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Issuing date: January 10, 2022

Safety Data Sheet (SDS)

Prepared in accordance with Regulation (EC) No. 1907/2006 (REACH), Annex Ⅱ, as amended by
Commission Regulation (EU) 2020/878.

1. Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product name: Polyurethane adhesive
1.2. Relevant identified uses of the substance or mixture and uses advised against: It is used for sealing and
bonding. Restrictions on use: Do NOT use it in an application which may contaminate food or do harm to
human health.
1.3. Details of the supplier of the safety data sheet
Company: Zhejiang Guoneng Technology Co., Ltd.
Address: NO.1518 MENGXI ROAD, HUZHOU, ZHEJIANG, CHINA
TEL: 0086-572-2109399
FAX: 0086-572-2352225
Email: [email protected]
1.4. Emergency telephone number
Emergency telephone number: 0086-572-2109399
Intended use: It is used for sealing and bonding.
Further information:Zhejiang Guoneng Technology Co., Ltd.

2. Hazards identification
2.1. Classification of the substance or mixture:
2.1.1. Classification according to Regulation (EC) No 1272/2008 (CLP): No classification for thisproduct.
2.1.2. Additional information: For full text of Hazard- and EU Hazard-statements: see SECTION 16.
2.2. Label elements
Labelling according to Regulation (EC) No 1272/2008 [CLP]:
Hazard Pictograms: Not applicable.
Signal Word: Not applicable.
Hazard Statements:
No relevant classification for this product.
Precautionary Statements:
No special requirements.
Response Precautionary Statements:
No special requirements.
Storage precautionary statements:
No special requirements.
Disposal precautionary statements:
No special requirements.
2.3. Other hazards: Not found.
Information of endocrine disrupting substances:No endocrine disruptors.
This mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of 0. 1% or higher.
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3. Composition/information on ingredients
Product description: substance ( ); preparation/mixture (√)

Classification
according to
% by
Ingredients/Components CAS No. EC No. Index No. Regulation (EC)
weight
No 1278/2008
(CLP).

Physical Hazards:
not classified
Tolylene dissocyanate Health hazards:
39279-01-1 / Not available 20-40% not classified
polyurethane resin
Environmental
hazards:
not classified

Eyhylene glycol 107-21-1 203-473-3 Not available 25-30% H302 Acute Tox. 4

Physical Hazards:
not classified
Health hazards:
Diisodecyl adipate 27178-16-1 248-299-9 Not available 10-20% not classified
Environmental
hazards:
not classified

Physical Hazards:
not classified
Health hazards:
Calcium carbonate 471-34-1 207-439-9 Not available 15-20% not classified
Environmental
hazards:
not classified

Note: The mixture does not contain endocrine disruptors.

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4. First aid measures

4.1. Description of first aid measures:

General notes: No information available.

Following inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a

POISON CENTER or doctor/physician if you feel unwell.

Following skin contact: Rinse skin with water [or shower]. If skin irritation occurs: Get medical advice/attention.

Following eye contact: Remove contact lenses if present and easy to do, continue rinsing. If eye irritation

persists: Get medical advice/attention.

Following ingestion: Rinse mouth. Do not induce vomiting without professional instruction. Call a POISON

CENTER or doctor/physician if you feel unwell.

Self-protection of the first aider: No special requirement.

4.2. Most important symptoms/effects, acute and delayed: Acute effect: Not found. Delayed effect: Not found.

4.3. Indication of any immediate medical attention and special treatment needed: Treat according to

symptoms.

5. Fire-fighting measures

5.1. Extinguishing Media

Suitable extinguishing media: Use water spray, dry chemicals, carbon dioxide, foam, dry sand for extinction.

Unsuitable Extinguishing Media: High volume water jet. Discharging cylinder shape water from fire hose

may lead to spread fire to the surroundings.

5.2. Special hazards arising from the substance or mixture: The product is not flammable, and has no special

danger.

Hazardous combustion products: It may release smoke, carbon monoxide, carbon dioxide and other

hazardous gas from thermal decomposition.

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5.3. Advice for fire-fighters:

For initial fire, use dry powder, carbon dioxide, etc.
For large fire, it is effective to use fire foam, etc. to shut off air supply.
Fire-fighters must wear self-contained breathing apparatus and full protective equipment (e.g. fire-retardant
clothing).
Deny unnecessary entry to the place around the fire.
Remove containers from fire area if it can be done without risk.
Cool surrounding facilities, etc. with water spray.
Extinguish fire from upwind, and the fire extinguishing method should be appropriate to the situation in the
surroundings.

6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures: Use proper personal protective
equipment as indicated in Section 8.
6.2. Environmental Precautions: Keep cleaning run-offs out of municipal sewers and open bodies of water.
Comply with local and national laws and regulations.
6.3. Methods and materials for containment and cleaning up:
Small Spill:
Mop up or absorb with an inert dry material (e.g. sand, dry lime) and place in an appropriately labeled waste
disposal container.
Large Spill:
Isolate contaminated area and set up a warning board. The persons handling emergency are recommended
wearing protective clothing. Do NOT touch spilled material. Keep away from heat and sources of ignition.
Build up dike or dig pit for collection. Spray fog water to cool down and dilute vapor. Dilute the spilled liquid till it
is not combustible. Protect the working staff. Collect the spilled material with explosion-proof pump into an
appropriate container and transport the waste to the disposal place.
6.4. Reference to other sections:
For more information, please refer to Section 8 and Section 13.

7. Handling and storage

7.1. Precautions for safe handing:
Wash hands thoroughly after handling.
7.2. Conditions for safe storage, including any in compatibilities
Technical measures and storage conditions: Store it in a well-ventilated, cool and dry store room. Long-time
direct sunlight and high temperature. Keep out of the reach of children.
Incompatible materials: No information available.
Packaging materials: Aluminum tube or plastic tube.
Requirements for storage rooms and vessels: Well-ventilated and dry.
Storage class
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Further information on storage conditions: The storeroom should be equipped with proper facilities for
accidental fire.
7.3. Specific end use(s): It is used for sealing and bonding.

8. Exposure controls/personal protection

8.1. Control parameters:Commission Directive 98/24/EC and related indicative lists: Not set up
Exposure Controls:
Ingredients COSHH Workplace OSHA PEL-TWA ACGIH TLV-TWA
exposure limits-
TWA
No ingredients have an exposure
Not available Not available Not available
limit
8.2. Exposure controls:
8.2.1. Appropriate engineering controls
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. Install washer eyes and safety showers near to the handling and storage area.
8.2.2. Personal protection equipment:
Hand protection:
Recommend wearing protective gloves (e.g. rubber gloves).

Eye protection:
Wear safety glasses when liquid may splash.

Respiratory Protection:
Use an approved respirator if exposure limits are exceeded or if irritation or other symptoms occur.

Body Protection:
Recommend wearing general working clothing.
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General protective and hygienic measures:

Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Avoid contact with eyes and broken skin.
8.2.3 Environmental exposure controls:
Maintain levels below Community environmental protection thresholds.

9. Physical and chemical properties

9.1. Information on basic physical and chemical properties
General Information
Physical state Paste
Colour Black, grey, etc
Particle characteristics Even and delicate paste
Odour Aromatic Odor
Odour threshold No data available
pH No data available
Melting point/freezing point No data available
Initial boiling point and boiling range No data available
Flash point ＞120°C (＞248°F)

Evaporation rate No data available

Flammability (solid, gas) Non-flammable
Flammable/Explosive Limits-Lower Vol % No data available
Flammable/Explosive Limits-Upper Vol % No data available
Vapour pressure No data available
Vapour density ＞AIR

Density 1.40±0.20 g/cm

3

Solubility (water) No data available

Partition coefficient: n-octanol/water No data available
Auto-ignition temperature No data available
Decomposition temperature No data available

Kinematic viscosity（mm2/s） No data available

Explosive properties No data available

Oxidizing properties No data available
VOC Content 48.0 g / L
9.2. Other information: Not available.
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10. Stability and reactivity

10.1. Reactivity: This product is stable under normal ambient and anticipated storage and handling conditions of

temperature and pressure.

10.2. Chemical stability: No information available.

10.3. Possibility of hazardous reactions: The product is not flammable, and has no special danger.

10.4. Conditions to avoid: Long-time direct sunlight and high temperature.

10.5. Incompatible materials: No information available.

10.6. Hazardous decomposition products: It may release smoke, carbon monoxide, carbon dioxide and other

hazardous gas from thermal decomposition.

11. Toxicological information

11.1. Information on toxicological effects:

Skin corrosion/irritation: No classification for this product.

Serious eye damage/eye irritation: No classification for this product.

Respiratory sensitizer: No classification for this product.

Skin sensitizer: No classification for this product.

Germ cell mutagenicity: No classification for this product.

Carcinogenicity: No classification for this product.

Reproductive Toxicity: No classification for this product.

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Specific target organ toxicity, single

exposure: No classification for this product.

Specific target organ toxicity, repeated

exposure: No classification for this product.
Aspiration hazard: No classification for this product.

Effects on or via lactation: No classification for this product.

11.2. Endocrine disruptor information: The mixture does not contain endocrine disruptors.

12. Ecological information

12.1. Toxicity: No data available for the whole product.
12.2. Persistence and Degradability: No data available for the whole product.
12.3. Bioaccumulative Potential: No information available.
12.4. Mobility in Soil: As it is liquid, it can move in soil.
12.5. Results of PBT and vPvB Assessment: This mixture contains no components considered to be either
persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of
0. 1% or higher.
12.6. Endocrine disruptor information: The mixture does not contain endocrine disruptors.
12.7. Additional information: No information available.

13. Disposal considerations

13.1. Waste treatment methods
13.1.1. Product / Packaging disposal:
It is recommended to use incineration method to dispose of waste.
After contents are completely removed, dispose of its container at hazardous or special waste collection point.
Waste codes / waste designations according to LoW
EWC code: 20 01 28
In other countries different conditions might be valid. All national and local laws have to be considered.
13.1.2. Waste treatment-relevant information:
Paste a label on the container indicating the possible hazards of the waste.
13.1.3. Sewage disposal-relevant information:
Do not discharge waste into sewage without any treatment.
13.1.4. Other disposal recommendations: Any disposal practice must be in compliance with country, local, state,
and federal laws and regulations.

14. Transport Information

ADR and RID / Air-Transportation- IATA DGR/ICAO/Sea-Transportation-IMO/IMDG.:
14.1. UN number or ID number: Not applicable.
14.1. UN proper shipping name: Not regulated.
14.2. Transport hazard class (es): Not applicable.
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14.4. Packing group: Not applicable.

14.5. Assigned Pictogram: Not applicable.
14.6. Environmental hazards (Marine Pollutant (Yes/No)): No.
14.7.EMS NO.: Not applicable
14.8. Special precautions for user: Check whether the package is completed or sealed before transporting;
make sure no damage of packages and prevent goods from falling down during transporting; the transport vehicle
should be equipped with facilities for fire-fighting and accidental release handling; do NOT transport this product
together with incompatible substances; stay away from fire and areas of high temperature during stopovers.
14.9. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable.

15. Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture:
The product is classified and labelled according to Regulation (EC)No 1272/2008 and related
amending regulations. The safty data sheet, is complied According to Regulation (EU) 2015/830.
Candidate List of Substances of very high concern (SVHC) according to ECHA: Not listed.
REACH Regulation Annex XVII Regulation List: Not listed.
REACH Regulation Annex XIV Authorization List: Not listed.

Germany – WGK: Not classified.

15.2. Chemical Safety Assessment: A Chemical Safety Assessment has not been carried out.

Other relevant regulations:

Sara:

Section 355 (extremely hazardous substances): Not listed.

SARA 313: Not listed.

Toxic Substances Control Act (TSCA):

Ingredient (s) CAS No. TSCA Inventory

Tolylene dissocyanate polyurethane resin 39279-01-1 Listed
Eyhylene glycol 107-21-1 Listed
Diisodecyl adipate 27178-16-1 Listed
Calcium carbonate 471-34-1 Listed
Clean Water Act:
Chemical Name CWA - Reportable CWA - Toxic CWA - Priority CWA –
Quantities Pollutants Pollutants Hazardous
Substances
Not applicable Not applicable Not listed Not listed Not listed
Carcinogenicity categories: Not listed by ACGIH, IARC and NTP.
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16. Other information

DISCLAIMER:
All the information of this SDS is true and effective, and only for reference. Our company will not control
the way how people use it, neither will we be responsible for any consequence. The users shall decide
how to properly use the product or adopt certain production way for some special purpose. The above-
mentioned precautionary measures are helpful to avoid damage to the property or life safety during the
operation or use of this product.The users of this SDS must make independent judgments on the
correctness and completeness and then decide its suitability according to the actual situation. The users
should take the relevant legal responsibilities for the consequences of use.

References:
EC No.1907/2006 (REACH)
EC No. 1272/2008 (CLP)
Commission Regulation (EU) 2015/830

For full text of Hazard- and EU Hazard-statements:

Not applicable. Not applicable.
Classification and procedure used to derive the classification for mixtures according to Regulation (EC)
1272/2008 [CLP]:
Classification according to Regulation (EC) Nr.
Classification procedure
1272/2008
Not applicable. Not applicable.

Full description of some acronyms:

CAS-Chemical Abstracts Service
EINECS-European Inventory of Existing Commercial Chemical Substances
ADR:European Agreement concerning the International Carriage of Dangerous Goods by Road
RID：Regulations concerning the International Carriage of Dangerous Goods by Rail
IMO-International Maritime Organization
IMDG-International Maritime Dangerous Goods
IATA DGR-International Air Transport Association Dangerous Goods Regulations
ICAO-International Civil Aviation Organization
MARPOL-International Convention for the Prevention of Pollution from Ships
IBC Code-International Code for the Construction and Equipment, of Ships Carrying Dangerous Chemicals
in Bulk
TSCA-Toxic Substances Control Act
OSHA-Occupational Safety and Health Administration
ACGIH-American Conference of Governmental Industrial Hygienists

The Issuing date:January 10, 2022

SDS Version: 1

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