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ICSEians Chemistry Prelim - 01

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84 views12 pages

ICSEians Chemistry Prelim - 01

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radhikadaksh1983
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‭ AIITS- All India ICSEians Test Series (Science-2 Chemistry Prelim -01)‬

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‭ICSEians Chemistry Prelim- 01‬


‭ ime: 2 hours + 15 mins
T Maximum Marks: 80‬
‭Grade: 10th ICSE Subject: Chemistry‬

‭(SECTION- A)‬
‭ uestion: 1‬
Q
‭Choose the correct option for the given questions: [15 x 1= 15] :‬
‭1.‬ ‭The arrangement of elements in the Modern Periodic Table is based on:‬
‭(a) increasing atomic number in the group.‬
‭(b) increasing atomic mass in the group.‬

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‭(c) increasing atomic number in the period.‬
‭(d) increasing atomic mass in the group.‬

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‭2.‬ ‭When fused Lead Bromide is electrolysed, we observe:‬
‭(a) Silver- grey metal is deposited at the Anode and reddish- brown gas is‬
‭liberated at the Cathode.‬
‭(b) Silver- grey metal is deposited at the Cathode and reddish- brown gas‬
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‭is liberated at the Anode.‬
‭(c) Silver- grey fumes are liberated at the Cathode and Reddish- brown‬
‭metal is deposited at the Anode.‬
‭(d) Silver- grey fumes at the anode and Reddish- brown metal deposited‬
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‭at the Cathode.‬

‭3.‬ ‭Assertion (A):‬‭Copper (II) oxide is a base but not an alkali.‬


‭Reason (R):‬‭Copper (II) oxide is soluble in water.‬
‭IC

‭(a) Both (A) and (R) are true and (R) is the correct explanation of (A).‬
‭(b) Both (A) and (R) are true but (R) is not the correct explanation of (A).‬
‭(c) (A) is true, but (R) is false.‬
‭(d) (A) is false, but (R) is true.‬

‭4.‬ ‭A 10.0g sample of a mixture of Calcium Chloride and Sodium Chloride is‬
‭treated with Sodium Carbonate to precipitate the Calcium as Calcium‬
‭Carbonate. This Calcium Carbonate is heated to convert all the Calcium‬
‭to Calcium Oxide and the final mass of CaO is 1.62g. The % by mass of‬
‭CaCl‬‭2‬ ‭in the original mixture is:‬
‭1‬
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(‭ a) 15.2% (b) 32.1% (c) 21.8% (d) 11.07%‬
‭5.‬ ‭A solution of Potassium hydroxide is poured into two test tubes A and B.‬
‭Phenolphthalein is added to A and Methyl orange is added to B. W, X, Y‬
‭and Z are four observations made regarding the colour changes in each‬
‭test tube. Which of the observations below correctly shows the colour‬
‭changes in both of the test tubes ?‬
‭Phenolphthalein in A‬ ‭Phenolphthalein in B‬
‭W‬ ‭Pink to colourless‬ ‭Pink to orange‬
‭X‬ ‭Remains pink‬ ‭Remains orange‬

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‭Y‬ ‭Colourless to Pink‬ ‭Orange to Yellow‬
‭Z‬ ‭Remains Colourless‬ ‭Yellow to orange‬

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‭(a) W (b) X (c) Y (d) Z‬

‭6.‬ ‭The compound formed by the complete chlorination of ethyne is:‬


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‭(a) 1,1,2,2- tetrachloroethane‬
‭(b) 1,2,1,2- tetrachloroethane‬
‭(c) 1,2,2- trichloroethane‬
‭(d) 1,1,2- trichloroethane‬
SE

‭7.‬ ‭C‭2‬ ‬‭H‬‭2‬ ‭+ 2 Hydrogen‬‭(Ni, 200‬‭o‭C



)→………………‬‭.‬‭Which of the following‬
‭is true for the given reaction ?‬
‭(a) The intermediate product is unsaturated while the final product is‬
‭saturated alkene.‬
‭IC

‭(b) The intermediate product is unsaturated while the final product is‬
‭saturated alkane.‬
‭(c) The reaction stops after a one step reaction.‬
‭(d) This is an example of a substitution reaction.‬

‭8.‬ ‭Which of the following is true for aqueous ammonia ?‬


‭(a) its pH is > 7.‬
‭(b) its pH is < 7.‬
‭(c) it has pH = 7.‬

‭2‬
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‭(d) it has pH in the range 4 to 6.‬

‭9.‬ ‭If a laboratory experiment is conducted to replicate the purification of‬


‭bauxite to alumina using the Bayer’s process, which of the following‬
‭observations would indicate the process is proceeding correctly ?‬
‭(a) The temperature of the reaction mixture decreases steadily.‬
‭(b) A white precipitate forms when sodium hydroxide is added to‬
‭Bauxite.‬
‭(c) The reaction mixture turns pink upon addition of sodium hydroxide.‬
‭(d) Bubbles of oxygen gas are released during the reaction.‬

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‭10.‬‭In a hypothetical scenario where the scrubbing tower fails during the‬
‭Contact process, what would be the most likely consequence ?‬

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‭(a) An increase in the purity of the sulphuric acid.‬
‭(b) The emission of unreacted sulphur dioxide into the atmosphere.‬
‭(c) The formation of a higher concentration of oleum.‬
‭(d) The sulphuric acid produced would have a higher viscosity.‬
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‭11.‬‭Which of the following best describes the energy change when an ionic‬
‭bond is formed between a metal and a non- metal ?‬
‭A. Energy is absorbed when a metal atom loses an electron and a non-‬
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‭metal gains an electron.‬


‭B. Energy is released when a metal atom loses an electron and a non-‬
‭metal gains an electron.‬
‭C. Energy is neither released nor absorbed because the reaction is‬
‭isothermal.‬
‭IC

‭D. Energy is first absorbed and then released in equal amounts, making‬
‭the overall energy change zero.‬
‭(a) Only A (b) Only B (c) Only C (d) None of the above‬

‭12.‬‭A chemist combines a solution containing magnesium ions with a‬


‭solution that contains carbonate ions. A white precipitate forms upon‬
‭mixing. Which of the following reactions represents this process ?‬
‭(a) Mg‬‭2+‬ ‭+ CO‬‭3‭2‬ -‬ ‭→ MgCO‬‭3‬
‭(b) Mg‬‭2+‬ ‭+ 20H‬‭-‬ ‭→ Mg(OH)‬‭2‬
‭3‬
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(‭ c) Mg‬‭2+‬ ‭+ SO‬‭4‭2‬ -‬ ‭→ Mg‬‭2‭S
‬ O‬‭4‬
‭2+‬ ‭1-‬
‭(d) Mg‬ ‭+ 2NO‬‭3‬ ‭→Mg(SO‬‭3‭)‬ ‬

‭13.‬‭The basicity of Phosphoric acid is:‬


‭(a) 1 (b) 2 (c) 3 (d) 4‬

‭14.‬‭2.7g of Ag‬‭2‭C
‬ O‬‭3‬‭on being heated strongly yields a residue weighing:‬
‭(a) 2.11g (b) 2.48g (c) 2.32g (d) 2.64g‬

‭15.‬‭A student investigated the effect of heat on Copper (II) Nitrate crystals in‬
‭a test- tube. She observed that a brown gas P was given off, and a black‬

S‬
‭solid Q remained in the test- tube. She added solution S to dissolve the‬
‭solid Q remained in the test- tube. She added solution S to dissolve the‬

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‭solid. Which of the following correctly identifies the substances P, Q and‬
‭S ?‬
‭ eddish‬
R ‭Black Solid Q‬ ‭Solution S‬
‭Brown Gas P‬
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‭(a)‬ ‭nitrogen‬ ‭copper‬ ‭ odium‬
S
‭hydroxide‬
‭(b)‬ ‭Nitrogen‬ ‭ opper (II)‬
C ‭ ydrochloric‬
H
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‭oxide‬ ‭Acid‬
‭(c)‬ ‭ itrogen‬
N ‭Copper‬ ‭ odium‬
S
‭dioxide‬ ‭hydroxide‬
‭(d)‬ ‭ itrogen‬
N ‭ opper (II)‬
C ‭ ydrochloric‬
H
‭IC

‭dioxide‬ ‭Oxide‬ ‭Acid‬


‭ uestion: 2‬
Q
‭(i) Complete the following sentences by choosing the correct answers‬
‭from the brackets: [5 x 1= 5]‬
‭(a) The number of hydrogen atoms present in 1 mole of sulphuric acid‬
‭and 1 mole of sulphurous acid are (X) and (Y), respectively. Relationship‬
‭between X and Y is ___________. (X=Y/ cannot compare X and Y).‬

‭4‬
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(‭ b) Nikita wanted to gift her friend a decorative piece that is quite hard‬
‭and strong, does not get corroded and can be polished. She selected a‬
‭statue that matched her criteria as it was made of an alloy whose main‬
‭constituent was_________. (Zn/Cu)‬

(‭ c) If a hydrocarbon has the formula of C‬‭50‬‭H‬‭98‬‭, then it is likely to‬


‭undergo__________ reaction (addition/ substitution), and the‬
‭hydrocarbon is a/an __________ (saturated/unsaturated) hydrocarbon.‬
‭(d) The correct order of increasing volatility of the acids is___________.‬
‭(HCl < CH‬‭3‭C
‬ OOH < HNO‬‭3‬ ‭/ HCl < HNO‬‭3‬ ‭< CH‬‭3‭C
‬ OOH).‬

S‬
(‭ e) The Lanthanide series of inner transition elements are placed in the‬
‭__________ period. (sixth / seventh).‬

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‭(ii) Calculate the following: [5]‬
‭(a) A drug Marijuana owes its activity to tetrahydrocannabinol, which‬
‭contains 70% as many carbon atoms as hydrogen atoms as oxygen atoms.‬
‭The number of moles in a gram of tetrahydrocannabinol is 0.00318.‬
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‭Determine its molecular formula. [3]‬

(‭ b) A dot at the end of this sentence has a mass of about 1 microgram.‬


‭Assuming that the black stuff is carbon, calculate the approximate‬
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‭number of atoms of Carbon needed to make such a dot. (Given:‬


‭Avagadro’s number = 6.023 x 10‬‭23‬‭). [2]‬

(‭ iii)‬‭(a) State the position of following elements in the Modern Periodic‬


‭Table: [2]‬
‭IC

‭(1) Calcium‬
‭(2) Argon‬
‭(b) Draw an electron dot cross structure showing formation of‬
‭Ammonium ion. [3]‬

(‭ iv) Study the paragraph given and answer the questions that‬
‭follow:[5]‬

‭5‬
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‭ amkrishnan is a scrap dealer and wishes to obtain pure Copper from the‬
R
‭scrap Copper rod he got from the customer. He sets up an apparatus and‬
‭is able to obtain pure copper successfully.‬
‭(a) Name the process used by Ramkrishnan to obtain pure Copper metal.‬
‭(b) State the observation at Anode over a period of time.‬
‭(c) What should Ramkrishnan place at Cathode ?‬
‭(d) What chemical Ramkrishnan must have used as an electrolyte ?‬
‭(e) Ramkrishan finds some blackish- brown insoluble particles have‬
‭settled down at the bottom of the Anode. What is that called as ?‬

(‭ v) (1) Observe the reactions given below and answer the following‬

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‭questions: [4]‬

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(‭ a) Identify the compound P.‬


‭(b) Give the chemical formula of Z.‬
‭(c) Write the reaction taking place between the identified compound P‬
‭and sulphuric acid.‬
‭IC

‭(d) Name the compound Y.‬

‭6‬
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‭(2) State the IUPAC name of the following structure: [1]‬

S‬
(‭ Section- B)- 40 Marks‬
‭(Attempt any‬‭four‬‭set of questions out 6.)‬

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‭ uestion: 3 [10]‬
Q
‭(i) Ionisation energies of 4 elements A, B, C and D are 496, 403, 520 and 419‬
‭kJ/mol, respectively. If these elements belong to the same group in the Periodic‬
IA
‭Table, which element will occupy the top position in the group answer ? Justify‬
‭your answer. [2]‬

(‭ ii) A, B and C are three elements which undergo chemical reactions according‬
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‭to the following equations:‬


‭A‬‭2‬‭O‬‭3‬ ‭+ 2B → B‬‭2‭O
‬ ‬‭3‬ ‭+ 2A‬
‭3CSO‬‭4‬ ‭+ 2B → B‬‭2‭(‬ SO‬‭4‭)‬ ‬‭3‬ ‭+ 3C‬
‭3CO + 2A → A‬‭2‭O ‬ + 3C‬
‭Answer the following questions:‬
‭IC

‭(a) Which element is the most reactive ?‬


‭(b) Which element is the least reactive ?‬

(‭ iii) Why is pure Acetic Acid also called Glacial Acetic Acid ? [1]‬
‭Question: 4‬
‭(i) Ethyl alcohol is a colourless liquid. It is used as a major constituent in‬
‭alcoholic beverages and also in the manufacture of many chemicals. When a‬
‭Chemical Manufacturing Unit ordered ethyl alcohol, they were supplied with a‬
‭purple- coloured alcohol instead of a colourless one.‬
‭7‬
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‭State the reason and the purpose of this colour change. [1]‬

(‭ ii) Calcite (CaCO‬‭3‬‭), a sedimentary rock, is found most abundantly in many‬


‭geological environments. It has a perfect cleavage in 3 directions, which makes‬
‭it the most difficult rock to cut, and moreover, the labour of cutting calcite is‬
‭also very high. What term related to metallurgy will suitably describe Calcite in‬
‭the context of extracting calcium from calcite ? [1]‬

(‭ iii) Draw the structure of the following organic compound:‬‭2- methyl‬


‭butane‬‭.[2]‬

S‬
(‭ iv) LSD is a complex compound whose mass is made up of 74.27% carbon,‬
‭7.79% hydrogen, 12.99% nitrogen and 4.95% oxygen. What percent of the‬

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‭atoms in LSD are Carbon atoms ? [2]‬

‭(v) Give balanced equations for the following: [3]‬


‭(a)‬‭The reaction of aluminium with boiling concentrated sodium hydroxide‬
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‭solution.‬
‭(b)‬‭Dissociation of lead acetate solution.‬
‭(c)‬‭Heating of ethanol at 170‬‭o‭C

in the presence of concentrated sulphuric‬
‭acid.‬
SE

‭(vi) Hydrogen Chloride fumes in the air. Justify. [1]‬


‭Question: 5‬
‭(i) In the Haber’s process, the optimum yield of ammonia is obtained when a‬
‭temperature of 450‬‭o‭C ‬
-500‬‭o‬‭C, a pressure of 200 atmospheres, an iron catalyst‬
‭and promoter molybdenum are used.‬
‭IC

‭ ow and why would the yield of ammonia be affected if the temperature was‬
H
‭raised to 600‬‭o‭C

? [2]‬

(‭ ii) A student was asked to draw the flowchart for the extraction of zinc from‬
‭zinc blende based on the principles of Metallurgy. What he drew is given below.‬

‭8‬
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‭2 steps out of the 5 were incorrect. Identify and correct them. [2]‬

S‬
‭(iii) Name the alkyl component of acetic acid. [1]‬

‭(iv) 6.00gm of H‬‭2‬ ‭reacts with 29.00gm of O‬‭2‬ ‭to yield water. [3]‬

N
‭(a)‬‭Write the balanced equation for the above reaction.‬
‭(b)‬‭Calculate the maximum amount of H‬‭2‬‭O that can be formed.‬
‭(c)‬‭Calculate the amount of reactants which remains unreacted.‬
IA
‭(v) Brown ring test is used for the identification of nitrate ions. [2]‬
‭(a) Why is freshly prepared Ferrous sulphate solution used in the above test?‬
‭(b) What is the chemical name of the brown ring?‬
‭Question: 6‬
SE

‭(i) Identify the following: [5]‬


‭(a)‬‭A homogeneous mixture of two or more metals or a metal and a non-‬
‭metal in a definite proportion in their molten state.‬
‭(b)‬‭A reaction in which the hydrogen of an alkane is replaced by a halogen.‬
‭IC

‭(c)‬‭The amount of substance which contains the same number of units as the‬
‭number of atoms in carbon- 12.‬
‭(d)‬‭28g of nitrogen and 44g of carbon dioxide at the same conditions of‬
‭temperature and pressure occupy the same amount of space. What term‬
‭describes such space occupied by any gas ?‬
‭(e)‬‭Name a positive non-metallic ion which is basic in nature.‬

(‭ ii) Match the reactants in Column A to their methods of preparation in Column‬


‭B. [5]‬‭(answers can repeat).‬
‭9‬
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‭Column A‬ ‭Column B‬
‭(a)‬ ‭Zinc Oxide + Sulphuric Acid‬ ‭(i)‬ ‭Synthesis Reaction‬
‭(b)‬ ‭Iron + Chlorine‬ ‭(ii)‬ ‭Precipitation Reaction‬
‭(c)‬ B
‭ arium Chloride + Sodium‬ ‭(iii)‬ ‭Neutralisation Reaction‬
‭Sulphate‬
‭(d)‬ M
‭ agnesium + Hydrochloric‬ ‭(iv)‬ ‭Neutralisation by Titration‬
‭Acid‬
‭(e)‬ P
‭ otassium Hydroxide + Nitric‬ ‭(v)‬ ‭Displacement‬

S‬
‭Acid‬
‭ uestion: 7‬
Q
‭(i) Calculate the following: [5]‬

N
‭(a)‬‭In an experiment, it is found that 2.0769g of pure X produces‬
‭3.6769g of pure X‬‭2‭O ‬ ‭5‬ ‭.‬ The number of moles of X is ? [2]‬
‭(b)‬‭An element ‘X’ reacts with hydrogen leading to the formation of a‬
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‭class of compounds that is analogous to hydrocarbons. 5.00g of ‘X’‬
‭forms 5.625g of a mixture of two compounds of ‘X’- (XH‬‭4‬ ‭& X‬‭2‭H‬ ‬‭6‭)
‬‬
‭in the molar ratio 2:1. Determine the molar mass of X. [2]‬
‭(c)‬‭The number of moles of‬‭Fullerene‬‭(C‬‭60‬‭) in 1.44kg‬‭Fullerene‬‭are ? [1]‬
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‭(ii) Complete the following table: [5]‬


‭Oxidising Agent‬ ‭Effective Change‬ ‭ ecrease in Oxidation‬
D
‭Number‬
‭IC

‭KMnO‬‭4‬ ‭in acid solution.‬ ‭MnO‬‭-‬ ‭→ Mn‬‭2+‬ ‭(i)‬


‭ MnO‬‭4‬‭in neutral‬
K ‭3‬
‭solution.‬ ‭(ii)‬
‭ IO‬‭3‬ ‭in concentrated‬
K ‭4‬
‭acid.‬ ‭(iii)‬
‭(iv)‬ ‭Cl‬‭2‬‭→ Cl‬‭-.‬ ‭1‬
‭K‭2‬ ‬‭Cr‬‭2‬‭O‬‭7‬ ‭in acid‬

‭10‬
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‭2-‬ ‭3+‬
‭solution.‬ ‭Cr‬‭2‭O
‬ ‬‭7‬ ‭→ Cr‬ ‭(v)‬
‭ uestion: 8‬
Q
‭(i) A compound with molecular formula, C‬‭3‭H
‬ ‭8‬ ‭O
‬ reacts with sodium metal‬
‭to evolve hydrogen gas. What are the possible structures of the compound?‬
‭[2]‬

(‭ ii) Name a molecule which contains both a single and a double bond‬
‭between carbon and oxygen atom. [2]‬

‭(iii) What is the valency of Carbon in CH‬‭3‬‭—— CH‬‭3‬‭, CH‬‭2‬ ‭=CH‬‭2‬‭, and‬

S‬
‭CH ≡ CH ? [1]‬

N
(‭ iv) Given below in column A is a schematic diagram of the electrolytic‬
‭reduction of alumina. Identify the parts labelled as A, B and C with the‬
‭correct options from the Column B. [3]‬
IA
SE
‭IC

(‭ v) What weight of AgCl will be precipitated when a solution containing‬


‭4.77g of NaCl is added to a solution of 5.77g of AgNO‬‭3‬ ‭? [2]‬

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‭11‬
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‭Our Centres- Varanasi | Kandivali | Borivali | Marol | Dadar | Matunga | Vile Parle | Dahisar (E) | Lucknow |‬
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‭Any query regarding the paper or AIITS contact us on‬‭[email protected]‬‭or 9867814567 / 9588333344‬
‭ AIITS- All India ICSEians Test Series (Science-2 Chemistry Prelim -01)‬
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S‬
N
IA
SE
‭IC

‭12‬
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‭Our Centres- Varanasi | Kandivali | Borivali | Marol | Dadar | Matunga | Vile Parle | Dahisar (E) | Lucknow |‬
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