1.

Diagram below shows the apparatus set-up for the neutralisation reaction between sulphuric acid,
H2SO4 and sodium hydroxide solution, NaOH.

(a) Name the above method.

___________________________________________________________________________________
[1 mark]
3 3 -3
(b) 25 cm of sulphuric acid, H2SO4 neutralises 50 cm of 0.1 moldm sodium hydroxide solution, NaOH.
I. Write the chemical equation for the reaction.
_____________________________________________________________________________
[2 marks]
II. Calculate the number of moles of sulphuric acid, H2SO4 needed in this reaction.

[2 marks]

III. Calculate the molarity of the sulphuric acid, H2SO4.

[2 marks]
(c) Why a tile is used in this activity?
____________________________________________________________________________________
__________________________________________________________________________________
[1 mark]
(d) Name the term used to describe the point in the titration at which the acid-base indicator changes the
colour.
___________________________________________________________________________________
[1 mark]
1
2. The following information shows two solutions of hydrochloric acid, HCl with different concentrations.

Solution A 50 cm3 of 1.0 moldm-3 hydrochloric acid solution, HCl

Solution B 50 cm3 of 2.0 moldm-3 hydrochloric acid solution, HCl

(a) Calculate the number of moles of hydrochloric acid, HCl in each solution.

[2 marks]
(b) Both solutions are mixed. Calculate the number of moles of hydrochloric acid, HCl in the final
solution.

[1 mark]

(c) What is the volume of 2.0 moldm -3 ammonia solution, NH3 needed to neutralise the final acid
solution?

[2 marks]

3. Diagram below shows the apparatus set-up for the preparation of nitrate salt S and nitrate salt T
through Method I and Method II respectively.

2
 (a) Name one nitrate salt that can be prepared through Method I and Method II.
_____________________________________________________________________________
[2 marks]
(b) Write a chemical equation for nitrate salt T if its metal oxide formula is TO. Then, calculate the
mass of nitrate salt T produced.
[Relative atomic mass : T = 24, O = 16, N = 14, H = 1 ]

[5 marks]
(c) Calculate the concentration, in gdm-3, of hydroxide solution S in Method I. Given the molar
mass of hydroxide S solution is 40 gmol-1.

[3 marks]

4. 0.195 g of potassium is put into 500 cm 3 of cold water. When the reaction is completed, 100 cm 3 of
0.10 moldm-3 hydrochloric acid is added to form solution X.
[Relative atomic mass : K = 39]
(a) Calculate the number of moles of hydroxide ions formed when potassium reacts with water.

[2 marks]
3
 (b) What is the number of moles of hydrogen ions in 100 cm3 of 0.10 moldm-3 hydrochloric acid?

[2 marks]

(c) Write an ionic equation to represent the neutralisation reaction.

_____________________________________________________________________________
[1 mark]
(d) Suggest the pH value for solution X. explain your answer.
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
[2 marks]

5. The table below shows strong monoprotic acids HA and HB with different concentrations.

Monoprotic acid Concentration (moldm-3)

HA 0.10
HB 0.01

(a) State the meaning of strong acid.

_____________________________________________________________________________
[1 mark]
(b) Based on the information in the table, which acid has a lower pH value? Explain your answer.
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
[3 marks]
3 -3
(c) 20 cm of 0.2 moldm potassium hydroxide solution is put in a conical flask. Then a few drops
of phenolphthalein are added. This solution is titrated with HA acid.
I. What is the colour change of the mixture at end point?
_____________________________________________________________________________
[1 mark]
II. Write a chemical equation for the reaction.
_____________________________________________________________________________
[1 mark]
III. Calculate the volume of HA acid used.

[2 marks]

4
6. The diagram below shows Experiment I and II in the preparation of two different salts.

(a) Write the formula of salt produced in Experiment I.

_____________________________________________________________________________
[1 mark]
(b) Experiment I is repeated using hydrochloric acid of the same concentration to replace
sulphuric acid. What is the volume of hydrochloric acid needed to neutralise completely the
alkali in the conical flask? Give a reason for your answer.
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
[2 marks]
(c) Based on Experiment II,
I. Why must zinc powder be added in excess?
_____________________________________________________________________________
[1 mark]
II. Write the chemical equation for the reaction that occurred.
_____________________________________________________________________________
[2 marks]
III. Calculate the maximum mass of the salt formed.
[Relative atomic mass : N = 14, O = 16, Zn = 65]

[3 marks]

5
7. Table 2 shows the concentrations and pH values of three solutions.

Solution Sulphuric acid Ethanoic acid Sodium hydroxide

Concentration 0.5 0.5 y
(mol dm-3)
pH value 1 5 13

(a) Which of the solution in Table 2 has the highest concentration of hydrogen ions? Explain your
answer.
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
[2 marks]
(b) A students carried out an experiment to determine the value of y. In the experiment, 20 cm3 of
sulphuric acid in Table 2 is used to neutralise 25 cm 3 of sodium hydroxide solution using
titration method.
I. Write the chemical equation involved.
_____________________________________________________________________________
[2 marks]
II. Calculate the value of y.

[2 marks]

8. The diagram below shows the formation of zinc nitrate and its reactions with other chemical
compounds.

(a) Compound T is a white powder that reacts with dilute nitric acid to form zinc nitrate. Name
compound T.
_____________________________________________________________________________
[1 mark]

6
 (b) When zinc nitrate solution is added to sodium carbonate solution in a beaker, precipitate W
and sodium nitrate solution are formed.
I. Name precipitate W.
_____________________________________________________________________________
[1 mark]
II. How can you separate precipitate W from the sodium nitrate solution?
_____________________________________________________________________________
[1 mark]
(c) When zinc nitrate is heated, substance A, gas B and nitrogen dioxide gas are produced.
I. Write the chemical equation for the decomposition of zinc nitrate when heated.
_____________________________________________________________________________
[2 marks]
II. Calculate the volume of nitrogen dioxide gas produced at room conditions, when 37.8g of zinc
nitrate is heated.
[Molar volume of gas at room conditions = 24 dm3 mol-1]

[3 marks]
9. The diagram below shows a flow chart of zinc salts.

(a) State the solubility of zinc chloride salt.

_____________________________________________________________________________
[1 mark]
(b) Based on the diagram,
I. Identify
Solution S : ___________________________________________________
Solution T : ___________________________________________________
7
 Solution U : ___________________________________________________ [3
marks]
II. State the type of reaction for Step I.
_____________________________________________________________________________
[1 mark]
III. Write a balance chemical equation for the reaction occurs in Step I.
_____________________________________________________________________________
[2 marks]
IV. What is the mass of ZnCO3 produced when 0.1 mole ZnCl2 reacts with solution S?

[1 mark]

10. The table below shows the apparatus set up for two sets of reactions, Set I and II involving lead(II)
nitrate. Set I is the effect of heat on lead(II) nitrate while Set II is the reaction between lead(II) nitrate
and sodium carbonate solution.

(a) Write a chemical formula of lead(II) nitrate.

_____________________________________________________________________________
[1 mark]
(b) Based on Set I,
I. State the gas produced when lead(II) nitrate is heated.
_____________________________________________________________________________
[1 mark]
II. Write the equation for the reaction occurred.
_____________________________________________________________________________
[2 marks]

8
III. If 33.1g of lead(II) nitrate is used, calculate the mass of lead(II) oxide formed.
[Relative atomic mass : Pb = 207, N = 14, O = 16]

[2 marks]
(c) Based on Set II,
I. State the name of precipitate X.
_____________________________________________________________________________
[1 mark]
II. State the type of the reaction.
_____________________________________________________________________________
[1 mark]
III. Write the equation for the reaction occurred.
_____________________________________________________________________________
[2 marks]