0% found this document useful (0 votes)
50 views19 pages

BATCH-1 24-05-2023 SR - Super60 NUCLEUS&ALL BT-1 Jee-Adv (2022-P2) GTA-27 Q.Paper

Uploaded by

PHYSICS LS
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
0% found this document useful (0 votes)
50 views19 pages

BATCH-1 24-05-2023 SR - Super60 NUCLEUS&ALL BT-1 Jee-Adv (2022-P2) GTA-27 Q.Paper

Uploaded by

PHYSICS LS
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 19

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI


A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec:Sr.Super60_NUCLEUS&ALL_BT-1 JEE-ADVANCE-2022-P2 Date: 24-05-2023
Time: 02.00Pm to 05.00Pm GTA-27 Max. Marks: 180
24-05-2023_Sr.Super60_NUCLEUS&ALL_BT-1_Jee-Adv(2022-P2)_GTA-27_Syllabus

PHYSICS : TOTAL SYLLABUS


CHEMISTRY : TOTAL SYLLABUS
MATHEMATICS : TOTAL SYLLABUS

Name of the Student: ___________________ H.T. NO:


Sri Chaitanya IIT Academy 24-05-2023_Sr.Super60_NUCLEUS&ALL_BT-1_Jee-Adv(2022-P2)_GTA-27_Q.P
JEE-ADVANCE-2022-P2-Model
Time:3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 8) Questions with Integer Answer Type +3 -1 8 24
Questions with Multiple Correct Choice
Sec – II(Q.N : 9 – 14) +4 -2 6 24
with partial mark
Sec – III(Q.N : 15 – 18) Questions with Single Correct Choice +3 -1 4 12
Total 18 60

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 19 – 26) Questions with Integer Answer Type +3 0 8 24
Questions with Multiple Correct Choice
Sec – II(Q.N : 27 – 32) +4 -2 6 24
with partial mark
Sec – III(Q.N : 33 – 36) Questions with Single Correct Choice +3 -1 4 12
Total 18 60

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 37 – 44 Questions with Integer Answer Type +3 0 8 24
Questions with Multiple Correct Choice
Sec – II(Q.N : 45 – 50) +4 -2 6 24
with partial mark
Sec – III(Q.N : 51 – 54) Questions with Single Correct Choice +3 -1 4 12
Total 18 60

Sec: Sr.Super60_NUCLEUS&ALL_BT’S Space for rough work Page 2


Sri Chaitanya IIT Academy 24-05-2023_Sr.Super60_NUCLEUS&ALL_BT-1_Jee-Adv(2022-P2)_GTA-27_Q.P
MATHEMATICS Max Marks: 60
SECTION-I
(INTEGER ANSWER TYPE)
• This section contains EIGHT (08) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual Numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct integer is entered;
Zero Marks: 0 If the question is unanswered;
Negative Marks: -1 In all other cases
1. Let A  {1,2,3,.,100}, B  {3k  1∣k  N }, C  {2k ∣k  N } , then the

n  A   B  C    . Then 
4
2. 5 soccer teams participate in a tournament. Each team plays all the other teams exactly
once. If a team wins a game, 3 points are awarded. If a team loses a game, no points are
awarded. If the game is tie, both teams get 1 point. At the end of all the games, 4 of the 5
teams get 1, 2, 5 and 8 points in total. The total score of the fifth team is k. Then k  4 

3. Point A lies on circle ( x  20) 2  y 2  4 and points B lies on circle x 2  y 2  36 . The mid
point of AB is M such that all possible positions of M form a region. If area of the
region is 2 (  N), then   ____

4. Two circles are given as S1  x 2  y 2  14 x  6 y  40  0 and

S 2  x 2  y 2  2 x  6 y  7  0 with their centres as C1 and C2 respectively. If equation


of another circle S3 whose centre C3 lies on the line 3x  4 y  16  0 and touches the
circle S1 externally and also C1C2  C2C3  C3C1 is minimum is

x 2  y 2  ax  by  c  0, then the value of (a  b  c) is ____


5. Suppose that we have 3 cards that are identical in form, except that both sides of the first
card are colored red, both sides of the second card are colored black, and one side of the
third card is colored red and the other side black. The 3 cards are mixed up in a hat, and 1
card is randomly selected and put down on the ground. If the upper side of the chosen card
is colored red, the probability that the other side, colored black is m , then the value of 6m
is _____

Sec: Sr.Super60_NUCLEUS&ALL_BT’S Space for rough work Page 3


Sri Chaitanya IIT Academy 24-05-2023_Sr.Super60_NUCLEUS&ALL_BT-1_Jee-Adv(2022-P2)_GTA-27_Q.P
6. Let E and M be 3  3 matrices satisfying the system of equations
T
EM   EM   20 I and  E  M T  17  E  M T , where I denotes identity matrix of

order 3. If E 2  M 2 
a
I (where a and b are co-prime), then
a  b 
b 743

7. lim

ln 1  tan 1 x  sinx  x   ______
x 0 x2
4
x cos x   sin
0
1 2
 t  dt
1 3
8. Let  is root of h( x)  0 where h( x )  xf x 6  x 2 g x 6 and       2

2
i (where


i 2  1 . If h( x) is a real monic polynomial of degree 7 and f ( x), g ( x) are also
polynomials of degree 1 and 0 respectively, then f (2) is equal to _____
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
•This section contains SIX (06) questions.
•Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
•For each question, choose the option(s) corresponding to (all) the correct answer(s).
•Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If only (all) the correct option(s) is(are) chosen; Partial Marks +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: -2 In all other cases.
40 160 200 320
9. For the equation     6 x 2  27 x, then which of the following
x 1 x  4 x  5 x  8
option(s) is/are true?
A) Number of real solutions of above equation is 3
B) If E denotes the product of non-zero or complex roots of equation, then sum of divisors
of E is 2904
C) It S denotes the set of all real roots of equation then, sum of elements of S taken two
at a time is 81
D) If 1, 2  R be two roots of equation such that log 2  21  is defined, then it
must be 1
10. If a function f : R  R such that f ( x )  x 2 x  tan 1 x  sin x , then which of the

following option(s) is /are correct?


Sec: Sr.Super60_NUCLEUS&ALL_BT’S Space for rough work Page 4
Sri Chaitanya IIT Academy 24-05-2023_Sr.Super60_NUCLEUS&ALL_BT-1_Jee-Adv(2022-P2)_GTA-27_Q.P
A) f ( x) is a bijective function
B) f ( x )  f 1( x) has only one real solution

 
C) f ( x )  f x 2  2 x has exactly 3 real solutions

   
D) f tan 1 x  f tan 1 x 2 has exactly 2 real solutions
11. A straight line passes through the fixed point A(3,2) and meets the coordinate axes at P
and Q. If the mid-point of PQ is X, As the gradient of the line varies, the point X moves
on the curve C, then which of the following option(s) is/are true?
A) Equation of the curve C is 2 xy  2 x  3 y
B) Equation of the curve C is 3xy  3x  2 y  5
C) if the tangent drawn to the curve C at A, meets the coordinate axes at H and K, then
HA : AK ::1:1
D) if the tangent drawn to the curve C at A, meets the coordinate axes at H and K, then
HA : AK ::1: 2
12. If A, B are two 4  4 matrices with real entries such that | A  B | 0 and they satisfy the
equations A 2  2 B  I 4  O 4 , B2  2 A  I 4  O 4 , ( I 4 denotes unit matrix of order 4), then
which of the following option(s) is/are true?
A) A  I B) | A  B | 16 C) | A  I 4 |2  256 D) A  B  2I 4
   
      | a || b |   | a || b |  
13. Let a  r  (r  b )b  a and a  b . If f ( )  [ r a b ], where  in angle
2 2
   
between vectors a and b , also given that a and b are unit vectors,
then which of the following option(s) is/are true?
3
A) Local maximum value of f ( ) is
2
3
B) Maximum value of f ( ) is
2
1
C) Minimum value of f ( ) is
2
1
D) Local minimum value of f ( ) is
2

Sec: Sr.Super60_NUCLEUS&ALL_BT’S Space for rough work Page 5


Sri Chaitanya IIT Academy 24-05-2023_Sr.Super60_NUCLEUS&ALL_BT-1_Jee-Adv(2022-P2)_GTA-27_Q.P
14. The first of the two samples has 100 items with mean 15 and standard deviation 3. If the
whole group has 250 items with mean 15.6 and standard deviation 13.44, then which of
the following option(s) is/are true?
A) the mean of the second group is 16
B) the standard deviation of the second group is 4
C) the mean of the second group is 4
D) the standard deviation of the second group is 2
SECTION – III
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
14
 1 1
15. The number of distinct terms in the expansion of  x   y   is ____
 x y
A) 225 B) 210 C) 196 D) 224

16. If   4 tan 1( 3  1) and   8cot 1 2 , then choose the INCORRECT statement
47 48
A) cos   0 B) 1  tan   3 C) 0  tan   3 D) tan 1  tan 1
48 49

 2| x|   | x| 
17. The area enclosed by curve f ( x )  sin 1    sin 1
  and g ( x)  tan 1 x
 1  x2  
 1 x
2 

between the two lines x  1 to x  1 is _____sq. units
A)  B)   ln 4 C)   ln 2 D)   ln 2

dy
18. Let y  e x  e x  e x   , then which of the following is not equal to ?
dx

ex y2  y ex e x
A) B) C) D)
2 y 1 (2 y  1) 1  4e x
1  4e x
Sec: Sr.Super60_NUCLEUS&ALL_BT’S Space for rough work Page 6
Sri Chaitanya IIT Academy 24-05-2023_Sr.Super60_NUCLEUS&ALL_BT-1_Jee-Adv(2022-P2)_GTA-27_Q.P
PHYSICS Max Marks: 60
SECTION-I
(INTEGER ANSWER TYPE)
• This section contains EIGHT (08) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual Numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct integer is entered;
Zero Marks: 0 If the question is unanswered;
Negative Marks: -1 In all other cases
19. A car of mass 1000kg can deliver constant mechanical power of 7460 W. If at a certain
instant the car is moving with just half the maximum velocity it can attain against a

resistance of 2000 N, find its acceleration at that instant. in ms 2  


20. Sound from two coherent sources S1 and S2 are produced in phase, and detected at point
P, equidistant from both the sources. Speed of sound in normal air is 340 m/sec, but in
some part in path S1 there is a zone of Hot air having temperature 4 times the normal
temperature, and width (d = 85m). What should be minimum frequency of sound, so that
minimum intensity can be found at P? (in Hz)

S1 d
4T0

S2

21. Two identical springs are attached to a small block P. The outer ends of the springs are
fixed at A and B such that AB is vertical. When P is in equilibrium the extension of top
spring is 20 cm and extension of bottom spring is 10 cm. If the period of small vertical

oscillations of P about its equilibrium position is sec , then fill the value of N.
N 2
(Take ,g=10m/s2)

Sec: Sr.Super60_NUCLEUS&ALL_BT’S Space for rough work Page 7


Sri Chaitanya IIT Academy 24-05-2023_Sr.Super60_NUCLEUS&ALL_BT-1_Jee-Adv(2022-P2)_GTA-27_Q.P
A

22. An electron is accelerated by a potential difference of 9.375 V. Find the de-Broglie



wavelength associated with it in A .  h  6.6 1034 Js;m  9.11031 kg;e  1.6 1019 c  (Give

your answer in nearest integer)


23. A concave mirror is placed at the bottom of an empty tank with face upwards and axis
vertical. When sunlight falls normally on the mirror, it is focused at distance of 32 cm
 4
from the mirror. If the tank is filled with water     upto a height of 20 cm, then find
 3
the height above water surface (in cm) at which the sunlight will now get focused at
24. The magnetic flux through a metal ring varies with time t according

 
to B  3 at 3  bt 2 Tm2 , with a  2 s 3 and b  6 s 2 . The resistance of the ring is 3 .

Determine the maximum current induced in the ring during the interval from t=0 to t=2s.
25. A freshly prepared sample of a radioisotope of half-life 1386s has activity

103 disintegrations per second. Given that log e 2  0.693 , find the fraction of the initial
number of nuclei (expressed in nearest, integer percentage) that will decay in the first 80s
after preparation of the sample.

Sec: Sr.Super60_NUCLEUS&ALL_BT’S Space for rough work Page 8


Sri Chaitanya IIT Academy 24-05-2023_Sr.Super60_NUCLEUS&ALL_BT-1_Jee-Adv(2022-P2)_GTA-27_Q.P
26. In the photoelectric experiment, if we use a monochromatic light, the I-V curve is as
shown. If work function of the metal is 2 eV, estimate the power of light used (in W).
Assume efficiency of photo emission to be 103% , i.e, number of photoelectrons emitted
are 103% of number of photons incident on metal.
I

10A

V
Vs  5volt

SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
•This section contains SIX (06) questions.
•Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
•For each question, choose the option(s) corresponding to (all) the correct answer(s).
•Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If only (all) the correct option(s) is(are) chosen; Partial Marks +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: -2 In all other cases.

27. For the AC circuit shown, the reading of ammeter and voltmeter are 5A and volts 50 5
volts respectively, then
V
20mH

10 50F

A 
A) Average power delivered by the source is 250W
B) rms voltage of AC source is 50 volts
C) rms voltage of AC source is 100 volts
D) frequency of AC source is 1000 / 2 Hz
Sec: Sr.Super60_NUCLEUS&ALL_BT’S Space for rough work Page 9
Sri Chaitanya IIT Academy 24-05-2023_Sr.Super60_NUCLEUS&ALL_BT-1_Jee-Adv(2022-P2)_GTA-27_Q.P
28. Three satellites are revolving around the earth: one along the circular orbit and the other
two along elliptical orbits whose major axes are equal to the diameter of the circular orbit.
The masses of the satellites are same. Choose the CORRECT options:

Earth Earth
Earth

Satellite  1 Satellite  2 Satellite  3

A) Energy is same for all the satellites.


B) Angular momentum of satellite-1 is maximum.
C) Angular momentum of satellite-2 is more than satellite-3.
D) Energy of satellite-1 is more than satellite-3.
29. Consider the situation shown in diagram:
VC
VB
A VA

CAR OBSERVER Reflecting wall


Observer hears sound from car directly and also after reflection from the wall. Choose the
CORRECT statement(s):
A) If VB  VC  0 , then beat frequency heard by observer is zero irrespective of V A .
B) If V A  0 , beat frequency heard by observer is zero irrespective of VB & VC .
C) If VB  0 , observer will surely hear beat for any value of V A & VC .
D) For V A  VB  VC , beat frequency heard by observer may be zero.
30. Diagram shows a wedge kept on a rough surface. A ball of mass ‘m’ is dropped on the
slant face of the wedge. If the collision is perfectly elastic, choose the CORRECT
statement(s):
m

M  2m

 

Sec: Sr.Super60_NUCLEUS&ALL_BT’S Space for rough work Page 10


Sri Chaitanya IIT Academy 24-05-2023_Sr.Super60_NUCLEUS&ALL_BT-1_Jee-Adv(2022-P2)_GTA-27_Q.P
A) The ball of mass ‘m’ may jump to the same maximum height from the point of impact
for some values of  except 0 .
B) Friction acting between wedge and ground is impulsive in nature.
C) Momentum of the system (M+m) can be conserved in horizontal direction.
D) We can choose some axis such that momentum of system (M+m) is conserved along
that axis.
31. A horizontal beam supported at each end sags under its own weight. Then the beam will
experience
Support

Centre line
A) Tensile stress B) Compressive stress
C) Shear stress D) Bulk stress
32. A string of mass m is fixed at both its ends. The fundamental mode of string is excited and
it has an angular frequency  and the maximum displacement amplitude A. Then:
1
A) The maximum kinetic energy of the string is Ek  mA2 2
4
1
B) The maximum kinetic energy of the string is Ek  mA2 2
2
C) The mean kinetic energy of the string averaged over one periodic time is
1
 Ek  mA2 2
4
D) The mean kinetic energy of the string averaged over one periodic time is
1
 Ek  mA2 2
8
SECTION – III
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases

Sec: Sr.Super60_NUCLEUS&ALL_BT’S Space for rough work Page 11


Sri Chaitanya IIT Academy 24-05-2023_Sr.Super60_NUCLEUS&ALL_BT-1_Jee-Adv(2022-P2)_GTA-27_Q.P
33. The first diffraction minimum due to the single slit diffraction is seen at   30 for a light
of wavelength 5000A falling perpendicularly on the slit. The width of the slit is

A) 2.5  105 cm B) 1.25 105 cm C) 10  105 cm D) 5 105 cm


34. A conducting sphere A of radius rA carries a charge Q. Another conducting sphere B of
radius rB is uncharged initially. Both the spheres are separated by a very large distance.
Sphere A is connected with sphere B through a long conducting wire of zero resistance
through a switch S as shown in the figure. At t=0 switch S is closed.
rA
rB

Q
S

B
A
As soon as the current flow through the wire vanishes, switch S is opened, sphere A is
again charged to a total charge Q and then switch S is again closed and the process is
continued for infinite times. If q is the charge transferred to sphere B when the switch S is
closed for the first time, then total charge on the sphere B after large number of such
processes is
qQ r
A) Q B) C) Q B D) None of these
Qq rA
35. A rigid spherical body is spinning around an axis without any external torque. Due to
increase in temperature its volume increases by 3%. Then percentage change in its angular
speed is
A) -2% B) -1% C) -3% D) 1%
36. The signal received by the dish on the top of the house installed by “TATA SKY”
company for viewing television channels through DTH set top box is a
A) space wave B) sky wave C) ground wave D) combination of a and b

Sec: Sr.Super60_NUCLEUS&ALL_BT’S Space for rough work Page 12


Sri Chaitanya IIT Academy 24-05-2023_Sr.Super60_NUCLEUS&ALL_BT-1_Jee-Adv(2022-P2)_GTA-27_Q.P
CHEMISTRY Max Marks: 60
SECTION-I
(INTEGER ANSWER TYPE)
• This section contains EIGHT (08) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual Numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct integer is entered;
Zero Marks: 0 If the question is unanswered;
Negative Marks: -1 In all other cases
37. The number of CH 2  (Methylene) groups in the final product formed from the
following reactions sequence is ___________
1 Br2 /   Mono 
 2  alc.KOH / 
 Major product 
 3 (i) O3
(ii) Zn / H 2O
 4  Conc.H2SO4 / 

38. Identify the most acidic hydrogen in ascorbic acid (vitamin C)

39. Mole fraction of N 2 gas in air is 0.8. Henry law constant for N 2 in water is 2.22  104 atm.
The moles of N 2 gas present in 1L of solution which is in equilibrium with air at 10 atm

is a  102 . find a ?

40. The vapour pressure of pure perfluoro cyclohexane  C6 F12  are given by

1895
Solid C6 F12 : log10 P  mm of Hg   8.68 
T
1530
Liquid C6 F12 : log10 P  mm of Hg   7.60 
T
The molar enthalpy of fusion of solid C6 F12 is approximately x kJ the value of x is

Sec: Sr.Super60_NUCLEUS&ALL_BT’S Space for rough work Page 13


Sri Chaitanya IIT Academy 24-05-2023_Sr.Super60_NUCLEUS&ALL_BT-1_Jee-Adv(2022-P2)_GTA-27_Q.P
41. Two flasks A and B have equal volume. A is maintained at 300K and B at 600K. While A
contains H 2 gas, B has an equal mass of CH 4 . Assuming ideal gas behavior find out the
CH 4
ratio of mean free path i.e.
H 2

? Given :  CH  2 H
4 2 
42. During the discharge of a lead storage battery, the density of H2SO4 fell from 1.225 gm/ml
to 0.98 gm/ml. H 2 SO4 of density 1.225 gm/ml is 40% by weight and that of density 0.98
gm/ml is 20% by weight. The number of ampere hours for which the battery is used
containing 1 L of the acid is 16.08 x. Calculate the value of x.
(volume remains constant during the process)
43. The number of pairs of elements having same number of unpaired electrons in 3d-
series___
44. Find the number of types of metals present in a mixture of ores containing Bauxite,
Haematite , Magnetite, Siderite, Spalerite, Calamine, Cuprite
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
•This section contains SIX (06) questions.
•Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
•For each question, choose the option(s) corresponding to (all) the correct answer(s).
•Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If only (all) the correct option(s) is(are) chosen; Partial Marks +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: -2 In all other cases.
45. The correct statement(s) concerning the structures P, Q, R and S is/are

P) Q) R) S)
A) Q and S are geometrical isomers B) R and S are resonating structures
C) P and R are tautomers D) P and Q are resonating structures

Sec: Sr.Super60_NUCLEUS&ALL_BT’S Space for rough work Page 14


Sri Chaitanya IIT Academy 24-05-2023_Sr.Super60_NUCLEUS&ALL_BT-1_Jee-Adv(2022-P2)_GTA-27_Q.P
46. In which of the following ethers C-O bond can be cleaved by conc. HI at high
temperature?

O O
A) B)

O O O CH3
C) D)
47. The correct statements regarding various types of molecular speeds is/are
A) Increasing temperature increases the fraction of molecules possessing Umps.
B) Increasing temperature increases Umps
C) In a sample of gas, at a given temperature molecules with extremely low and
extremely high speeds are both very less likely
D) At the same temperature , lighter gases have narrow distribution of molecular speeds
than the heavier gases
48. Two liquids A and B form a non-ideal solution which obey the equation

PTotal  PA0  3( PB 0  PA0 ) X B  2( PA0  PB 0 ) X B 2 . when equimolar mixture of A and B


is distilled ,what is the composition (by mole fraction) when this mixture will have a
single boiling point. (X-molefraction)
A) X A  1 / 4 B) X B  3 / 4 C) X A  1 / 2 D) X B  1 / 2
49. In which case EAN value is satisfied

 
A)  Fe  5C5 H 5 
2 
 B)  Ni  dmg 2 

 
C) Co  CO  4  D)  Mn  CO 5 
50. Which of the following reactions will give 'O2 ' on reaction with water
A) F2  H 2O  B) XeF2  H 2O 
C) XeF4  H 2O  D) XeF6  H 2O 
Sec: Sr.Super60_NUCLEUS&ALL_BT’S Space for rough work Page 15
Sri Chaitanya IIT Academy 24-05-2023_Sr.Super60_NUCLEUS&ALL_BT-1_Jee-Adv(2022-P2)_GTA-27_Q.P
SECTION – III
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
51.

i) O3 dil OH
Polymer  P  Q
ii) Zn/H2O  O

Incorrect for above reaction sequence is


A) (P) exist in both cis and trans forms
B) (P) is a 1, 4-addition polymer of 2-methylbuta-1, 3-diene
C) (Q) can show both tollen’s and Iodoform test
D) Q gives positive Iodoform test but no reaction with NaHSO3
52. The major product of the following reaction is
H

O
O MnO2
CH3 OH Major product
Acetone

OH
H
H
O
O
O
O CH3 C H
CH3 C H
O
O
C H
A) O B) OH
H H

O O
O O
CH3 CH3
OH COOH

C H C H

C) O D) O

Sec: Sr.Super60_NUCLEUS&ALL_BT’S Space for rough work Page 16


Sri Chaitanya IIT Academy 24-05-2023_Sr.Super60_NUCLEUS&ALL_BT-1_Jee-Adv(2022-P2)_GTA-27_Q.P
53. In antarctica ozone depletion is due to formation of the following compounds
A) Acrolein B) PAN C) SO2 , SO3 D) Chlorine nitrate
54. Correct statement among the following
A) KHF2 , KHCl2 both are existing
B) ICl on hydrolysis produce HI and HOCl
C) ‘F’ acts as central atom in the inter halogens

D) UF6 is used for enriching of 235U but not UCl6

Sec: Sr.Super60_NUCLEUS&ALL_BT’S Space for rough work Page 17


Sri Chaitanya IIT Academy 24-05-2023_Sr.Super60_NUCLEUS&ALL_BT-1_Jee-Adv(2022-P2)_GTA-27_Q.P

Sec: Sr.Super60_NUCLEUS&ALL_BT’S Space for rough work Page 18


Sri Chaitanya IIT Academy 24-05-2023_Sr.Super60_NUCLEUS&ALL_BT-1_Jee-Adv(2022-P2)_GTA-27_Q.P

Sec: Sr.Super60_NUCLEUS&ALL_BT’S Space for rough work Page 19

You might also like