Subject: Chemistry Class-12
Topic: Solutions DPP: 1
1. A solution of two liquids boils at a temperature more than the boiling point of either
them. Hence, the binary solution shows
a) Negative deviation from Raoult’s law
b)Positive deviation from Raoult’s law
c) No deviation from Raoult’s law
d)Positive or negative deviation from Raoult’s law depending upon the composition
2. Vapour pressure of pure ‘A’ is 70 mm of Hg at 25∘ 𝐶 . It from an ideal solution with ‘B’ in
which mole fraction of A is 0.8. If the vapour pressure of the solution is 84 mm of Hg at
25∘ 𝐶, the vapour pressure of pure ‘B’ at 25∘ 𝐶 is
a) 28 mm b)56 mm c) 70 mm d)140 mm
3. Abnormal colligative properties are observed only when the dissolved non-volatile
solute in a given dilute solution
a) Is a non-electrolyte b) Offers an intense colour
c) Associates of dissociates d) Offers no colour
4. As a result of osmosis, the volume of the concentrated solution :
a) Gradually decreases
b)Gradually increases
c) Suddenly increases
d)None of these
5. At a suitable pressure near the freezing point of ice, there exists :
a) Only ice
b)Ice and water
c) Ice and vapour
d)Ice, water and vapours, all existing side by side
6. Which of the following concentration units is independent of temperature?
a) Normality b)Molarity c) Molality d)ppm
7. In cold countries, ethylene glycol is added to water in the radiators of cars during
winters. It results in :
a) Lowering in boiling point
b)Reducing viscosity
c) Reducing specific heat
d)Lowering in freezing point
8. Calculate the molal depression constant of a solvent which has freezing point 16.6℃
and latent heat of fusion 180.75 𝐽𝑔−1 .
a) 2.68 b)3.86 c) 4.68 d)2.86
9. The freezing point depression constant for water is 1.86 K kg𝑚𝑜𝑙 −1. If 45 g of ethylene
glycol is mixed with 600 g of water , the freezing point of the solution is
a) 2.2 K b)270.95 K c) 273 K d)275.35 K
10. The movement of solvent molecules through a semipermeable membrane is called
a) Electrolysis b)Electrophoresis c) Osmosis d)Cataphoresis
11. An aqueous solution of methanol in water has vapour pressure
a) Less than that of water b) More than that of water
c) Equal to that of water d) Equal to that of methanol
12. Which pair shows a contraction in volume on mixing along with evolution of heat?
a) 𝐶𝐻𝐶𝑙3 + 𝐶6 𝐻6 b) 𝐻2 𝑂 + 𝐻𝐶𝑙 c) 𝐻2 𝑂 + 𝐻𝑁𝑂3 d)All of these
Sumit Sarovar, Behind Three Dots Jr. School, Ramghat Road, Aligarh
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13. The vapour pressure of water at 20∘ 𝐶 𝑖𝑠 17.5 𝑚𝑚𝐻𝑔.
𝐼𝑓 18 𝑔 𝑜𝑓 𝑔𝑙𝑢𝑐𝑜𝑠𝑒 (𝐶6 𝐻12 𝑂6 ) is added to 178.2 g of water at 20∘ 𝐶, the vapour
pressure of the resulting solution will be
a) 17.675 mmHg b)15.750 mmHg c) 16.500 mmHg d)17.325 mmHg
′
14. At 80 ͦ𝐶 , the vapour pressure of pure liquid ′𝐴 is 520 mm Hg and that of pure liquid ′𝐵′
is 1000 mm Hg. If a mixture of solution ′𝐴′ 𝑎𝑛𝑑 ′𝐵′ boils at 80°𝐶 and 1 atm pressure, the
amount of ′𝐴′ in the mixture is : (1 atm = 760 mm Hg)
a) 50 mol per cent b)52 mol per cent c) 34 mol per cent d)48 mol per cent
15. Van’t Hoff factor(𝑖):
a) Is less than one in case of dissociation
b)Is more than one in case of association
𝑛𝑜𝑟𝑚𝑎𝑙 𝑚𝑜𝑙𝑒𝑐𝑢𝑙𝑎𝑟 𝑚𝑎𝑠𝑠
c) 𝑖=
𝑜𝑏𝑠𝑒𝑟𝑣𝑒𝑑 𝑚𝑜𝑙𝑒𝑐𝑢𝑙𝑎𝑟 𝑚𝑎𝑠𝑠
𝑜𝑏𝑠𝑒𝑟𝑣𝑒𝑑 𝑚𝑜𝑙𝑒𝑐𝑢𝑙𝑎𝑟 𝑚𝑎𝑠𝑠
d) 𝑖=
𝑛𝑜𝑟𝑚𝑎𝑙 𝑚𝑜𝑙𝑒𝑐𝑢𝑙𝑎𝑟 𝑚𝑎𝑠𝑠
16. Following solutions at the same temperature will be isotonic :
a) 3.42 g of cane sugar in one litre water and 0.18 g of glucose in one litre water
b)3.42 g of cane sugar in one litre water and 0.18 g of glucose in 0.1 litre water
c) 3.42 g of cane sugar in one litre water and 0.585 g of NaCl in one litre water
d)3.42 g of cane sugar in one litre water and 1.17 g of NaCl in one litre water
17. The osmatic pressure of a 5% (wt./vol) solution of cane sugar at 150℃ is
a) 3.078 atm b)4.078 atm c) 5.078 atm d)2.45 atm
18. Ethylene glycol is used as an antifreeze in a cold climate. Mass of ethylene glycol which
should be added to 4 kg of water to prevent it from freezing at −6∘ 𝐶 will be
(𝐾𝑓 𝑓𝑜𝑟 𝑤𝑎𝑡𝑒𝑟 = 1.86 𝐾 𝑘𝑔 𝑚𝑜𝑙 −1 . and molar mass of ethylene glycol = 62 𝑔 𝑚𝑜𝑙 −1)
a) 804.32 g b)204.30 g c) 400.00 g d)304.60 g
19. Mole fraction of solute in benzene is 0.2 then find molality of solute
a) 3.2 b)2 c) 4 d)3.6
20. When a solute is added in two immiscible solvents, it distributes itself between two
liquids so that its concentration in first liquid is 𝑐1 and that in the second liquid is 𝑐2 . If
the solute forms a stable trimer in the first liquid, the distribution law suggests that :
a) 3𝑐1 = 𝑐2
3
b)𝑐1 / √𝑐2 = constant
c) 𝑐1 /3 = 𝑐2
3
d)𝑐2 / √𝑐1 = constant
ANSWER-KEY
Q. 1 2 3 4 5 6 7 8 9 10
A. A D C B D C D B B C
Q. 11 12 13 14 15 16 17 18 19 20
A. B D D A C B C A A D
Sumit Sarovar, Behind Three Dots Jr. School, Ramghat Road, Aligarh
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8791002022, 9319685017
