Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Sr.Super60_Elite, Target & LIIT-BTs Paper -1(Adv-2022-P1-Model) Date: 24-03-2024
Time: 09.00Am to 12.00Pm GTA-19/18 Max. Marks: 180
24-03-2024_Sr.Super60_Elite, Target &LIIT-BTs_Jee-Adv(2022-P1)_GTA-19/18_Syllabus

MATHEMATICS : TOTAL SYLLABUS

PHYSICS : TOTAL SYLLABUS

CHEMISTRY : TOTAL SYLLABUS

Name of the Student: ___________________ H.T. NO:

 Sri Chaitanya IIT Academy 24-03-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2022-P1)_GTA-19/18_Q.P

JEE-ADVANCE-2022-P1-Model
Time:3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Numerical Value
Sec – I(Q.N : 1 – 8) +3 0 8 24
Answer Type
Questions with Multiple Correct
Sec – II(Q.N : 9 – 14) +4 -2 6 24
Choice with partial mark
Sec – III(Q.N : 15 – 18) Matching Type +3 -1 4 12
Total 18 60

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Numerical Value
Sec – I(Q.N : 19 – 26) +3 0 8 24
Answer Type
Questions with Multiple Correct Choice
Sec – II(Q.N : 27 – 32) +4 -2 6 24
with partial mark
Sec – III(Q.N : 33 – 36) Matching Type +3 -1 4 12
Total 18 60

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Numerical Value
Sec – I(Q.N : 37 – 44 +3 0 8 24
Answer Type
Questions with Multiple Correct Choice
Sec – II(Q.N : 45 – 50) +4 -2 6 24
with partial mark
Sec – III(Q.N : 51 – 54) Matching Type +3 -1 4 12
Total 18 60

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MATHEMATICS Max Marks: 60
SECTION – I
(NUMERICAL VALUE TYPE)
This section contains EIGHT (08) questions.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer. If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will bee evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the correct numerical value is entered ;
Partial Mark: 0 In all other cases.
4
1. The value of k , which the minimises the value of the integral  x  4  x   k dx is
0
2. A quadrilateral ABCD in inscribed in a parabola having equation y 2  16 x such that
three of its sides AB, BC, CD passes through the fixed points  2,0  ,  3,0  &  6, 0 
respectively. The fourth side DA passes through a fixed point  h, 0  , then h  ____
3. If p , q , r  p  0, q  0, r  0  are the non-zero roots of the equation
p  2q  3r  6
x3  3 px 2  3q 2 x  r 3  0 then the value of  ………
3 p  2q  r  2
4. Consider the two quadratic equations is x,
2 x 2  4 x cos   5cos 2   3 , x 2  2 x cos   2 cos 2   1
If these two equations have atleast one common root for some    0, 2   , then the
number of possible value of ,
5. A circle with radius 6 units, is externally tangent to a circle with radius 24 units. Area of
the triangular region formed by the three common tangent lines, drawn to these two
circles is ____
9 a  1 39
6. If  20 C2r 20C2r  2 
r 0 a
 C22  19C11 then a 
7. Suppose that, log10 ( x  2)  log10 y  0 and x  y  2  x  y . Then the value of
(x  y) , is  where    = ………… ([.] denotes G I F)
3 3

8. If A   log tan  60   r  B   log tan  60   r  , where  r  ,
r 1
 2 3  r 1
 2 3  3r
9
r=1,2,3 then the value of A+B at   is …….
4

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SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.

The probability Pk that a family has k children is given by Pk  1  2a  2   , k  2 .

 k 1
9.
It is known that a family has two boys. Then which of the following is/are true?
27 1
A) Probability that the family has only two children is when a 
64 2
27 1
B) Probability that the family has only two children is when a 
64 3
81 1
C) Probability that the family has two girls as well is when a 
512 2
81 1
D) Probability that the family has two girls as well is when a 
512 3
10. Let f be a function defined on the set of positive rational numbers with the property
that f  ab   f  a   f  b   positive rational numbers a & b.Further more, suppose that f
also has the property that f  p   p for every prime number p. which of the following
numbers x, for which f  x   0
17 11 25 7
A) B) C) D)
32 16 11 9
11. From  2, 0  , a line in drawn to intersect the circle x 2  y 2  1 at two points A and B An
ellipse with foci A, B, passing through  2, 0  is drawn whose eccentricity can be
1 1 3 2
A) B) C) D)
3 2 5 5
              
12. If | a  b  c || a  b  c || a  b  c || b  c  a | and if | a |  | b || c | 0 , then which of the
following option is/are correct?
  
| 4a  4b  3c |
A) Maximum value of  is 5
|c |

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  
| 4a  4b  3c |
B) Minimum value of  is 15
|c |
  
| 4a  4b  3c |
C) Minimum value of  is 17
|c |
  
| 4a  4b  3c |
D) Maximum value of  is 3 5
|c |

13. Let an  2an 1  an  2  n  4C4 ; n  2, a0  0, a1  5 .

Then which of the following is / are true
A) a4  206 B) a4  205 C) a6  917 D) a6  918
14. Let ABC be a triangle and a, b and c are length of the sides, opposite to vertices A, B and
 
C respectively. If  and  are two non collinear unit vectors satisfying
    
(a  b)  (b  c)   (c  a)(   )  0. Then which of the following is/are True for
ABC ?
A) ABC is an acute angled triangle
B) ABC is an obtuse angled triangle
C) ABC is a right angled triangle
D) R  2 r (where R and r are circum radius and in-radius of ABC
SECTION – III
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosed (i.e. the question is unanswered);
Negative Marks: –1 In all other cases.

15. 
Let I  m    ln 1  2mcos x  m 2 dx 
0

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COLUMN - I COLUMN – II
1 Im P 1

I  m 
2 I  9 Q 2

I  3
3 I  81 R 3

I  3
4 I  25  S 4

I 5 
A) 1-P ; 2-Q; 3-S; 4- Q B) 1-Q ; 2-P; 3-S ; 4- Q
C) 1-P ; 2-P; 3-S ; 4- Q D) 1-P ; 2- S; 3-R ; 4- P
16. Consider the circles z  1  3 and z  z0  4 , z  C 0

COLUMN - I COLUMN – II
1 If two circles cut orthogonally, then the maximum value of P 4
z0 , is
2 If two circles touch internally, then the maximum value of Q 8
z0 , is
3 If two circles touch externally, then the minimum value of R 6
z0 , is
4 If two circles cut orthogonally, then the minimum value of S 2
z0 , is
A) 1-R ; 2-R; 3-S; 4- P B) 1-S; 2-Q; 3-R;4-P
C) 1-S ; 2- S; 3- P ;4- Q D) 1-R ; 2-S ; 3-R; 4-P
a b  1 0
17. Let M     : a , b , c , d   ( set of all real numbers ) and I  0 1 
 c d   
If A  M , tr( A)  x, det( A)  y then

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COLUMN - I COLUMN – II
1 Value of det( A  I )  ____, when x = 2, P 1
y=3
2 Value of det( A  I )  ____, when x = 2, Q 2
y=3
3 Value of det( A  I )  ____, when x = 3, R 6
y=2
4 Value of det( A  I )  ____, when x = 3, S 0
y=2
A) 1-R ; 2- Q;3-S ;4-R B)1-Q; 2-S; 3-Q;4-R
C)1-Q ; 2- S ; 3-R ;4-Q D) 1-R; 2- S; 3-Q;4-Q
n 2k 2  4k  1
18. Let sn  
2

k 1 k 2  k

COLUMN - I COLUMN – II
1 If s10   , then, [ ]  P 1
Where [.] denotes G I F
2 If s9   , then, [  ]  Q 2
Where [.] denotes G I F
3 If s  m, then, [ m]  R 4
Where [.] denotes G I F
4 If s8   , then, [ ]  S 3
Where [.] denotes G I F
A) 1-Q;2-S;3-P; 4-R B)1-Q;2-Q;3-S; 4-Q
C)1-S; 2-Q;3-R; 4-Q D) 1-Q; 2- Q;3-Q; 4-S

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PHYSICS Max Marks: 60
SECTION – I
(NUMERICAL VALUE TYPE)
This section contains EIGHT (08) questions.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer. If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will bee evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the correct numerical value is entered ;
Partial Mark: 0 In all other cases.
19. Switch S was kept closed for a long time in the circuit shown. At t=0, switch was open.
Find the current through the inductor L1 , immediately after the switch is open
(in A)
L1 R1
L1  L

L2 L2  2 L
R2
  10V
R1  2
R2  5
 S

20. A beam of light has three wavelengths 4000A ,5000A and 6000A with a total intensity
W
of 3  103 equally distributed amongst the three wavelengths. The beam fall
m2
normally on an area 2cm2 of clean metallic surface of work function 2.4 eV. If quantum
yield of photoemission is 1%, then the saturation photocurrent is x  109 A . Find x
(Take hc=12400 eV. A )
21. A uniform rod AB is suspended by two light strings, as shown in figure. The tension in
the left string just after the right string is cut is 100  N. Find ‘  ’. Take Mass of rod as
70 3kg and g  9.8m / s 2 .

60 30

A 30

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22. A conducting rod of length   2 5m and mass m=4kg, lies on a rough horizontal table
 1
    . If the current in the conductor is I  2A , then find the minimum magnitude of
 2
uniform magnetic field B (in T) such that conducting rod just start to translate along X-

axis (Neglect the radius of the rod) (Take g  9.8m / s 2 )

23. An ideal mono-atomic gas is confined in a cylinder with the help of a piston that can slide
inside the cylinder without friction. The cylinder is placed on a horizontal platform in a
vacuum chamber. The walls of the cylinder and the piston are made of heat insulating
materials. Initially the temperature of the gas is T0 and the piston stays in equilibrium as
shown in the figure. The temperature of the gas is quickly increased  times and then the
gas is allowed to expand. If the piston rises and again acquires an equilibrium state, find
temperature of the gas in this new equilibrium state. (in kelvin) (Take,   2, T0  273K )

24. Resistances R1 and R 2 are 5 and 5 3 respectively. Reactance of inductor is


5 3 and of capacitor is 5 . Source voltage oscillates as V  10 2 sin t Volts . 
Average power delivered by source is (in watt) take  3  1.732 

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R1 L

R2
C



25. A block is placed on a long and wide inclined plane that makes angle   45 with the
horizontal. The coefficient of kinetic friction between the block and the plane is  k  2 .
After a quick push, the block acquires velocity v 0  6 2m / s that makes angle
  600 with the line of fastest descent. Find the time interval t (in s) during which the
block is in motion. (Take g  9.8m / s 2 )
26. A simple harmonic plane progressive wave is travelling along +ve X-axis having
amplitude A and    rad / s . At t=1s, particle at x=2m and x=3m are moving in
downward and upward direction respectively at position y   A / 2 . The smallest

time  in s  ,when maximum power transfer will take place at x=11/4 m is.
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
27. Two large parallel metal plates are located in vacuum. One of these serve as cathode, a
source of electrons with negligible initial speed. An electron flow directed toward the
opposite plate produces a space charge causing the potential in the gap between the plate
vary as V  ax 4/3 , where a is a +ve constant, and x is distance from cathode. Then
A) Magnitude of electric field is proportional to x1/3
2/3
B) Volume charge density is proportional to x
1/3
C) Current density is proportional to x
D) Current density is independent of x
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28. There is long straight conducting wire in which a steady electric current I is flowing.
There are two observers A and B observing electric field E and magnetic field B at a
point P near the conducting wire. Observer A is stationary whereas observer B is moving
with drift speed of electron in the wire in the direction of electric current in it. Which
options are CORRECT.

Vd
P

A B

A) Electric field observed by A and B are same

B) Electric field observed by A is zero, whereas by B is non-zero
C) Magnetic field observed by A and B are same
D) Magnetic field observed by B is zero, whereas by A is non-zero.
29. A flat closed tube of rectangular cross-section has inner radius ‘a’ and outer radius ‘b’. It
is filled completely with water and is kept flat on a horizontal surface. Now, entire water
in the tube is rotated with a uniform and steady angular velocity '  ' about the vertical
axis of the tube. Viscous forces between the tube and water is neglected and density of
water is  . 1 and 2 are two points in water in the same horizontal plane as shown in
figure. Let P be the pressure and E be energy of fluid particle per unit volume. Then
1 

2 a b

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1 1

A) P1  P2   b2  a 2 2
2
 
B) P2  P1   b2  a 2 2
2

C) E1  E 2 D) E1  E 2    b 2  a 2  2

30. A 30 kg shell in free space explodes into three identical fragments. After the explosion,
the fragments rush apart. Forces of mutual interaction between the fragments are long
range attractive conservative forces. Immediately after the explosion, velocities of the

 
fragments relative to an inertial frame are 3iˆ  2ˆj m / s, 2im  
ˆ / s and 5iˆ  5jˆ m / s . If

entire energy released in the explosion is converted into kinetic energy of fragments then:
A) Energy released in explosion is 335 J
B) Energy released in explosion is 260 J
C) After sufficiently long time, when the forces of mutual interaction ceases to act, total
kinetic energy of fragments become minimum.
D) After sufficiently long time, total kinetic energy of all fragments is 75 J
31. Two small dipoles p1 and p2 , oriented perpendicular to each other are lying in a plane as

shown in figure. p1 is oriented along the line of separation and p2 is oriented

perpendicular to line of separation. Then which of the following option(s) is/are

INCORRECT at this position:

p1 p2
A) Force of interaction between them is attractive is nature
B) Force of interaction between them is repulsive in nature.
C) Magnitude of net force between them is zero.

D) Magnitude of force is inversely proportional to r 4 (r is separation between the two

small dipoles)
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32. A current I flows in a long single layer solenoid with cross-sectional radius R. The
number of turns per unit length of the solenoid equals n. The current at which the
winding may rupture if the tensile strength of the wire is equal to F  N  .
1 F F F F
A) B) C) 2 D) 4
2 0 nR 0nR 0nR 0nR
SECTION – III
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosed (i.e. the question is unanswered);
Negative Marks: –1 In all other cases.

 3  2t 
33. A time varying magnetic field B    T exist in a cylindrical region directed into
 2 
the plane. A conducting ring of radius r=1m, having resistance R1   for upper half
ring and R 2  2 for lower half ring is placed with it’s centre coinciding with axis of
cylindrical region as shown.
 R1 

 r 
A B
   
 R2

B
List I contains physical quantity in conducting ring and List-II contains their values in SI
unit.
List I List II
I) Potential difference between A and B P) 1
2
II) Magnitude of induced electric field E* (due to time varying Q) 1
magnetic field) 6
III) Electric current in the loop R) 
6
IV) Electrostatic field E 2 in lower half of the ring S) 1
3

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A) I  P,II  Q, III  S, IV  Q B) I  R, II  P, III  Q,IV  S
C) I  R, II  S,III  Q,IV  P D) I  R, II  P, III  S, IV  Q
34. Three particles A, B and C are situated at the vertices of an equilateral triangle ABC of
side  at an instant. Each of the particle moves with a constant speed  . A always has
it’s velocity along AB, B along BC and C along CA. physical quantities for each particle
in this situation at this instant is enlisted in list I. Corresponding values (in SI units) is
enlisted in list-II. (Take   2m ;   3m / s )
List I List II
I) Angular velocity of velocity vector (i.e. rate P) 1.3
of rotation of velocity vector)
II) Linear acceleration Q) 0.97
III) Angular acceleration of velocity vector R) 2.3
IV) Radius of curvature of path S) 0.75
A) I  S,II  R,III  Q,IV  P B) I  S,II  Q,III  R,IV  P
C) I  S,II  P,III  Q, IV  R D) I  S,II  P,III  R, IV  Q
2 2
35. In x-y plane, there exist 2 circles C1 :  x  1   y  2   4 and
2 2
C2 :  x  5   y  2   4 . In the region, there exist two variable forces given by:


k 1  y  ˆi   x  2  ˆj
 
F1  k 1  y  ˆi   x  2  ˆj and F2 
1  y 2   x  2 2
Let Wij represent the work done by Fi in a complete rotation in anticlockwise direction
for cyclic path along circle C j . Match Wij in Column-I to its value in Column-II.
Column-I Column-II
P) W11 1) 2k
Q) W12 2) 4k
R) W21 3) 8k
S) W22 4) 16k
5) 0
A) P  2,Q  2;R  1,S  5 B) P  3,Q  3;R  1,S  5
C) P  3,Q  3;R  5,S  5 D) P  3,Q  3;R  1,S  1

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36. A satellite is taken to a height ‘h’ above earth’s surface and imparted a transverse
velocity  . Depending upon imparted velocity  , different types of satellite motion are
possible. In List-I, velocities are enlisted, in List-II possible trajectories are enlisted.
GM 2GM
(Take, V0  ; Ve  ; where M and R are mass and radius of earth
Rh Rh
respectively)
List I List II
I) v  v0 P) Elliptical trajectory, point of projection being
APOGEE of ellipse
II) v0  v  ve Q) Elliptical trajectory, point of projection being
PERIGEE of ellipse
III) v  ve R) Parabolic trajectory, satellite escaping from
earth’s gravitational field
IV) v  ve S) Hyperbolic trajectory, satellite escaping from
earth’s gravitational field
A) I  P,II  Q, III  R,IV  S B) I  Q, II  P, III  R,IV  S
C) I  P,II  Q, III  S, IV  R D) I  Q, II  P, III  S, IV  R

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CHEMISTRY Max Marks: 60
SECTION – I
(NUMERICAL VALUE TYPE)
This section contains EIGHT (08) questions.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer. If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will bee evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the correct numerical value is entered ;
Partial Mark: 0 In all other cases.
37. 1.34g of an organic compound (having some methoxy groups) with the molecular weight
134 gives 7.05 g of AgI precipitate in the Zeisel’s method of estimation of methoxy
groups. The weight percentage of methoxy group(s) in the organic compound is (G.A.W.
of Ag is 108g, I is 127g)
38. Monochlorination of C2 H 5 D leads to a mixture containing 93% of C2 H 4 DCl and 7% of
C2 H 5Cl . Based on this data, C-H is ‘X’ times more reactive than C-D. (Assume that
reactivity of all C-H bonds in C2 H 4 DCl are equally reactive). X value is_____
39.

0.70 L 0.30 L
0.2 M 0.2 M
NH3 solution MgCl2 solution

Mix

What minimum mass (in g) of  NH 4 2 SO4 should be added to the above mixture cause
the Mg  OH 2 formed to re-dissolve?

 KSP for Mg OH 2  6.0 1012 and Kb for NH3  2 105 

t 10 min
40. In an elementary chemical reaction A  aq  
1/ 2  2 B  aq   C  aq 
Reaction mixture react with another reactant T and n-factor of A, B and C when react
with T is in the ratio 2: 1: 2 respectively. The reaction started by taking ‘A’ only. If
volume of ‘T’ used at 10 min is 40 ml. Volume of T used at t = 0 is x ml, at t = 20 min, is
yz
y ml and at t   is z ml . Find out the value of ......?
x
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41. The equilibrium of the reaction N 2  g   3H 2  g   2 NH 3  g  is set up at 300 K by

mixing N 2  g  and H 2  g  .The standard free energy of formation of NH 3  g  is -15.53

kJ/mol. If after one hour of mixing the partial pressure of N 2 , H 2 and NH 3 , are 50, 2 and
200 bar respectively and the enthalpy change of reaction is -4.2 kJ, what is the entropy

 
change of the reaction. in JK 1 Given : n100  4.6, RT  2500 J 

42. Consider the following experiments:

Experiment 1:
Sodium hexanitrocobaltate(III) solution
 Yellow ppt  A   side products
NH 4Cl salt solution 

Experiment 2:
Hexachloroplatinic(IV) acid
 Yellow ppt  B   side products
NH 4Cl salt solution 

Then the total number of unpaired electrons present in A and B is___

43. Weight(in grams) of gas obtained when 12.25 grams of potassium chlorate is
decomposed completely in the presence of MnO 2 catalyst is ____
(Given that: GAW of K =39, Cl = 35.5, O=16)
44. A given amount(moles) of Fe2 is oxidised by 6 moles of permanganate ion in acidic
medium. The number of moles of dichromate ion required to oxidise the same
amount(moles) of Fe2 in acidic medium is ___
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
45. For which of the following equilibrium, equilibrium constant KC  1

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O HO OH


 H 2O 
A)
O OH
HO


 H 2O 
B)
O OH
HO
Ph Ph
Ph Ph

 H 2O 
O O
C) O O

 CF3CH  OH 
D) CF3CHO  H 2O  2

46. Among the following correct reactivity order in acid catalysed hydrolysis is/are

A)
>
O O
CF3 O O

>
B) O
O

O
C) CH 3 C O
O > CH 3 C
NO2
O

CH 3 OCH 3 H 3C OCH 3
D) C > C
CH 3 OCH 3 H 3C H

47. In a constant pressure calorimeter with heat capacity of 450JK 1 , 200 ml of 0.9 M HCl

and 200 ml of 0.45 M Ba  OH 2 are mixed. The density of final solution is 1gm ml-1 .

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Initially, both solutions are at 21 C . Select correct


statement Given : H Neutralization  56.2 kJ mol 1 
 

Specific heat of H 2O  4.184 J gm 1 .

A) H  of reaction is 10.116  103 J

B) Some HCl is left unreacted

C) Final temperature is 25.76 C

D) Some Ba  OH 2 is left unreacted

48. 1.22 g of C6 H 5COOH is added in two different solvents:

i) In 100 g CH3COCH 3; Tb  0.17, Kb  1.7 Kg  K / mol
ii) In 100 g C6 H 6 ; Tb  0.13, Kb  2.6 Kg  K / mol
which of the following is/are correct?
A) Apparent molecular weight of C6 H 5COOH in both the solvents is equal.
B) Apparent molecular weight of C6 H 5COOH in both the solvents is not equal
C) C6 H 5COOH dimerizes in benzene
D) C6 H 5COOH remains in monomeric form in acetone.
49. Which of the following statement(s) is/are correct?
A) Availability of 4f electrons results in the formation of compounds in +4 state for all
the lanthanoid members of the 4f series

B) In Cr2O 72  , all ‘chromium – oxygen’ bond lengths are not identical

C) Among SO 2 , H 2S, NH3 and H 2O; H 2S has the smallest bond angle
3 3 3
D) Co  CN 6   Co  NH 3 6   Co  H 2O 6  : correct order of absorption of

wave length of light in the visible region

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50. Reaction I: Al2O3  6HCl  9H 2O  Product  X 
Reaction II: Al2O3  6NaOH  3H 2O  Product  Y 
Consider the above given two reactions and identify the incorrect statement(s) regarding
‘X’ and ‘Y’?
A) Central atoms are in the different hybridized state
B) In X, aluminium is present in the anionic part whereas in Y, aluminium is present in
the cationic part
C) In both X and Y, coordination number of Al3 is same
D) Ratio of number of moles of X and Y formed is 2 : 3
SECTION – III
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosed (i.e. the question is unanswered);
Negative Marks: –1 In all other cases.
51.
List-I(Preparation of polymer) List-II (Mechanism involved)

I) Novolac from phenol and HCHO / H  P) Step growth polymerization

II) PHBV from its monomers Q) Aromatic electrophilic substitution
III) LDPE from ethene at 1000-2000atm, R) Free radical addition
350-570k, in the presence of traces O2
IV) Melamine – formaldehyde resin from S) Nucleophilic acylsubstitution
its monomers
T) Nucleophilic addition
The correct match is
A) I – Q; II – S; III – PR; IV – T B) I – PQ; II – PT; III – R; IV – PT
C) I – PQ; II – PS; III – R; IV – PT D) I – PT; II – PS; III – R; IV – PQ
52. In the List-I some reactions given, in the List-II some tests given. Major products in the
final steps of reactions in the List-I to be matched with the tests given by it. In the
reaction if two products formed in the final step, select the tests given by each product at
independently.

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List-I List-II
OH P) Effervescence with NaHCO3

1) Conc.H 2 SO4
2) Conc.HNO3
I)
1) ph3 p Q) Decolourisation of bromine water
CH 3  CH 2Cl
2) n  BuLi
O
3) CH 3  C  CH 3
II)
1) C2 H5ONa R) Positive Brady’s test
CH 3COOC2 H 5 
2) H 3O
3) 
III)

i ) H , H 2O2 S) Soluble in aqueousNaOH
ph  C  CH 2  

ii ) H 3O

IV) ph

T) Yellow precipitate on heating with

NaOI
The correct match is
A) I – PS; II – T; III – ST; IV – QR T B) I – S; II – Q; III – RT; IV – PQRST
C) I – PS; II – QT; III – RT; IV – QR D) I – PS; II – Q; III – RT; IV – QRST
53.
List I List II
(Oxoacids of phosphorous) (Characteristic bonds)
I) Phosphinic acid P) Contains P – O – P linkage
II) Phosphonic acid Q) Contains P = O linkage
III) Hypophosphoric acid R) Contains P – OH linkage
IV) Pyrophosphoric acid S) Contains P – H linkage
T) Contains P – P linkage

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Correct match is:
A) I  Q, R,S;II  QRT;III  P,Q,R;IV  QRT
B) I  Q, R,S;II  QRS;III  Q,R,T;IV  P,Q, R
C) I  Q, R,T;II  QRS;III  Q,R,T;IV  P,Q,S
D) I  Q, R,T;II  PQR;III  Q, R,T;IV  P,Q,S
54. Match the following
List-I List-II
I) 2 Ag   Cu  2 Ag  Cu 2 P) Ecell  0.5605 V

E0  0.34
Cu 2 / Cu

E0  0.80
Ag  / Ag

 Ag    102 M , Cu 2   104

   
II) Ni | Ni 2 1M  Cu 2  0.1M  | Cu Q) Ecell  0.0295 V

E0 2  0.25 V , E 0  0.34 V
Ni / Ni Cu 2 / Cu

III) Pt H 2  P1 atm  H  1M  || H  1M  | H 2 ( P2 atm) Pt R) 0

Ecell  Ecell
P1  P2

IV) Zn  Hg  C1M  | Zn2  aq  | Hg  Zn  C2 M  S) Ecell  0.59V

C1  1 gm / 100 gm of Hg, C2  10 gm / 100 gm of Hg

T) 0
Ecell 0
A) I  S ; II  T ; III  P; IV  Q B) I  R; II  P; III  T ; IV  Q
C) I  S ; II  Q; III  R; IV  T D) I  R; II  P; III  Q; IV  T

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