VELAMMAL KNOWLEDGE PARK, PONNERI

NEET WORK SHEET

Class :XII

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SUB : CHEMISTRY TOPIC : CHEMICAL KINETICS
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RATE OF CHEMICAL REACTION :
1. In the reaction, A  2 B  C  2 D , the initial rate  d  A / dt was found to be
2.6  102 Ms 1 . What is the value of  d  B  / dt in M s-1?
2 2 1 3
1) 2.6  10 2) 5.2  10 3)1.0  10 4) 6.5  10
2. The rate of reaction
Cl3CCHO  NO  CHCl3  NO  CO is given by equation,
Rate  k Cl3CCHO  NO  If concentration is expressed in mol/L, the un
units of k are
1) L2 mol-2s-1 2) Mol L-1 s-1 3) L mol-1 s-1 4) s-1
3. For a reaction, X → Y, the graph of the product concentration (x) versus (t) came
d  X 
out to be a straight line passing through the origin. Hence the graph of
dt
and time would be
1) Straight line with a negative slope and an interc
intercept on y-axis
2) Straight line with a positive slope and an intercept on y – axis
3) A straight line parallel to x – axis 4) A hyperbola
d  NH 3 
4. For the reaction, N 2  3H 2  2 NH3 , if  2  10 4 mol L1s 1 , the value of
dt
d  H 2 
would be
dt
4 1 1 4 1 1
1) 4  10 mol L s 2) 6  10 mol L s
4 1 1 4 1 1
3) 1  10 mol L s 4) 3  10 mol L s
5. For the reaction,
1
N2O5  g   2 NO2  g   O2  g 
2
The value of rate of disappearance of N2O5 is given as 6.25  10 3 mol L1s 1 . The
rate of formation of NO2 and O2 is given respectively as
1) 6.25  10 3 mol L1s 1 and 6.25  10 3 mol L1s 1
2) 1.25  10 2 mol L1s 1 and 3.125  10 3 mol L1s 1
3) 6.25  10 3 mol L1s 1 and 3.125  10 3 mol L1s 1
4) 1.25  10 2 mol L1s 1 and 6.25  10 3 mol L1s 1
6. For the reaction,
3A → product,
the concentration of ‘A’ is decreased from 0.8M to 0.2M in 20 minutes. Then the
rate of reaction is ____ M.min-1.
1) 0.03 2) 0.02 3) 0.01 4) 0.6’

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7. For the reaction,
N2(g) +3H2(g)→2NH3(g),
the rate of disappearance of H2 is 4.8  10 4 M .sec 1 . Then the rate of appearance of
NH3 is ____ M.sec-1.
1) 3.2  10 4 2) 4.8  10 4 3) 2.4  10 4 4) 1.6  10 4
8. For the reaction,
N 2  g   3 H 2  g   2 NH 3  g 
the rate of formation of ammonia is 34g/hr. Then the rate of disappearance of
hydrogen is ______ g/hr.
1) 17 2) 51 3) 6 4) 28
9. The rate of a gaseous reaction is given by K[A] [B]. If the volume of reaction
1
vessel is reduced to of the initial volume then the reaction rate relative to the
4
original rate is _______ times.
1 1
1) 2) 3) 8 4)16
16 8
10. Observe the following reaction,
A g   3B g   2C g  . The rate of this reaction,
 d  A  3 1 1 d B
  is 3  10 mole lit min . What is the value of  in mole lit-1 min-1?
 dt  dt
3
1) 3  10 2) 9  10 3 3) 103 4) 1.5  10 3
11. For the reaction,
4 NH 3  5O2  4 NO  6 H 2O , the rate of reaction with respect to NH3 is 2  10 3 Ms 1 .
Then the rate of the reaction with respect to oxygen in Ms-1 is
1) 2  10 3 2) 1.5  10 3 3) 2.5  10 3 4) 3  10 3
12. For a reaction, 2 A  products , the concentration of ‘A’ is decreased from 0.04M to
0.02M in 10 minutes. Then the rate of reaction is ____M.min -1.
1) 2  10 3 2) 1  10 3 3) 4  10 3 4) 2  10 2
13. At 300C, the rate of a reaction is 5 units. Then the rate of same reaction at 70 0C
is _____ units. (Assume temperature coefficient is 3)
1) 80 2) 405 3) 1215 4) 135
14. For the reaction, A  B  2C  D, which one is the incorrect statement?
1) Rate of disappearance of A = Rate of disappearance of B
2) Rate of disappearance of A = Rate of appearance of D
3) Rate of disappearance of B = 2 × rate of appearance of C
1
4) Rate of disappearance of B   rate of appearance of C
2
15. For an elementary reaction, 2 A  B  C  D , the concentration of B is kept
constant and that of A is tripled, the new rate of reaction will be:
1) Nine times 2) Three times 3) Six times 4) Four times
16. For the reaction: R → P, the concentration of reactant decreases from 0.03 M to
0.02M in 25 min. Calculate the average rate of reaction in mol L -1s-1.
1) 6.66  106 molL1s 1 2) 3.33  106 molL1s 1
3) 6.66  105 molL1s 1 4) 3.33  105 molL1s 1

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17. For the decomposition reaction:
N2O4 g   2 NO2 g  ; the initial pressure of N2O4 falls from 0.46 atm to 0.28 atm in
30 minute. What is the rate of appearance of NO2?
1) 12 102 atm.min 1 2) 1.2 102 atm.min 1
3) 1.2 102 atm.min 1 4) 1.8  10 1 atm.min 1
18. The rate of a chemical reaction (except zero order reaction).
1) Increases as the reaction proceeds 2) Decreases as the reaction proceeds
3) May increase or decrease during the reaction
4) Remains constant as the reaction proceeds

FACTORS IN FLUENCING RATE OF REACTION :

19. For the reaction, A  B  products , it is observed that
(i) On doubling the initial concentration of A only, the rate of reaction is also
doubled and
(ii) On doubling the initial concentration of both A and B, there is a change by a
factor of 8 in the rate of the reaction.
The rate of this reaction is given by
      B    B
3) rate = k  A B  4) rate = k A
2 2 2 2
1) rate = k A B 2) rate = k A
20. For a reaction between A and B the order with respect to A is 2 and the order
with respect to B is 3. The concentrations of both A and B are doubled, the rate
will increase by a factor of
1) 12 2) 16 3) 32 4) 10
21. The reaction A + 2B + C  2D + E is found to be 1, 2 and zero order with
respect to A, B and C respectively. What will be the final rate when compared to
initial rate, if concentration of each reactant is doubled?
1) 2 times 2) 4 times 3) 8 times 4) 16 times
22. For the reaction, 2A + B  products, when the concentration of A and B both
were doubled, the rate of the reaction increased from 0.3 mol L–1s–1 to 2.4 mol
L–1s–1. When the concentration of A alone is doubled, the rate increased from
0.3 mol L–1s–1to 0.6 mol L–1s–1. Which one of the following statements is correct?
1) Order of the reaction with respect to A is 2
2) Order of the reaction with respect to B is 1
3) Order of the reaction with respect to B is 2 4) Total order of the reaction is 4
23. Which of the following is not a favourable condition for higher rate of reaction?
1) Higher concentrations of reactants 2) Presence of a +ve catalyst
3) Higher temperature 4) Higher activation energy
24. For the reaction,
2 N 2O5  g   4 NO2  g   O2  g 
The concentration of N2O5 decreases from 2.33mol.lit-1 to 2.08mol.lit-1 in 50
minutes. Then rate of production of NO2 during this period is ____mol.lit-1.min-1.
1) 0.005 2) 0.02 3) 0.04 4) 0.01
25. Assertion (A) : Rate of reaction will be generally doubled, when temperature
increases from 298 k to 308 k.
Reason (R) :The activation energy of reaction decreases with increase in
temperature.
1) Both A & R are correct and R is correct explanation of A.
2) Both A & R are correct but R is not correct explanation of A.
3) A is correct and R is incorrect. 4) Both A and R are incorrect.

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26. A gaseous reaction,
1
A2  g   B  g   C  g  ,
2
shows increase of pressure from 100mm to 120mm in 5 min. The rate of
disappearance of A2 is
1) 4mm min-1 2) 40 mm min-1 3) 8mm min-1 4) 20mm min-1
27. On increasing the temperature, the rate of which of the following reaction
increases?
1) Only endothermic reaction 2) Only exothermic reaction
3) Both endothermic and exothermic reaction
4) Neither endothermic nor exothermic
28. For a chemical reaction A2  2 B   Product , rate controlling step is
1
A2  B   C. If the concentration of B is doubled, the rate of reaction will
2
1) Remain the same 2) Becomes four times
3) Becomes 1.414 times 4) Becomes double
ORDER OF REACTION, MOLECULARITY :
29. For a reaction A  B  Products , it is found experimentally that the rate of the
   B
1.5 2.5
reaction  k A . The order of the reaction is
1) -1 2) +1 3) 3.75 4) 4
2 2 2 1
30. The rate constant of a reaction is 2.3  10 mol L min . The order of reaction is
1) Zero 2) 1 3) 2 4) 3
31. Which one of the following statements for the order of a reaction is incorrect?
1) Order can be determined only experimentally
2) Order is not influenced by stoichiometric coefficient of the reactants
3) Order of a reaction is sum of power to the concentration terms of reactants to
express the rate of reaction.
4) Order of reaction is always whole number.
32. The reaction of hydrogen and iodine monochloride is given as:
H 2 g   2 ICl g   2 HCl g   I 2 g 
This reaction is of first order with respect to H2(g) and ICl(g), following mechanisms
were proposed.
Mechanism A:
H 2 g   2 ICl g   2 HCl g   I 2 g 
Mechanism B:
H 2 g   ICl g   HCl g   HI  g  ; slow
HI  g   ICl g   HCl g   I 2 g  ; fast
Which of the above mechanism(s) can be consistent with the given information
about the reaction?
1) A and B both 2) Neither A nor B 3) A only 4) B only
33. Mechanism of a hypothetical reaction.
X 2  Y2  2 XY , is given below:
(i) X 2  X  X  fast 
(ii) X  Y
2 XY +Y(slow) (iii) X  Y  XY  fast 
The overall order of the reaction will be
1) 2 2) 0 3) 1.5 4) 1

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34. At 300 K the half-life
life of a sample of a gaseous compound initially at 1 atm is
100 sec. When the initial pressure is 0.5 atm then the half half-life
life is 50sec. The
order of reaction is
1) One 2) Zero 3) Second 4) Half
35. 50% of a given reaction
tion is completed in 20 minutes and 75% of same reaction
is completed in 60 minutes. Then the order of the reaction is
1) 2 2) 1 3) 0 4) 3
36. For a reaction,
A → products,
90% of initially taken ‘A’ is reacted in 30 minutes and 99% of initially taken ‘A’
is reacted in 60 minutes. Then the order of the reaction is _____
1) 0 2) 1 3) 2 4) 3
37. The given plots represent the variation of the concentrati
concentration
on of a reactant R with
time for two different reactions (i) and (ii). The respective orders of the reactions
are

1) 0, 1 2) 1, 1 3) 1, 0 4) 0, 2
38. It is true that
1) A zero order reaction is a single step reaction
*2) A zero order reaction is a multistep reaction
3) A first order reaction is always a single step reaction
4) A second order reaction is always a multistep reaction
39. For a reaction, A → products, the rate constant of the reaction at 300C is
2.4  10 3 min 1 and at 400C it is 7.2  10 3 min 1 . Then the order of the reaction is
1) 0 2) 1 3) 2 4) 3
40. The rate of a certain reaction at differdifferent times is as follows
Time 0 10 20 30
Rate 3.2  10 2
3.18  10 2
3.22  10 2
3.19  10 2
The order of the reaction is
1) 1 2) Zero 3) 2 4) 3
41. For a reaction, A2 +B2 →2AB, →2 following mechanism is proposed
Mechanism:
A2   2 A  fast 
 2 B  fast 
B2 
 AB  slow 
A  B 
Then the order of the reaction is
1) 1 2) 2 3) 0 4) 0.5
42. Among the following statements,
A) Molecularity of the reactio
reaction is always non-zero
zero positive integer.
B) Ester hydrolysis is an example of pseudo first order reaction.
C) Rate constant of a reaction is same in the presence and absence of catalyst.
1) All A, B and C are correct. 2) Only A and B are correct.
3) Onlyly A and C are correct. 4) Only B and C are correct.

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43. The following data were obtained for the thermal decomposition of nitrous oxide
on finely divided gold:
t(minutes) 0 20 40 60 80
Concentration of N2O(mol L-1) 0.10 0.08 0.06 0.04 0.02
The order of reaction is:
1) Zero 2) 1 3) 2 4) 3
44. Radioactive decay is of:
1) Zero order 2) First order 3) Second order 4) Third order
45. The rate of reaction was found to be equal to its rate constant at any
concentration of the reactant. The order of the reaction is:
1) Zero order 2) First order 3) Second order 4) Third order
46. Which of the following statements for the order of a reaction is incorrect?
1) Order of reaction is always whole number
2) Order can be determined experimentally
3) Order is not influenced by stoichiometric coefficient of the reactants
4) Order of reaction is sum of power to the concentration terms of reactants to
express the rate of reaction.
47. The inversion of cane sugar is represented by,
C12 H 22O11  H 2O 
 C6 H12O6  C6 H12O6
It is a reaction of:
1) Second order 2) Unimolecular 3) Pseudo-unimolecular 4) Zero order
48. Assertion (A) : Molecularity of a reaction cannot be more than three.
Reason (R) : Probability of simultaneous collision between more than three
particles is very less.
1) Both A & R are correct and R is correct explanation of A.
2) Both A & R are correct but R is not correct explanation of A.
3) A is correct and R is incorrect. 4) Both A and R are incorrect.

INTEGRATED ZERO ORDER RATE EQUATION :

49. A substance having initial concentration 'a' mole/L reacts according to zero
order reaction. The time taken for 100% completion of reaction is
1) 2a/k 2) a/k 3) a/2k 4) k/a.
50. The rate constant of a given reaction is 0.0231min -1. Then 99.9% of given
reaction completes in ____ minutes if the initial concentration of the reactant is
4M.
1) 173.16 2) 300 3) 86.58 4) 126.52
51. For a zero order reaction, A → products, at 400C the rate of reaction is found to
be 4  10 3 M .min 1 . If the initial concentration of the reactant is 4M, then 100% of
the reaction completes in ______ minutes.
1) 1000 2) 2000 3) 500 4) Insufficient data
INTEGRATED 1st ORDER RATE EQUATION :
52. For a first order reaction, X → Product, the initial concentration of X is 0.1M and
after 40 minutes it becomes 0.025 M. Calculate the rate of reaction at reactant
concentration of 0.01 M
4 1 5 1
1) 3.47  10 M min 2) 3.47  10 M min
6 1 4 1
3) 1.735  10 M min 4) 1.735  10 M min
53. For a first order reaction, the time taken to reduce the initial concentration by a
factor of 1/4 is 20 minutes. The time required to reduce initial concentration by
a factor of 1/16 is
1) 20 min 2) 10 min 3) 80 min 4) 40 min
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54. A reaction is 50% complete in 2 hours and 75% complete in 4 hours. The order of
reaction is
1) 1 2) 2 3) 3 4) 0
55. If the rate constant for a first order reaction is k, the time (t) required for the
completion of 99% of the reaction is given by
1) t = 2.303/k 2) t = 0.693/k 3) t = 6.909/k 4) t = 4.606/k
56. The reaction A  B follows first order kinetics. The time taken for 0.8 mole of A
to produce 0.6 mole of B is 1 hour. What is the time taken for conversion of 0.9
mole of A to produce 0.675 mole of B?
1) 1 hour 2) 0.5 hour 3) 0.25 hour 4) 2 hours
57. Rate constant of a first order reaction is 6.93×10–3 min–1. If we start with
10 mol/L. It is reduced to 1.25 mol/L in
1) 100 minute 2) 200 minute 3) 30 minute 4) 300 minute
58. The concentration of a reactant in a solution falls from 0.2 M to 0.1 M in 2
hours
and to 0.05 M in 4 hours. The order of reaction is
1) Zero 2) Two 3) One 4) Half
59. The gaseous reaction A (g)  2B (g) + C (g) obeys first order kinetics. If the
initial P = 90 mm and pressure after 10 minutes = 180 mm. The velocity
constant, K of the reaction is
1) 1.15 × 10+3 s–1 2) 2.30 × 10+3 s–1
3) 3.45 × 10 s–3 –1 4) 1.15 × 10–3 s–1
60. A first order reaction has a specific reaction rate of 10 2 s 1 . How much time will
it take for 20g of the reactant to reduce to 5g?
1) 238.6 s 2) 138.6 s 3) 346.5 s 4) 693.0 s
61. For a reaction,
A → product;
The graph drawn between the concentration of product (in mol.lit -1) on y-axis
and time (in minutes) on x-axis gives a straight line with +ve slope and zero
intercept. The slope of the straight line is 2  10 2 mol.lit-1.min-1. Then the half life
of the reaction is _____ minutes when the initial concentration of the reactant is
4M.
1) 400 2) 200 3) 100 4) 50
62. For a zero order reaction,
A → products,
Initial concentration of the reactant is 0.6M. In 20 minutes the concentration of
reactant decreases to 0.2M. Then 100% of the reaction completes in
______minutes.
1) 60 2) 30 3) 40 4) 20
63. In a first order reaction, the concentration of the reactant decreases from 0.8M
to 0.4M in 15 minutes. The time taken for the concentration to change from
0.1M to 0.025 M is:
1) 30 min 2) 15 min 3) 7.5 min 4) 60 min
ANHENIOUS EQUATION :
64. Rate constant k of a reaction varies with temperature according to the equation
E0
log k  cons tan t  . When a graph is plotted for log k versus 1/T a
2.303RT
straight line with a slope -5632 is obtained. The energy of activation for this
reaction is
1) 127.67 kJ mol-1 2)107.84 kJ mol-1
3) 86 kJ mol -1 4) 246.8 kJ mol-1
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 16 2000 / T
65. The rate constant k1 and k2 for two different reactions are 10 e and
1015.e 1000 / T , respectively. The temperature at which k1 = k2 is
1000 2000
1) 2000K 2) K 3) 1000K 4) K
2.303 2.303
66. Consider the given plots for a reaction obeying Arrhenius equation (0°C < T <
300°C) : (k and Ea are rate constant and activation energy, respectively)

Choose the correct option:

1) I is wrong but II is right 2) Both I and II are correct
3) Both I and II are wrong 4) I is right but II is wrong
67. For a reaction, consider the plot of In k versus 1/T given in the figure. If the
rate constant of this reaction at 400 K is 10–5 s–1, then the rate constant at
500 K is

1) 4 × 10–4 s–1 2) 10–6 s–1 3) 2 × 10–4 s–1 4) 10–4 s–1

68. What is the activation energy for a reaction if its rate doubles when the
temperature is raised from 20 o C to 35o C ?  R  8.314 J mol 1 K 1 
(Given: log2 = 0.3)
1) 342 kJ mol1 2) 269 kJ mol1 3) 34.7 kJ mol 1 4) 15.1 kJ mol 1
69. For a reaction Ea = 0 and k  3.2  10 4 s 1 at 300 K. The value of k at 310 K would
be :
1) 6.4  10 4 s 1 2) 3.2  10 4 s 1 3) 3.2  108 s 1 4) 3.2  105 s 1
70. For a reaction, the graph drawn between log K vs 1/T gives a straight line with –
ve slope and +ve intercept. The magnitude of the slope is 4000. Then the
activation energy is _______ KJ.
1) 33.256 2) 18.424 3) 9.212 4) 76.59
71. For a reaction, the rate constant is given by
K  (4.5  1011 s 1 )e 2800 / T the maximum value of ‘K’ that can be possible on raising
the temperature is _______.
2800 1
1) 4.5  1011 s 1 2) 2800s 1 3) 2.303  2800s 1 4) s
2.303
72. For N 2  g   3 H 2  g    2 NH 3  g   22kcal , Ea for the reaction is 70kcal. Hence the
activation energy for 2 NH 3  g  
 N 2  g   3 H 2  g  is:
1)92 kcal 2) 70 kcal 3) 48 kcal 4)22 kcal
73. The decomposition of hydrocarbon follows the equation:
 
k  4.5 1011 s 1 e28000 / TK
Its activation energy will be:
1) 232.7 kJ/mol 2) 116.4 kJ/mol 3) 464.2 kJ/mol 4) 669.7 kJ/mol
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74. The rate of a reaction doubles when its temperature changes from 300K to
310K. Activation energy of such a reaction will be
 R  8.314JK 1
mol 1 and log 2  0.3010 
1) 48.6kJ mol 1 2) 58.5kJ mol 1 3) 60.5kJ mol 1 4) 53.6kJ mol 1
COLLISION THEORY, EFFECT OF CATALYST :
1
75. For A  B  C  D, H  20kJmol . The activation energy of the forward
reaction is 85 kJ mol-1. The activation energy for backward reaction is ………..
1) 65 2) 105 3) 85 4) 40
76. Select the correct statement regarding activation energy
1) Activation energy may be greater than heat of reaction
2) Activation energy is less than threshold energy
3) Rate of reaction decreases as activation energy increases
*4) All of these
77. Select the correct diagram for an endothermic reaction that proceeds through
two steps, with the second step is rate determining:

78. Assertion (A): The rate of a reaction increases when a positive catalyst is
introduced into reaction mixture.
Reason(R) : A +ve catalyst provides an alternate path for reacting molecules
where higher activation energy is required.
1) If both (A) and (R) are correct and (R) is the correct explanation of (A).
2) If both (A) and (R) are correct but (R) is not the correct explanation of (A).
3) If (A) is correct but (R) is incorrect
4) If (A) is incorrect but (R) is correct
79. Assertion (A): If the activation energy of reaction is zero, temperature will have
no effect on the rate constnat.
Reason(R) : Lower the activation energy, higher is the rate of reaction.
1) If both (A) and (R) are correct and (R) is the correct explanation of (A).
2) If both (A) and (R) are correct but (R) is not the correct explanation of (A).
3) If (A) is correct but (R) is incorrect 4) If (A) is incorrect but (R) is correct
80. For exothermic reaction, the energy of activation of the reactants is
1) equal to the energy of activation of products
2) less than the energy of activation of products
3) greater than the energy of activation of products
4) sometimes greater and sometimes less than that of the products
81. Among the following statements.
A) Increase in temperature increases the rate of either endothermic or
exothermic reaction.
B) Order of the reaction is always non-zero +ve integer.
C) For a zero order reaction, the half life of reaction will be doubled when the
initial concentration of the reactant is doubled.
1) All A, B and C are correct 2) Only A and B are correct
3) Only B and C are correct 4) Only A and C are correct

9
82. Assertion (A) : A +ve catalyst increases the rate of a reaction.
Reason (R) : A +ve catalyst decreases the activation energy by providing an
alternate path for the reaction.
1) Both A & R are correct and R is correct explanation of A.
2) Both A & R are correct but R is not correct explanation of A.
3) A is correct and R is incorrect.
4) Both A and R are incorrect.
83. According to the collision theory of reaction rates, the rate of reaction increases
with temperature due to:
1) Greater number of collisions 2) Higher velocity of reacting molecules
3) Greater number of molecules having the activation energy.
4) Decrease in the activation energy
84. The activation energy of a reaction can be lowered by:
1) Using a positive catalyst 2) Increasing temperature
3) Decreasing temperature 4) Increasing concentration of the reactants
85. Which of the following is not affected by the catalyst?
1) Heat of reaction 2)  G for the reaction
3) Equilibrium constant 4) All of these

HALF LIFE-ZERO, 1st ORDER :

86. The half – life period of a radioactive element is 140 days. After 560 days one
gram of the element will reduce to
1) 1/2g 2) 1/4g 3) 1/8g 4) 1/16g
87. The half-life for radioactive decay of 14C is 5730 years. An archaeological
artifact containing wood had only 80% of the 14C found in a living tree, the age
of the sample is
1) 184 years 2) 1845 years 3) 18.45 years 4) 3690 years
88. 2g of a radioactive substance is taken. Its half life is 10 days. The amount of
substance that remains undecayed is ______ g after 5 days.
1) 0.5 2) 1.5 3) 1.0 4) 1.414
89. For a first order reaction, A   B , the reaction rate at reactant concentration
of 0.01 M is found to be 2.0  10 5 mol L1s 1 . The half-life period of the reaction is
1) 220 s 2) 30 s 3) 300 s 4) 347 s
90. For a reaction, A → products, the rate constant of the reaction is 2.4  10 2 M .min 1
and initial concentration of the reactant is 1.2M. Then 75% of the reaction
completes in _____ minutes.
1) 25 2) 50 3) 37.5 4) 75
91. For a zero order reaction, when the initial concentration of the reactant is 8M,
half life of the reaction is 40 minutes. If initial concentration of the reactant is
4M, the time take for the 75% completion of the same reaction is minutes.
1) 60 2) 80 3) 100 4) 30
92. For a reaction, A → products, the graph drawn between rate of reaction in
M.min–1
& concentration of reactant, A (in mol.lit–1) gives a straight lines passing through
the origin. The slope of the straight line is 0.0693min –1. Then the half life of the
reaction is ____minutes.
1) 10 2) 23.03 3)6.93 4) 69.3
93. In the first order reaction, the concentration of reaction is reduced to 25% in
one hour. The half-life period of the reaction is:
1) 2 hrs 2) 4 hrs 3)1/2 hr 4) 1/4 hr

10
94. Initial amount of reactant in first order reaction is 16g: Half-life of reaction is
2 min. The amount of reactant will remain after 8 min ____
1) 1g 2) 2g 3) 3g 4) 4g
95. Half –life of a first order reaction is 10 min. What will be the time required for
99.9% completion of the same reaction?
1) 20 min 2) 30 min 3) 100 min 4) 1000 min

RATE LAW, RATE CONSTANT :

96. In the reaction,
CH 3COCH 3 g   C2 H 4 g   H 2 g   CO g 
the initial pressure is found to be 0.40 atm and after 10min, it was 0.50atm. The
rate constant for first order reaction is [log4 = 0.6021, log3.5=0.5441]
1) 0.0133 min-1 2) 0.4 s-1 3) 10s-1 4) 0.6 min-1
97. The unit of rate constant for a zero order reaction is
1) s-1 2) mol L s-1 3) mol L-1 s-1 4) no unit
For the reaction : 2 N 2O5  4 NO2  O2 rate and rate constant are 1.02  10 and
4
98.
3.4  10 5 sec 1 respectively, then concentration of N 2O5 at that time will be
4
3) 1.02  10 M 4) 3.4  10 M
5
1) 1.732M 2) 3M
99. The data for the reaction A  B  C , is
Exp. [A]0 [B]0 Initial rate
1) 0.012 0.035 0.10
2) 0.024 0.070 0.80
3) 0.024 0.035 0.10
4) 0.012 0.070 0.80
The rate law corresponds to the above date is
      B    
3 2 2 3 4
1) rate = k A B 2) rate = k A 3) rate = k B 4) k B
3 1 1
100. The rate constant of the reaction A  B is 0.6  10 mol L s . If the
concentration of A is 5M, then concentration of B after 20 minutes is
1) 3.60M 2) 0.36M 3) 0.72M 4) 1.08M
101. For a reaction
1
N 2O5  2 NO2  O2
2
d ( N2O5 )
Given :   k1  N2O5 
st
d ( NO2 )
 k2  N2O5 
st
d (O2 )
 k3  N 2O5 
st
The relationship between k1, k2 and k3 are
1) 2k1 = k2 = 4k3 2) k1 = k2 = k3 3) 2k1 = 4k2 = k3 4) ½k1 = k2 = ¼k3
102. The rate law for the reaction AB + CD (aq)  AD + CB is given by R = k[AB].
The rate of reaction will be
1) Unaffected by increasing temperature of the reaction
2) Halved on reducing the concentration of CD to one-half
3) Increasing on increasing the concentration of CD
4) Halved on reducing the concentration of AB to one-half

11
103. The chemical reaction, 2O3 
 3O2 proceeds as follows :
O3 
 O2  O (fast)
O  O3   2O2 (slow)
The rate law expression should be :
1) r  k O3  2) r  k O3  O2  3) r  k O3 O2  4) r  O3 O2 
2 2 1 2

104. For a reaction,

A + B → products, the rate law is given by,
rate  K  A  B 
3/ 2 1/ 2

Then the units of rate constant are

1) mol-1.lit. min-1 2) mol.lit-1.min-1 3) mol-2.lit2.min-1 4) min-1
105. For a reaction, A +B→products, the rate of reaction is given by
rate =K[A]2[B]3.
If the concentration of A is tripled and the concentration of B is doubled then
the rate of reaction.
1) Increases by 12 times 2) Increases by 36 times
3) Increases by 72 times 4) Remains same.
106. For a reaction, A → products, the graph drawn between initial concentration (in
mol.lit-1) of the reactant on x  axis and half life (in minutes) on Y-axis gives a
straight line with a slope of 50 units. Then the rate constant of the reaction is __
1) 0.01 min-1 2) 100 min-1 3) 0.02 mol. lit-1. min-1 4) 0.01 mol.lit-1.min-1
107. The rate constant is numerically the same for three reactions of first, second
and third order respectively. Which of the following is correct:
1) If [A] = 1 then r1 = r2 = r3 2) If [A] < 1 then r1> r 2> r3
3) If [A] > 1 then r3> r2> r1 4) All of these
108. 90% of a given reaction is completed in 26 minutes while 99% of same reaction
is completed in 52 minutes. Then the units of rate constant of given reaction ___
1) mol-1.lit.time-1 2) mol.lit-1.time-1 3) time-1 4) mol-2.lit2.time-1
109. For a reaction, A + B → products
The rate of reaction is increased by eight times when the concentrations both
A and B are doubled. The rate of reaction remains same when the concentration
of ‘A’ alone is doubled. Then rate law is given by
1) Rate = K[A] [B]2 2)Rate = K[A] [B]3
3) Rate = K[A] [B] 4) Rate = K[B]3
110. For the first order thermal decomposition of SO 2Cl2 at constant volume,
SO2Cl2  g  
 SO2  g   Cl2  g 
Expt Time/s Total pressure in atm
1 0 0.5
2 100 0.6
The rate constant of the reaction is ________
1) 1.25  10 2 s 1 2) 2.23  10 3 s 1 3) 9.69  10 4 s 1 4) 2.65  10 3 s 1
111. In the first order reaction, the concentration of reactant decreases from 1.0M to
0.25M in 20 minutes. The value of specific rate is
1) 69.32 2) 6.932 3) 0.6932 *4) 0.06932
112. For the first order reaction A → product, the half-life is 200 seconds. The rate
constant of the reaction is:
1) 3.46 102 s 1 2) 3.46 103 s 1 3) 3.46 104 s 1 4) 3.46 105 s 1

12
113. The rate constant of a first order reaction at 27 0C is 10-3 min-1. The temperature
coefficient of this reaction is 2. What is the rate constant (in min -1) at 170C for
this reaction?
1) 10-3 2) 5  10 4 3) 2  103 4) 10 2
114. Consider a first order gas phase decomposition reaction given below:
A g   B  g   C  g 
The initial pressure of the system before decomposition of A was pi . After lapse
of time ‘t’, total pressure of the system increased by x units and became ‘pt’. The
rate constant k for the reaction is given as:
2.303 pi 2.303 pi
1) k  log 2) k  log
t pi  2 x t 2 pi  pt
2.303 pi 2.303 pi
3) k  log 4) k  log
t 2 pi  pt t pi  x
115. Consider the chemical reaction,
N 2  g   3H 2  g    2 NH 3  g 
The rate of reaction can be expressed in terms of time derivative of
concentration of N2(g), H2(g) or NH3(g). Identify the correct relationship amongst
the rate expressions:
d  N2  1 d H2  1 d  NH 3  d  N2  d H2  d  NH 3 
1) rate     2) rate    3  3
dt 3 dt 2 dt dt dt dt
d  N2  1 d  H 2  1 d  NH 3  d  N2  d  H 2  d  NH 3 
3) rate    4) rate   
dt 3 dt 2 dt dt dt dt
116. The rate of the reaction
CCl3  CHO  NO   CHCl3  NO  CO
is given by the equation, rate  k CCl3CHO][ NO  . If the concentration is
expressed in mol L-1, the unit of k are :
1) mol 2 L2 s 1 2) mol L1s 1 3) L mol 1s 1 4) Sec 1
117. A reaction is first order in ‘A’ and second order in ‘B’. How many times the
reaction rate will increase if the concentration of both ‘A’ and ‘B’ are doubled?
1) 4 times *2) 8 times 3) 6 times 4) 12 times
118. The experimental data for the reaction 2 A  B2  2 AB , is
Expt . No [A] [B2] Rate(Ms-1)
1) 0.50M 0.50M 1.6  104
2) 0.50M 1.00M 3.2 104
3) 1.0M 1.00M 3.2 104
The rate law for the above reaction is:
1) rate = k[B2] 2) rate=k[B2]2 3) rate=k[A]2[B2] 4) rate = k[A][B2]2
119. In which of the following cases does the reaction goes farthest to completion.
1
1) K = 102 2) K=10 3) K =1 4) K 
10

*******

13
 ANSWER KEY
No Key No Key No Key No Key No Key
1 2 26 3 51 1 76 4 101 1
2 3 27 3 52 1 77 4 102 4
3 3 28 3 53 4 78 3 103 2
4 4 29 4 54 1 79 2 104 1
5 2 30 4 55 4 80 2 105 3
6 3 31 4 56 1 81 4 106 4
7 1 32 4 57 4 82 1 107 4
8 3 33 3 58 3 83 3 108 3
9 4 34 2 59 4 84 1 109 4
10 2 35 1 60 2 85 4 110 2
11 1 36 2 61 3 86 4 111 4
12 2 37 3 62 2 87 2 112 2
13 2 38 2 63 1 88 4 113 2
14 3 39 2 64 2 89 4 114 2
15 1 40 2 65 2 90 3 115 1
16 1 41 1 66 2 91 4 116 3
17 3 42 2 67 4 92 1 117 2
18 2 43 1 68 3 93 3 118 1
19 1 44 2 69 2 94 1 119 1
20 3 45 1 70 4 95 3
21 3 46 1 71 1 96 1
22 3 47 3 72 1 97 3
23 4 48 1 73 1 98 2
24 4 49 2 74 4 99 3
25 3 50 2 75 2 100 3

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