Topic-wise DPPs for NEET Aspirants

Thermodynamics
DPP- I – Heat, Internal Energy, State function and variables, 0th and 1st Law of Thermodynamics,
Specific heats and PV- Graph

1. If an ideal gas is compressed isothermally then

a) No work is done against gas b) Heat is released by the gas
c) The internal energy of gas will increase d) Pressure does not change
2. For free expansion of the gas which of the following is true
a) 𝑄 = 𝑊 = 0 and ∆𝐸!"# = 0 b) 𝑄 = 0, 𝑊 > 0 and ∆𝐸!"# = −𝑊
c) 𝑊 = 0, 𝑄 > 0 and ∆𝐸!"# = 𝑄 d) 𝑊 > 0, 𝑄 < 0 and ∆𝐸!"# = 0
3. When heat is given to a gas in an isothermal change, the result will be
a) External work done b) Rise in temperature
c) Increase in internal energy d) External work done and also rise in temp.
4. The internal energy of the gas increases in
a) Adiabatic expansion b) Adiabatic compression
c) Isothermal expansion d) Isothermal compression
5. The specific heat of an ideal gas varies with temperature 𝑇 as
a) 𝑇 $ b) 𝑇 % c) 𝑇 &% d) 𝑇 '
6. Blowing air with open mouth is an example of
a) Isobaric process b) Isochoric process c) Isothermal process d) Adiabatic process
7. In isothermic process, which statement is wrong
a) Temperature is constant b) Internal energy is constant
c) No exchange of energy d) (a) and (b) are correct
8. If a system undergoes contraction of volume then the work done by the system will be
a) Zero b) Negligible c) Negative d) Positive
9. For an ideal gas, in an isothermal process
a) Heat content remains constant b) Heat content and temperature remain constant
c) Temperature remains constant d) None of the above
10. The phenomenon of sound propagation in air is
a) Isothermal process b) Isobaric process c) Adiabatic process d) None of these
11. The first law of thermodynamics is concerned with the conservation of
a) Momentum b) Energy c) Mass d) Temperature
12. First law of thermodynamics is given by
a) 𝑑𝑄 = 𝑑𝑈 + 𝑃𝑑𝑉 b) 𝑑𝑄 = 𝑑𝑈 × 𝑃𝑑𝑉 c) 𝑑𝑄 = (𝑑𝑈 + 𝑑𝑉)𝑃 d) 𝑑𝑄 = 𝑃𝑑𝑈 + 𝑑𝑉
13. In a cyclic process, work done by the system is
a) Zero b) Equal to heat given to the system
c) More than the heat given to system d) Independent of heat given to the system
14. A system goes from A to B via two processes I and II as shown in figure. If ∆𝑈$ and ∆𝑈% are the changes in
internal energies in the processes I and II respectively, then

Relation between ∆𝑈$ and ∆𝑈% cannot be

a) ∆𝑈$ = ∆𝑈% b)
determined
c) ∆𝑈% > ∆𝑈$ d) ∆𝑈% < ∆𝑈$
15. Out of the following which quantity does not depend on path
a) Temperature b) Energy c) Work d) None of these
16. When two bodies 𝐴 and 𝐵 are in thermal equilibrium
a) The kinetic energies of all the molecules of 𝐴 and 𝐵 will be equal
b) The potential energies of all the molecules of 𝐴 and 𝐵 will be equal
c) The internal energies of the two bodies will be equal
d) The average kinetic energy of the molecules of the two bodies will be equal
17. If amount of heat given to a system be 50 J and work done on the system be 15 J, then change in internal
energy of the system is
a) 35 J b) 50 J c) 65 J d) 15 J
18. If the door of a refrigerator is kept open, then which of the following is true
a) Room is cooled b) Room is heated
c) Room is either cooled or heated d) Room is neither cooled nor heated
19. Which of the following is unique function of initial and final states?
a) dQ b) dW c) dU d) ∆𝑄 and ∆𝑊
20. If a gas is heated at constant pressure, its isothermal compressibility
a) Remains constant
b) Increases linearly with temperature
c) Decreases linearly with temperature
d) Decreases inversely with temperature
21. A mono atomic gas is supplied the heat 𝑄 very slowly keeping the pressure constant. The work done by
the gas will be
2 3 2 1
a) 𝑄 b) 𝑄 c) 𝑄 d) 𝑄
3 5 5 5
22. Which of the following statement is correct for any thermodynamic system?
a) The internal energy changes in all processes
b) Internal energy and entropy are state functions
c) The change in entropy can never be zero
d) The work done in an adiabatic process is always zero
23. A gas i𝛾 = (k, expands isobarically. The percentage of heat supplied that increases thermal energy and
)
that is involved in doing work for expansion is
a) l40: 60 b) 60: 40 c) 50: 50 d) 25: 30
24. dU+dW=0 is valid for
a) Adiabatic process b) Isothermal process c) Isobaric process d) Isochoric process
25. When water is converted into ice, its entropy
a) Increases b) Decreases
c) Remains unchanged d) First decreases and then increases
26. If the heat 110 J is added to a gaseous system and it acquires internal energy of 40 J, then the amount of
internal work done is
a) 40 J b) 70 J c) 150 J d) 110 J
27. The temperature of the system decreases in the process of
a) Free expansion b) Adiabatic expansion
c) Isothermal expansion d) Isothermal compression
28. When a small amount of heat ∆𝑄 is added to an enclosed gas, then increase in internal energy and external
work done are related as
a) 𝑚𝐶* ∆𝑇 = 𝑄 + 𝑝∆𝑉 b) ∆𝑄 = 𝑚𝐶* ∆𝑇 + 𝑝∆𝑉 c) 𝑚𝐶* = ∆𝑄 + 𝑝∆𝑉 d) ∆𝑄 = 𝑚𝐶+ ∆𝑇 + 𝑝∆𝑉
29. A thermodynamical system is changed from state (𝑝$ 𝑉$ )to (𝑝% , 𝑉% ) by two different processes, the quantity
which will remain same will be
a) Δ𝑄 b) Δ𝑊 c) Δ𝑄 + Δ𝑊 d) Δ𝑄 − Δ𝑊
30. The work done in which of the following process is zero?
a) Isothermal process b) Adiabatic process c) Isochoric process d) None of these
&$
31. Value of two principle specific heats of a gas in cal (mol K) determined bt different students are given.
Which is most reliable?
a) 5, 2 b) 6, 5 c) 7, 5 d) 7, 4
32. Which is incorrect
a) In an isobaric process, ∆𝑃 = 0 b) In an isochoric process, ∆𝑊 = 0
c) In an isothermal process, ∆𝑇 = 0 d) In an isothermal process, ∆𝑄 = 0
33. In adiabatic expansion of a gas
a) Its pressure increases b) Its temperature falls
c) Its density increases d) Its thermal energy increases
34. In figure a certain mass of gas traces three paths 1, 2, 3 from state 𝐴 to state 𝐵. If work done by the gas
along three paths are 𝑊$ , 𝑊% , 𝑊) respectively, then

a) 𝑊$ < 𝑊% < 𝑊) b) 𝑊$ = 𝑊% = 𝑊) c) 𝑊$ > 𝑊% > 𝑊) d) Cannot say

35. The state of a thermodynamic system is represented by
a) Pressure only b) Volume only
c) Pressure, volume and temperature d) Number of moles
36. During an isothermal expansion, a confined ideal gas does −150𝐽 of work against its surrounding. This
implies that
a) 150 𝐽 of heat has been added to the gas
b) 150 𝐽 of heat has been removed from the gas
c) 300 𝐽 of heat has been added to the gas
d) No heat is transferred because the process is isothermal
37. The specific heat of a gas in an isothermal process is
a) Infinite b) Zero c) Negative d) Remains constant

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 : HINTS AND SOLUTIONS:
1 (b) 14 (a)
In isothermal process, heat is released by the gas The change in internal energy does not depend
to maintain the constant temperature upon path followed by the process. It only
2 (a) depends on initial and final states.

3 (a) Hence, ∆𝑈$ = ∆𝑈%

In isothermal change, temperature remains 15 (a)
constant, 16 (c)
Hence ∆𝑈 = 0 17 (c)
Also from ∆𝑄 = ∆𝑈 + ∆𝑊 ⇒ ∆𝑄 = ∆𝑊 Here 𝑑𝑄 = 50 J, 𝑑𝑊 = −15 J
4 (b) 𝑑𝑈 = 𝑑𝑄 − 𝑑𝑊 = 50 − (−15) = 65 J
In adiabatic process ∆𝑈 = −∆𝑊. In compression 18 (b)
∆𝑊 is negative, so ∆𝑈 is positive 𝑖. 𝑒. internal In a refrigerator, the heat dissipated in the
energy increases atmosphere is more than that taken from the
5 (d) cooling chamber, therefore the room is heated if
Specific heat of an ideal gas does not depend upon the door of a refrigerator is kept open
temperature 19 (c)
6 (a) The internal energy U of a thermodynamic system
We know that blowing air (if sudden) is an is a characteristic property of the state of the
adiabatic process. But it is not given as sudden system, it does not matter, how that state has
process. Also, as the mouth is open, pressure been obtained U is a unique function because it
inside and outside is same. Thus, blowing air with depends only upon the state of the system.
open mouth is isobaric process. 20 (a)
7 (c) 𝐸- = 𝑃, if 𝑃 = constant, 𝐸- = constant
In isothermal process, exchange of energy takes 21 (c)
place between system and surrounding to ∆𝑄 = ∆𝑈 + ∆𝑊 ⇒ ∆𝑊 = (∆𝑄). − ∆𝑈
maintain the system temperature constant (∆𝑄)/
= (∆𝑄). •1 − €
8 (c) (∆𝑄).
∆𝑊 = 𝑃∆𝑉, here ∆𝑉 is negative so ∆𝑊 will be 𝐶/ 3 2
= (∆𝑄). •1 − ‚ = 𝑄 •1 − ‚ = 𝑄
negative 𝐶. 5 5
(
9 (c) ∵ (∆𝑄). = 𝑄 and 𝛾 = ) for monoatomic gas
In isothermal process temperature remains 22 (b)
constant Internal energy does not change in isothermal
10 (b) process. ∆𝑆 can be zero for adiabatic process.
Velocity of sound in air increases (𝑣, ) with Work done in adiabatic process may be non-zero.
increase in temperature[𝑣, = 𝑣' + 0.61𝑡]but is 23 (b)
independent of pressure variation. )
𝑄$ 𝐶/ 𝑑𝑇 % 𝑅 3
11 (b) = = = that is 60: 40.
𝑄% 𝑝 𝑑𝑇 𝑅 2
24 (d)
12 (a)
In adiabatic process
∆𝑄 = ∆𝑈 + ∆𝑊 and ∆𝑊 = 𝑃∆𝑉
13 (b) ∆𝑄 = 0
For cyclic forces Δ𝑈 = 0, So, Δ𝑄 = Δ𝑊
Therefore, first law of thermodynamics becomes

dU+dW=0
 30 (c)
Isochoric process takes place at constant volume.
25 (b)
Entropy is a measure of disorder. When water is Since, there is no change of volume (∆𝑉 = 0)
converted into ice, disorder decreases, hence therefore
entropy decreases. 𝑊 = 𝑝 ∆𝑉 = 0
26 (b) 31 (c)
Here, 𝑑𝑄 = 110 J, 𝑑𝑈 = 40 J, 𝑑𝑊 =? 𝐶+ − 𝐶* = 𝑅 = 2 cal (mol K)&$ Difference in the
From 𝑑𝑄 = 𝑑𝑈 + 𝑑𝑊
two values must be 2
𝑑𝑊 = 𝑑𝑄 − 𝑑𝑈 = 110 − 40 = 70 J
32 (d)
27 (b)
In isothermal process ∆𝑄 ≠ 0
In adiabatic expansion of a gas system, gas
33 (b)
expands, so temperature of the system decreases.
34 (c)
28 (b)
As work done by the gas = area under the 𝑝 − 𝑉
∆𝑄 = ∆𝑈 + ∆𝑊 = 𝑚𝐶* (∆𝑇) + 𝑝(∆𝑉)
curve, therefore 𝑊$ > 𝑊% > 𝑊)
29 (d)
35 (c)
For all processes, change in internal energy
For all thermodynamic purposes, the state of a
∆𝑈(∆𝑄 − ∆𝑊) does not change. It depends only
system can be represented by specifying its
on initial and final states.
pressure p, volume V and the temperature T
provided the system is in equilibrium.
36 (b)
∆𝑄 = ∆𝑈 + ∆𝑊
∆𝑄 = 0 − 150 𝐽
So, heat has been given by the system
37 (a)
In isothermal process temperature remains
constant
0
𝑖. 𝑒. , ∆𝑇 = 0. Hence according to 𝐶 = 1∆3 ⇒
𝐶456 = ∞

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