Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456

Skull Crusher-18
for JEE (Advanced) - (Class XII)
Chemistry

Chapter Name : Surface Chemistry

Topic Name

je e
: Adsorption isotherm, Classification and Application of Colloids, preparation of Colloids.

I. One Option Correct Type

e t_
1. Which one of the given statements is correct about emulsion?

n e
(1) Emulsions do not show Brownian motion or tyndall effect
s _
ie
(2) Emulsions show Brownian motion but do not show tyndall effect

r
s e
(3) Emulsions do not show Brownian motion but show tyndall effect

t
es
(4) Emulsions show both Brownian motion as well as tyndall effect

2.
T
Identify the incorrect match among the following.

@
(1) Micelles - Associated Colloid

-
T g
(2) Protein Sol - Macromolecular Colloid

(3) Sulphur Sol - Multimolecular Colloid

(4) Soaps - Multimolecular Colloid

II. One or More Options Correct Type

3. Which of the given statement(s) is/are correct?

(1) Entropy of micellization is negative as a large number of molecules associate to form larger molecules

(2) Entropy of micellization is positive due to the increased freedom of hydrophobic chain in the non-polar

interior of the micelle as compared to aqueous environment

(3) Enthalpy of micellization is often positive

(4) The micellization process is governed primarily by the entropy gain associated with it

Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456 [1]
Chemistry Skull Crusher-18 for JEE (Advanced) - (Class XII)

III. Matching the column Type

4. Column–I contains sols and Column–II contains properties associated with the sol. Match entries in
Column–I with entries in Column–II.

Column–I Column–II

(A) Al2O3.xH2O (P) In electrophoresis, Colloidal particles move towards cathode

(B) CdS Sol (Q In electrophoresis, Colloidal particles move towards anode

)

(C) TiO2 (R In electro – osmosis, dispersion medium moves towards

) cathode

(D) Gold Sol (S) In electro – osmosis dispersion medium moves towards anode

(T) Precipitating power of AlCl3 > NaCl

IV. Integer Type

je e
5.

Calculate the value of

y
.
e _
Consider the following facts/events and if y is the number of property or application or example of colloids.

t
(i) Colour of sky
2

n e
(ii) Rainfall
s _
(iii) Formation of delta
r ie
(iv) Cottrell precipitator

t s e
es
(v) Purification of drinking water by addition of alum
(vi) Formation of photographic film
(vii) Rubber formation T
(viii) Brownian motion
(ix) Tyndall effect - @
(x) Blood
T g
x x
6. The plot of log   vs log[P(atm)] was found to have an intercept on the log   axis equal to (-2) and a
m m
slope of 0.5. Find the amount of solute in g adsorbed on 100 g of adsorbent when the pressure equals 4
atm.

❑ ❑ ❑

Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456 [2]
Skull Crusher-18 for JEE (Advanced) - (Class XII) Chemistry

Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456

Skull Crusher-18
for JEE (Advanced) - (Class XII)
Chemistry

[ANSWERS KEY]
1.
2.
Answer (4)
Answer (4)
je e
3. Answer (2, 3, 4)

e t_
4.
5.
Answer A(P, S); B(Q, R, T); C(P, S); D(Q, R, T)
Answer (05)
n e
6. Answer (2)
s _
r ie
t s e
T es
- @
T g

Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456 [3]
Chemistry Skull Crusher-18 for JEE (Advanced) - (Class XII)

Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456

Skull Crusher-18
for JEE (Advanced) - (Class XII)
Chemistry

[ANSWERS & SOLUTIONS]

1. Answer (4)
Emulsions show both these phenomena.
je e
2. Answer (4)

e t_
3.
Soaps form an associated colloid.
Answer (2, 3, 4)
n e
s _
S is positive for micellisation. H is generally positive and this is compensated by the large negative value
of (–TS)
r ie
4.
s
Answer A(P, S); B(Q, R, T); C(P, S); D(Q, R, T)

t e
es
Al2O3. xH2O, TiO2 → Positively charged sol

T
CdS and Gold Sol → Negatively charged sol
5. Answer (05)

- @
All properties/events are related to colloidal system

y
2
=5
T g
6. Answer (2)

x 1
log = logK + logP
m n

1 1 1
logK = –2  K = and =
100 n 2

x 2
   = K (P ) =
1/2
= 0.02
m 100

 x = 0.02 × 100 = 2 g

❑ ❑ ❑

Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456 [4]