at constant T and P (1) 40 (2) 60 (3) 80 (4) 20
(3) mix H = 0 at constant T and P 30. Isotonic solutions have same
(4) mix G = 0 at constant T and P (1) Vapour pressure
(2) Freezing temperature
NEET(UG)(Odisha) 2019 (3) Osmotic pressure
25. Which of the following statements is correct (4) Boiling temperature
regarding a solution of two compounds A and
B exhibiting positive deviation from ideal NEET (UG) 2021
behaviour? 31. The following solutions were prepared by
(1) Intermolecular attractive forces between dissolving 10 g of glucose (C6H12O6) in 250 ml
A-A and B-B are stronger than those of water (P1), 10 g of urea (CH4N2O) in 250 ml
between A-B. of water (P2) and 10 g of sucrose (C12H22O11)
(2) mix H = 0 at constant T and P in 250 ml of water (P3). The right option for
(3) mix V = 0 at constant T and P the decreasing order of osmotic pressure of
(4) Intermolecular attractive forces between A- these solutions is :
A and B-B are equal to those between A-B. (1) P2 > P1 > P3 (2) P1 > P2 > P3
(3) P2 > P3 > P1 (4) P3 > P1 > P2
26. The density of 2 M aqueous solution of NaOH is
32. The correct option for the value of vapour
1.28 g/cm3. The molality of the solution is
pressure of a solution at 45°C with benzene to
[Given that molecular mass of NaOH = 40 g mol–1]
octane in molar ratio 3 : 2 is :
(1) 1.20 m (2) 1.56 m
[At 45°C vapour pressure of benzene is 280
(3) 1.67 m (4) 1.32 m
mm Hg and that of octane is 420 mm Hg.
Assume Ideal gas]
NEET (UG) 2020 (1) 160 mm of Hg (2) 168 mm of Hg
27. The freezing point depression constant (Kf) of (3) 336 mm of Hg (4) 350 mm of Hg
benzene is 5.12 K kg mol–1. The freezing point
depression for the solution of molality 0.078 m NEET (UG) 2022
containing a non-electrolyte solute in benzene is 33. In one molal solution that contains 0.5 mole of
(rounded off upto two decimal places) : a solute, there is
(1) 0.60 K (2) 0.20 K (1) 500 g of solvent (2) 100 mL of solvent
(3) 0.80 K (4) 0.40 K (3) 1000 g of solvent (4) 500 mL of solvent
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Solutions
34. KH value for some gases at the same where KH is Henry's Law constant in water.
temperature 'T' are given : The order of their solubility in water is :
gas KH/k bar (1) Ar < CO2 < CH4 < HCHO
Ar 40.3 (2) Ar < CH4 < CO2 < HCHO
CO2 1.67 (3) HCHO < CO2 < CH4 < Ar
HCHO 1.83 × 10–5 (4) HCHO < CH4 < CO2 < Ar
CH4 0.413
(Previous Year Questions) ANSWER KEY
Question 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Answer 2 1 2 2 3 2 1 2 4 1 3 3 4 1 3
Question 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Answer 2 1 1 4 2 2 3 1 3 1 3 4 2 1 3
Question 31 32 33 34
Answer 1 3 1 1
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