JEE Main – 3 | JEE - 2024

Date: --/01/2023 Maximum Marks: 300

Timing: 11:00 AM to 2:00 PM

General Instructions
1. The test is of 3 hours duration and the maximum marks is 300.
2. The question paper consists of 3 Parts (Part I: Physics, Part II: Chemistry, Part III: Mathematics). Each Part
has two sections (Section 1 & Section 2).
3. Section 1 contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE CHOICE is correct.
4. Section 2 contains 5 Numerical Value Type Questions. The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer. If the answer is a decimal numerical
value, then round-off the value to TWO decimal places. If the answer is an Integer value, then do not add
zero in the decimal places. In the OMR, do not bubble the  sign for positive values. However, for negative
values, Θ sign should be bubbled. (Example: 6, 81, 1.50, 3.25, 0.08)
5. No candidate is allowed to carry any textual material, printed or written, bits of papers, pager, mobile phone, any
electronic device, etc. inside the examination room/hall.
6. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
7. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in the
Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.
8. Do not fold or make any stray mark on the Answer Sheet (OMR).

Marking Scheme
1. Section – 1: +4 for correct answer, –1 (negative marking) for incorrect answer, 0 for all other cases.

2. Section – 2: +4 for correct answer, –1 (negative marking) for incorrect answer, 0 for all other cases.

Name of the Candidate (In CAPITALS) :

Roll Number :

OMR Bar Code Number :

Candidate's Signature : Invigilator's Signature

Syllabus
Physics – Energy and Momentum, Rotation & Gravity
Chemistry – Chemical Bonding, Thermodynamics, Chemical Equilibrium, States of Matter
Mathematics – Straight Lines, Complex Numbers, Sequence & Series
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PART - I : PHYSICS 100 MARKS

SECTION-1
This section contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE CHOICE is correct.
1. A body of mass 3 kg is under a constant force which causes a displacement s in metres in it, given by
1 2
relation s  t , where t is in seconds. Work done by the force in 2 seconds is:
3
19 5 3 8
(A) J (B) J (C) J (D) J
5 19 8 3
2. A T-shaped object made from two rods of same material and area with length
shown in the figure is lying on a smooth floor. A force F is applied at the point
P parallel to AB such that the object has only translational motion without
rotation. Find the location of P with respect to C.
4 3 2
(A) l (B)  l (C)  l (D)  l
3 2 3
3. A thin rod of length L is lying along the x-axis with its ends at x = 0 and x = L. Its linear density
(mass/length) varies with x as k (x/L)n, where n can be zero or any positive number. If the position xCM of
the centre of mass of the rod is plotted against n, which of the following graphs best approximates the
dependence of xCM on n?

(A) (B) (C) (D)

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4. The figure shows the position – time (x – t) graph of one
– dimensional motion of a body of mass 0.4 kg. The magnitude
of each impulse is:
(A) 0.4 Ns
(B) 0.8 Ns
(C) 1.6 Ns
(D) 0.2 Ns
5. A particle of mass m moving in the x direction with speed 2v is hit by particle of mass 2m moving in the y
direction with speed v. If the collision is perfectly inelastic, the percentage loss in the energy during the
collision is close to:
(A) 44 % (B) 50 % (C) 56 % (D) 62 %
6. The speeds of two identical cars are u and 4u at a specific instant. The ratio of the respective distance in
which the two cars are stopped from that instant is:
(A) 1:1 (B) 1:4 (C) 1:8 (D) 1 : 16

7. The block of mass M moving on a frictionless horizontal surface

collides with a spring of spring constant K and compresses it by length
L. The maximum momentum of the block after collision is:

ML2 KL2
(A) (B) Zero (C) (D) MK L
K 2M
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8. Circular platform is free to rotate in a horizontal plane about a vertical axis passing through its center. A
tortoise is sitting at the edge of the platform. Now, the platform is given an angular velocity 0 . When the
tortoise moves along a chord of the platform with a constant velocity (with respect to the platform), the
angular velocity of the platform (t ) will vary with time t as:

(A) (B)

(C) (D)

9. A block of mass m is attached to a pulley disc of equal mass m and radius r by means of a slack string as
shown. The pulley is hinged about its centre on a horizontal table and the block is projected with an initial
velocity of 5 m/s. Its velocity when the string becomes taut will be:

(A) 3 m/s (B) 2.5 m/s (C) 5/3 m/s (D) 10/3 m/s

10. A pulley of radius 2 m start rotating about its axis by the action of a force F  (20t  5t 2 ) N (where, t
is measured in seconds) applied tangentially. If the moment of inertia of the pulley about its axis of
rotation is 10kg  m 2 , then the number of rotations made by the pulley before its direction of motion is
reserved, is:
(A) More than 3 but less than 6 (B) More than 6 but less than 9
(C) More than 9 (D) Less than 3
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11. Point masses m1 and m2 are placed at the opposite ends of a rigid rod of
length L, and negligible mass. The rod is to be set into rotation about an
axis perpendicular to it. The position of point P on this rod through which
the axis should pass so that the work required to set the rod rotation with
angular velocity 0 is minimum, is given by :
m2 m2 L
(A) x L (B) x
m1 m1  m2
m1 L m1
(C) x (D) x L
m1  m2 m2
12. A mass m moves in a circle on a smooth horizontal plane with velocity v0 at
a radius R. The mass is attached to a string which passes through a smooth
hole in the plane as shown. Find the KE of mass if the radius is halved by
pulling the string through hole.
1 2 1 2
(A) 2mv02 (B) mv0 (C) mv02 (D) mv0
2 4
13. Three identical spherical shells, each of mass m and radius r are placed as shown in
figure. Consider an axis XX  which is touching to two shells and passing through
diameter of third shell. Moment of inertia of the system consisting of these three
spherical shells about XX  axis is :
16 2 11 2
(A) mr (B) 4mr 2 (C) mr (D) 3mr 2
5 5
14. The ratio of radii of gyration of a circular ring and a circular disc, of the same mass and same radius, about
an axis passing through their centres and perpendicular to their planes are :
(A) 1: 2 (B) 3:2 (C) 2 :1 (D) 2 :1
15. The energy required to move a satellite of mass m from an orbit of radius 2R to 3R is (where M is the mass
of the earth and R is the radius of the earth)
GMm GMm GMm GMm
(A) (B) (C) (D)
12 R 8R 3R 6R
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16. The escape velocity for a body projected vertically upward from the surface of the earth is 11 km/s. If the
body is projected at an angle of 45° with vertical, the escape velocity will be:
11
(A) 11.2 km / s (B) 22 km / s (C) 11km / s (D) km / s
2
17. Suppose the gravitational force varies inversely as the nth power of distance. Then the time period of a
planet in a circular orbit of radius R around the sun will be proportional to:
R
n 1/2
R
n – 1 /2
R
n –2 /2
(A) (B) (C) Rn (D)
18. The change in the value of g at a height h above the surface of the earth is the same as at a depth d below
the earth. When both d and h are much smaller than the radius of the earth, which one of the following is
correct?
h 3h
(A) d (B) d (C) d = 2h (D) d=h
2 2
19. Two bodies of masses m and 4m are placed at a distance r. The magnitude of gravitational potential at a
point on the line joining them where the gravitational field is zero is:
4Gm 6Gm 9Gm
(A) zero (B) (C) (D)
r r r
20. Four particles, each of mass M and equidistant from each other, move along a circle of radius R under the
action of their mutual gravitational attraction. The speed of each particle is:
GM 1 GM
(A) (1  2 2) (B) (1  2 2)
R 2 R
GM GM
(C) (D) 2 2
R R
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SECTION-2
Section 2 contains 5 Numerical Value Type Questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value of the answer. If the answer is a decimal numerical value, then
round-off the value to TWO decimal places. If the answer is an Integer value, then do not add zero in the decimal
places. In the OMR, do not bubble the  sign for positive values. However, for negative values, Θ sign should be
bubbled. (Example: 6, 81, 1.50, 3.25, 0.08)
1. Find the distance of the center of mass of a composite solid cone and solid cylinder made of same material
from point O (in cm).

2. Two blocks of equal masses m are released from the top of a smooth
fixed wedge as shown in the figure. Find the magnitude of the
acceleration of the center of mass of the two blocks.
3. A uniform rod of mass m and length l  2h strikes the rough ground after falling through a distance h. If
3 yg x
the rod does not bounce. The angular velocity of the rod just after the impact is . Find
x h y

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4. A sphere of mass m rolls without sliding by the thread which hangs a body of
mass m. Ignoring the friction at the pulley, the speed of COM of sphere is
10
gy , when block moves vertically down by a distance y. Find x.
9x

5. A solid sphere of uniform density and radius R applies a gravitational force of attraction equal to F1 on a
particle placed at a distance 2R from the centre of the sphere. A spherical cavity of radius (R/2) is now
made in the sphere as shown in figure. The sphere with the cavity now applies a gravitational force F2 on
the same particle. The ratio ( ( F2 / F1 )  ( P / q) then | P  q | is:

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PART - II : CHEMISTRY 100 MARKS

SECTION-1
This section contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE CHOICE is correct.
1. Which of the following equation represent enthalpy of formation for HI?
1 1
(A) H 2 (g)  I2 (g) 
 2HI (g) (B) H 2 (g)  I 2 (g) 
 HI (g)
2 2
1 1 1 1
(C) H 2 (g)  I 2 (s) 
 HI (g) (D) H 2 (g)  I 2 () 
 HI (g)
2 2 2 2
2. Which of the following graph correctly represents the following equilibrium?
 P, KC  10
R 

(A) (B) (C) (D)

3. Which of the following is true for given equilibrium?
 CaO(s)  CO 2 (g); K P  3atm
CaCO3 (s) 
(A) On removing small amount of CaO, reaction goes forward
(B) On adding small amount of CaCO3, reaction goes forward
(C) PCO2  3 at equilibrium
(D) All of these
4. A man consumes 120 gm of glucose, if 50% of the energy given by glucose is available for muscular work
and requires 100 kJ to walk 1 km distance. What distance will be travelled (in km) by man using energy of
glucose consumed. H combustion of glucose is –2800 kJ/mol. (MGlucose = 180 g/mol)
(A) 4.8 km (B) 9.33 km (C) 14.4 km (D) 2.4 km
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5. Amongst LiCl, RbCl, BeCl2 and MgCl2 the compounds with the greatest and the least ionic character,
respectively are:
(A) LiCl and RbCl (B) RbCl and BeCl2
(C) MgCl2 and BeCl2 (D) RbCl and MgCl2
6. Given graph represents variation of compressibility factor Z with pressure for
gases A, B and C. Which of the following is the correct order of ease of
liquefication?
(A) A>B>C (B) A<B<C
(C) A=B>C (D) A=C>B
7. Which of the following hydrogen bonds is strongest?
(A) O  H - - - F (B) O  H - - - H (C) FH ---F (D) O  H---O
8. Based upon VSEPR theory, match the shape (geometry) of the molecules in List-I with the molecules in
List-II and Select the most appropriate option.
List-I List-II (molecules)
(P) T-shaped (I) XeF4
(Q) Trigonal planar (II) SF4
(R) Square planar (III) ClF3
(S) See-saw (IV) BF3
(A) (P)-(I), (Q)-(II), (R)-(III), (S)-(IV) (B) (P)-(III), (Q)-(IV), (R)-(I), (S)-(II)
(C) (P)-(III), (Q)-(IV), (R)-(II), (S)-(I) (D) (P)-(IV), (Q)-(III), (R)-(I), (S)-(II)

9.  2 NH3 (g);

N 2 (g)  3H 2 (g)  H  0
% yield of NH3 can be increased by:
I. Increasing temperature II. Increasing pressure
III. Removing NH3 IV. Adding He at constant pressure
The correct option is:
(A) I, II (B) I, II, III (C) I, II, IV (D) I, II, III, IV
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10. Which of the following is true as per graph?
I. Entropy increases with temperature
II. Ssolid  Sliquid  Sgas
III. Melting point = 273 K
IV. Boiling point = 373 K
The correct option is:
(A) I, II (B) I, II, III
(C) I, III, IV (D) I, II, III, IV
11. A sample of a 1 mole ideal gas expands isothermally and reversibly at 1 atm, 300 K from 1 litre to 10
litres. Work done in isothermal reversible compression between two states mentioned will be:
[Take: R = 8.31 J/K-mol]
(A) 5.7 kJ (B) –5.7 kJ (C) 11.4 kJ (D) –11.4 kJ
12. Which of the following is correct?
(A) V1  V2  V3
(B) V1  V2  V3
(C) V1  V2  V3
(D) V1  V2  V3

13. How much energy is released when 6 moles of octane is burnt in air? Given  f H for CO2 (g), H 2O(l )
and C8H18 (l ) respectively are –490, –240 and + 160 J mol–1.
(A) –6.2 kJ (B) –37.4 kJ (C) –35.5 kJ (D) –20.0 kJ
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14. Given, Al(s)  Cl2 (g)  AlCl3 (s), H   704.2 kJ
2
3
2Al(s)  O2 (g)  Al2O3 (s), H   1676 kJ
2
1
Cl 2 (g)  O 2 (g)  ClO2 (g), H  102.5 kJ
2
What is the enthalpy change for the reaction below? (Choose the closest value)
3
2AlCl3 (s)  O 2 (g)  Al2O3 (s)  3Cl2 (g)
2
(A) –1830 kJ (B) –2278 kJ (C) –268 kJ (D) –1012 kJ
15. The decreasing values of bond angles from NH 3 (106) to SbH 3 (101) down group-15 of the periodic
table is due to:
(A) Decreasing lp-bp repulsion (B) Decreasing electronegativity
3
(C) Increases bp-bp repulsion (D) Increasing p-orbital character in sp
16. Which change occurs with the largest increase in entropy at 25ºC?
(A) Br2 (l )  Br2 (g) (B) C(graphite)  C(diamond)

(C) H 2O(s)  H 2O(l ) (D) HCl(g)  H 2O(l )  H 3O  (aq)  Cl  (aq)

17. A gas is first expanded such that the temperature rises. Then it is allowed to expand such that the
temperature falls. Which diagram represents the changes correctly?

(A) (B) (C) (D)

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18. In the following the correct bond order sequence is:
(A) O 22  O 2  O 2  O 2 (B) O 2  O 2  O 22  O 2
(C) O 2  O 2  O 2  O22 (D) O 2  O 2  O 22  O 2
19. Which statement is correct at 25ºC and 1 atm pressure?
(A) G of for Hg(1)  0 kJ mol1 (B) H of for I 2 (g)  0 kJ mol1
(C) H of for H 2O(1)  0 kJ mol1 (D) Sº for O 2 (g)  0 JK 1
1
20. For a particular reaction, H   38.3 kJ and S   113 JK mol1 . This reaction is:
(A) Spontaneous at all temperatures
(B) Non-spontaneous at all temperatures
(C) Spontaneous at temperatures below 66°C
(D) Spontaneous at temperatures above 66°C

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SECTION-2
Section 2 contains 5 Numerical Value Type Questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value of the answer. If the answer is a decimal numerical value, then
round-off the value to TWO decimal places. If the answer is an Integer value, then do not add zero in the decimal
places. In the OMR, do not bubble the  sign for positive values. However, for negative values, Θ sign should be
bubbled. (Example: 6, 81, 1.50, 3.25, 0.08)
1. C(graphite)  O 2 (g) 
 CO2 (g); H   393kJ / mol
C(diamond)  O 2 (g) 
 CO 2 (g); H   395 kJ / mol
HTransition (in kJ/mol) for C(graphite) to C(diamond) is equal to _______.
2. A sample of an ideal gas exert 1 atm pressure in a 500 ml flask at 300 K. Calculate the partial pressure (in
atm) exerted by the sample of ideal gas when it is put in a flask (1 L) filled with O2 at 600 K.
(Assuming gas does not react with O2)
3. 1 litre mixture of CO and CO2 is passed over red-hot coke. If the volume of resultant mixture is 1.6 L, then
% of CO by volume in initial mixture was ________.
4. In the reaction C(s)  CO 2 (g)  2CO(g), the equilibrium pressure is 12 atm. If 50% of CO2 reacts,
K p (in atm) for the change is ________.

5. The number of paramagnetic species among the following is ________.

B2 , Li 2 , C2 , C2 , O 22 , O 2 and He 2

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PART - III : MATHEMATICS 100 MARKS

SECTION-1
This section contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE CHOICE is correct.
x y
1. If 2p is the length of perpendicular from the origin to the lines   1, then a 2 ,8 p 2 , b2 are in:
a b
(A) A. P. (B) G.P. (C) H. P. (D) A.G.P.
2. The equation of the base of an equilateral triangle is x  y  2 and the vertex is (2, –1). The length of the
side of the triangle is:
(A) 3/ 2 (B) 2 (C) 2/3 (D) 3
3. Coordinates of the foot of the perpendicular drawn from (0,0) to the line joining (a cos , a sin ) and
(a cos  , a sin  ) are:
a b a a 
(A) 2,2
 
(B)  2 (cos   cos ), 2 (sin   sin ) 

     b a
(C)  cos 2 ,sin 2  (D) 2,2
   
4. Let L be the line 2x  y  2 . If the axes are rotated by 45o , then the intercepts made by the line L on the
new axes are respectively:
(A) 2 and 1 (B) 1 and 2
(C) 2 2 and 2 2 / 3 (D) 2 2 / 3 and 4 2
5. A point moves so that square of its distance from the point (3, – 2) is numerically equal to its distance from
the line 5 x  12 y  13 . The equation of the locus of the point is:

(A) 13x 2  13 y 2  83x  64 y  182  0 (B) x 2  y 2  11x  16 y  26  0

(C) x 2  y 2  11x  16 y  0 (D) x 2  y 2  11x  16 y  0

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6. The graph of the function cos x cos( x  2)  cos ( x  1) is:

(A) A straight line passing through (0,  sin 2 1) with slope 2

(B) A straight line passing through (0, 0)
(C) A parabola with vertex 75o
 
(D) A straight line passing through the point  ,  sin 2 1  and parallel to the x–axis
2 
z  12 5 z  4
7. Find the complex number z satisfying the equations  , 1
z  8i 3 z  8
(A) 6 (B) 6  8i (C) 6  8i,6 17i (D) 8i
8. If | z  25i | 15 , then | max .amp ( z )  min .amp( z ) |
3 3
(A) cos 1   (B)   2 cos 1  
5 5
  3 3 3
(C)  cos 1   (D) sin 1    cos 1  
2 5 5 5
r r
9. If zr  cos 2  i sin 2 , where r = 1, 2, 3,….,n, then lim z1 z2 z3...zn is equal to:
n n n
(A) cos   i sin  (B) cos(/2)  i sin(/2)
3 i
(C) ei /2 (D) e
10. Let z, w be complex numbers such that z  iw  0 and arg zw   . Then arg z equals:
(A) 5 / 4 (B) /2 (C) 3 / 4 (D) /4
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2 2 2
11. The value of the expression 1.(2  )(2   )  2.(3  )(3   )  ....... ....  (n  1).(n  )(n   ),
where  is an imaginary cube root of unity, is:
1 1
(A) (n  1)n(n 2  3n  4) (B) (n  1)n(n 2  3n  4)
2 4
1 1
(C) (n  1)n(n 2  3n  4) (D) (n  1)n(n 2  3n  4)
2 4
12. If a  cos(2 / 7)  i sin(2 / 7), then the quadratic equation whose roots are   a  a 2  a 4 and

  a3  a 5  a 6 is:
(A) x 2  x  2  0 (B) x 2  x  2  0 (C) x 2  x  2  0 (D) x2  x  2  0
13. Let  is an imaginary cube root of unity, then the value of
2(  1)(2  1)  3(2  1)(22  1)  ..... (n  1)(n  1)(n2  1) is:
2 2
 n(n  1)   n(n  1) 
(A)  2   n (B)  2 
2 2
 n(n  1)   n(n 1) 
(C)  2   n (D)  2 

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1 1 1 1
14. When     0 and b  a  c , then a, b, c are:
a c a b c  d
(A) In H.P. (B) In G.P. (C) In A.P. (D) In A.G.P
1 1 1
15. The value of  + ..... +  is, (where a is a constant)
(1  a )(2  a ) (2  a )(3  a ) (3  a )(4  a )
1 2 3
(A) (B) (C)  (D)
1 a 1 a 1 a
16. If the sum of first n terms of an A.P. be equal to the sum of its first m terms, (m  n) , then the sum of
its first (m  n) terms will be:
(A) 0 (B) n (C) m (D) mn
2
17. If 1  cos   cos   .......    2  2, then , (0    ) is:
(A) /8 (B) /6 (C) /4 (D) 3 / 4
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18. If a, b, c, d be in H.P., then:

(A) a2  c2  b2  d 2 (B) a2  d 2  b2  c2
(C) ac  bd  b 2  c 2 (D) ac  bd  b 2  d 2
1 2 3
19. The sum of the series
2 4
 2 4
  ......... to n terms is:
11 1 1 2  2 1  3  34
2

n(n 2  1) n(n  1) n(n 2  1) n(n  1)

(A) (B) (C) (D)
2
n  n 1 2
2(n  n  1) 2
2(n  n  1) n2  n  1
13 13  23 13  23  33
20. n th term of the series    ...... will be:
1 1 3 1 3  5
n 2  2n  1 n 2  2n  1 n2  2n  1
(A) n 2  2n  1 (B) (C) (D)
8 4 4
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SECTION-2
Section 2 contains 5 Numerical Value Type Questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value of the answer. If the answer is a decimal numerical value, then
round-off the value to TWO decimal places. If the answer is an Integer value, then do not add zero in the decimal
places. In the OMR, do not bubble the  sign for positive values. However, for negative values, Θ sign should be
bubbled. (Example: 6, 81, 1.50, 3.25, 0.08)
1. If the lines ax  y  1  0, x  by  1  0 and x  y  c  0 (a, b, c being distinct and different from 1) are
1 1 1
concurrent, then   
1 a 1 b 1 c
2. The area enclosed within the curve | x |  | y | 1 is ________.
3. If z, iz and z  iz are the vertices of a triangle whose area is 2 units, then the value of | z | is ________.

4. If f ( x) is a function satisfying f ( x  y )  f ( x) f ( y ) for all x, y  N such that f (1)  3 and

n
 f ( x)  120 . Then the value of n is ________.
x1

5. In a G.P. the sum of three numbers is 14, if 1 is added to first two numbers and subtracted from third
number, the series becomes A.P., then the greatest number is ________.

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