Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Jr.Super60_NUCLEUS & STERLING BT WTA-31/WTA-26 Date: 17-12-2023
Time: 09:00AM to 12:00PM JEE-ADV_(2021-P2) Max. Marks: 180

KEY SHEET
PHYSICS
1 BC 2 ABD 3 BCD 4 ABC 5 BCD 6 ABCD

7 5 8 5 9 24 10 6 11 4 12 0

13 A 14 D 15 C 16 D 17 2 18 2

19 7

CHEMISTRY
20 ACD 21 ABD 22 AD 23 BD 24 BD 25 CD

26 38 27 2 28 3 29 52 30 4 31 5

32 D 33 C 34 A 35 D 36 6 37 4

38 8

MATHEMATICS
39 AB 40 ABC 41 ACD 42 ACD 43 AB 44 BD

45 1 46 3 47 15 48 4 49 0 50 27

51 A 52 A 53 B 54 C 55 3 56 6

57 1
 Sri Chaitanya IIT Academy 17-12-2023_Jr.S60_NUCLEUS & STERLING BT_Jee-Adv(2021-P2)_WTA-31&WTA-26_Key & Sol’s

SOLUTIONS
PHYSICS
r
1. E
3 0
Slope of E-r graph gives 
2.

2 Q 2Q

2 0
1  cos 530  
5 0
2Q Q

2 0
1  cos 37 0  
5 0
dv
3. E
dr
q
4.  E.ds  enclosed
0
1
5. q1   kr4 r 2 dr   k
0
r
2k
q2   4 r 2 dr  4 kr 2  4 k
1
r
q net   k  4r 2  3
Electric potential just outside B is given as
Kq net
V
r
Total charge of configuration for rB  2 given as
q net  13 k
Electric field just outside B is given as
Kq net
E
r2
1  k  4r  3
2

E
4 0 r2
5
At rB  this electric field becomes
2
22 k
25  0

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 Sri Chaitanya IIT Academy 17-12-2023_Jr.S60_NUCLEUS & STERLING BT_Jee-Adv(2021-P2)_WTA-31&WTA-26_Key & Sol’s
1 P sin 
4 0 r 3 1 2P cos 
E
4 0 r3
 


6. P
P
Ez   2 cos 2   sin 2  
4 0 r 3 
R
7. Q    0 r 2 4 r 2 dr
0

KQ
E
r2
R
8. Q    0 r 2 4 r 2 dr
0

KQ
E 2
r
9. A1  10cm  30cm 
A1  300 cm 2  0.03m 2
1  EA1 cos 
1   7.8 10 4   0.03 cos1800
1  2.34 kNm 2C 1

d/2
10. Q  EA    x Adx
2
0
0

11. Dipole moment is given as

 p
p  0 i  j
2
 
Electric field at a point B along tangent Should be zero since circle is equipotential so
eternal electric field must be equal to the electric field of dipole at point B as shown in
figure below, thus net electric at point B is zero

Kp
E0  as E B  0
R3
Ko0  p0 
 R3   
E 0  4 0 E 0 

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1/3
 p0 
 R  
 4 0 E 0 

Total electric field at point A is given as vector sum of field due to dipole and external
field which is given as
EA 
2Kp Kp 3K p 0  
R3
 3  3
R R 2
i j  
EB
 0
EA
12. Dipole moment is given as
 p
 
p  0 i  j
2
Electric field at a point B along tangent Should be zero since circle is equipotential so
eternal electric field must be equal to the electric field of dipole at point B as shown in
figure below, thus net electric at point B is zero

Kp
E0  as E B  0
R3
Ko0  p0 
 R3   
E 0  4 0 E 0 
1/3
 p0 
 R  
 4 0 E 0 

Total electric field at point A is given as vector sum of field due to dipole and external
field which is given as
EA 
2Kp Kp 3K p 0  
R3
 3  3
R R 2
i j  
EB
 0
EA
4 R 3
R/2
13. Q1  0
4 r 2dr 
24
R
 r 
Q2   2 1  R 4 r dr
2

R /2

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 Sri Chaitanya IIT Academy 17-12-2023_Jr.S60_NUCLEUS & STERLING BT_Jee-Adv(2021-P2)_WTA-31&WTA-26_Key & Sol’s
Q1 4 R / 24 4 3
 
Q1  Q 2 15 R / 24 15
3

  q
  enclosed
E.ds
0
4 R 3
R/2
14. Q1  0
4 r 2dr 
24
R
 r 
Q2   2 1  R 4 r dr
2

R /2

Q1 4 R 3 / 24 4
 
Q1  Q 2 15 R / 24 15
3

  q
 E.ds  enclosed
0
15. The direction of electric field is x-y plane as shown in the figure.

The magnitude of electric field is

E  E 2x  E 2y  3  1  2 V / m
The direction of electric field is given by
Ey 1
 tan 1  300
Ex 3
Hence electric field
 
is normal to square frame LMNO as shown in figure.
 Electric flu  E.A  EA cos 0  2  1  2 V / m
Since flux is maximum at   600 , rotation by 300 either way would lead to decrease in
flux.
Line ON and NM are both normal to uniform electric field. Hence work done by
electric field as a point charge 1 C is taken from O to M is zero.
16. The direction of electric field is x-y plane as shown in the figure.

The magnitude of electric field is

E  E 2x  E 2y  3  1  2 V / m
The direction of electric field is given by
Ey 1
 tan 1  300
Ex 3
Hence electric field
 
is normal to square frame LMNO as shown in figure.
 Electric flu  E.A  EA cos 0  2  1  2 V / m

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 Sri Chaitanya IIT Academy 17-12-2023_Jr.S60_NUCLEUS & STERLING BT_Jee-Adv(2021-P2)_WTA-31&WTA-26_Key & Sol’s
Since flux is maximum at   600 , rotation by 300 either way would lead to decrease in
flux
  V  V  V 
17.  E    i j k 
 x y z 
V
 6  8y 2  8x
x
V
 16xy  8  6z
y
V
 6y
z
At(0,0,0)
V V V
 6,  8, 0
x y z

E  6i  8j
(0,0,0)

 E  10NC1
 
 F q E

 F  20N

18. r  2i  2j  k
P cos 
Vk
r2
K  2P0  3 1 4aq 7 7aq
19. E 1  
x 3
4 4 0 x 3 2 2 0 x 2
  7

CHEMISTRY
20. EAN  35
21. Fe is in +2 O.S.
22. Only (A) and (D) have ionisable Cl 
23. Conceptual
24. Conceptual
25.
O N

Co N
N
O N
4O  Co  N bond angles for each oygen
 80  Co  N for 1 cobalt.
 24 such angles for 3 cobalt.
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 Sri Chaitanya IIT Academy 17-12-2023_Jr.S60_NUCLEUS & STERLING BT_Jee-Adv(2021-P2)_WTA-31&WTA-26_Key & Sol’s
26. EAN  28  2  12  38
27.  Ni 2  5  C5 H 5  
 2

28. Cr  Co 6   24  6  2  36
4
 Fe  Ox 3   26  2  4  3  36
3
Cu  CN  4   29  1  4  2  36
2
 Ni  NH 3 6   28  2  6  2  38

29. EAN  45  1  8  52
30. 28  2  2  x  34  x  4
31. Formula of compound is  Fe  H 2O 2  en 2  py 2  2  SO4 3
Hence total moles of ions=5
32. A   Cr  H 2 O 6  Cl3
33. Quantitative ppt n of AgCl is required
34. ‘R’ gives maximum number of ions
1
35. Cr 3  C 2O 4  4  NH 3  0  ; EAN  24  3  12  33
 2 2 

36. General formula of alum is X 2SO 4 .Y2  SO 4  .24H 2O . It contain four cations two X  and
two Y3 and each one is coordinated by six water molecules
37. The SECONDARY valency of Pd in  Pd  NH3 4  Cl 2 is 4
38. y x  62 8

MATHEMATICS
39. Conceptual
40. Conceptual
41 Conceptual
42. Radical axis is 8x  12y  5  0
43.

A
S'  0

O C

x 2  y 2  16
OA  4
O  0, 0    x1 , y1 
AC  5
 OC  3  r
Slope of AB is 3/4  Slope of OC is tan   4 / 3  sin   4 / 5, cos   3 / 5

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 Sri Chaitanya IIT Academy 17-12-2023_Jr.S60_NUCLEUS & STERLING BT_Jee-Adv(2021-P2)_WTA-31&WTA-26_Key & Sol’s
Required centre  x1  r cos  , y1  r sin  
 9 12   9 12 
i.e.,   ,  or  ,  
 5 5  5 5
44.

P  5,6 

P  5, 6  ; PA  PB  10
Given circle S  x 2  y 2  16  0
Equation of circle with centre P and radius 10 is  x  5    y  6   102
2 2

S'  x 2  y 2  10  12y  39  0
Equation of line '  ' is S' S  0
i.e., 10x  12y  22  0
5x  6y  11  0
45. S1  S2  0  x  y  1  0....(1)
S2  S3  0  4x  y  7  0....(2)
Solving (1) and (2) , we get  x, y    2, 1
46. S1  S2  0  x  y  1  0....(1)
S2  S3  0  4x  y  7  0....(2)
Solving (1) and (2) , we get  x, y    2, 1
2 2
47.   tan 1    tan  
3
  3
2 3
 sin   and cos    A '   OA cos  , OA sin  
13 13
 A '   3, 2 
Similarly, B '   OBcos  ,OBsin     6, 4 
Now, A ' B '  r1  r2
So, circles touch each other eternally.
The point of contact C divides C1C2 internally in ratio r1 : r2
 13 2 13 13 2 13 
3 6 2 4 
C   3 3 , 3 3    5, 10 
 
 13 2 13 13 2 13   3 
   
 3 3 3 3 
Therefore, required radical axis is a line perpendicular to A 'B' and passing through
10 3
point C, which is y     x  5
3 2
2
48.   tan 1  
3 

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 Sri Chaitanya IIT Academy 17-12-2023_Jr.S60_NUCLEUS & STERLING BT_Jee-Adv(2021-P2)_WTA-31&WTA-26_Key & Sol’s
2
 tan  
3
2 3
 sin   and cos  
13 13
 A '   OA cos  , OA sin  
 A '   3, 2 
Similarly, B'   OBcos  ,OBsin     6, 4 
Now, A ' B '  r1  r2
So, circles touch each other eternally.
The point of contact C divides C1C2 internally in ratio r1 : r2
 13 2 13 13 2 13 
3 6 2 4 
C   3 3 , 3 3    5, 10 
 
 13 2 13 13 2 13   3 
   
 3 3 3 3 
Therefore, required radical axis is a line perpendicular to A 'B' and passing through
10 3
point C, which is y    x  5
3 2
49. The common chord is S1  S2  0
4x   y  1  0
A

(-4,0) M
C

 AC  Radius of first circle  15

AB
AM   6
2
 CM  3
16  1
 3
16   2
Or   3
50. The common chord is S1  S2  0
4x   y  1  0
A

(-4,0) M
C

 AC  Radius of first circle  15

AB
AM   6
2
 CM  3
16  1
 3 Or   3
16   2

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 Sri Chaitanya IIT Academy 17-12-2023_Jr.S60_NUCLEUS & STERLING BT_Jee-Adv(2021-P2)_WTA-31&WTA-26_Key & Sol’s
51,52. The given circles are
S1  x 2  y 2  4x  22y  a  0.......(i) and
S2  x 2  y 2  2x  8y  b  0.......(ii)
The equation of common chord is S1  S2  0
 6x  14y   a  b   0..........(iii)
Since circle (i) bisects the circumference of circle(ii), so common chord passes through
centre(1,-4) of 2nd circle.
Hence, 6  56  a  b  0
 a  b  50
Now using A.M.-G.M. inequality, we get
ab
 ab
2
 ab  625
Hence, maimum value of (ab) equals 625.
53. S1  0, C1  1, 1 ,S2  0, C 2  2, 3 / 2  , r2  17 / 4
Common chord is 2x  y  1  0
2  1  1 2
d 
5 5
2 4
Length  2 r 2  d 2  2 1  
55
Equation of circle is 5  x  y   2x  6y  1  0
2 2

54. S1  0, C1  1, 1 ,S2  0, C 2  2, 3 / 2  , r2  17 / 4

Common chord is 2x  y  1  0
2  1  1 2
d 
5 5
2 4
Length  2 r 2  d 2  2 1  
55
Equation of circle is 5  x  y   2x  6y  1  0
2 2

55. common chord in 4 x  ky  1  0

2 r2  d 2  2 6  k  3
2r1r2
56.
r12  r22
57. Let r be the radius of second circle, then
 x  1   y  3  8
2 2

 x  4    y  3  r 2
2 2

Radical axis is  x  4    x  1  r 2  8
2 2

But given R.A is =0

 r 2  23

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