APÉNDICE D.
DATOS DE ENTRADA AL SIMULADOR DE LOS PROCESOS
EVALUADOS
Proceso de Producción de Ciclohexano
IN-UNITS ENG
COMPONENTS
HYDROGEN H2 /
BENZENE C6H6 /
CYCLO-01 C6H12-1 /
NITROGEN N2 /
METHANE CH4
FLOWSHEET
BLOCK M-110 IN=FEEDH2 FEEDBZ2 OUT=H2YBZ
BLOCK P-110 IN=FEEDBZ OUT=FEEDBZ2
BLOCK M-120 IN=H2YBZ RECICBZ2 SCOMP OUT=EPREHEAT
BLOCK HE-110 IN=EPREHEAT OUT=EREAC
BLOCK HE-130 IN=EREAC OUT=SREAC
BLOCK HE-120 IN=SREAC OUT=EFLASH
BLOCK CP-110 IN=ECOMP OUT=SCOMP
BLOCK VV-110 IN=EFLASH OUT=S1FLASH S2FLASH
BLOCK P-120 IN=RECICBZ1 OUT=RECICBZ2
BLOCK D-120 IN=S2FLASH OUT=RECICBZ1 ECOLUMNA
BLOCK D-110 IN=S1FLASH OUT=PURGA ECOMP
BLOCK TW-110 IN=ECOLUMNA OUT=DEST PRODUCTO
PROPERTIES NRTL
PROP-DATA NRTL-1
IN-UNITS ENG
PROP-LIST NRTL
BPVAL BENZENE CYCLO-01 0.0 328.9580974 .3000000000 0.0 0.0 &
0.0 171.3200026 177.3500026
BPVAL CYCLO-01 BENZENE 0.0 -78.01307938 .3000000000 0.0 &
0.0 0.0 171.3200026 177.3500026
STREAM FEEDBZ
SUBSTREAM MIXED TEMP=100. PRES=15. MOLE-FLOW=425.
MOLE-FLOW BENZENE 1.
STREAM FEEDH2
SUBSTREAM MIXED TEMP=120. PRES=335. MOLE-FLOW=1402.
MOLE-FLOW HYDROGEN 0.975 / NITROGEN 0.005 / METHANE 0.02
BLOCK M-110 MIXER
BLOCK M-120 MIXER
BLOCK D-110 FSPLIT
FRAC PURGA 0.08
BLOCK D-120 FSPLIT
FRAC RECICBZ1 0.3
171
BLOCK HE-110 HEATER
PARAM TEMP=300. PRES=330.
BLOCK HE-120 HEATER
PARAM TEMP=120. PRES=-5.
BLOCK VV-110 FLASH2
PARAM TEMP=120. PRES=-5.
BLOCK TW-110 RADFRAC
PARAM NSTAGE=15 EFF=MURPHREE
COL-CONFIG CONDENSER=PARTIAL-V
FEEDS ECOLUMNA 8
PRODUCTS DEST 1 V / PRODUCTO 15 L
P-SPEC 1 200. / 15 250.
COL-SPECS MOLE-B=420. MOLE-RR=1.2
STEFF-SEC SECNO=1 2 15 0.5
BLOCK HE-130 RSTOIC
PARAM TEMP=400. PRES=-15.
STOIC 1 MIXED BENZENE -1. / HYDROGEN -3. / CYCLO-01 1.
CONV 1 MIXED BENZENE 0.998
BLOCK P-110 PUMP
PARAM PRES=315.
BLOCK P-120 PUMP
PARAM PRES=315.
BLOCK CP-110 COMPR
PARAM TYPE=ASME-POLYTROP PRES=330. PEFF=0.8
EO-CONV-OPTI
STREAM-REPOR MOLEFLOW
172
Proceso de Producción de Metanol
IN-UNITS MET
COMPONENTS
METHANE CH4 /
ETHANE C2H6 /
PROPANE C3H8 /
CO2 CO2 /
CO CO /
H2 H2 /
OXYGEN O2 /
WATER H2O /
METHANOL CH4O /
ETHANOL C2H6O-2 /
NITROGEN N2 /
ARGON AR
PROPERTIES PENG-ROB
PROPERTIES NRTL
STREAM 1A
SUBSTREAM MIXED TEMP=35. <C> PRES=27. &
MASS-FLOW=65. <tonne/hr>
MASS-FRAC METHANE 0.88 / ETHANE 0.1 / PROPANE 0.02
STREAM 31
SUBSTREAM MIXED PRES=40. VFRAC=1. MOLE-FLOW=6000.
MOLE-FRAC WATER 1.
STREAM 32
SUBSTREAM MIXED TEMP=25. <C> PRES=1. MASS-FLOW=255000.
STDVOL-FRAC CO2 0.00036 / OXYGEN 0.1995 / WATER 0.04804 / &
NITROGEN 0.7436 / ARGON 0.0085
BLOCK MX-101 MIXER
BLOCK MX-102 MIXER
BLOCK MX-201 MIXER
BLOCK MX-301 MIXER
BLOCK D-101 FSPLIT
FRAC 3 0.5
BLOCK D-201 FSPLIT
FRAC 20 0.05 / 21 0.04
BLOCK MM-401 SEP
FRAC STREAM=37 SUBSTREAM=MIXED COMPS=CO2 WATER FRACS= &
0.999 0.9999
BLOCK F-101 HEATER
PARAM TEMP=780. <C> PRES=40.
173
BLOCK HE-101 HEATER
PARAM TEMP=240. <C> PRES=0.
BLOCK HE-201 HEATER
PARAM TEMP=200. <C> PRES=40.
BLOCK HE-202 HEATER
PARAM TEMP=20. <C> PRES=60.
BLOCK HE-301 HEATER
PARAM TEMP=25. <C> PRES=1.
BLOCK HE-401 HEATER
PARAM TEMP=60. <C> PRES=1.
BLOCK HE-402 HEATER
PARAM TEMP=15. <C> PRES=6.
BLOCK VV-201 FLASH2
PARAM PRES=0. DUTY=0.
BLOCK VV-401 FLASH2
PARAM PRES=0. DUTY=0.
BLOCK HE43 MHEATX
HOT-SIDE IN=38 OUT=39 TEMP=-67. <C> FREE-WATER=NO
COLD-SIDE IN=46 OUT=47 FREE-WATER=NO
BLOCK HE44 MHEATX
HOT-SIDE IN=39 OUT=40 FREE-WATER=NO
COLD-SIDE IN=42 OUT=43 TEMP=200. <K> FREE-WATER=NO
BLOCK T-301 RADFRAC
PARAM NSTAGE=7
COL-CONFIG CONDENSER=NONE
FEEDS 22 1 ON-STAGE
PRODUCTS 23 1 V / 24 7 L
P-SPEC 1 20.
COL-SPECS MOLE-B=9122.
BLOCK T-302 RADFRAC
PARAM NSTAGE=69 EFF=MURPHREE
COL-CONFIG CONDENSER=TOTAL
FEEDS 24 66
PRODUCTS 25 1 L / 26 69 L
P-SPEC 1 1.
COL-SPECS MOLE-D=2100. MOLE-RR=2.33
TRAY-SIZE 1 2 68 FLOAT FLOOD-FAC=0.9
PROPERTIES NRTL
STEFF-SEC SECNO=1 2 68 0.9
BLOCK T-303 RADFRAC
PARAM NSTAGE=78 EFF=MURPHREE
COL-CONFIG CONDENSER=TOTAL
FEEDS 26 30
PRODUCTS 28 78 L / 27 1 L
P-SPEC 1 1.
COL-SPECS MOLE-D=1548. MOLE-RR=4.
174
TRAY-SIZE 1 2 77 FLOAT FLOOD-FAC=0.9
PROPERTIES NRTL
STEFF-SEC SECNO=1 2 77 0.9
BLOCK T-401 RADFRAC
PARAM NSTAGE=20 ALGORITHM=STANDARD INIT-OPTION=CRYOGENIC
COL-CONFIG CONDENSER=PARTIAL-V
FEEDS 40 13
PRODUCTS 44 20 L / 41 1 V
P-SPEC 1 6.
COL-SPECS MOLE-B=1670. MOLE-RR=2.85
BLOCK T-402 RADFRAC
PARAM NSTAGE=35 ALGORITHM=STANDARD INIT-OPTION=CRYOGENIC
COL-CONFIG CONDENSER=PARTIAL-V
FEEDS 44 26
PRODUCTS 45 1 V / 46 35 L
P-SPEC 1 1.
COL-SPECS MOLE-B=1630. MOLE-RR=60.
BLOCK SM-201 RSTOIC
PARAM TEMP=250. <C> PRES=70.
STOIC 1 MIXED H2 -2. / CO -1. / METHANOL 1.
STOIC 2 MIXED CO2 -1. / H2 -3. / METHANOL 1. / WATER & 1.
STOIC 3 MIXED CO2 -2. / H2 -6. / ETHANOL 1. / WATER & 3.
CONV 1 MIXED CO 0.55
CONV 2 MIXED CO2 0.3
CONV 3 MIXED CO2 0.022
BLOCK SM-202 RSTOIC
PARAM TEMP=250. <C> PRES=70.
STOIC 1 MIXED H2 -2. / CO -1. / METHANOL 1.
STOIC 2 MIXED CO2 -1. / H2 -3. / METHANOL 1. / WATER & 1.
STOIC 3 MIXED CO2 -2. / H2 -6. / ETHANOL 1. / WATER & 3.
CONV 1 MIXED CO 0.55
CONV 2 MIXED CO2 0.3
CONV 3 MIXED CO2 0.022
BLOCK AR-101 RGIBBS
PARAM TEMP=950. <C> PRES=40.
BLOCK PR-101 RGIBBS
PARAM TEMP=780. <C> PRES=40.
BLOCK P-301 PUMP
PARAM PRES=40.
BLOCK P-401 PUMP
PARAM PRES=40.
BLOCK CP-101 COMPR
PARAM TYPE=ASME-POLYTROP PRES=40.
BLOCK CP-201 COMPR
PARAM TYPE=ASME-POLYTROP PRES=70.
175
BLOCK CP-202 COMPR
PARAM TYPE=ASME-POLYTROP PRES=70.
BLOCK TB-401 COMPR
PARAM TYPE=ISENTROPIC PRES=1. NPHASE=2 MODEL-TYPE=TURBINE
BLOCK-OPTION FREE-WATER=NO
BLOCK CP-401 MCOMPR
PARAM NSTAGE=3 TYPE=ASME-POLYTROPIC PRES=6.
FEEDS 33 1
PRODUCTS 34 3
COOLER-SPECS 1 TEMP=100. <C>
BLOCK CP-402 MCOMPR
PARAM NSTAGE=3 TYPE=ASME-POLYTROPIC PRES=40.
FEEDS 47 1
PRODUCTS 48 3
COOLER-SPECS 3 TEMP=200. <C> / 1 TEMP=200. <C>
BLOCK V-201 VALVE
PARAM P-OUT=60.
EO-CONV-OPTI
CONV-OPTIONS
WEGSTEIN MAXIT=80
STREAM-REPOR MOLEFLOW MOLEFRAC
176
Proceso de Producción de Dimetil-Éter
IN-UNITS MET
COMPONENTS
METANOL CH4O /
AGUA H2O /
DMT C2H6O-1
FLOWSHEET
BLOCK V-200 IN=8 OUT=9
BLOCK E-202 IN=6 4 OUT=7 5
BLOCK V-201 IN=15 OUT=16
BLOCK E-208 IN=14 OUT=15
BLOCK E-203 IN=7 OUT=8
BLOCK R-201 IN=5 OUT=6
BLOCK E-201 IN=3 OUT=4
BLOCK P-201 IN=1 OUT=2
BLOCK P-202 IN=13 OUT=13-A
BLOCK M-201 IN=2 13-A OUT=3
BLOCK T-201 IN=9 OUT=10 11
BLOCK T-202 IN=11 OUT=13 14
PROPERTIES UNIQUAC
ESTIMATE ALL
IN-UNITS ENG
UNIQ ALL ALL UNIFAC
PROP-DATA UNIQ-1
IN-UNITS ENG
PROP-LIST UNIQ
BPVAL METANOL AGUA -1.066200000 779.1812938 0.0 0.0 &
76.98200338 212.0000023 0.0
BPVAL AGUA METANOL .6437000000 -579.8361554 0.0 0.0 &
76.98200338 212.0000023 0.0
BPVAL METANOL DMT 0.0 -627.8180350 0.0 0.0 32.00000374 &
32.00000374 0.0
BPVAL DMT METANOL 0.0 -45.17999964 0.0 0.0 32.00000374 &
32.00000374 0.0
BPVAL AGUA DMT 0.0 -689.4514079 0.0 0.0 77.00000338 &
77.00000338 *
BPVAL DMT AGUA 0.0 275.6147252 0.0 0.0 77.00000338 &
77.00000338 *
PROP-SET IPE-1
IN-UNITS ENG
PROPNAME-LIS MASSVFRA MASSSFRA MASSFLMX VOLFLMX TEMP PRES &
MWMX MASSFLOW SUBSTREAM=ALL
PROP-SET IPE-2
IN-UNITS ENG
PROPNAME-LIS VOLFLMX MASSFLMX KMX SIGMAMX MUMX CPMX MWMX &
UNITS='kJ/kg-K' SUBSTREAM=MIXED PHASE=L
177
PROP-SET IPE-3
IN-UNITS ENG
PROPNAME-LIS VOLFLMX MASSFLMX KMX MUMX CPMX MWMX UNITS= &
'kJ/kg-K' SUBSTREAM=MIXED PHASE=V
STREAM 1
IN-UNITS ENG
SUBSTREAM MIXED TEMP=25. <C> PRES=1. <bar> &
MOLE-FLOW=246.919968 <kmol/hr>
MOLE-FRAC METANOL 1.
BLOCK M-201 MIXER
IN-UNITS ENG
PARAM PRES=-0.3 <bar>
BLOCK E-201 HEATER
IN-UNITS ENG
PARAM TEMP=154. <C> PRES=15.1 <bar>
BLOCK E-203 HEATER
IN-UNITS ENG
PARAM TEMP=100. <C> PRES=13.4 <bar>
BLOCK E-208 HEATER
IN-UNITS ENG
PARAM TEMP=50. <C> PRES=-0.5 <bar>
BLOCK E-202 HEATX
IN-UNITS ENG
PARAM T-COLD=250. <C> PRES-COLD=14.7 <bar> U-OPTION=PHASE &
F-OPTION=CONSTANT CALC-METHOD=SHORTCUT
FEEDS HOT=6 COLD=4
PRODUCTS HOT=7 COLD=5
HOT-SIDE DP-OPTION=CONSTANT
COLD-SIDE DP-OPTION=CONSTANT
BLOCK T-201 RADFRAC
IN-UNITS SI MASS-FLOW='tonne/year' MOLE-FLOW='kmol/hr' &
PRESSURE=bar TEMPERATURE=C DELTA-T=C PDROP=bar
PARAM NSTAGE=22
COL-CONFIG CONDENSER=TOTAL
FEEDS 9 16
PRODUCTS 11 22 L / 10 1 L
P-SPEC 1 10.3
COL-SPECS D:F=0.3974927 DP-COL=0.2 MOLE-RR=0.41701745
SPEC 1 MOLE-FRAC 0.9991 COMPS=DMT STREAMS=10
VARY 1 MOLE-RR 0.3 5.
BLOCK T-202 RADFRAC
IN-UNITS SI MASS-FLOW='tonne/year' MOLE-FLOW='kmol/hr' &
PRESSURE=bar TEMPERATURE=C DELTA-T=C PDROP=bar
PARAM NSTAGE=26
COL-CONFIG CONDENSER=TOTAL
FEEDS 11 19
PRODUCTS 14 26 L / 13 1 L
P-SPEC 1 7.3
COL-SPECS D:F=0.3402385 DP-COL=0.3 MOLE-RR=2.44502269
178
BLOCK R-201 RPLUG
IN-UNITS ENG
PARAM TYPE=ADIABATIC LENGTH=13. <meter> DIAM=0.7 <meter> &
PDROP=0.8 <bar> CAT-PRESENT=NO
REACTIONS RXN-IDS=R-1
BLOCK P-201 PUMP
IN-UNITS ENG
PARAM PRES=15.5 <bar>
BLOCK P-202 PUMP
IN-UNITS ENG
PARAM PRES=15.5 <bar>
BLOCK V-200 VALVE
IN-UNITS ENG
PARAM P-OUT=10.4 <bar>
BLOCK V-201 VALVE
IN-UNITS ENG
PARAM P-OUT=1.2 <bar>
EO-CONV-OPTI
CONV-OPTIONS
PARAM SPEC-METHOD=BROYDEN
WEGSTEIN MAXIT=100
BROYDEN MAXIT=100
STREAM-REPOR PROPERTIES=IPE-1 IPE-2 IPE-3
REACTIONS R-1 POWERLAW
IN-UNITS ENG
REAC-DATA 1 PHASE=V
RATE-CON 1 PRE-EXP=0.336 ACT-ENERGY=80480. <kJ/kmol> &
T-REF=25. <C>
STOIC 1 MIXED METANOL -2. / AGUA 1. / DMT 1.
POWLAW-EXP 1 MIXED METANOL 8.4
179
Proceso de Producción de Dimetiletanolamina
IN-UNITS MET
COMPONENTS
ETHYL-01 C2H4O-2 /
DIMET-01 C2H7N-2 /
DIMET-02 C4H11NO
FLOWSHEET
BLOCK REACTOR IN=ALIM-R OUT=SAL-R
BLOCK MEZCLADO IN=DMA OET DMA-R TORRE-R OUT=MEZCLA
BLOCK ENFRIADO IN=MEZCLA OUT=ALIM-R
BLOCK EVAP IN=SAL-R OUT=ALIM-T
BLOCK TANQUE IN=ALIM-T OUT=DMA-R LIQ-T
BLOCK TORRE IN=LIQ-T OUT=TORRE-R PRODUCTO
PROPERTIES NRTL
PROPERTIES AMINES
PROP-SET IPE-1
IN-UNITS ENG
PROPNAME-LIS MASSVFRA MASSSFRA MASSFLMX VOLFLMX TEMP PRES &
MWMX MASSFLOW SUBSTREAM=ALL
PROP-SET IPE-2
IN-UNITS ENG
PROPNAME-LIS VOLFLMX MASSFLMX KMX SIGMAMX MUMX CPMX MWMX &
UNITS='kJ/kg-K' SUBSTREAM=MIXED PHASE=L
PROP-SET IPE-3
IN-UNITS ENG
PROPNAME-LIS VOLFLMX MASSFLMX KMX MUMX CPMX MWMX UNITS= &
'kJ/kg-K' SUBSTREAM=MIXED PHASE=V
STREAM DMA
IN-UNITS MET
SUBSTREAM MIXED TEMP=25. <C> PRES=1. MOLE-FLOW=118.98
MOLE-FRAC ETHYL-01 0. / DIMET-01 1. / DIMET-02 0.
STREAM OET
IN-UNITS MET
SUBSTREAM MIXED TEMP=25. <C> PRES=1. MOLE-FLOW=39.66
MOLE-FRAC ETHYL-01 1. / DIMET-01 0. / DIMET-02 0.
BLOCK MEZCLADO MIXER
IN-UNITS MET
BLOCK ENFRIADO HEATER
IN-UNITS MET
PARAM PRES=0. VFRAC=0.
BLOCK EVAP HEATER
IN-UNITS MET
PARAM PRES=0. VFRAC=0.65
180
BLOCK TANQUE FLASH2
IN-UNITS MET
PARAM PRES=0. DUTY=0.
BLOCK TORRE RADFRAC
IN-UNITS MET
PARAM NSTAGE=5
COL-CONFIG CONDENSER=PARTIAL-V
FEEDS LIQ-T 2
PRODUCTS TORRE-R 1 V / PRODUCTO 5 L
P-SPEC 1 1.
COL-SPECS D:F=0.12 MOLE-RR=1.
BLOCK REACTOR RCSTR
IN-UNITS ENG
PARAM VOL=200. <l> TEMP=40. <C> PRES=1. <atm> NPHASE=1 &
PHASE=L CAT-PRESENT=NO
BLOCK-OPTION FREE-WATER=NO
REACTIONS RXN-IDS=R-1
DESIGN-SPEC DS-1
IN-UNITS MET
DEFINE FDMA MOLE-FLOW STREAM=ALIM-R SUBSTREAM=MIXED &
COMPONENT=DIMET-01
DEFINE FOXET MOLE-FLOW STREAM=ALIM-R SUBSTREAM=MIXED &
COMPONENT=ETHYL-01
SPEC "FDMA/FOXET" TO "3"
TOL-SPEC ".05"
VARY STREAM-VAR STREAM=DMA SUBSTREAM=MIXED &
VARIABLE=MOLE-FLOW
LIMITS "30" "120"
EO-CONV-OPTI
SENSITIVITY S-1
IN-UNITS MET
DEFINE FDMEA MOLE-FLOW STREAM=ALIM-T SUBSTREAM=MIXED &
COMPONENT=DIMET-02
DEFINE LDMEA MOLE-FLOW STREAM=LIQ-T SUBSTREAM=MIXED &
COMPONENT=DIMET-02
DEFINE XDMEA MOLE-FRAC STREAM=LIQ-T SUBSTREAM=MIXED &
COMPONENT=DIMET-02
TABULATE 1 "FDMEA"
TABULATE 2 "LDMEA"
TABULATE 4 "XDMEA"
TABULATE 3 "LDMEA/FDMEA"
VARY BLOCK-VAR BLOCK=EVAP VARIABLE=VFRAC SENTENCE=PARAM
RANGE LOWER="0" UPPER="1" INCR=".05"
STREAM-REPOR MOLEFLOW MOLEFRAC PROPERTIES=IPE-1 IPE-2 IPE-3
REACTIONS R-1 GENERAL
IN-UNITS ENG
REAC-DATA 1 NAME=RX1 REAC-CLASS=EQUILIBRIUM DELT=25. <C>
STOIC 1 MIXED ETHYL-01 -1. / DIMET-01 -1. / DIMET-02 1.
181
