GP Physical Sciences Grade 11 November 2023 P2 and Memo
GP Physical Sciences Grade 11 November 2023 P2 and Memo
com
PROVINCIAL EXAMINATION
2023
NOVEMBER 2023
GRADE 11
PAPER 2
TIME: 3 hours
MARKS: 150
2. This question paper consists of NINE questions. Answer ALL questions in the
ANSWER BOOK.
4. Number the answers correctly according to the numbering system used in this
question paper.
10. Round off your FINAL numerical answers to a minimum of TWO decimal places.
Four options are provided as possible answers to the following questions. Each
question has only ONE correct answer. Write only the letter (A – D) next to the
question number (1.1 to 1.10) in the ANSWER BOOK, for example 1.11D.
1.1 Which of the bonds between the atoms below has the highest polarity?
A H–N
B H - Cℓ
C H–O
D H–C (2)
1.2 The graph below shows how the potential energy varies with distance
between the nuclei of two oxygen atoms when a double bond between the
oxygen atoms (O = O) is formed.
Potential energy (kJ.mol-1)
Distance between
nuclei (pm)
Choose from the table below, the bond length and bond energy for O = O.
1.3 Consider the following statements: Which of the following is/are TRUE?
A Only (i)
B (i), (ii) and (iii)
C (ii) en (iv)
D (i), (ii) en (iv) (2)
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1.4 Intermolecular forces influence some physical properties of materials like surface
tension. Which of the following statements is correct?
A The stronger the intermolecular force, the higher the surface tension.
B The stronger the intermolecular force, the higher the rate of evaporation.
C The stronger the intermolecular force, the lower the melting point.
D The weaker the intermolecular force, the higher the boiling point. (2)
1.5 Determine what the new pressure in kPa will be if 750 ml nitrogen gas in the
atmosphere is compressed to 500 ml, keeping the temperature constant?
A 2,70 x 10 -4 kPa
B 67,53 kPa
C 151,95 kPa
D 1,5 atm (2)
1.6 Hydrogen gas is a real gas that reacts like an ideal gas in the following situation:
1.9 Instant hot and cold packs function by dissolving a salt into water. As the salt
dissociates, heat is either released in an exothermic reaction or absorbed in an
endothermic reaction. Which of the following reactions will be best suited to be
used as a hot pack?
A Pb.
B Pb2+.
C Cu.
D Cu2+. (2)
[20]
Calcium carbonate is a dietary supplement used when the intake of calcium through the
diet is not enough. The body requires calcium to maintain healthy bones, muscles,
nervous system and heart. Calcium carbonate can also be used as an antacid to relieve
heartburn. Calcium carbonate can be produced with the following reaction:
2.5 Which of the two reactants in this reaction would most likely be:
2.7 Use electronegativity to determine the type of bonds that will form in CaO. (2)
2.9 Explain the answer to QUESTION 2.8 by using a calculation and referring to the
shape of the molecule. (2)
[18]
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The physical properties of matter, such as vapour pressure, melting or boiling points,
depend on intermolecular forces.
3.2 Group 17 on the periodic table forms diatomic molecules, e.g. F2 and Cℓ2.
3.2.1 What type of intermolecular forces will there be between the molecules?
(1)
3.2.2 Which ONE of the following halogens will have the highest boiling point?
Cℓ2 or I2. (1)
Volume scale
Air
Glass tube
Pressure gauge
4.3 Name and state the law that is being investigated here. (3)
4.4 Calculate the value of X using other values given on the graph. (3)
4.5 Like all real gases, this gas will liquify at very low temperatures. Explain why this
happens. (2)
4.6 If this experiment was conducted at a room temperature of 25 ˚C, calculate the
amount of mole of O2(g) at a pressure of 200kPa. (4)
4.8 Use the kinetic theory to describe how the above change will influence the
pressure experienced by the 20 cm3 N2(g). (3)
[21]
5.1. Aspirin is known by the chemical name acetylsalicylic acid. The empirical formula
of aspirin consists of 60,0% carbon and 4,44% hydrogen and oxygen.
5.2 The molar mass of hydrated sodium carbonate is found to be 268 g∙mol -1. The
formula of the hydrated sodium carbonate is Na2CO3.xH2O.
Calculate the number of moles of water (x) in the compound. (4)
[14]
6.1 If a solution of silver nitrate (AgNO3) is mixed with solution of potassium chloride
(KCℓ), a precipitate of AgCℓ is produced according to the following reaction:
6.2 Mary heats 50 g of CaCO3 that reacts according to the following reaction:
6.2.2 She obtains only 18,2 g CO2 gas. Determine the percentage purity of the
CaCO3. (5)
6.2.3 Calculate the mass of CO2 gas that Mary could collect if CaCO3 was only
70% pure. (5)
[24]
7.1.2 Give a reason why sulphuric acid is referred to as a diprotic acid. (2)
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HSO−
4 can behave either as an acid or a base.
7.1.3 Write down ONE word for the underlined phrase in the above sentence. (1)
7.2.2 Write down the balanced equation for the reaction of sulphuric acid with
water. (3)
7.3 In a titration, the learner finds that 20 cm3 of a 0,2 mol.dm-3 solution of sodium
hydrogen carbonate neutralises 12 cm3 of the sulphuric acid solution. The
balanced equation for this reaction is:
7.3.2 Which of the indicators listed below should be used in this titration?
Briefly explain your answer.
Certain chemical reactions are often used to reduce swelling after an athletic injury.
In a lab experiment the following reaction was tested and the sketch graph below was
obtained.
8.4 Which number on the graph represents the enthalpy for the reverse reaction? (1)
8.6 Give the number on the graph that represents the activated complex. (1)
8.7 Explain how a catalyst would affect the activation energy in the reaction. (2)
8.8 Redraw the sketch graph on you answer sheet and use a dotted line to indicate
the changes after adding a catalyst. (2)
[13]
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QUESTION 9 (Start on a new page.)
9.2.1 Give a reason why the reaction above is a redox reaction. (1)
9.2.2 Identify the FORMULA of the reducing agent. Explain the answer in
terms of the oxidation number. (2)
TOTAL: 150
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p1V1 p 2 V2
= pV = nRT
T1 T2
m N
n= n=
M NA
V n m
n= c= OR/OF c=
Vm V MV
ca Va n 𝑄 Q
= na n= or/of n =
cb Vb b 𝑒 𝑞𝑒
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TABLE 3: THE PERIODIC TABLE OF ELEMENTS/TABEL 3: DIE PERIODIEKE TABEL VAN ELEMENTE
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
(I) (II) (III) (IV) (V) (VI) (VII) (VIII)
Atomic number/
1 KEY/SLEUTEL Atoomgetal 2
2,1
H He
1 4
29
3 4 Electronegativity/ Symbol/ 5 6 7 8 9 10
1,9
Li Be Cu B C N O F Ne
1,0
1,5
2,0
2,5
3,0
3,5
4,0
Elektronegatiwiteit Simbool
7 9 11 12 14 16 19 20
63,5
11 12 13 14 15 16 17 18
Na Mg Aℓ Si P S Cℓ Ar
0,9
1,2
1,5
1,8
2,1
2,5
3,0
23 24
Approximate relative atomic mass/ 27 28 31 32 35,5 40
Benaderde relatiewe atoommassa
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
0,8
1,0
1,3
1,5
1,6
1,6
1,5
1,8
1,8
1,8
1,9
1,6
1,6
1,8
2,0
2,4
2,8
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39 40 45 48 51 52 55 56 59 59 63,5 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
0,8
1,0
1,2
1,4
1,8
1,9
2,2
2,2
2,2
1,9
1,7
1,7
1,8
1,9
2,1
2,5
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
86 88 89 91 92 96 101 103 106 108 112 115 119 122 128 127 131
55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tℓ Pb Bi Po At Rn
0,7
0,9
1,6
1,8
1,8
1,9
2,0
2,5
133 137 139 179 181 184 186 190 192 195 197 201 204 207 209
87 88 89
0,7
0,9
Fr Ra Ac 58 59 60 61 62 63 64 65 66 67 68 69 70 71
226 Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
140 141 144 150 152 157 159 163 165 167 169 173 175
90 91 92 93 94 95 96 97 98 99 100 101 102 103
Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
232 238
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−
NO 3 + 2H+ + e− ⇌ NO2(g) + H2O + 0,80
Fe3+ + e− ⇌ Fe2+ + 0,77
O2(g) + 2H+ + 2e− ⇌ H2O2 + 0,68
I2 + 2e− ⇌ 2I− + 0,54
+
Cu + e − ⇌ Cu + 0,52
+
SO2 + 4H + 4e − ⇌ S + 2H2O + 0,45
2H2O + O2 + 4e− ⇌ 4OH− + 0,40
Cu2+ + 2e− ⇌ Cu + 0,34
2−
SO 4 + 4H+ + 2e− ⇌ SO2(g) + 2H2O + 0,17
2+
Cu + e −
⇌ Cu +
+ 0,16
Sn4+ + 2e− ⇌ Sn2+ + 0,15
S + 2H+ + 2e− ⇌ H2S(g) + 0,14
2H+ + 2e− ⇌ H2(g) 0,00
Fe3+ + 3e− ⇌ Fe − 0,06
Pb2+ + 2e− ⇌ Pb − 0,13
Sn2+ + 2e− ⇌ Sn − 0,14
Ni2+ + 2e− ⇌ Ni − 0,27
Co2+ + 2e− ⇌ Co − 0,28
Cd2+ + 2e− ⇌ Cd − 0,40
Cr3+ + e− ⇌ Cr2+ − 0,41
2+
Fe + 2e −
⇌ Fe − 0,44
Cr3+ + 3e− ⇌ Cr − 0,74
Zn2+ + 2e− ⇌ Zn − 0,76
2H2O + 2e− ⇌ H2(g) + 2OH− − 0,83
Cr2+ + 2e− ⇌ Cr − 0,91
Mn2+ + 2e− ⇌ Mn − 1,18
Aℓ3+ + 3e− ⇌ Aℓ − 1,66
Mg2+ + 2e− ⇌ Mg − 2,36
Na+ + e− ⇌ Na − 2,71
Ca2+ + 2e− ⇌ Ca − 2,87
Sr2+ + 2e− ⇌ Sr − 2,89
Ba2+ + 2e− ⇌ Ba − 2,90
Cs+ + e- ⇌ Cs – 2,92
K+ + e− ⇌ K − 2,93
+
Li + e −
⇌ Li − 3,05
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TABLE 4B: STANDARD REDUCTION POTENTIALS
TABEL 4B: STANDAARD REDUKSIEPOTENSIALE
Half-reactions/Halfreaksies E (V)
Li+ + e− ⇌ − 3,05
K+ + e− ⇌ K − 2,93
Cs+ + e− ⇌ Cs − 2,92
Ba2+ + 2e− ⇌ Ba − 2,90
Sr2+ + 2e− ⇌ Sr − 2,89
Ca2+ + 2e− ⇌ Ca − 2,87
Na+ + e− ⇌ Na − 2,71
Mg2+ + 2e− ⇌ Mg − 2,36
Aℓ3+ + 3e− ⇌ Aℓ − 1,66
Mn2+ + 2e− ⇌ Mn − 1,18
Cr2+ + 2e− ⇌ Cr − 0,91
2H2O + 2e − ⇌ H2(g) + 2OH −
− 0,83
Zn2+ + 2e− ⇌ Zn − 0,76
Cr3+ + 3e− ⇌ Cr − 0,74
Fe2+ + 2e− ⇌ Fe − 0,44
Cr3+ + e− ⇌ Cr2+ − 0,41
Cd2+ + 2e− ⇌ Cd − 0,40
Co2+ + 2e− ⇌ Co − 0,28
Ni2+ + 2e− ⇌ Ni − 0,27
Sn2+ + 2e− ⇌ Sn − 0,14
Pb2+ + 2e− ⇌ Pb − 0,13
Fe3+ + 3e− ⇌ Fe − 0,06
2H+ + 2e− ⇌ H2(g) 0,00
S + 2H+ + 2e− ⇌ H2S(g) + 0,14
Sn4+ + 2e− ⇌ Sn2+ + 0,15
2+
Cu + e − ⇌ Cu +
+ 0,16
2−
SO 4 + 4H+ + 2e− ⇌ SO2(g) + 2H2O + 0,17
2+
Cu + 2e −
⇌ Cu + 0,34
2H2O + O2 + 4e − ⇌ 4OH −
+ 0,40
SO2 + 4H+ + 4e− ⇌ S + 2H2O + 0,45
Cu+ + e− ⇌ Cu + 0,52
I2 + 2e− ⇌ 2I− + 0,54
O2(g) + 2H+ + 2e− ⇌ H2O2 + 0,68
Fe3+ + e− ⇌ Fe2+ + 0,77
−
NO 3 + 2H+ + e− ⇌ NO2(g) + H2O + 0,80
+
Ag + e − ⇌ Ag + 0,80
Hg2+ + 2e− ⇌ Hg(ℓ) + 0,85
−
NO 3 + 4H+ + 3e− ⇌ NO(g) + 2H2O + 0,96
Br2(ℓ) + 2e − ⇌ 2Br −
+ 1,07
Pt2+ + 2 e− ⇌ Pt + 1,20
MnO2 + 4H+ + 2e− ⇌ Mn2+ + 2H2O + 1,23
O2(g) + 4H+ + 4e− ⇌ 2H2O + 1,23
2−
Cr2O 7 + 14H+ + 6e− ⇌ 3+
2Cr + 7H2O + 1,33
Cℓ2(g) + 2e − ⇌ 2Cℓ −
+ 1,36
−
MnO 4 + 8H+ + 5e− ⇌ 2+
Mn + 4H2O + 1,51
+
H2O2 + 2H +2 e − ⇌ 2H2O +1,77
Co3+ + e− ⇌ Co2+ + 1,81
F2(g) + 2e− ⇌ 2F− + 2,87
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PROVINCIAL EXAMINATION/
PROVINSIALE EKSAMEN
NOVEMBER 2023
GRADE/GRAAD 11
MARKING
GUIDELINES/NASIENRIGLYNE
PAPER/VRAESTEL 2
9 pages/bladsye
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QUESTION/VRAAG1
1.1 C ✓✓ (2)
1.2 B ✓✓ (2)
1.3 D ✓✓ (2)
1.4 A ✓✓ (2)
1.5 C ✓✓ (2)
1.6 A ✓✓ (2)
1.7 C ✓✓ (2)
1.8 D ✓✓ (2)
1.9 B ✓✓ (2)
1.10 B ✓✓ (2)
[20]
QUESTION/VRAAG 2
2.1 2.1.1.
✓✓ (2)
2.1.2.
2.2. A covalent bond is a bond in which electron pairs are shared between the two
atoms to form a molecule. ✓✓
ʼn Kovalente binding is ʼn binding waar elektronpare gedeel word tussen twee
atome om ʼn molekule te vorm. ✓✓ (2)
2.3 Calcium/Ca ✓
Kalsium/Ca ✓ (1)
2.4 The bond between positive ions and delocalised valence electrons in a
metal. ✓✓
ʼn Binding tussen positiewe ione en gedelokaliseerde elektrone in ʼn metaal.✓✓ (2)
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QUESTION/VRAAG 3
3.1 The temperature at which the vapour pressure of a substance equals
atmospheric pressure. ✓✓
Die temperatuur waarby die dampdruk van ʼn stof gelyk is aan die atmosferiese
druk. ✓✓ (2)
3.2.2 I2 ✓ (1)
QUESTION/VRAAG 4
4.1 What is the relationship between the pressure and volume of an enclosed
mass of gas, when the temperature is kept constant? ✓✓
Wat is die verband tussen die druk en volume van ʼn ingeslote massa gas,
indien die temperatuur konstant gehou word. ✓✓ (2)
4.2.1 Pressure ✓
Druk ✓ (1)
4.3 Boyle’s Law.✓ The pressure of an enclosed gas is inversely proportional to the
volume it occupies at a constant temperature ✓✓
Boyle se wet. ✓ Die druk van ʼn ingeslote gas is omgekeerd eweredig aan die
volume van die gas by ʼn konstante temperatuur. ✓✓ (3)
4.5 At low temperatures, a real gas’s particles will occupy space and have
volume. ✓✓
By lae temperature sal ʼn werklike gas se deeltjies spasie inneem en volume
besit. ✓✓
OR/OF
The attraction and repulsive forces between the particles become
significant. ✓✓ Thus, a real gas will liquify at low temperatures.
Die aantrekkings- en afstotingskragte tussen deeltjies raak
noemenswaardig. ✓✓ Dus sal ʼn werklike gas vervloei by lae temperature. (2)
4.6 pV = nRT ✓
200 x 103 (50 x 10-6) ✓= n 8,31 (298) ✓
n = 0,00403 mol/4,30 x 10-3 mol ✓ (4)
QUESTION/VRAAG 5
5.1 5.1.1 The simplest ratio in which the elements of the compound are bonded
to each other.✓✓
Die eenvoudigste verhouding waarin die elemente van ʼn verbinding
aanmekaar gebind is. ✓✓ (2)
𝑚 4,44
H: n= 𝑀 = = 4,44 mol
1
𝑚 35,56
O: n= 𝑀 = = 2,22 mol
16
C : H : O
5 4,44 2,22
: :
2,22 2,22 2,22
2,25 : 2 :1
9 : 8 :4
Empirical formula/Empiriese formule: C9H8O4 (6)
QUESTION/VRAAG 6
6.1 6.1.1 The limiting reagent is the reactant that is used up first.
Die beperkende reagens is die een wat eerste opgebruik word. ✓✓ (2)
6.2.2 𝑚 18,2
n(CO2) = 𝑀 = 44
= 0,414 mol
n(CaCO3) = n(CO2) = 0,414 mol
m(CaCO3) = nM
= 0,414(100)
= 41,4 g
41,4
% purity/suiwerheid = 50 x 100
= 82,8% (5)
m
6.2.3 % purity/suiwerheid = 70% = 50
m = 35 g CaCO3
𝑚 35
n(CaCO3) = 𝑀 = 100
= 0,35 mol
n(CO2) = n(CaCO3)
= 0,35 mol
m(CO2) = nM
= 0,35(44)
= 15,4 g (5)
[24]
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QUESTION/VRAAG 7
7.1.3 Ampholyte
Amfoliet (1)
7.3 7.3.1 na c V
= c a Va
nb b b
1 ca (0,012)
=
2 0,2 (0,02)
QUESTION/VRAAG 8
8.1 Endothermic✓
Endotermies (1)
8.2 The Products have more Potential energy than the reactants. ✓✓
Die produk het meer Potensiële energie as die reaktante.
OR/OF
More energy is absorbed than released ✓✓
Meer energie word geabsorbeer as vrygestel. ✓✓ (2)
8.3 + 14,8 kJ.mol-1✓✓ without a + sign only 1 mark/sonder ʼn + teken slegs een
punt (2)
8.6 3✓ (1)
NOTE/LET WEL:
8.8
✓ Dotted line from
reactants to products
✓ Stippellyn van
reaktante na produkte
✓ Lower that 3 and
higher than 4
✓ Laer as 3 en hoër as 4
Course of the reaction/verloop van
die reaksie (2)
[13]
QUESTION/VRAAG 9
9.1.2 +6 (2)
TOTAL/TOTAAL: 150
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TAXONOMY GRID
Recall Comprehension Analysis Evaluation
Q no: Mark Q no: Mark Q no: Mark Q no: Mark
1.1 2 1.3 2 1.2 2
1.7 2 1.4 2 1.5 2
1.6 2 1.10 2
1.8 2
1.9 2
2.2 2 2.1.1 2 2.7 2
2.1.2 2 2.9 2
2.3 1 2.4 2
2.6 2 2.5 2
2.8 1
3.1 2 3.2.1 1
3.2.2 1
3.2.3 3
3.3.1 2
4.7 2 4.1 2 4.4 3 4.8 3
4.2 2 4.6 4
4.3 3
4.5 2
5.1.1 2 5.1.2 6 5.2 4
5.1.3 2
6.1.1 2 6.1.2 5
6.1.3 4
6.2.1 3
6.2.2 5
6.2.3 5
7.1.1 2 7.1.2 2 7.3.1 5
7.1.3 1 7.2.1 3 7.2.2 2
7.3.2 3
8.1 1 8.2 2 8.8 2
8.5 2 8.3 2
8.4 1
8.6 1
8.7 2
9.1.1 2 9.1.2 2
9.2.1 1
9.2.2 2
9.2.3 2
9.2.4 4