Kurdistan Region – Iraq 0001 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _

High Committee for General Examinations

General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
A 13. Aqueous solution of NH3 is an Arrhenius base because:
A. it is proton accepter. B. it increases the concentration of hydronium ion.
C.it is an electron pair donor. D.it increases the concentration of hydroxide ion.
SN: 6000081
(science)
Answer the following questions : ( two marks for each right choice ) 14. While mixing a small quantity of water with a large quantity of ethanol, water considered as :-
1. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are contained A. solvent B. solute C. solution D. none of them
per 250g of water? 15. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for
A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol transition interval is (3.1- 4.4):
2. Which one of the following statements is incorrect? A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH
A. Many solids dissolve more quickly in a cold solvent than in warm solvent. 16. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :-
B. Gases are generally more soluble in water at low temperature. A. 3.1 B. 3.7 C. 10.9 D. 10.3
C. Aqueous solution is a mixture containing the solute soluble in water as a solvent. 17. The rate of the slow reaction increases by :
D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute A. the addition of a catalyst. B. increasing activation energy
surface is increased. C. increasing concentration. D. Both (A+C) are correct
3. The boiling point of a solution is higher than that of a pure solvent because :- 18. All of the following statements are true about the collision theory except:
A. Vapor-pressure lowering B. Freezing- point heightening A. all collisions between particles of reactant leads to the occurrence of the chemical reaction
C. Vapor-pressure heightening D. none of them B. the reaction rate is directly proportional with the number of effective collision.
4. A substance that can react as an acid or a base : C. in order for chemical reaction to occur, the reacting particles must collide
A. SO42- B. HSO3- C.CH3COO- D. NH4+ D. the particles of reactants must have enough energy to initiate the reaction.
19. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the
5. Which of the following solutions with the same concentrations has lower [H3O+]?
concentration of both reactants is doubled?
A. HCl B. H2O C. NH3 D. HF
A. the reaction rate remains the same. B. the reaction rate increases by a factor of two.
6. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight.
about the reaction ?
20. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O
A. The reaction is always spontaneous. B. The reaction is never spontaneous.
fast :N2O+H2 →N2+H2O which of the following is correct ?
C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature.
A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O
7. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal C. the reaction order is second D. Both (A+C) are correct
50kJ/mol ,the activation energy for reverse reaction is equal to
21. The energy required to raise the reactant to the level of the activated complex is:
A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol
A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction
8. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals : 22. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ?
-
A. 184.6kJ/mol B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol
9. Adding NH4Cl to NH3 solution leads to: 23. A substance that formed when a strong acid has lost a proton
A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+] A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations
10. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion? 24. For an exothermic dissolution process, the increasing of the temperature causes:
A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct

11. The net ionic equation for the precipitation Nickel ( II )sulfide is : 25. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the
A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s) right ?
C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water. A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure

12. When barium chloride solution is mixed with sodium nitrate: 26. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct?
A. sodium chloride precipitates B. barium nitrate precipitates A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound.
C. precipitation does not occur D. Both ( A + B ) are correct C. a liquid is polar molecular compound. D. none of them
27. All of them are correct except: 41. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M
A. An ionic compound at solid state does not conduct electric current. the value of the equilibrium constant equals:
B. Alloy is a mixture the atoms of two or more metals are uniformly mixed. A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84
C. The Brownian motion is a motion due to collision rapidly moving molecules. 42. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the
D. HCl does not soluble in water. concentration of carbonate ions is:
28. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M
nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant? 43. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if :
A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined
29. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is: 44. Which of the following ions hydrolyze in aqueous solution?
A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2 A.NO3- B. CO32- C. SO42- D. none of them is correct
30. When polar compound ionizes completely in water the compound is: 45. The common-ion causes:
A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte. A. increasing precipitation. B. decreasing ionization.
31. The dilute aqueous solution of a weak acid contains: C. shifting equilibrium to left. D. all of them are correct.
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct 46. Which of the following is homogenous mixture?
32. Which of the following is the equilibrium constant for an anion hydrolysis reaction? A. milk B. 24-karat gold C. tap water D. oil and water
[HB][OH− ] [B− ] [HB] [B− ][OH− ]
A. B. C. D. 47. Which of the following is a binary acid?
[B− ] [HB][OH− ] [B− ][OH− ] [HB]
A. H2S B.H2CO3 C. H2O2 D. all of them are correct
33. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base?
48. The solution that contains the precisely known concentration of a solute is known as:
A.F- B. BF3 C. BF4- D. none of them is correct A. saturated solution B. dilute solution C. standard solution D. buffer solution
34. The strength of an acid does not depend on: 49. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is;
A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy A. SO42- B. Al+3 C. H3O+ D. all of them are correct.
C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct 50. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct?
35. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous.
solution? C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous.
A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M
36. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat
is 0.449J/g.K?
A. 202kJ B.27.83J C.1002J D. 202J A
37. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is
called:
A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat
38. Which of the following represents the formation equation?
A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2
39. The entropy increases at:
A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct
40. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature,
what would be the value of that constant for the reverse reaction at the same condition?
A. 0.05 B. 0.1 C. 10 D. 5
 Kurdistan Region – Iraq 0002 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
B 14. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the
concentration of both reactants is doubled?
A. the reaction rate remains the same. B. the reaction rate increases by a factor of two.
SN: 6000082
(science) C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight.
Answer the following questions : ( two marks for each right choice )
1. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a 15. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat
nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant? is 0.449J/g.K?
A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m A. 202kJ B.27.83J C.1002J D. 202J

2. Adding NH4Cl to NH3 solution leads to: 16. The net ionic equation for the precipitation Nickel ( II )sulfide is :
A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+] A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s)
C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water.
3. A substance that formed when a strong acid has lost a proton
A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations 17. The energy required to raise the reactant to the level of the activated complex is:
A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction
4. Which of the following is a binary acid?
A. H2S B.H2CO3 C. H2O2 D. all of them are correct 18. Which of the following is homogenous mixture?
A. milk B. 24-karat gold C. tap water D. oil and water
5. Which of the following represents the formation equation?
A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2 19. A substance that can react as an acid or a base :
A. SO42- B. HSO3- C.CH3COO- D. NH4+
6. While mixing a small quantity of water with a large quantity of ethanol, water considered as :-
A. solvent B. solute C. solution D. none of them 20. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct?
7. The strength of an acid does not depend on: A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous.
A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous.
C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct 21. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature,
8. The dilute aqueous solution of a weak acid contains: what would be the value of that constant for the reverse reaction at the same condition?
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct A. 0.05 B. 0.1 C. 10 D. 5
9. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is 22. Which of the following ions hydrolyze in aqueous solution?
called: A.NO3- B. CO32- C. SO42- D. none of them is correct
A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat
23. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :-
10. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are A. 3.1 B. 3.7 C. 10.9 D. 10.3
contained per 250g of water?
A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol 24. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is;
A. SO42- B. Al+3 C. H3O+ D. all of them are correct.
11. Which of the following is the equilibrium constant for an anion hydrolysis reaction?
[HB][OH− ] [B− ] [HB] [B− ][OH− ] 25. All of them are correct except:
A. B. C. D. A. An ionic compound at solid state does not conduct electric current.
[B− ] [HB][OH− ] [B− ][OH− ] [HB]
B. Alloy is a mixture the atoms of two or more metals are uniformly mixed.
12. For an exothermic dissolution process, the increasing of the temperature causes:
C. The Brownian motion is a motion due to collision rapidly moving molecules.
A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct
D. HCl does not soluble in water.
13. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O
26. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct?
fast :N2O+H2 →N2+H2O which of the following is correct ?
A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound.
A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O
C. a liquid is polar molecular compound. D. none of them
C. the reaction order is second D. Both (A+C) are correct
27. The boiling point of a solution is higher than that of a pure solvent because :-
A. Vapor-pressure lowering B. Freezing- point heightening
C. Vapor-pressure heightening D. none of them
28. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if : 43. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base?
A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined
A.F- B. BF3 C. BF4- D. none of them is correct
29. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the
right ? 44. When polar compound ionizes completely in water the compound is:
A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte.

30. When barium chloride solution is mixed with sodium nitrate: 45. All of the following statements are true about the collision theory except:
A. sodium chloride precipitates B. barium nitrate precipitates A. all collisions between particles of reactant leads to the occurrence of the chemical reaction
C. precipitation does not occur D. Both ( A + B ) are correct B. the reaction rate is directly proportional with the number of effective collision.
C. in order for chemical reaction to occur, the reacting particles must collide
31. The solution that contains the precisely known concentration of a solute is known as:
D. the particles of reactants must have enough energy to initiate the reaction.
A. saturated solution B. dilute solution C. standard solution D. buffer solution
46. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is:
32. The common-ion causes:
A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2
A. increasing precipitation. B. decreasing ionization.
C. shifting equilibrium to left. D. all of them are correct. 47. The rate of the slow reaction increases by :
A. the addition of a catalyst. B. increasing activation energy
33. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals :
C. increasing concentration. D. Both (A+C) are correct
-
A. 184.6kJ/mol B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol
48. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M
34. Which of the following solutions with the same concentrations has lower [H3O+]? the value of the equilibrium constant equals:
A. HCl B. H2O C. NH3 D. HF A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84
35. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal 49. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of
50kJ/mol ,the activation energy for reverse reaction is equal to solution?
A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M
36. Aqueous solution of NH3 is an Arrhenius base because: 50. Which one of the following statements is incorrect?
A. it is proton accepter. B. it increases the concentration of hydronium ion. A. Many solids dissolve more quickly in a cold solvent than in warm solvent.
C.it is an electron pair donor. D.it increases the concentration of hydroxide ion. B. Gases are generally more soluble in water at low temperature.
37. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ? C. Aqueous solution is a mixture containing the solute soluble in water as a solvent.
A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute
surface is increased.
38. The entropy increases at:
A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct
39. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion?
A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol B
40. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the
concentration of carbonate ions is:
A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M
41. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true
about the reaction ?
A. The reaction is always spontaneous. B. The reaction is never spontaneous.
C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature.
42. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for
transition interval is (3.1- 4.4):
A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH
 Kurdistan Region – Iraq 0003 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
C 12. All of them are correct except:
A. An ionic compound at solid state does not conduct electric current.
B. Alloy is a mixture the atoms of two or more metals are uniformly mixed.
SN: 6000083
(science) C. The Brownian motion is a motion due to collision rapidly moving molecules.
Answer the following questions : ( two marks for each right choice )
D. HCl does not soluble in water.
1. The net ionic equation for the precipitation Nickel ( II )sulfide is :
A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s) 13. All of the following statements are true about the collision theory except:
C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water. A. all collisions between particles of reactant leads to the occurrence of the chemical reaction
B. the reaction rate is directly proportional with the number of effective collision.
2. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals : C. in order for chemical reaction to occur, the reacting particles must collide
-
A. 184.6kJ/mol B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol D. the particles of reactants must have enough energy to initiate the reaction.
3. Which one of the following statements is incorrect? 14. The strength of an acid does not depend on:
A. Many solids dissolve more quickly in a cold solvent than in warm solvent. A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy
B. Gases are generally more soluble in water at low temperature. C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct
C. Aqueous solution is a mixture containing the solute soluble in water as a solvent. 15. Which of the following is the equilibrium constant for an anion hydrolysis reaction?
D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute [HB][OH− ] [B− ] [HB] [B− ][OH− ]
A. B. C. D.
surface is increased. [B− ] [HB][OH− ] [B− ][OH− ] [HB]

4. The energy required to raise the reactant to the level of the activated complex is: 16. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of
A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction solution?
5. Which of the following is homogenous mixture? A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M
A. milk B. 24-karat gold C. tap water D. oil and water 17. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat
6. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal is 0.449J/g.K?
50kJ/mol ,the activation energy for reverse reaction is equal to A. 202kJ B.27.83J C.1002J D. 202J
A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol 18. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is
7. When barium chloride solution is mixed with sodium nitrate: called:
A. sodium chloride precipitates B. barium nitrate precipitates A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat
C. precipitation does not occur D. Both ( A + B ) are correct 19. While mixing a small quantity of water with a large quantity of ethanol, water considered as :-
8. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature, A. solvent B. solute C. solution D. none of them
what would be the value of that constant for the reverse reaction at the same condition? 20. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is;
A. 0.05 B. 0.1 C. 10 D. 5 A. SO42- B. Al+3 C. H3O+ D. all of them are correct.

9. The dilute aqueous solution of a weak acid contains: 21. Which of the following is a binary acid?
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct A. H2S B.H2CO3 C. H2O2 D. all of them are correct

10. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the 22. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M
concentration of carbonate ions is: the value of the equilibrium constant equals:
A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84

11. For an exothermic dissolution process, the increasing of the temperature causes: 23. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the
A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct right ?
A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure
24. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :-
A. 3.1 B. 3.7 C. 10.9 D. 10.3
25. A substance that can react as an acid or a base : 40. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ?
A. SO42- B. HSO3- C.CH3COO- D. NH4+ A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol
41. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for
26. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion?
transition interval is (3.1- 4.4):
A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol
A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH
27. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct?
42. The solution that contains the precisely known concentration of a solute is known as:
A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous. A. saturated solution B. dilute solution C. standard solution D. buffer solution
C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous.
43. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the
28. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are concentration of both reactants is doubled?
contained per 250g of water? A. the reaction rate remains the same. B. the reaction rate increases by a factor of two.
A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight.
29. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a 44. Adding NH4Cl to NH3 solution leads to:
nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant? A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+]
A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
45. When polar compound ionizes completely in water the compound is:
30. The rate of the slow reaction increases by : A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte.
A. the addition of a catalyst. B. increasing activation energy
46. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is:
C. increasing concentration. D. Both (A+C) are correct
A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2
31. The common-ion causes:
47. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct?
A. increasing precipitation. B. decreasing ionization.
A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound.
C. shifting equilibrium to left. D. all of them are correct.
C. a liquid is polar molecular compound. D. none of them
32. Aqueous solution of NH3 is an Arrhenius base because:
A. it is proton accepter. B. it increases the concentration of hydronium ion. 48. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base?
C.it is an electron pair donor. D.it increases the concentration of hydroxide ion. A.F- B. BF3 C. BF4- D. none of them is correct
33. The entropy increases at: 49. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if :
A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined
34. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true 50. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O
about the reaction ? fast :N2O+H2 →N2+H2O which of the following is correct ?
A. The reaction is always spontaneous. B. The reaction is never spontaneous. A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O
C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature. C. the reaction order is second D. Both (A+C) are correct
35. The boiling point of a solution is higher than that of a pure solvent because :-
A. Vapor-pressure lowering B. Freezing- point heightening
C. Vapor-pressure heightening D. none of them
36. A substance that formed when a strong acid has lost a proton C
A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations
37. Which of the following ions hydrolyze in aqueous solution?
A.NO3- B. CO32- C. SO42- D. none of them is correct
38. Which of the following represents the formation equation?
A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2
39. Which of the following solutions with the same concentrations has lower [H3O+]?
A. HCl B. H2O C. NH3 D. HF
 Kurdistan Region – Iraq 0004 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
D 13. Adding NH4Cl to NH3 solution leads to:
A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+]
SN: 6000084 14. Which of the following is the equilibrium constant for an anion hydrolysis reaction?
(science) [HB][OH− ] [B− ] [HB] [B− ][OH− ]
Answer the following questions : ( two marks for each right choice ) A. B. C. D.
[B− ] [HB][OH− ] [B− ][OH− ] [HB]
1. The energy required to raise the reactant to the level of the activated complex is:
A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction 15. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for
transition interval is (3.1- 4.4):
2. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature, A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH
what would be the value of that constant for the reverse reaction at the same condition?
A. 0.05 B. 0.1 C. 10 D. 5 16. The dilute aqueous solution of a weak acid contains:
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct
3. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base? 17. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is:
A.F- B. BF3 C. BF4- D. none of them is correct A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2

4. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct? 18. The strength of an acid does not depend on:
A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound. A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy
C. a liquid is polar molecular compound. D. none of them C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct

5. The rate of the slow reaction increases by : 19. The solution that contains the precisely known concentration of a solute is known as:
A. the addition of a catalyst. B. increasing activation energy A. saturated solution B. dilute solution C. standard solution D. buffer solution
C. increasing concentration. D. Both (A+C) are correct 20. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true
6. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are contained about the reaction ?
per 250g of water? A. The reaction is always spontaneous. B. The reaction is never spontaneous.
A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature.

7. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion? 21. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of
A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol solution?
A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M
8. A substance that formed when a strong acid has lost a proton
A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations 22. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal
50kJ/mol ,the activation energy for reverse reaction is equal to
9. Aqueous solution of NH3 is an Arrhenius base because:
A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol
A. it is proton accepter. B. it increases the concentration of hydronium ion.
C.it is an electron pair donor. D.it increases the concentration of hydroxide ion. 23. The net ionic equation for the precipitation Nickel ( II )sulfide is :
10. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s)
is 0.449J/g.K? C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water.
A. 202kJ B.27.83J C.1002J D. 202J 24. A substance that can react as an acid or a base :
11. All of them are correct except: A. SO42- B. HSO3- C.CH3COO- D. NH4+
A. An ionic compound at solid state does not conduct electric current.
25. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if :
B. Alloy is a mixture the atoms of two or more metals are uniformly mixed.
A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined
C. The Brownian motion is a motion due to collision rapidly moving molecules.
D. HCl does not soluble in water. 26. Which of the following solutions with the same concentrations has lower [H3O+]?
A. HCl B. H2O C. NH3 D. HF
12. The common-ion causes:
A. increasing precipitation. B. decreasing ionization.
C. shifting equilibrium to left. D. all of them are correct.
27. All of the following statements are true about the collision theory except: 41. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals :
A. all collisions between particles of reactant leads to the occurrence of the chemical reaction A. 184.6kJ/mol -
B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol
B. the reaction rate is directly proportional with the number of effective collision.
C. in order for chemical reaction to occur, the reacting particles must collide 42. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M
D. the particles of reactants must have enough energy to initiate the reaction. the value of the equilibrium constant equals:
A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84
28. While mixing a small quantity of water with a large quantity of ethanol, water considered as :-
A. solvent B. solute C. solution D. none of them 43. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is
called:
29. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat
concentration of both reactants is doubled?
A. the reaction rate remains the same. B. the reaction rate increases by a factor of two. 44. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O
C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight. fast :N2O+H2 →N2+H2O which of the following is correct ?
A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O
30. For an exothermic dissolution process, the increasing of the temperature causes: C. the reaction order is second D. Both (A+C) are correct
A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct
45. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the
31. The boiling point of a solution is higher than that of a pure solvent because :- concentration of carbonate ions is:
A. Vapor-pressure lowering B. Freezing- point heightening A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M
C. Vapor-pressure heightening D. none of them
46. Which of the following represents the formation equation?
32. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is; A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2
A. SO42- B. Al+3 C. H3O+ D. all of them are correct.
47. Which of the following is a binary acid?
33. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ? A. H2S B.H2CO3 C. H2O2 D. all of them are correct
A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol
48. Which of the following is homogenous mixture?
34. When polar compound ionizes completely in water the compound is: A. milk B. 24-karat gold C. tap water D. oil and water
A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte.
49. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the
35. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :- right ?
A. 3.1 B. 3.7 C. 10.9 D. 10.3 A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure
36. When barium chloride solution is mixed with sodium nitrate: 50. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a
A. sodium chloride precipitates B. barium nitrate precipitates nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant?
C. precipitation does not occur D. Both ( A + B ) are correct A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
37. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct?
A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous.
C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous.
38. Which one of the following statements is incorrect? D
A. Many solids dissolve more quickly in a cold solvent than in warm solvent.
B. Gases are generally more soluble in water at low temperature.
C. Aqueous solution is a mixture containing the solute soluble in water as a solvent.
D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute
surface is increased.
39. The entropy increases at:
A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct
40. Which of the following ions hydrolyze in aqueous solution?
A.NO3- B. CO32- C. SO42- D. none of them is correct
 Kurdistan Region – Iraq 0005 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
E 12. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct?
A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous.
SN: 6000085 C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous.
(science)
Answer the following questions : ( two marks for each right choice ) 13. The net ionic equation for the precipitation Nickel ( II )sulfide is :
1. A substance that formed when a strong acid has lost a proton A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s)
A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water.
2. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if : 14. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct?
A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound.
C. a liquid is polar molecular compound. D. none of them
3. Which one of the following statements is incorrect?
A. Many solids dissolve more quickly in a cold solvent than in warm solvent. 15. All of the following statements are true about the collision theory except:
B. Gases are generally more soluble in water at low temperature. A. all collisions between particles of reactant leads to the occurrence of the chemical reaction
C. Aqueous solution is a mixture containing the solute soluble in water as a solvent. B. the reaction rate is directly proportional with the number of effective collision.
D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute C. in order for chemical reaction to occur, the reacting particles must collide
surface is increased. D. the particles of reactants must have enough energy to initiate the reaction.
4. A substance that can react as an acid or a base : 16. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :-
A. SO42- B. HSO3- C.CH3COO- D. NH4+ A. 3.1 B. 3.7 C. 10.9 D. 10.3
17. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is;
5. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat is
A. SO42- B. Al+3 C. H3O+ D. all of them are correct.
0.449J/g.K?
A. 202kJ B.27.83J C.1002J D. 202J 18. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion?
6. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol
concentration of carbonate ions is: 19. The boiling point of a solution is higher than that of a pure solvent because :-
A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M A. Vapor-pressure lowering B. Freezing- point heightening
7. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal C. Vapor-pressure heightening D. none of them
50kJ/mol ,the activation energy for reverse reaction is equal to 20. For an exothermic dissolution process, the increasing of the temperature causes:
A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct

8. The rate of the slow reaction increases by : 21. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is:
A. the addition of a catalyst. B. increasing activation energy A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2
C. increasing concentration. D. Both (A+C) are correct 22. The solution that contains the precisely known concentration of a solute is known as:
9. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the right A. saturated solution B. dilute solution C. standard solution D. buffer solution
?
23. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base?
A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure
A.F- B. BF3 C. BF4- D. none of them is correct
10. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] what happens to the reaction rate when the
2,

concentration of both reactants is doubled? 24. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of
A. the reaction rate remains the same. B. the reaction rate increases by a factor of two. solution?
C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight. A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M
11. Which of the following represents the formation equation? 25. Adding NH4Cl to NH3 solution leads to:
A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2 A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+]
26. The entropy increases at:
A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct
27. All of them are correct except: 42. Aqueous solution of NH3 is an Arrhenius base because:
A. An ionic compound at solid state does not conduct electric current. A. it is proton accepter. B. it increases the concentration of hydronium ion.
B. Alloy is a mixture the atoms of two or more metals are uniformly mixed. C.it is an electron pair donor. D.it increases the concentration of hydroxide ion.
C. The Brownian motion is a motion due to collision rapidly moving molecules. 43. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are
D. HCl does not soluble in water. contained per 250g of water?
28. Which of the following solutions with the same concentrations has lower [H3O+]? A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol
A. HCl B. H2O C. NH3 D. HF 44. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature,
29. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M what would be the value of that constant for the reverse reaction at the same condition?
the value of the equilibrium constant equals: A. 0.05 B. 0.1 C. 10 D. 5
A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84
45. When barium chloride solution is mixed with sodium nitrate:
30. Which of the following ions hydrolyze in aqueous solution? A. sodium chloride precipitates B. barium nitrate precipitates
A.NO3- B. CO32- C. SO42- D. none of them is correct C. precipitation does not occur D. Both ( A + B ) are correct
31. Which of the following is homogenous mixture? 46. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O
A. milk B. 24-karat gold C. tap water D. oil and water fast :N2O+H2 →N2+H2O which of the following is correct ?
32. The dilute aqueous solution of a weak acid contains: A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct C. the reaction order is second D. Both (A+C) are correct
33. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a 47. While mixing a small quantity of water with a large quantity of ethanol, water considered as :-
nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant? A. solvent B. solute C. solution D. none of them
A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m 48. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ?
34. Which of the following is a binary acid? A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol
A. H2S B.H2CO3 C. H2O2 D. all of them are correct 49. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true
35. Which of the following is the equilibrium constant for an anion hydrolysis reaction? about the reaction ?
[HB][OH− ] [B− ] [HB] [B− ][OH− ] A. The reaction is always spontaneous. B. The reaction is never spontaneous.
A. B. C. D.
[B− ] [HB][OH− ] [B− ][OH− ] [HB]
C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature.
36. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals : 50. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for
-
A. 184.6kJ/mol B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol transition interval is (3.1- 4.4):
37. The energy required to raise the reactant to the level of the activated complex is: A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH
A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction
38. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is
called:
A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat
E
39. When polar compound ionizes completely in water the compound is:
A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte.
40. The common-ion causes:
A. increasing precipitation. B. decreasing ionization.
C. shifting equilibrium to left. D. all of them are correct.
41. The strength of an acid does not depend on:
A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy
C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct
 Kurdistan Region – Iraq 0006 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
F 13. While mixing a small quantity of water with a large quantity of ethanol, water considered as :-
A. solvent B. solute C. solution D. none of them
SN: 6000086 14. Adding NH4Cl to NH3 solution leads to:
(science)
Answer the following questions : ( two marks for each right choice ) A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+]
1. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for 15. Which of the following ions hydrolyze in aqueous solution?
transition interval is (3.1- 4.4): A.NO3- B. CO32- C. SO42- D. none of them is correct
A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH 16. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the
2. The common-ion causes: concentration of carbonate ions is:
A. increasing precipitation. B. decreasing ionization. A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M
C. shifting equilibrium to left. D. all of them are correct. 17. Which of the following represents the formation equation?
3. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct? A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2
A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound. 18. Which of the following is a binary acid?
C. a liquid is polar molecular compound. D. none of them A. H2S B.H2CO3 C. H2O2 D. all of them are correct
4. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base? 19. When barium chloride solution is mixed with sodium nitrate:
A.F- B. BF3 C. BF4- D. none of them is correct A. sodium chloride precipitates B. barium nitrate precipitates
C. precipitation does not occur D. Both ( A + B ) are correct
5. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the right
20. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if :
?
A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined
A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure
21. Aqueous solution of NH3 is an Arrhenius base because:
6. Which of the following solutions with the same concentrations has lower [H3O+]?
A. it is proton accepter. B. it increases the concentration of hydronium ion.
A. HCl B. H2O C. NH3 D. HF
C.it is an electron pair donor. D.it increases the concentration of hydroxide ion.
7. Which of the following is the equilibrium constant for an anion hydrolysis reaction?
[HB][OH− ] [B− ] [HB] [B− ][OH− ] 22. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal
A. B. C. D. 50kJ/mol ,the activation energy for reverse reaction is equal to
[B− ] [HB][OH− ] [B− ][OH− ] [HB]

8. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct? A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol
A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous. 23. The solution that contains the precisely known concentration of a solute is known as:
C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous. A. saturated solution B. dilute solution C. standard solution D. buffer solution

9. A substance that formed when a strong acid has lost a proton 24. The net ionic equation for the precipitation Nickel ( II )sulfide is :
A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s)
C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water.
10. All of them are correct except:
A. An ionic compound at solid state does not conduct electric current. 25. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion?
B. Alloy is a mixture the atoms of two or more metals are uniformly mixed. A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol
C. The Brownian motion is a motion due to collision rapidly moving molecules. 26. A substance that can react as an acid or a base :
D. HCl does not soluble in water.
A. SO42- B. HSO3- C.CH3COO- D. NH4+
11. The strength of an acid does not depend on:
A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy 27. Which one of the following statements is incorrect?
C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct A. Many solids dissolve more quickly in a cold solvent than in warm solvent.
B. Gases are generally more soluble in water at low temperature.
12. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :- C. Aqueous solution is a mixture containing the solute soluble in water as a solvent.
A. 3.1 B. 3.7 C. 10.9 D. 10.3 D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute
surface is increased.
28. The rate of the slow reaction increases by : 42. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O
A. the addition of a catalyst. B. increasing activation energy fast :N2O+H2 →N2+H2O which of the following is correct ?
C. increasing concentration. D. Both (A+C) are correct A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O
29. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature, C. the reaction order is second D. Both (A+C) are correct
what would be the value of that constant for the reverse reaction at the same condition? 43. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M
A. 0.05 B. 0.1 C. 10 D. 5 the value of the equilibrium constant equals:
A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84
30. The dilute aqueous solution of a weak acid contains:
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct 44. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is
called:
31. The entropy increases at: A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat
A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct
45. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat
32. The energy required to raise the reactant to the level of the activated complex is: is 0.449J/g.K?
A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction A. 202kJ B.27.83J C.1002J D. 202J
33. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals : 46. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are
-
A. 184.6kJ/mol B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol contained per 250g of water?
A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol
34. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true
about the reaction ? 47. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ?
A. The reaction is always spontaneous. B. The reaction is never spontaneous. A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol
C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature. 48. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the
35. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is; concentration of both reactants is doubled?
A. SO42- B. Al+3 C. H3O+ D. all of them are correct. A. the reaction rate remains the same. B. the reaction rate increases by a factor of two.
C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight.
36. For an exothermic dissolution process, the increasing of the temperature causes:
A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct 49. When polar compound ionizes completely in water the compound is:
A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte.
37. Which of the following is homogenous mixture?
A. milk B. 24-karat gold C. tap water D. oil and water 50. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is:
A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2
38. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a
nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant?
A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
39. All of the following statements are true about the collision theory except:
A. all collisions between particles of reactant leads to the occurrence of the chemical reaction
F
B. the reaction rate is directly proportional with the number of effective collision.
C. in order for chemical reaction to occur, the reacting particles must collide
D. the particles of reactants must have enough energy to initiate the reaction.
40. The boiling point of a solution is higher than that of a pure solvent because :-
A. Vapor-pressure lowering B. Freezing- point heightening
C. Vapor-pressure heightening D. none of them
41. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of
solution?
A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M
 Kurdistan Region – Iraq 0007 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
G 11. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O
fast :N2O+H2 →N2+H2O which of the following is correct ?
A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O
SN: 6000087
(science) C. the reaction order is second D. Both (A+C) are correct
Answer the following questions : ( two marks for each right choice )
1. Which of the following is homogenous mixture? 12. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true
A. milk B. 24-karat gold C. tap water D. oil and water about the reaction ?
A. The reaction is always spontaneous. B. The reaction is never spontaneous.
2. Which one of the following statements is incorrect?
C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature.
A. Many solids dissolve more quickly in a cold solvent than in warm solvent.
B. Gases are generally more soluble in water at low temperature. 13. Which of the following ions hydrolyze in aqueous solution?
C. Aqueous solution is a mixture containing the solute soluble in water as a solvent. A.NO3- B. CO32- C. SO42- D. none of them is correct
D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute 14. The common-ion causes:
surface is increased. A. increasing precipitation. B. decreasing ionization.
3. The net ionic equation for the precipitation Nickel ( II )sulfide is : C. shifting equilibrium to left. D. all of them are correct.
A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s) 15. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal
C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water. 50kJ/mol ,the activation energy for reverse reaction is equal to
4. Which of the following is a binary acid? A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol
A. H2S B.H2CO3 C. H2O2 D. all of them are correct 16. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct?
5. All of the following statements are true about the collision theory except: A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound.
A. all collisions between particles of reactant leads to the occurrence of the chemical reaction C. a liquid is polar molecular compound. D. none of them
B. the reaction rate is directly proportional with the number of effective collision. 17. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the
C. in order for chemical reaction to occur, the reacting particles must collide concentration of carbonate ions is:
D. the particles of reactants must have enough energy to initiate the reaction. A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M
6. When barium chloride solution is mixed with sodium nitrate: 18. The energy required to raise the reactant to the level of the activated complex is:
A. sodium chloride precipitates B. barium nitrate precipitates A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction
C. precipitation does not occur D. Both ( A + B ) are correct
19. For an exothermic dissolution process, the increasing of the temperature causes:
7. All of them are correct except: A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct
A. An ionic compound at solid state does not conduct electric current.
B. Alloy is a mixture the atoms of two or more metals are uniformly mixed. 20. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of
C. The Brownian motion is a motion due to collision rapidly moving molecules. solution?
D. HCl does not soluble in water. A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M
21. Adding NH4Cl to NH3 solution leads to:
8. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base?
A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+]
A.F- B. BF3 C. BF4- D. none of them is correct
22. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a
9. Which of the following represents the formation equation? nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant?
A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2 A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
10. Which of the following is the equilibrium constant for an anion hydrolysis reaction? 23. The solution that contains the precisely known concentration of a solute is known as:
[HB][OH− ] [B− ] [HB] [B− ][OH− ]
A. B. C. D. A. saturated solution B. dilute solution C. standard solution D. buffer solution
[B− ] [HB][OH− ] [B− ][OH− ] [HB]
24. A substance that formed when a strong acid has lost a proton
A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations
25. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is; 39. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for
A. SO42- B. Al+3 C. H3O+ D. all of them are correct. transition interval is (3.1- 4.4):
26. A substance that can react as an acid or a base : A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH

A. SO42- B. HSO3- C.CH3COO- D. NH4+ 40. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the
right ?
27. When polar compound ionizes completely in water the compound is: A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure
A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte.
41. Aqueous solution of NH3 is an Arrhenius base because:
28. The entropy increases at: A. it is proton accepter. B. it increases the concentration of hydronium ion.
A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct C.it is an electron pair donor. D.it increases the concentration of hydroxide ion.
29. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals : 42. While mixing a small quantity of water with a large quantity of ethanol, water considered as :-
-
A. 184.6kJ/mol B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol A. solvent B. solute C. solution D. none of them
30. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat 43. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if :
is 0.449J/g.K? A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined
A. 202kJ B.27.83J C.1002J D. 202J 44. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ?
31. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol
concentration of both reactants is doubled? 45. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is:
A. the reaction rate remains the same. B. the reaction rate increases by a factor of two. A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2
C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight.
46. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M
32. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is the value of the equilibrium constant equals:
called: A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84
A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat
47. Which of the following solutions with the same concentrations has lower [H3O+]?
33. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct? A. HCl B. H2O C. NH3 D. HF
A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous.
48. The rate of the slow reaction increases by :
C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous. A. the addition of a catalyst. B. increasing activation energy
34. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :- C. increasing concentration. D. Both (A+C) are correct
A. 3.1 B. 3.7 C. 10.9 D. 10.3 49. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion?
35. The strength of an acid does not depend on: A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol
A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy
50. The boiling point of a solution is higher than that of a pure solvent because :-
C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct
A. Vapor-pressure lowering B. Freezing- point heightening
36. The dilute aqueous solution of a weak acid contains: C. Vapor-pressure heightening D. none of them
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct
37. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature,
what would be the value of that constant for the reverse reaction at the same condition?
A. 0.05 B. 0.1 C. 10 D. 5 G
38. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are
contained per 250g of water?
A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol
 Kurdistan Region – Iraq 0008 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
H 13. Which one of the following statements is incorrect?
A. Many solids dissolve more quickly in a cold solvent than in warm solvent.
B. Gases are generally more soluble in water at low temperature.
SN: 6000088
(science) C. Aqueous solution is a mixture containing the solute soluble in water as a solvent.
Answer the following questions : ( two marks for each right choice )
D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute
1. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat is surface is increased.
0.449J/g.K?
A. 202kJ B.27.83J C.1002J D. 202J 14. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals :
-
A. 184.6kJ/mol B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol
2. Adding NH4Cl to NH3 solution leads to:
A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+] 15. The boiling point of a solution is higher than that of a pure solvent because :-
3. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion? A. Vapor-pressure lowering B. Freezing- point heightening
C. Vapor-pressure heightening D. none of them
A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol
16. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is;
4. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true
A. SO42- B. Al+3 C. H3O+ D. all of them are correct.
about the reaction ?
A. The reaction is always spontaneous. B. The reaction is never spontaneous. 17. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ?
C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature. A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol

5. When barium chloride solution is mixed with sodium nitrate: 18. The energy required to raise the reactant to the level of the activated complex is:
A. sodium chloride precipitates B. barium nitrate precipitates A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction
C. precipitation does not occur D. Both ( A + B ) are correct 19. Which of the following solutions with the same concentrations has lower [H3O+]?
6. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are contained A. HCl B. H2O C. NH3 D. HF
per 250g of water? 20. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M
A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol the value of the equilibrium constant equals:
7. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the right A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84
? 21. The entropy increases at:
A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct
8. For an exothermic dissolution process, the increasing of the temperature causes: 22. A substance that can react as an acid or a base :
A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct
A. SO42- B. HSO3- C.CH3COO- D. NH4+
9. Which of the following is the equilibrium constant for an anion hydrolysis reaction?
[HB][OH− ] [B− ] [HB] [B− ][OH− ]
23. A substance that formed when a strong acid has lost a proton
A. B. C. D. A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations
[B− ] [HB][OH− ] [B− ][OH− ] [HB]

10. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :- 24. Which of the following represents the formation equation?
A. 3.1 B. 3.7 C. 10.9 D. 10.3 A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2

11. Which of the following ions hydrolyze in aqueous solution? 25. All of the following statements are true about the collision theory except:
A.NO3- B. CO32- C. SO42- D. none of them is correct A. all collisions between particles of reactant leads to the occurrence of the chemical reaction
B. the reaction rate is directly proportional with the number of effective collision.
12. Which of the following is homogenous mixture?
C. in order for chemical reaction to occur, the reacting particles must collide
A. milk B. 24-karat gold C. tap water D. oil and water
D. the particles of reactants must have enough energy to initiate the reaction.

26. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base?
A.F- B. BF3 C. BF4- D. none of them is correct
27. The common-ion causes: 41. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature,
A. increasing precipitation. B. decreasing ionization. what would be the value of that constant for the reverse reaction at the same condition?
C. shifting equilibrium to left. D. all of them are correct. A. 0.05 B. 0.1 C. 10 D. 5
28. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the 42. All of them are correct except:
concentration of carbonate ions is: A. An ionic compound at solid state does not conduct electric current.
A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M B. Alloy is a mixture the atoms of two or more metals are uniformly mixed.
29. The dilute aqueous solution of a weak acid contains: C. The Brownian motion is a motion due to collision rapidly moving molecules.
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct D. HCl does not soluble in water.
30. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is 43. When polar compound ionizes completely in water the compound is:
called: A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte.
A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat 44. Which of the following is a binary acid?
31. The solution that contains the precisely known concentration of a solute is known as: A. H2S B.H2CO3 C. H2O2 D. all of them are correct
A. saturated solution B. dilute solution C. standard solution D. buffer solution 45. The rate of the slow reaction increases by :
32. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal A. the addition of a catalyst. B. increasing activation energy
50kJ/mol ,the activation energy for reverse reaction is equal to C. increasing concentration. D. Both (A+C) are correct
A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol 46. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for
33. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is: transition interval is (3.1- 4.4):
A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2 A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH

34. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct? 47. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of
A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound. solution?
C. a liquid is polar molecular compound. D. none of them A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M
35. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the 48. Aqueous solution of NH3 is an Arrhenius base because:
concentration of both reactants is doubled? A. it is proton accepter. B. it increases the concentration of hydronium ion.
A. the reaction rate remains the same. B. the reaction rate increases by a factor of two. C.it is an electron pair donor. D.it increases the concentration of hydroxide ion.
C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight. 49. The net ionic equation for the precipitation Nickel ( II )sulfide is :
36. The strength of an acid does not depend on: A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s)
A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water.
C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct 50. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct?
37. While mixing a small quantity of water with a large quantity of ethanol, water considered as :- A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous.
A. solvent B. solute C. solution D. none of them C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous.
38. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if :
A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined
39. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a
nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant? H
A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
40. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O
fast :N2O+H2 →N2+H2O which of the following is correct ?
A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O
C. the reaction order is second D. Both (A+C) are correct
 Kurdistan Region – Iraq 0009 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
I 13. Which of the following is a binary acid?
A. H2S B.H2CO3 C. H2O2 D. all of them are correct
SN: 6000089 14. The solution that contains the precisely known concentration of a solute is known as:
(science)
Answer the following questions : ( two marks for each right choice ) A. saturated solution B. dilute solution C. standard solution D. buffer solution
1. The rate of the slow reaction increases by : 15. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ?
A. the addition of a catalyst. B. increasing activation energy A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol
C. increasing concentration. D. Both (A+C) are correct
16. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true
2. Which of the following solutions with the same concentrations has lower [H3O+]? about the reaction ?
A. HCl B. H2O C. NH3 D. HF A. The reaction is always spontaneous. B. The reaction is never spontaneous.
3. While mixing a small quantity of water with a large quantity of ethanol, water considered as :- C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature.
A. solvent B. solute C. solution D. none of them 17. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base?
4. The boiling point of a solution is higher than that of a pure solvent because :-
A.F- B. BF3 C. BF4- D. none of them is correct
A. Vapor-pressure lowering B. Freezing- point heightening
C. Vapor-pressure heightening D. none of them 18. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :-
A. 3.1 B. 3.7 C. 10.9 D. 10.3
5. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature,
what would be the value of that constant for the reverse reaction at the same condition? 19. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct?
A. 0.05 B. 0.1 C. 10 D. 5 A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous.
C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous.
6. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if :
A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined 20. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the
right ?
7. The strength of an acid does not depend on:
A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure
A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy
C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct 21. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat
is 0.449J/g.K?
8. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal
A. 202kJ B.27.83J C.1002J D. 202J
50kJ/mol ,the activation energy for reverse reaction is equal to
A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol 22. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion?
A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol
9. Adding NH4Cl to NH3 solution leads to:
A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+] 23. Aqueous solution of NH3 is an Arrhenius base because:
A. it is proton accepter. B. it increases the concentration of hydronium ion.
10. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the
C.it is an electron pair donor. D.it increases the concentration of hydroxide ion.
concentration of carbonate ions is:
A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M 24. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a
nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant?
11. Which one of the following statements is incorrect?
A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
A. Many solids dissolve more quickly in a cold solvent than in warm solvent.
B. Gases are generally more soluble in water at low temperature. 25. When polar compound ionizes completely in water the compound is:
C. Aqueous solution is a mixture containing the solute soluble in water as a solvent. A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte.
D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute 26. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O
surface is increased. fast :N2O+H2 →N2+H2O which of the following is correct ?
12. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O
called: C. the reaction order is second D. Both (A+C) are correct
A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat
27. The entropy increases at: 41. The net ionic equation for the precipitation Nickel ( II )sulfide is :
A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s)
28. All of the following statements are true about the collision theory except: C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water.
A. all collisions between particles of reactant leads to the occurrence of the chemical reaction 42. Which of the following is homogenous mixture?
B. the reaction rate is directly proportional with the number of effective collision. A. milk B. 24-karat gold C. tap water D. oil and water
C. in order for chemical reaction to occur, the reacting particles must collide 43. When barium chloride solution is mixed with sodium nitrate:
D. the particles of reactants must have enough energy to initiate the reaction. A. sodium chloride precipitates B. barium nitrate precipitates
29. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of C. precipitation does not occur D. Both ( A + B ) are correct
solution? 44. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct?
A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound.
30. For an exothermic dissolution process, the increasing of the temperature causes: C. a liquid is polar molecular compound. D. none of them
A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct 45. A substance that can react as an acid or a base :
31. A substance that formed when a strong acid has lost a proton A. SO42- B. HSO3- C.CH3COO- D. NH4+
A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations
46. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is:
32. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] what happens to the reaction rate when the
2,
A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2
concentration of both reactants is doubled?
47. The common-ion causes:
A. the reaction rate remains the same. B. the reaction rate increases by a factor of two.
A. increasing precipitation. B. decreasing ionization.
C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight.
C. shifting equilibrium to left. D. all of them are correct.
33. All of them are correct except:
48. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for
A. An ionic compound at solid state does not conduct electric current.
transition interval is (3.1- 4.4):
B. Alloy is a mixture the atoms of two or more metals are uniformly mixed.
A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH
C. The Brownian motion is a motion due to collision rapidly moving molecules.
D. HCl does not soluble in water. 49. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals :
-
A. 184.6kJ/mol B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol
34. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is;
A. SO42- B. Al+3 C. H3O+ D. all of them are correct. 50. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M
35. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are the value of the equilibrium constant equals:
contained per 250g of water? A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84
A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol
36. Which of the following represents the formation equation?
A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2
37. The energy required to raise the reactant to the level of the activated complex is:
D. CO 2 →C(graphite) +O2
I
A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction
38. The dilute aqueous solution of a weak acid contains:
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct
39. Which of the following is the equilibrium constant for an anion hydrolysis reaction?
[HB][OH− ] [B− ] [HB] [B− ][OH− ]
A. B. C. D.
[B− ] [HB][OH− ] [B− ][OH− ] [HB]

40. Which of the following ions hydrolyze in aqueous solution?

A.NO3- B. CO32- C. SO42- D. none of them is correct
 Kurdistan Region – Iraq 0010 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
J 13. Which of the following ions hydrolyze in aqueous solution?
A.NO3- B. CO32- C. SO42- D. none of them is correct
SN: 6000090 14. The solution that contains the precisely known concentration of a solute is known as:
(science)
Answer the following questions : ( two marks for each right choice ) A. saturated solution B. dilute solution C. standard solution D. buffer solution
1. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O 15. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the
fast :N2O+H2 →N2+H2O which of the following is correct ? concentration of carbonate ions is:
A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M
C. the reaction order is second D. Both (A+C) are correct 16. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for
2. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ? transition interval is (3.1- 4.4):
A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH
3. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if : 17. Adding NH4Cl to NH3 solution leads to:
A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+]

4. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base? 18. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion?
A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol
A.F- B. BF3 C. BF4- D. none of them is correct
19. When polar compound ionizes completely in water the compound is:
5. All of the following statements are true about the collision theory except: A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte.
A. all collisions between particles of reactant leads to the occurrence of the chemical reaction
B. the reaction rate is directly proportional with the number of effective collision. 20. The boiling point of a solution is higher than that of a pure solvent because :-
C. in order for chemical reaction to occur, the reacting particles must collide A. Vapor-pressure lowering B. Freezing- point heightening
D. the particles of reactants must have enough energy to initiate the reaction. C. Vapor-pressure heightening D. none of them

6. For an exothermic dissolution process, the increasing of the temperature causes: 21. The strength of an acid does not depend on:
A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy
C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct
7. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M
the value of the equilibrium constant equals: 22. The rate of the slow reaction increases by :
A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84 A. the addition of a catalyst. B. increasing activation energy
C. increasing concentration. D. Both (A+C) are correct
8. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the right
? 23. Which of the following solutions with the same concentrations has lower [H3O+]?
A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure A. HCl B. H2O C. NH3 D. HF

9. Which of the following is a binary acid? 24. The energy required to raise the reactant to the level of the activated complex is:
A. H2S B.H2CO3 C. H2O2 D. all of them are correct A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction

10. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the 25. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :-
concentration of both reactants is doubled? A. 3.1 B. 3.7 C. 10.9 D. 10.3
A. the reaction rate remains the same. B. the reaction rate increases by a factor of two. 26. When barium chloride solution is mixed with sodium nitrate:
C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight. A. sodium chloride precipitates B. barium nitrate precipitates
11. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are C. precipitation does not occur D. Both ( A + B ) are correct
contained per 250g of water? 27. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is;
A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol A. SO42- B. Al+3 C. H3O+ D. all of them are correct.
12. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is: 28. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature,
A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2 what would be the value of that constant for the reverse reaction at the same condition?
A. 0.05 B. 0.1 C. 10 D. 5
29. The net ionic equation for the precipitation Nickel ( II )sulfide is : 41. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals :
A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s) A. 184.6kJ/mol -
B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol
C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water.
42. The common-ion causes:
30. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is A. increasing precipitation. B. decreasing ionization.
called: C. shifting equilibrium to left. D. all of them are correct.
A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat
43. A substance that formed when a strong acid has lost a proton
31. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations
50kJ/mol ,the activation energy for reverse reaction is equal to
A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol 44. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of
solution?
32. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M
about the reaction ?
45. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct?
A. The reaction is always spontaneous. B. The reaction is never spontaneous.
C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature. A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous.
C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous.
33. The dilute aqueous solution of a weak acid contains:
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct 46. Which of the following is homogenous mixture?
A. milk B. 24-karat gold C. tap water D. oil and water
34. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat
is 0.449J/g.K? 47. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a
A. 202kJ B.27.83J C.1002J D. 202J nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant?
A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
35. Aqueous solution of NH3 is an Arrhenius base because:
A. it is proton accepter. B. it increases the concentration of hydronium ion. 48. Which of the following represents the formation equation?
C.it is an electron pair donor. D.it increases the concentration of hydroxide ion. A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2
36. A substance that can react as an acid or a base : 49. The entropy increases at:
A. SO42- B. HSO3- C.CH3COO- D. NH4+ A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct
50. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct?
37. Which of the following is the equilibrium constant for an anion hydrolysis reaction?
[HB][OH− ] [B− ] [HB] [B− ][OH− ] A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound.
A. B. C. D. C. a liquid is polar molecular compound. D. none of them
[B− ] [HB][OH− ] [B− ][OH− ] [HB]

38. Which one of the following statements is incorrect?

A. Many solids dissolve more quickly in a cold solvent than in warm solvent.
B. Gases are generally more soluble in water at low temperature.
C. Aqueous solution is a mixture containing the solute soluble in water as a solvent. J
D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute
surface is increased.
39. While mixing a small quantity of water with a large quantity of ethanol, water considered as :-
A. solvent B. solute C. solution D. none of them
40. All of them are correct except:
A. An ionic compound at solid state does not conduct electric current.
B. Alloy is a mixture the atoms of two or more metals are uniformly mixed.
C. The Brownian motion is a motion due to collision rapidly moving molecules.
D. HCl does not soluble in water.
 Kurdistan Region – Iraq 0011 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
K 13. Which of the following is the equilibrium constant for an anion hydrolysis reaction?
A.
[HB][OH− ]
[B− ]
B.
[B− ]
[HB][OH− ]
C.
[HB]
[B− ][OH− ]
D.
[B− ][OH− ]
[HB]
SN: 6000091
(science) 14. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M
Answer the following questions : ( two marks for each right choice )
the value of the equilibrium constant equals:
1. For an exothermic dissolution process, the increasing of the temperature causes: A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84
A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct
15. The net ionic equation for the precipitation Nickel ( II )sulfide is :
2. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct? A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s)
A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound. C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water.
C. a liquid is polar molecular compound. D. none of them
16. Which of the following solutions with the same concentrations has lower [H3O+]?
3. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :- A. HCl B. H2O C. NH3 D. HF
A. 3.1 B. 3.7 C. 10.9 D. 10.3
17. Which of the following represents the formation equation?
4. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion? A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2
A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol
18. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for
5. Which one of the following statements is incorrect? transition interval is (3.1- 4.4):
A. Many solids dissolve more quickly in a cold solvent than in warm solvent. A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH
B. Gases are generally more soluble in water at low temperature.
19. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the
C. Aqueous solution is a mixture containing the solute soluble in water as a solvent.
concentration of carbonate ions is:
D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute
A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M
surface is increased.
20. The strength of an acid does not depend on:
6. The entropy increases at:
A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy
A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct
C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct
7. Which of the following is homogenous mixture?
21. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is;
A. milk B. 24-karat gold C. tap water D. oil and water
A. SO42- B. Al+3 C. H3O+ D. all of them are correct.
8. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O
22. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the
fast :N2O+H2 →N2+H2O which of the following is correct ?
concentration of both reactants is doubled?
A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O
A. the reaction rate remains the same. B. the reaction rate increases by a factor of two.
C. the reaction order is second D. Both (A+C) are correct
C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight.
9. When polar compound ionizes completely in water the compound is:
23. The dilute aqueous solution of a weak acid contains:
A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte.
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct
10. The energy required to raise the reactant to the level of the activated complex is:
A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction 24. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base?

11. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal A.F- B. BF3 C. BF4- D. none of them is correct
50kJ/mol ,the activation energy for reverse reaction is equal to 25. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat
A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol is 0.449J/g.K?
12. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct? A. 202kJ B.27.83J C.1002J D. 202J
A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous. 26. The solution that contains the precisely known concentration of a solute is known as:
C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous. A. saturated solution B. dilute solution C. standard solution D. buffer solution
27. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are 41. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true
contained per 250g of water? about the reaction ?
A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol A. The reaction is always spontaneous. B. The reaction is never spontaneous.
28. A substance that can react as an acid or a base : C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature.

A. SO42- B. HSO3- C.CH3COO- D. NH4+ 42. When barium chloride solution is mixed with sodium nitrate:
A. sodium chloride precipitates B. barium nitrate precipitates
29. Which of the following ions hydrolyze in aqueous solution? C. precipitation does not occur D. Both ( A + B ) are correct
A.NO3- B. CO32- C. SO42- D. none of them is correct
43. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is
30. Adding NH4Cl to NH3 solution leads to: called:
A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+] A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat
31. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if : 44. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals :
A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined -
A. 184.6kJ/mol B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol
32. All of the following statements are true about the collision theory except:
A. all collisions between particles of reactant leads to the occurrence of the chemical reaction 45. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature,
B. the reaction rate is directly proportional with the number of effective collision. what would be the value of that constant for the reverse reaction at the same condition?
C. in order for chemical reaction to occur, the reacting particles must collide A. 0.05 B. 0.1 C. 10 D. 5
D. the particles of reactants must have enough energy to initiate the reaction. 46. The common-ion causes:
33. All of them are correct except: A. increasing precipitation. B. decreasing ionization.
A. An ionic compound at solid state does not conduct electric current. C. shifting equilibrium to left. D. all of them are correct.
B. Alloy is a mixture the atoms of two or more metals are uniformly mixed. 47. A substance that formed when a strong acid has lost a proton
C. The Brownian motion is a motion due to collision rapidly moving molecules. A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations
D. HCl does not soluble in water.
48. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of
34. Aqueous solution of NH3 is an Arrhenius base because:
solution?
A. it is proton accepter. B. it increases the concentration of hydronium ion.
A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M
C.it is an electron pair donor. D.it increases the concentration of hydroxide ion.
49. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ?
35. The boiling point of a solution is higher than that of a pure solvent because :-
A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol
A. Vapor-pressure lowering B. Freezing- point heightening
C. Vapor-pressure heightening D. none of them 50. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the
right ?
36. The rate of the slow reaction increases by :
A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure
A. the addition of a catalyst. B. increasing activation energy
C. increasing concentration. D. Both (A+C) are correct
37. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is:
A. R=k[A][B] B. R=k[A2B]
38. Which of the following is a binary acid?
C. R=k[A]2[B] D. R=k[A][B]2
K
A. H2S B.H2CO3 C. H2O2 D. all of them are correct
39. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a
nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant?
A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
40. While mixing a small quantity of water with a large quantity of ethanol, water considered as :-
A. solvent B. solute C. solution D. none of them
 Kurdistan Region – Iraq 0012 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
L 13. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct?
A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous.
SN: 6000092 C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous.
(science)
Answer the following questions : ( two marks for each right choice ) 14. When polar compound ionizes completely in water the compound is:
1. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals : A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte.
-
A. 184.6kJ/mol B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol 15. For an exothermic dissolution process, the increasing of the temperature causes:
A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct
2. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the
concentration of both reactants is doubled? 16. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M
A. the reaction rate remains the same. B. the reaction rate increases by a factor of two. the value of the equilibrium constant equals:
C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight. A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84
3. The boiling point of a solution is higher than that of a pure solvent because :- 17. Aqueous solution of NH3 is an Arrhenius base because:
A. Vapor-pressure lowering B. Freezing- point heightening A. it is proton accepter. B. it increases the concentration of hydronium ion.
C. Vapor-pressure heightening D. none of them C.it is an electron pair donor. D.it increases the concentration of hydroxide ion.
4. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the right 18. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature,
? what would be the value of that constant for the reverse reaction at the same condition?
A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure A. 0.05 B. 0.1 C. 10 D. 5
5. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ? 19. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if :
A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined
6. The dilute aqueous solution of a weak acid contains: 20. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant?
7. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
solution? 21. Which of the following ions hydrolyze in aqueous solution?
A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M A.NO3- B. CO32- C. SO42- D. none of them is correct
8. All of them are correct except: 22. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal
A. An ionic compound at solid state does not conduct electric current. 50kJ/mol ,the activation energy for reverse reaction is equal to
B. Alloy is a mixture the atoms of two or more metals are uniformly mixed. A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol
C. The Brownian motion is a motion due to collision rapidly moving molecules.
D. HCl does not soluble in water. 23. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion?
A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol
9. A substance that can react as an acid or a base :
24. Adding NH4Cl to NH3 solution leads to:
A. SO42- B. HSO3- C.CH3COO- D. NH4+
A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+]
10. The common-ion causes:
25. Which of the following is the equilibrium constant for an anion hydrolysis reaction?
A. increasing precipitation. B. decreasing ionization. [HB][OH− ] [B− ] [HB] [B− ][OH− ]
C. shifting equilibrium to left. D. all of them are correct. A. B. C. D.
[B− ] [HB][OH− ] [B− ][OH− ] [HB]

11. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is 26. The entropy increases at:
called: A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct
A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat
27. Which of the following is homogenous mixture?
12. Which of the following represents the formation equation? A. milk B. 24-karat gold C. tap water D. oil and water
A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2
28. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for 41. The rate of the slow reaction increases by :
transition interval is (3.1- 4.4): A. the addition of a catalyst. B. increasing activation energy
A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH C. increasing concentration. D. Both (A+C) are correct
29. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O 42. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is:
fast :N2O+H2 →N2+H2O which of the following is correct ? A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2
A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O 43. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is;
C. the reaction order is second D. Both (A+C) are correct A. SO42- B. Al+3 C. H3O+ D. all of them are correct.
30. Which of the following is a binary acid? 44. The net ionic equation for the precipitation Nickel ( II )sulfide is :
A. H2S B.H2CO3 C. H2O2 D. all of them are correct A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s)
31. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water.
is 0.449J/g.K? 45. The energy required to raise the reactant to the level of the activated complex is:
A. 202kJ B.27.83J C.1002J D. 202J A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction
32. Which of the following solutions with the same concentrations has lower [H3O+]?
46. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true
A. HCl B. H2O C. NH3 D. HF
about the reaction ?
33. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the A. The reaction is always spontaneous. B. The reaction is never spontaneous.
concentration of carbonate ions is: C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature.
A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M
47. A substance that formed when a strong acid has lost a proton
34. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct? A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations
A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound.
48. The solution that contains the precisely known concentration of a solute is known as:
C. a liquid is polar molecular compound. D. none of them
A. saturated solution B. dilute solution C. standard solution D. buffer solution
35. All of the following statements are true about the collision theory except:
49. While mixing a small quantity of water with a large quantity of ethanol, water considered as :-
A. all collisions between particles of reactant leads to the occurrence of the chemical reaction
A. solvent B. solute C. solution D. none of them
B. the reaction rate is directly proportional with the number of effective collision.
C. in order for chemical reaction to occur, the reacting particles must collide 50. Which one of the following statements is incorrect?
D. the particles of reactants must have enough energy to initiate the reaction. A. Many solids dissolve more quickly in a cold solvent than in warm solvent.
B. Gases are generally more soluble in water at low temperature.
36. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :-
C. Aqueous solution is a mixture containing the solute soluble in water as a solvent.
A. 3.1 B. 3.7 C. 10.9 D. 10.3
D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute
37. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are surface is increased.
contained per 250g of water?
A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol

38. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base?
A.F- B. BF3 C. BF4- D. none of them is correct
L
39. The strength of an acid does not depend on:
A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy
C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct
40. When barium chloride solution is mixed with sodium nitrate:
A. sodium chloride precipitates B. barium nitrate precipitates
C. precipitation does not occur D. Both ( A + B ) are correct
 Kurdistan Region – Iraq 0013 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
M 13. When barium chloride solution is mixed with sodium nitrate:
A. sodium chloride precipitates B. barium nitrate precipitates
C. precipitation does not occur D. Both ( A + B ) are correct
SN: 6000093
(science)
Answer the following questions : ( two marks for each right choice ) 14. A substance that formed when a strong acid has lost a proton
1. When polar compound ionizes completely in water the compound is: A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations
A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte. 15. The net ionic equation for the precipitation Nickel ( II )sulfide is :
2. While mixing a small quantity of water with a large quantity of ethanol, water considered as :- A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s)
A. solvent B. solute C. solution D. none of them C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water.

3. Which one of the following statements is incorrect? 16. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :-
A. Many solids dissolve more quickly in a cold solvent than in warm solvent. A. 3.1 B. 3.7 C. 10.9 D. 10.3
B. Gases are generally more soluble in water at low temperature. 17. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a
C. Aqueous solution is a mixture containing the solute soluble in water as a solvent. nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant?
D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
surface is increased. 18. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat
4. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are contained is 0.449J/g.K?
per 250g of water? A. 202kJ B.27.83J C.1002J D. 202J
A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol
19. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true
5. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the about the reaction ?
concentration of both reactants is doubled? A. The reaction is always spontaneous. B. The reaction is never spontaneous.
A. the reaction rate remains the same. B. the reaction rate increases by a factor of two. C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature.
C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight.
20. All of them are correct except:
6. For an exothermic dissolution process, the increasing of the temperature causes: A. An ionic compound at solid state does not conduct electric current.
A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct B. Alloy is a mixture the atoms of two or more metals are uniformly mixed.
7. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for C. The Brownian motion is a motion due to collision rapidly moving molecules.
transition interval is (3.1- 4.4): D. HCl does not soluble in water.
A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH 21. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O
8. The dilute aqueous solution of a weak acid contains: fast :N2O+H2 →N2+H2O which of the following is correct ?
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O
C. the reaction order is second D. Both (A+C) are correct
9. All of the following statements are true about the collision theory except:
A. all collisions between particles of reactant leads to the occurrence of the chemical reaction 22. The boiling point of a solution is higher than that of a pure solvent because :-
B. the reaction rate is directly proportional with the number of effective collision. A. Vapor-pressure lowering B. Freezing- point heightening
C. in order for chemical reaction to occur, the reacting particles must collide C. Vapor-pressure heightening D. none of them
D. the particles of reactants must have enough energy to initiate the reaction. 23. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ?
10. The strength of an acid does not depend on: A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol
A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy 24. Adding NH4Cl to NH3 solution leads to:
C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+]
11. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is: 25. Aqueous solution of NH3 is an Arrhenius base because:
A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2 A. it is proton accepter. B. it increases the concentration of hydronium ion.
12. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion? C.it is an electron pair donor. D.it increases the concentration of hydroxide ion.
A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol
26. The common-ion causes: 41. The energy required to raise the reactant to the level of the activated complex is:
A. increasing precipitation. B. decreasing ionization. A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction
C. shifting equilibrium to left. D. all of them are correct. 42. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if :
27. Which of the following is homogenous mixture? A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined
A. milk B. 24-karat gold C. tap water D. oil and water
43. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base?
28. Which of the following ions hydrolyze in aqueous solution?
A.NO3- B. CO32- C. SO42- D. none of them is correct A.F- B. BF3 C. BF4- D. none of them is correct
44. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct?
29. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of
solution? A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous.
A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous.

30. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct? 45. Which of the following is a binary acid?
A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound. A. H2S B.H2CO3 C. H2O2 D. all of them are correct
C. a liquid is polar molecular compound. D. none of them 46. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is;
31. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the A. SO42- B. Al+3 C. H3O+ D. all of them are correct.
concentration of carbonate ions is: 47. The entropy increases at:
A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct
32. Which of the following solutions with the same concentrations has lower [H3O+]? 48. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the
A. HCl B. H2O C. NH3 D. HF right ?
33. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure
50kJ/mol ,the activation energy for reverse reaction is equal to 49. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature,
A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol what would be the value of that constant for the reverse reaction at the same condition?
34. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M A. 0.05 B. 0.1 C. 10 D. 5
the value of the equilibrium constant equals: 50. The rate of the slow reaction increases by :
A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84 A. the addition of a catalyst. B. increasing activation energy
35. The solution that contains the precisely known concentration of a solute is known as: C. increasing concentration. D. Both (A+C) are correct
A. saturated solution B. dilute solution C. standard solution D. buffer solution
36. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals :
A. 184.6kJ/mol -
B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol

37. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is
M
called:
A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat
38. Which of the following is the equilibrium constant for an anion hydrolysis reaction?
[HB][OH− ] [B− ] [HB] [B− ][OH− ]
A. B. C. D.
[B− ] [HB][OH− ] [B− ][OH− ] [HB]

39. A substance that can react as an acid or a base :

A. SO42- B. HSO3- C.CH3COO- D. NH4+
40. Which of the following represents the formation equation?
A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2
 Kurdistan Region – Iraq 0014 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
N 12. Aqueous solution of NH3 is an Arrhenius base because:
A. it is proton accepter. B. it increases the concentration of hydronium ion.
C.it is an electron pair donor. D.it increases the concentration of hydroxide ion.
SN: 6000094
(science)
Answer the following questions : ( two marks for each right choice ) 13. The solution that contains the precisely known concentration of a solute is known as:
1. Which of the following is a binary acid? A. saturated solution B. dilute solution C. standard solution D. buffer solution
A. H2S B.H2CO3 C. H2O2 D. all of them are correct 14. Which of the following is homogenous mixture?
2. When polar compound ionizes completely in water the compound is: A. milk B. 24-karat gold C. tap water D. oil and water
A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte. 15. A substance that can react as an acid or a base :

3. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base? A. SO42- B. HSO3- C.CH3COO- D. NH4+

A.F- B. BF3 C. BF4- D. none of them is correct 16. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true
about the reaction ?
4. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M A. The reaction is always spontaneous. B. The reaction is never spontaneous.
the value of the equilibrium constant equals: C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature.
A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84
17. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the
5. When barium chloride solution is mixed with sodium nitrate: concentration of both reactants is doubled?
A. sodium chloride precipitates B. barium nitrate precipitates A. the reaction rate remains the same. B. the reaction rate increases by a factor of two.
C. precipitation does not occur D. Both ( A + B ) are correct C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight.
6. The boiling point of a solution is higher than that of a pure solvent because :- 18. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct?
A. Vapor-pressure lowering B. Freezing- point heightening
A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous.
C. Vapor-pressure heightening D. none of them
C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous.
7. Which one of the following statements is incorrect?
A. Many solids dissolve more quickly in a cold solvent than in warm solvent. 19. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal
B. Gases are generally more soluble in water at low temperature. 50kJ/mol ,the activation energy for reverse reaction is equal to
C. Aqueous solution is a mixture containing the solute soluble in water as a solvent. A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol
D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute 20. Which of the following solutions with the same concentrations has lower [H3O+]?
surface is increased. A. HCl B. H2O C. NH3 D. HF
8. All of the following statements are true about the collision theory except: 21. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if :
A. all collisions between particles of reactant leads to the occurrence of the chemical reaction A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined
B. the reaction rate is directly proportional with the number of effective collision.
22. The strength of an acid does not depend on:
C. in order for chemical reaction to occur, the reacting particles must collide
A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy
D. the particles of reactants must have enough energy to initiate the reaction.
C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct
9. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the
23. A substance that formed when a strong acid has lost a proton
concentration of carbonate ions is:
A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations
A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M
24. The dilute aqueous solution of a weak acid contains:
10. The common-ion causes:
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct
A. increasing precipitation. B. decreasing ionization.
C. shifting equilibrium to left. D. all of them are correct. 25. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O
fast :N2O+H2 →N2+H2O which of the following is correct ?
11. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the
A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O
right ?
C. the reaction order is second D. Both (A+C) are correct
A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure
26. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals : 41. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is:
A. 184.6kJ/mol -
B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2

27. The net ionic equation for the precipitation Nickel ( II )sulfide is : 42. While mixing a small quantity of water with a large quantity of ethanol, water considered as :-
A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s) A. solvent B. solute C. solution D. none of them
C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water. 43. Adding NH4Cl to NH3 solution leads to:
28. The entropy increases at: A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+]
A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct 44. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ?
29. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature, A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol
what would be the value of that constant for the reverse reaction at the same condition? 45. All of them are correct except:
A. 0.05 B. 0.1 C. 10 D. 5 A. An ionic compound at solid state does not conduct electric current.
B. Alloy is a mixture the atoms of two or more metals are uniformly mixed.
30. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :- C. The Brownian motion is a motion due to collision rapidly moving molecules.
A. 3.1 B. 3.7 C. 10.9 D. 10.3 D. HCl does not soluble in water.
31. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are 46. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is;
contained per 250g of water? A. SO42- B. Al+3 C. H3O+ D. all of them are correct.
A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol
47. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat
32. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a is 0.449J/g.K?
nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant? A. 202kJ B.27.83J C.1002J D. 202J
A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
48. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct?
33. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound.
called: C. a liquid is polar molecular compound. D. none of them
A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat
49. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of
34. Which of the following ions hydrolyze in aqueous solution?
solution?
A.NO3- B. CO32- C. SO42- D. none of them is correct
A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M
35. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion?
50. Which of the following represents the formation equation?
A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol
A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2
36. Which of the following is the equilibrium constant for an anion hydrolysis reaction?
[HB][OH− ] [B− ] [HB] [B− ][OH− ]
A. B. C. D.
[B− ] [HB][OH− ] [B− ][OH− ] [HB]

37. For an exothermic dissolution process, the increasing of the temperature causes:
A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct
N
38. The rate of the slow reaction increases by :
A. the addition of a catalyst. B. increasing activation energy
C. increasing concentration. D. Both (A+C) are correct
39. The energy required to raise the reactant to the level of the activated complex is:
A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction
40. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for
transition interval is (3.1- 4.4):
A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH
 Kurdistan Region – Iraq 0015 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
O 14. While mixing a small quantity of water with a large quantity of ethanol, water considered as :-
A. solvent B. solute C. solution D. none of them
SN: 6000095 15. Which of the following solutions with the same concentrations has lower [H3O+]?
(science)
Answer the following questions : ( two marks for each right choice ) A. HCl B. H2O C. NH3 D. HF
1. The dilute aqueous solution of a weak acid contains: 16. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion?
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol
2. All of them are correct except: 17. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is:
A. An ionic compound at solid state does not conduct electric current. A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2
B. Alloy is a mixture the atoms of two or more metals are uniformly mixed.
18. When polar compound ionizes completely in water the compound is:
C. The Brownian motion is a motion due to collision rapidly moving molecules.
A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte.
D. HCl does not soluble in water.
19. The entropy increases at:
3. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ?
A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct
A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol
20. Which of the following is homogenous mixture?
4. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the
A. milk B. 24-karat gold C. tap water D. oil and water
concentration of carbonate ions is:
A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M 21. The energy required to raise the reactant to the level of the activated complex is:
A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction
5. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals :
A. 184.6kJ/mol -
B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol 22. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct?
A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound.
6. A substance that can react as an acid or a base : C. a liquid is polar molecular compound. D. none of them
A. SO42- B. HSO3- C.CH3COO- D. NH4+ 23. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for
7. Which of the following is a binary acid? transition interval is (3.1- 4.4):
A. H2S B.H2CO3 C. H2O2 D. all of them are correct A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH

8. The solution that contains the precisely known concentration of a solute is known as: 24. The common-ion causes:
A. saturated solution B. dilute solution C. standard solution D. buffer solution A. increasing precipitation. B. decreasing ionization.
C. shifting equilibrium to left. D. all of them are correct.
9. The boiling point of a solution is higher than that of a pure solvent because :-
A. Vapor-pressure lowering B. Freezing- point heightening 25. Aqueous solution of NH3 is an Arrhenius base because:
C. Vapor-pressure heightening D. none of them A. it is proton accepter. B. it increases the concentration of hydronium ion.
C.it is an electron pair donor. D.it increases the concentration of hydroxide ion.
10. For an exothermic dissolution process, the increasing of the temperature causes:
A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct 26. Which of the following ions hydrolyze in aqueous solution?
A.NO3- B. CO32- C. SO42- D. none of them is correct
11. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of
27. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a
solution?
nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant?
A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M
A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
12. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is;
28. Which of the following is the equilibrium constant for an anion hydrolysis reaction?
A. SO42- B. Al+3 C. H3O+ D. all of them are correct. [HB][OH− ] [B− ] [HB] [B− ][OH− ]
A. B. C. D.
13. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the [B− ] [HB][OH− ] [B− ][OH− ] [HB]
right ? 29. The rate of the slow reaction increases by :
A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure A. the addition of a catalyst. B. increasing activation energy
C. increasing concentration. D. Both (A+C) are correct
30. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat 42. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true
is 0.449J/g.K? about the reaction ?
A. 202kJ B.27.83J C.1002J D. 202J A. The reaction is always spontaneous. B. The reaction is never spontaneous.
31. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature.
called: 43. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if :
A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined
32. The strength of an acid does not depend on: 44. When barium chloride solution is mixed with sodium nitrate:
A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy A. sodium chloride precipitates B. barium nitrate precipitates
C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct C. precipitation does not occur D. Both ( A + B ) are correct
33. Which of the following represents the formation equation? 45. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are
A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2 contained per 250g of water?
34. Which one of the following statements is incorrect? A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol
A. Many solids dissolve more quickly in a cold solvent than in warm solvent. 46. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct?
B. Gases are generally more soluble in water at low temperature. A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous.
C. Aqueous solution is a mixture containing the solute soluble in water as a solvent. C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous.
D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute
surface is increased. 47. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :-
A. 3.1 B. 3.7 C. 10.9 D. 10.3
35. All of the following statements are true about the collision theory except:
A. all collisions between particles of reactant leads to the occurrence of the chemical reaction 48. The net ionic equation for the precipitation Nickel ( II )sulfide is :
B. the reaction rate is directly proportional with the number of effective collision. A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s)
C. in order for chemical reaction to occur, the reacting particles must collide C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water.
D. the particles of reactants must have enough energy to initiate the reaction. 49. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal
50kJ/mol ,the activation energy for reverse reaction is equal to
36. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base?
A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol
A.F- B. BF3 C. BF4- D. none of them is correct
50. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the
37. Adding NH4Cl to NH3 solution leads to: concentration of both reactants is doubled?
A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+] A. the reaction rate remains the same. B. the reaction rate increases by a factor of two.
38. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight.
the value of the equilibrium constant equals:
A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84
39. A substance that formed when a strong acid has lost a proton
A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations O
40. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature,
what would be the value of that constant for the reverse reaction at the same condition?
A. 0.05 B. 0.1 C. 10 D. 5

41. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O
fast :N2O+H2 →N2+H2O which of the following is correct ?
A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O
C. the reaction order is second D. Both (A+C) are correct
 Kurdistan Region – Iraq 0016 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
P 14. All of them are correct except:
A. An ionic compound at solid state does not conduct electric current.
B. Alloy is a mixture the atoms of two or more metals are uniformly mixed.
SN: 6000096
(science) C. The Brownian motion is a motion due to collision rapidly moving molecules.
Answer the following questions : ( two marks for each right choice )
D. HCl does not soluble in water.
1. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature,
what would be the value of that constant for the reverse reaction at the same condition? 15. The energy required to raise the reactant to the level of the activated complex is:
A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction
A. 0.05 B. 0.1 C. 10 D. 5
16. Which of the following is the equilibrium constant for an anion hydrolysis reaction?
2. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion? [HB][OH− ] [B− ] [HB] [B− ][OH− ]
A. B. C. D.
A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol [B− ] [HB][OH− ] [B− ][OH− ] [HB]

3. Which of the following is a binary acid? 17. When barium chloride solution is mixed with sodium nitrate:
A. H2S B.H2CO3 C. H2O2 D. all of them are correct A. sodium chloride precipitates B. barium nitrate precipitates
C. precipitation does not occur D. Both ( A + B ) are correct
4. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base?
18. While mixing a small quantity of water with a large quantity of ethanol, water considered as :-
A.F- B. BF3 C. BF4- D. none of them is correct A. solvent B. solute C. solution D. none of them
5. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is: 19. For an exothermic dissolution process, the increasing of the temperature causes:
A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2 A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct
6. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if : 20. Aqueous solution of NH3 is an Arrhenius base because:
A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined A. it is proton accepter. B. it increases the concentration of hydronium ion.
7. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are contained C.it is an electron pair donor. D.it increases the concentration of hydroxide ion.
per 250g of water? 21. Adding NH4Cl to NH3 solution leads to:
A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+]
8. When polar compound ionizes completely in water the compound is: 22. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ?
A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte. A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol
9. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a 23. A substance that formed when a strong acid has lost a proton
nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant? A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations
A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
24. The net ionic equation for the precipitation Nickel ( II )sulfide is :
10. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct? A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s)
A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous. C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water.
C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous. 25. Which of the following solutions with the same concentrations has lower [H3O+]?
11. Which of the following is homogenous mixture? A. HCl B. H2O C. NH3 D. HF
A. milk B. 24-karat gold C. tap water D. oil and water 26. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M
12. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct? the value of the equilibrium constant equals:
A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound. A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84
C. a liquid is polar molecular compound. D. none of them 27. The boiling point of a solution is higher than that of a pure solvent because :-
13. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of A. Vapor-pressure lowering B. Freezing- point heightening
C. Vapor-pressure heightening D. none of them
solution?
A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M
28. Which one of the following statements is incorrect? 41. The solution that contains the precisely known concentration of a solute is known as:
A. Many solids dissolve more quickly in a cold solvent than in warm solvent. A. saturated solution B. dilute solution C. standard solution D. buffer solution
B. Gases are generally more soluble in water at low temperature. 42. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal
C. Aqueous solution is a mixture containing the solute soluble in water as a solvent. 50kJ/mol ,the activation energy for reverse reaction is equal to
D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute
A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol
surface is increased.
43. A substance that can react as an acid or a base :
29. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for
transition interval is (3.1- 4.4): A. SO42- B. HSO3- C.CH3COO- D. NH4+
A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH 44. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat
30. The dilute aqueous solution of a weak acid contains: is 0.449J/g.K?
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct A. 202kJ B.27.83J C.1002J D. 202J
31. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O 45. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :-
fast :N2O+H2 →N2+H2O which of the following is correct ? A. 3.1 B. 3.7 C. 10.9 D. 10.3
A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O 46. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the
C. the reaction order is second D. Both (A+C) are correct concentration of carbonate ions is:
32. All of the following statements are true about the collision theory except: A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M
A. all collisions between particles of reactant leads to the occurrence of the chemical reaction 47. The common-ion causes:
B. the reaction rate is directly proportional with the number of effective collision. A. increasing precipitation. B. decreasing ionization.
C. in order for chemical reaction to occur, the reacting particles must collide C. shifting equilibrium to left. D. all of them are correct.
D. the particles of reactants must have enough energy to initiate the reaction.
48. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is
33. Which of the following represents the formation equation? called:
A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2 A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat
34. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals : 49. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the
-
A. 184.6kJ/mol B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol concentration of both reactants is doubled?
A. the reaction rate remains the same. B. the reaction rate increases by a factor of two.
35. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is;
C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight.
A. SO42- B. Al+3 C. H3O+ D. all of them are correct.
50. The strength of an acid does not depend on:
36. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true
A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy
about the reaction ?
C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct
A. The reaction is always spontaneous. B. The reaction is never spontaneous.
C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature.
37. The rate of the slow reaction increases by :
A. the addition of a catalyst.
C. increasing concentration.
B. increasing activation energy
D. Both (A+C) are correct
P
38. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the
right ?
A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure
39. The entropy increases at:
A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct
40. Which of the following ions hydrolyze in aqueous solution?
A.NO3- B. CO32- C. SO42- D. none of them is correct
 Kurdistan Region – Iraq 0017 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
Q 13. Which one of the following statements is incorrect?
A. Many solids dissolve more quickly in a cold solvent than in warm solvent.
B. Gases are generally more soluble in water at low temperature.
SN: 6000097
(science) C. Aqueous solution is a mixture containing the solute soluble in water as a solvent.
Answer the following questions : ( two marks for each right choice )
D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute
1. Which of the following is a binary acid? surface is increased.
A. H2S B.H2CO3 C. H2O2 D. all of them are correct
14. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base?
2. Adding NH4Cl to NH3 solution leads to:
A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+] A.F- B. BF3 C. BF4- D. none of them is correct
3. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are contained 15. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the
per 250g of water? concentration of both reactants is doubled?
A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol A. the reaction rate remains the same. B. the reaction rate increases by a factor of two.
4. Which of the following solutions with the same concentrations has lower [H3O+]? C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight.
A. HCl B. H2O C. NH3 D. HF 16. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal
5. All of them are correct except: 50kJ/mol ,the activation energy for reverse reaction is equal to
A. An ionic compound at solid state does not conduct electric current. A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol
B. Alloy is a mixture the atoms of two or more metals are uniformly mixed. 17. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ?
C. The Brownian motion is a motion due to collision rapidly moving molecules. A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol
D. HCl does not soluble in water.
18. The strength of an acid does not depend on:
6. Which of the following represents the formation equation? A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy
A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2 C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct
7. Which of the following is homogenous mixture? 19. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if :
A. milk B. 24-karat gold C. tap water D. oil and water A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined
8. For an exothermic dissolution process, the increasing of the temperature causes: 20. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true
A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct
about the reaction ?
9. The boiling point of a solution is higher than that of a pure solvent because :- A. The reaction is always spontaneous. B. The reaction is never spontaneous.
A. Vapor-pressure lowering B. Freezing- point heightening C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature.
C. Vapor-pressure heightening D. none of them
21. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of
10. While mixing a small quantity of water with a large quantity of ethanol, water considered as :- solution?
A. solvent B. solute C. solution D. none of them A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M
11. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is 22. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct?
called: A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound.
A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat C. a liquid is polar molecular compound. D. none of them
12. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M 23. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :-
the value of the equilibrium constant equals: A. 3.1 B. 3.7 C. 10.9 D. 10.3
A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84
24. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct?
A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous.
C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous.
25. The energy required to raise the reactant to the level of the activated complex is:
A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction
26. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the 40. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the
right ? concentration of carbonate ions is:
A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M
27. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is; 41. Aqueous solution of NH3 is an Arrhenius base because:
A. SO42- B. Al+3 C. H3O+ D. all of them are correct. A. it is proton accepter. B. it increases the concentration of hydronium ion.
28. The entropy increases at: C.it is an electron pair donor. D.it increases the concentration of hydroxide ion.
A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct 42. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is:
29. The net ionic equation for the precipitation Nickel ( II )sulfide is : A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2
A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s) 43. The common-ion causes:
C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water. A. increasing precipitation. B. decreasing ionization.
30. The rate of the slow reaction increases by : C. shifting equilibrium to left. D. all of them are correct.
A. the addition of a catalyst. B. increasing activation energy 44. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals :
C. increasing concentration. D. Both (A+C) are correct A. 184.6kJ/mol -
B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol
31. All of the following statements are true about the collision theory except: 45. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for
A. all collisions between particles of reactant leads to the occurrence of the chemical reaction transition interval is (3.1- 4.4):
B. the reaction rate is directly proportional with the number of effective collision. A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH
C. in order for chemical reaction to occur, the reacting particles must collide
D. the particles of reactants must have enough energy to initiate the reaction. 46. When polar compound ionizes completely in water the compound is:
A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte.
32. Which of the following is the equilibrium constant for an anion hydrolysis reaction?
[HB][OH− ] [B− ] [HB] [B− ][OH− ] 47. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O
A. B. C. D.
[B− ] [HB][OH− ] [B− ][OH− ] [HB] fast :N2O+H2 →N2+H2O which of the following is correct ?
33. Which of the following ions hydrolyze in aqueous solution? A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O
A.NO3- B. CO32- C. SO42- D. none of them is correct C. the reaction order is second D. Both (A+C) are correct

34. When barium chloride solution is mixed with sodium nitrate: 48. A substance that can react as an acid or a base :
A. sodium chloride precipitates B. barium nitrate precipitates A. SO42- B. HSO3- C.CH3COO- D. NH4+
C. precipitation does not occur D. Both ( A + B ) are correct
49. A substance that formed when a strong acid has lost a proton
35. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion? A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations
A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol 50. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a
36. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature, nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant?
what would be the value of that constant for the reverse reaction at the same condition? A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
A. 0.05 B. 0.1 C. 10 D. 5

37. The solution that contains the precisely known concentration of a solute is known as:
A. saturated solution B. dilute solution
38. The dilute aqueous solution of a weak acid contains:
C. standard solution D. buffer solution
Q
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct
39. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat
is 0.449J/g.K?
A. 202kJ B.27.83J C.1002J D. 202J
 Kurdistan Region – Iraq 0018 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
R 13. All of them are correct except:
A. An ionic compound at solid state does not conduct electric current.
B. Alloy is a mixture the atoms of two or more metals are uniformly mixed.
SN: 6000098
(science) C. The Brownian motion is a motion due to collision rapidly moving molecules.
Answer the following questions : ( two marks for each right choice )
D. HCl does not soluble in water.
1. When barium chloride solution is mixed with sodium nitrate:
A. sodium chloride precipitates B. barium nitrate precipitates 14. Which of the following represents the formation equation?
C. precipitation does not occur D. Both ( A + B ) are correct A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2

2. Aqueous solution of NH3 is an Arrhenius base because: 15. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if :
A. it is proton accepter. B. it increases the concentration of hydronium ion. A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined
C.it is an electron pair donor. D.it increases the concentration of hydroxide ion. 16. The entropy increases at:
3. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct
50kJ/mol ,the activation energy for reverse reaction is equal to 17. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct?
A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous.
4. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are contained C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous.
per 250g of water? 18. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a
A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant?
5. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat is A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
0.449J/g.K? 19. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is
A. 202kJ B.27.83J C.1002J D. 202J called:
6. The dilute aqueous solution of a weak acid contains: A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct 20. Which of the following solutions with the same concentrations has lower [H3O+]?
7. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the right A. HCl B. H2O C. NH3 D. HF
? 21. While mixing a small quantity of water with a large quantity of ethanol, water considered as :-
A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure A. solvent B. solute C. solution D. none of them
8. The common-ion causes: 22. A substance that formed when a strong acid has lost a proton
A. increasing precipitation. B. decreasing ionization. A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations
C. shifting equilibrium to left. D. all of them are correct.
23. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M
9. The rate of the slow reaction increases by : the value of the equilibrium constant equals:
A. the addition of a catalyst. B. increasing activation energy A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84
C. increasing concentration. D. Both (A+C) are correct
24. Which of the following is the equilibrium constant for an anion hydrolysis reaction?
10. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is; [HB][OH− ] [B− ] [HB] [B− ][OH− ]
A. B. C. D.
A. SO42- B. Al+3 C. H3O+ D. all of them are correct. [B− ] [HB][OH− ] [B− ][OH− ] [HB]

11. For an exothermic dissolution process, the increasing of the temperature causes: 25. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is:
A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2

12. When polar compound ionizes completely in water the compound is: 26. All of the following statements are true about the collision theory except:
A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte. A. all collisions between particles of reactant leads to the occurrence of the chemical reaction
B. the reaction rate is directly proportional with the number of effective collision.
C. in order for chemical reaction to occur, the reacting particles must collide
D. the particles of reactants must have enough energy to initiate the reaction.
27. A substance that can react as an acid or a base : 40. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base?
A. SO42- B. HSO3- C.CH3COO- D. NH4+
A.F- B. BF3 C. BF4- D. none of them is correct
28. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true 41. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O
about the reaction ? fast :N2O+H2 →N2+H2O which of the following is correct ?
A. The reaction is always spontaneous. B. The reaction is never spontaneous. A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O
C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature. C. the reaction order is second D. Both (A+C) are correct
29. Which of the following is a binary acid? 42. Which of the following is homogenous mixture?
A. H2S B.H2CO3 C. H2O2 D. all of them are correct A. milk B. 24-karat gold C. tap water D. oil and water
30. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct? 43. The boiling point of a solution is higher than that of a pure solvent because :-
A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound. A. Vapor-pressure lowering B. Freezing- point heightening
C. a liquid is polar molecular compound. D. none of them C. Vapor-pressure heightening D. none of them
31. The energy required to raise the reactant to the level of the activated complex is: 44. Adding NH4Cl to NH3 solution leads to:
A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+]
32. The solution that contains the precisely known concentration of a solute is known as: 45. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature,
A. saturated solution B. dilute solution C. standard solution D. buffer solution what would be the value of that constant for the reverse reaction at the same condition?
33. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion? A. 0.05 B. 0.1 C. 10 D. 5
A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol
46. The net ionic equation for the precipitation Nickel ( II )sulfide is :
34. The strength of an acid does not depend on: A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s)
A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water.
C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct
47. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ?
35. Which one of the following statements is incorrect? A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol
A. Many solids dissolve more quickly in a cold solvent than in warm solvent.
48. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals :
B. Gases are generally more soluble in water at low temperature. -
A. 184.6kJ/mol B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol
C. Aqueous solution is a mixture containing the solute soluble in water as a solvent.
D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute 49. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for
surface is increased. transition interval is (3.1- 4.4):
36. Which of the following ions hydrolyze in aqueous solution? A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH
A.NO3- B. CO32- C. SO42- D. none of them is correct 50. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the
37. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :- concentration of carbonate ions is:
A. 3.1 B. 3.7 C. 10.9 D. 10.3 A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M

38. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the
concentration of both reactants is doubled?
A. the reaction rate remains the same.
C. the reaction rate increases by a factor of four.
B. the reaction rate increases by a factor of two.
D. the reaction rate increases by a factor eight. R
39. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of
solution?
A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M
 Kurdistan Region – Iraq 0019 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
S 14. In equilibrium gaseous reaction: 2NO+Cl2
right ?
2NOCl +energy, which of the following shift the reaction to the

A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure

SN: 6000099
(science)
Answer the following questions : ( two marks for each right choice ) 15. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true
1. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct? about the reaction ?
A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound. A. The reaction is always spontaneous. B. The reaction is never spontaneous.
C. a liquid is polar molecular compound. D. none of them C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature.

2. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the 16. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is
concentration of carbonate ions is: called:
A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat

3. When polar compound ionizes completely in water the compound is: 17. Which of the following is a binary acid?
A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte. A. H2S B.H2CO3 C. H2O2 D. all of them are correct

4. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :- 18. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of
A. 3.1 B. 3.7 C. 10.9 D. 10.3 solution?
A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M
5. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature,
what would be the value of that constant for the reverse reaction at the same condition? 19. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ?
A. 0.05 B. 0.1 C. 10 D. 5 A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol

6. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals : 20. Which of the following solutions with the same concentrations has lower [H3O+]?
- A. HCl B. H2O C. NH3 D. HF
A. 184.6kJ/mol B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol
21. All of the following statements are true about the collision theory except:
7. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if : A. all collisions between particles of reactant leads to the occurrence of the chemical reaction
A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined B. the reaction rate is directly proportional with the number of effective collision.
8. Which of the following is homogenous mixture? C. in order for chemical reaction to occur, the reacting particles must collide
A. milk B. 24-karat gold C. tap water D. oil and water D. the particles of reactants must have enough energy to initiate the reaction.
9. The dilute aqueous solution of a weak acid contains: 22. Which of the following represents the formation equation?
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2
10. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the 23. The net ionic equation for the precipitation Nickel ( II )sulfide is :
concentration of both reactants is doubled? A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s)
A. the reaction rate remains the same. B. the reaction rate increases by a factor of two. C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water.
C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight. 24. All of them are correct except:
11. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is: A. An ionic compound at solid state does not conduct electric current.
A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2 B. Alloy is a mixture the atoms of two or more metals are uniformly mixed.
C. The Brownian motion is a motion due to collision rapidly moving molecules.
12. The rate of the slow reaction increases by :
D. HCl does not soluble in water.
A. the addition of a catalyst. B. increasing activation energy
C. increasing concentration. D. Both (A+C) are correct 25. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is;
A. SO42- B. Al+3 C. H3O+ D. all of them are correct.
13. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are
contained per 250g of water? 26. While mixing a small quantity of water with a large quantity of ethanol, water considered as :-
A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol A. solvent B. solute C. solution D. none of them
27. For an exothermic dissolution process, the increasing of the temperature causes:
A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct
28. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M 41. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base?
the value of the equilibrium constant equals:
A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84 A.F- B. BF3 C. BF4- D. none of them is correct

29. Which of the following is the equilibrium constant for an anion hydrolysis reaction? 42. Which one of the following statements is incorrect?
[HB][OH− ] [B− ] [HB] [B− ][OH− ] A. Many solids dissolve more quickly in a cold solvent than in warm solvent.
A. B. C. D.
[B− ] [HB][OH− ] [B− ][OH− ] [HB] B. Gases are generally more soluble in water at low temperature.
30. The boiling point of a solution is higher than that of a pure solvent because :- C. Aqueous solution is a mixture containing the solute soluble in water as a solvent.
A. Vapor-pressure lowering B. Freezing- point heightening D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute
C. Vapor-pressure heightening D. none of them surface is increased.

31. The common-ion causes: 43. Which of the following ions hydrolyze in aqueous solution?
A. increasing precipitation. B. decreasing ionization. A.NO3- B. CO32- C. SO42- D. none of them is correct
C. shifting equilibrium to left. D. all of them are correct. 44. A substance that can react as an acid or a base :
32. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a A. SO42- B. HSO3- C.CH3COO- D. NH4+
nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant?
45. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion?
A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol
33. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O
46. The solution that contains the precisely known concentration of a solute is known as:
fast :N2O+H2 →N2+H2O which of the following is correct ?
A. saturated solution B. dilute solution C. standard solution D. buffer solution
A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O
C. the reaction order is second D. Both (A+C) are correct 47. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat
is 0.449J/g.K?
34. The strength of an acid does not depend on:
A. 202kJ B.27.83J C.1002J D. 202J
A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy
C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct 48. The energy required to raise the reactant to the level of the activated complex is:
A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction
35. Adding NH4Cl to NH3 solution leads to:
A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+] 49. When barium chloride solution is mixed with sodium nitrate:
A. sodium chloride precipitates B. barium nitrate precipitates
36. The entropy increases at:
C. precipitation does not occur D. Both ( A + B ) are correct
A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct
50. A substance that formed when a strong acid has lost a proton
37. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal
A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations
50kJ/mol ,the activation energy for reverse reaction is equal to
A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol
38. Aqueous solution of NH3 is an Arrhenius base because:
A. it is proton accepter.
C.it is an electron pair donor.
B. it increases the concentration of hydronium ion.
D.it increases the concentration of hydroxide ion.
S
39. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct?
A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous.
C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous.
40. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for
transition interval is (3.1- 4.4):
A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH
 Kurdistan Region – Iraq 0020 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
T 12. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a
nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant?
A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
SN: 6000100
(science)
Answer the following questions : ( two marks for each right choice ) 13. A substance that can react as an acid or a base :
1. All of them are correct except: A. SO42- B. HSO3- C.CH3COO- D. NH4+
A. An ionic compound at solid state does not conduct electric current.
14. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true
B. Alloy is a mixture the atoms of two or more metals are uniformly mixed.
about the reaction ?
C. The Brownian motion is a motion due to collision rapidly moving molecules.
A. The reaction is always spontaneous. B. The reaction is never spontaneous.
D. HCl does not soluble in water.
C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature.
2. The common-ion causes:
A. increasing precipitation. B. decreasing ionization. 15. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of
C. shifting equilibrium to left. D. all of them are correct. solution?
A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M
3. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is:
A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2 16. The boiling point of a solution is higher than that of a pure solvent because :-
A. Vapor-pressure lowering B. Freezing- point heightening
4. Which one of the following statements is incorrect? C. Vapor-pressure heightening D. none of them
A. Many solids dissolve more quickly in a cold solvent than in warm solvent.
B. Gases are generally more soluble in water at low temperature. 17. While mixing a small quantity of water with a large quantity of ethanol, water considered as :-
C. Aqueous solution is a mixture containing the solute soluble in water as a solvent. A. solvent B. solute C. solution D. none of them
D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute 18. Which of the following ions hydrolyze in aqueous solution?
surface is increased. A.NO3- B. CO32- C. SO42- D. none of them is correct
5. The dilute aqueous solution of a weak acid contains: 19. The solution that contains the precisely known concentration of a solute is known as:
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct A. saturated solution B. dilute solution C. standard solution D. buffer solution
6. When polar compound ionizes completely in water the compound is: 20. Which of the following represents the formation equation?
A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte. A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2
7. A substance that formed when a strong acid has lost a proton 21. Which of the following is a binary acid?
A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations A. H2S B.H2CO3 C. H2O2 D. all of them are correct
8. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is; 22. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base?
A. SO42- B. Al+3 C. H3O+ D. all of them are correct.
A.F- B. BF3 C. BF4- D. none of them is correct
9. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for
transition interval is (3.1- 4.4): 23. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct?
A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous.
10. The entropy increases at: C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous.
A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct 24. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are
11. All of the following statements are true about the collision theory except: contained per 250g of water?
A. all collisions between particles of reactant leads to the occurrence of the chemical reaction A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol
B. the reaction rate is directly proportional with the number of effective collision. 25. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat
C. in order for chemical reaction to occur, the reacting particles must collide is 0.449J/g.K?
D. the particles of reactants must have enough energy to initiate the reaction. A. 202kJ B.27.83J C.1002J D. 202J
26. When barium chloride solution is mixed with sodium nitrate: 39. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion?
A. sodium chloride precipitates B. barium nitrate precipitates A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol
C. precipitation does not occur D. Both ( A + B ) are correct
40. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature,
27. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] what happens to the reaction rate when the
2,
what would be the value of that constant for the reverse reaction at the same condition?
concentration of both reactants is doubled? A. 0.05 B. 0.1 C. 10 D. 5
A. the reaction rate remains the same. B. the reaction rate increases by a factor of two.
C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight. 41. The net ionic equation for the precipitation Nickel ( II )sulfide is :
A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s)
28. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct?
C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water.
A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound.
C. a liquid is polar molecular compound. D. none of them 42. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if :
A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined
29. Aqueous solution of NH3 is an Arrhenius base because:
A. it is proton accepter. B. it increases the concentration of hydronium ion. 43. Which of the following is homogenous mixture?
C.it is an electron pair donor. D.it increases the concentration of hydroxide ion. A. milk B. 24-karat gold C. tap water D. oil and water

30. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal 44. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ?
50kJ/mol ,the activation energy for reverse reaction is equal to A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol
A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol 45. Adding NH4Cl to NH3 solution leads to:
A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+]
31. Which of the following is the equilibrium constant for an anion hydrolysis reaction?
[HB][OH− ] [B− ] [HB] [B− ][OH− ] 46. For an exothermic dissolution process, the increasing of the temperature causes:
A. B. C. D.
[B− ] [HB][OH− ] [B− ][OH− ] [HB] A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct
32. The strength of an acid does not depend on: 47. The rate of the slow reaction increases by :
A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy A. the addition of a catalyst. B. increasing activation energy
C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct C. increasing concentration. D. Both (A+C) are correct
33. Which of the following solutions with the same concentrations has lower [H3O+]? 48. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M
A. HCl B. H2O C. NH3 D. HF the value of the equilibrium constant equals:
34. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84
concentration of carbonate ions is: 49. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :-
A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M A. 3.1 B. 3.7 C. 10.9 D. 10.3
35. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is 50. The energy required to raise the reactant to the level of the activated complex is:
called: A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction
A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat
36. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals :
-
A. 184.6kJ/mol B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol

37. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O
T
fast :N2O+H2 →N2+H2O which of the following is correct ?
A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O
C. the reaction order is second D. Both (A+C) are correct
38. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the
right ?
A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure
 Kurdistan Region – Iraq 0021 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
U 14. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O
fast :N2O+H2 →N2+H2O which of the following is correct ?
A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O
SN: 6000101
(science) C. the reaction order is second D. Both (A+C) are correct
Answer the following questions : ( two marks for each right choice )
1. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the 15. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the
concentration of both reactants is doubled? concentration of carbonate ions is:
A. the reaction rate remains the same. B. the reaction rate increases by a factor of two. A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M
C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight. 16. All of them are correct except:
2. The strength of an acid does not depend on: A. An ionic compound at solid state does not conduct electric current.
A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy B. Alloy is a mixture the atoms of two or more metals are uniformly mixed.
C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct C. The Brownian motion is a motion due to collision rapidly moving molecules.
D. HCl does not soluble in water.
3. The net ionic equation for the precipitation Nickel ( II )sulfide is :
A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s) 17. The solution that contains the precisely known concentration of a solute is known as:
C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water. A. saturated solution B. dilute solution C. standard solution D. buffer solution
18. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct?
4. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of
A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound.
solution?
C. a liquid is polar molecular compound. D. none of them
A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M
19. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if :
5. The entropy increases at:
A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined
A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct
20. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true
6. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :-
about the reaction ?
A. 3.1 B. 3.7 C. 10.9 D. 10.3
A. The reaction is always spontaneous. B. The reaction is never spontaneous.
7. The boiling point of a solution is higher than that of a pure solvent because :- C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature.
A. Vapor-pressure lowering B. Freezing- point heightening
21. The rate of the slow reaction increases by :
C. Vapor-pressure heightening D. none of them
A. the addition of a catalyst. B. increasing activation energy
8. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M C. increasing concentration. D. Both (A+C) are correct
the value of the equilibrium constant equals:
22. Which one of the following statements is incorrect?
A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84
A. Many solids dissolve more quickly in a cold solvent than in warm solvent.
9. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the right B. Gases are generally more soluble in water at low temperature.
? C. Aqueous solution is a mixture containing the solute soluble in water as a solvent.
A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute
10. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ? surface is increased.
A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol 23. A substance that can react as an acid or a base :
11. Which of the following is the equilibrium constant for an anion hydrolysis reaction? A. SO42- B. HSO3- C.CH3COO- D. NH4+
[HB][OH− ] [B− ] [HB] [B− ][OH− ]
A. B. C. D. 24. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion?
[B− ] [HB][OH− ] [B− ][OH− ] [HB]
A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol
12. A substance that formed when a strong acid has lost a proton
A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations 25. When polar compound ionizes completely in water the compound is:
13. While mixing a small quantity of water with a large quantity of ethanol, water considered as :- A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte.
A. solvent B. solute C. solution D. none of them
26. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature, 40. Adding NH4Cl to NH3 solution leads to:
what would be the value of that constant for the reverse reaction at the same condition? A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+]
A. 0.05 B. 0.1 C. 10 D. 5 41. Which of the following represents the formation equation?
27. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is: A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2
A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2 42. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal
28. When barium chloride solution is mixed with sodium nitrate: 50kJ/mol ,the activation energy for reverse reaction is equal to
A. sodium chloride precipitates B. barium nitrate precipitates A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol
C. precipitation does not occur D. Both ( A + B ) are correct 43. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is;
29. Which of the following solutions with the same concentrations has lower [H3O+]? A. SO42- B. Al+3 C. H3O+ D. all of them are correct.
A. HCl B. H2O C. NH3 D. HF 44. Which of the following is homogenous mixture?
30. The common-ion causes: A. milk B. 24-karat gold C. tap water D. oil and water
A. increasing precipitation. B. decreasing ionization. 45. The energy required to raise the reactant to the level of the activated complex is:
C. shifting equilibrium to left. D. all of them are correct. A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction
31. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is 46. Which of the following ions hydrolyze in aqueous solution?
called: A.NO3- B. CO32- C. SO42- D. none of them is correct
A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat
47. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals :
32. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat A. 184.6kJ/mol -
B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol
is 0.449J/g.K?
A. 202kJ B.27.83J C.1002J D. 202J 48. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are
contained per 250g of water?
33. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base? A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol
A.F- B. BF3 C. BF4- D. none of them is correct 49. All of the following statements are true about the collision theory except:
34. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for A. all collisions between particles of reactant leads to the occurrence of the chemical reaction
transition interval is (3.1- 4.4): B. the reaction rate is directly proportional with the number of effective collision.
A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH C. in order for chemical reaction to occur, the reacting particles must collide
D. the particles of reactants must have enough energy to initiate the reaction.
35. The dilute aqueous solution of a weak acid contains:
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct 50. Which of the following is a binary acid?
A. H2S B.H2CO3 C. H2O2 D. all of them are correct
36. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a
nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant?
A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
37. Aqueous solution of NH3 is an Arrhenius base because:
A. it is proton accepter. B. it increases the concentration of hydronium ion.
U
C.it is an electron pair donor. D.it increases the concentration of hydroxide ion.
38. For an exothermic dissolution process, the increasing of the temperature causes:
A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct
39. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct?
A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous.
C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous.
 Kurdistan Region – Iraq 0022 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
V 13. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature,
what would be the value of that constant for the reverse reaction at the same condition?
A. 0.05 B. 0.1 C. 10 D. 5
SN: 6000102
(science)
Answer the following questions : ( two marks for each right choice ) 14. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is;
1. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if : A. SO42- B. Al+3 C. H3O+ D. all of them are correct.
A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined 15. Which of the following solutions with the same concentrations has lower [H3O+]?
2. A substance that can react as an acid or a base : A. HCl B. H2O C. NH3 D. HF
A. SO42- B. HSO3- C.CH3COO- D. NH4+ 16. Which of the following represents the formation equation?
A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2
3. All of the following statements are true about the collision theory except:
A. all collisions between particles of reactant leads to the occurrence of the chemical reaction 17. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is
B. the reaction rate is directly proportional with the number of effective collision. called:
C. in order for chemical reaction to occur, the reacting particles must collide A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat
D. the particles of reactants must have enough energy to initiate the reaction. 18. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :-
4. Which of the following is a binary acid? A. 3.1 B. 3.7 C. 10.9 D. 10.3
A. H2S B.H2CO3 C. H2O2 D. all of them are correct 19. The energy required to raise the reactant to the level of the activated complex is:
5. The net ionic equation for the precipitation Nickel ( II )sulfide is : A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction
A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s) 20. The entropy increases at:
C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water. A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct
6. The dilute aqueous solution of a weak acid contains: 21. When polar compound ionizes completely in water the compound is:
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte.
7. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals : 22. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a
-
A. 184.6kJ/mol B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant?
A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
8. The common-ion causes:
A. increasing precipitation. B. decreasing ionization. 23. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ?
C. shifting equilibrium to left. D. all of them are correct. A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol
9. The rate of the slow reaction increases by : 24. While mixing a small quantity of water with a large quantity of ethanol, water considered as :-
A. the addition of a catalyst. B. increasing activation energy A. solvent B. solute C. solution D. none of them
C. increasing concentration. D. Both (A+C) are correct 25. Which of the following is homogenous mixture?
10. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat A. milk B. 24-karat gold C. tap water D. oil and water
is 0.449J/g.K? 26. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is:
A. 202kJ B.27.83J C.1002J D. 202J A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2
11. All of them are correct except: 27. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the
A. An ionic compound at solid state does not conduct electric current. concentration of both reactants is doubled?
B. Alloy is a mixture the atoms of two or more metals are uniformly mixed. A. the reaction rate remains the same. B. the reaction rate increases by a factor of two.
C. The Brownian motion is a motion due to collision rapidly moving molecules. C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight.
D. HCl does not soluble in water.
28. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are
12. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct? contained per 250g of water?
A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound. A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol
C. a liquid is polar molecular compound. D. none of them
29. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for 41. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base?
transition interval is (3.1- 4.4):
A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH A.F- B. BF3 C. BF4- D. none of them is correct

30. Which of the following ions hydrolyze in aqueous solution? 42. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of
A.NO3- B. CO32- C. SO42- D. none of them is correct solution?
31. Which one of the following statements is incorrect? A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M
A. Many solids dissolve more quickly in a cold solvent than in warm solvent. 43. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M
B. Gases are generally more soluble in water at low temperature. the value of the equilibrium constant equals:
C. Aqueous solution is a mixture containing the solute soluble in water as a solvent. A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84
D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute 44. The strength of an acid does not depend on:
surface is increased. A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy
32. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct
fast :N2O+H2 →N2+H2O which of the following is correct ? 45. Adding NH4Cl to NH3 solution leads to:
A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+]
C. the reaction order is second D. Both (A+C) are correct
46. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal
33. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the 50kJ/mol ,the activation energy for reverse reaction is equal to
concentration of carbonate ions is:
A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol
A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M
47. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the
34. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct?
right ?
A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous.
A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure
C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous.
48. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion?
35. For an exothermic dissolution process, the increasing of the temperature causes: A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol
A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct
49. A substance that formed when a strong acid has lost a proton
36. Aqueous solution of NH3 is an Arrhenius base because:
A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations
A. it is proton accepter. B. it increases the concentration of hydronium ion.
C.it is an electron pair donor. D.it increases the concentration of hydroxide ion. 50. The solution that contains the precisely known concentration of a solute is known as:
A. saturated solution B. dilute solution C. standard solution D. buffer solution
37. When barium chloride solution is mixed with sodium nitrate:
A. sodium chloride precipitates B. barium nitrate precipitates
C. precipitation does not occur D. Both ( A + B ) are correct
38. Which of the following is the equilibrium constant for an anion hydrolysis reaction?
A.
[HB][OH− ]
B.
[B− ]
C.
[HB]
D.
[B− ][OH− ]
V
[B− ] [HB][OH− ] [B− ][OH− ] [HB]

39. The boiling point of a solution is higher than that of a pure solvent because :-
A. Vapor-pressure lowering B. Freezing- point heightening
C. Vapor-pressure heightening D. none of them
40. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true
about the reaction ?
A. The reaction is always spontaneous. B. The reaction is never spontaneous.
C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature.
 Kurdistan Region – Iraq 0023 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
W 13. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a
nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant?
A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
SN: 6000103
(science)
Answer the following questions : ( two marks for each right choice ) 14. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the
1. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the right concentration of carbonate ions is:
? A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M
A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure 15. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the
2. The rate of the slow reaction increases by : concentration of both reactants is doubled?
A. the addition of a catalyst. B. increasing activation energy A. the reaction rate remains the same. B. the reaction rate increases by a factor of two.
C. increasing concentration. D. Both (A+C) are correct C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight.

3. The common-ion causes: 16. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if :
A. increasing precipitation. B. decreasing ionization. A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined
C. shifting equilibrium to left. D. all of them are correct. 17. When polar compound ionizes completely in water the compound is:
4. Aqueous solution of NH3 is an Arrhenius base because: A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte.
A. it is proton accepter. B. it increases the concentration of hydronium ion. 18. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for
C.it is an electron pair donor. D.it increases the concentration of hydroxide ion. transition interval is (3.1- 4.4):
5. Which one of the following statements is incorrect? A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH
A. Many solids dissolve more quickly in a cold solvent than in warm solvent. 19. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is:
B. Gases are generally more soluble in water at low temperature. A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2
C. Aqueous solution is a mixture containing the solute soluble in water as a solvent. 20. Which of the following is the equilibrium constant for an anion hydrolysis reaction?
D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute [HB][OH− ] [B− ] [HB] [B− ][OH− ]
surface is increased. A. B. C. D.
[B− ] [HB][OH− ] [B− ][OH− ] [HB]

6. The boiling point of a solution is higher than that of a pure solvent because :- 21. All of them are correct except:
A. Vapor-pressure lowering B. Freezing- point heightening A. An ionic compound at solid state does not conduct electric current.
C. Vapor-pressure heightening D. none of them B. Alloy is a mixture the atoms of two or more metals are uniformly mixed.
7. A substance that can react as an acid or a base : C. The Brownian motion is a motion due to collision rapidly moving molecules.
D. HCl does not soluble in water.
A. SO42- B. HSO3- C.CH3COO- D. NH4+
22. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion?
8. When barium chloride solution is mixed with sodium nitrate:
A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol
A. sodium chloride precipitates B. barium nitrate precipitates
C. precipitation does not occur D. Both ( A + B ) are correct 23. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is
called:
9. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals :
-
A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat
A. 184.6kJ/mol B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol
24. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct?
10. The dilute aqueous solution of a weak acid contains: A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound.
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct C. a liquid is polar molecular compound. D. none of them
11. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :- 25. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature,
A. 3.1 B. 3.7 C. 10.9 D. 10.3 what would be the value of that constant for the reverse reaction at the same condition?
12. Which of the following solutions with the same concentrations has lower [H3O+]? A. 0.05 B. 0.1 C. 10 D. 5
A. HCl B. H2O C. NH3 D. HF
26. Which of the following ions hydrolyze in aqueous solution?
A.NO3- B. CO32- C. SO42- D. none of them is correct
27. The net ionic equation for the precipitation Nickel ( II )sulfide is : 41. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M
A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s) the value of the equilibrium constant equals:
C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water. A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84

28. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of 42. The solution that contains the precisely known concentration of a solute is known as:
solution? A. saturated solution B. dilute solution C. standard solution D. buffer solution
A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M 43. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O
29. All of the following statements are true about the collision theory except: fast :N2O+H2 →N2+H2O which of the following is correct ?
A. all collisions between particles of reactant leads to the occurrence of the chemical reaction A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O
B. the reaction rate is directly proportional with the number of effective collision. C. the reaction order is second D. Both (A+C) are correct
C. in order for chemical reaction to occur, the reacting particles must collide 44. The energy required to raise the reactant to the level of the activated complex is:
D. the particles of reactants must have enough energy to initiate the reaction. A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction
30. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are 45. Adding NH4Cl to NH3 solution leads to:
contained per 250g of water? A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+]
A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol
46. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ?
31. Which of the following represents the formation equation? A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol
A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2
47. The strength of an acid does not depend on:
32. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy
about the reaction ? C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct
A. The reaction is always spontaneous. B. The reaction is never spontaneous.
48. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is;
C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature.
A. SO42- B. Al+3 C. H3O+ D. all of them are correct.
33. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal
49. A substance that formed when a strong acid has lost a proton
50kJ/mol ,the activation energy for reverse reaction is equal to
A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations
A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol
50. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat
34. Which of the following is homogenous mixture? is 0.449J/g.K?
A. milk B. 24-karat gold C. tap water D. oil and water A. 202kJ B.27.83J C.1002J D. 202J
35. The entropy increases at:
A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct
36. While mixing a small quantity of water with a large quantity of ethanol, water considered as :-
A. solvent B. solute C. solution D. none of them W
37. Which of the following is a binary acid?
A. H2S B.H2CO3 C. H2O2 D. all of them are correct

38. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base?
A.F- B. BF3 C. BF4- D. none of them is correct
39. For an exothermic dissolution process, the increasing of the temperature causes:
A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct
40. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct?
A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous.
C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous.
 Kurdistan Region – Iraq 0024 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
X 14. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of
solution?
SN: 6000104 A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M
(science)
Answer the following questions : ( two marks for each right choice ) 15. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for
1. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat is transition interval is (3.1- 4.4):
0.449J/g.K? A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH
A. 202kJ B.27.83J C.1002J D. 202J 16. Which of the following is a binary acid?
2. Adding NH4Cl to NH3 solution leads to: A. H2S B.H2CO3 C. H2O2 D. all of them are correct
A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+] 17. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a
3. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant?
50kJ/mol ,the activation energy for reverse reaction is equal to A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol 18. Which of the following solutions with the same concentrations has lower [H3O+]?
4. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :- A. HCl B. H2O C. NH3 D. HF
A. 3.1 B. 3.7 C. 10.9 D. 10.3 19. The rate of the slow reaction increases by :
5. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are contained A. the addition of a catalyst. B. increasing activation energy
per 250g of water? C. increasing concentration. D. Both (A+C) are correct
A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol 20. When polar compound ionizes completely in water the compound is:
6. Aqueous solution of NH3 is an Arrhenius base because: A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte.
A. it is proton accepter. B. it increases the concentration of hydronium ion. 21. Which of the following represents the formation equation?
C.it is an electron pair donor. D.it increases the concentration of hydroxide ion. A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2
7. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true 22. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion?
about the reaction ? A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol
A. The reaction is always spontaneous. B. The reaction is never spontaneous.
23. The boiling point of a solution is higher than that of a pure solvent because :-
C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature.
A. Vapor-pressure lowering B. Freezing- point heightening
8. The dilute aqueous solution of a weak acid contains: C. Vapor-pressure heightening D. none of them
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct
24. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the
9. Which of the following is the equilibrium constant for an anion hydrolysis reaction? concentration of carbonate ions is:
[HB][OH− ] [B− ] [HB] [B− ][OH− ] A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M
A. B. C. D.
[B− ] [HB][OH− ] [B− ][OH− ] [HB]
25. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M
10. The net ionic equation for the precipitation Nickel ( II )sulfide is : the value of the equilibrium constant equals:
A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s) A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84
C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water.
26. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the
11. The energy required to raise the reactant to the level of the activated complex is: concentration of both reactants is doubled?
A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction A. the reaction rate remains the same. B. the reaction rate increases by a factor of two.
12. A substance that formed when a strong acid has lost a proton C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight.
A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations 27. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ?
13. The strength of an acid does not depend on: A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol
A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy
C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct
28. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the 41. The common-ion causes:
right ? A. increasing precipitation. B. decreasing ionization.
A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure C. shifting equilibrium to left. D. all of them are correct.
29. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is: 42. Which of the following ions hydrolyze in aqueous solution?
A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2 A.NO3- B. CO32- C. SO42- D. none of them is correct
30. When barium chloride solution is mixed with sodium nitrate: 43. Which of the following is homogenous mixture?
A. sodium chloride precipitates B. barium nitrate precipitates A. milk B. 24-karat gold C. tap water D. oil and water
C. precipitation does not occur D. Both ( A + B ) are correct 44. A substance that can react as an acid or a base :
31. All of the following statements are true about the collision theory except: A. SO42- B. HSO3- C.CH3COO- D. NH4+
A. all collisions between particles of reactant leads to the occurrence of the chemical reaction
B. the reaction rate is directly proportional with the number of effective collision. 45. The entropy increases at:
C. in order for chemical reaction to occur, the reacting particles must collide A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct
D. the particles of reactants must have enough energy to initiate the reaction. 46. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is;
32. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct? A. SO42- B. Al+3 C. H3O+ D. all of them are correct.
A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound. 47. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals :
C. a liquid is polar molecular compound. D. none of them A. 184.6kJ/mol -
B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol
33. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if :
48. Which one of the following statements is incorrect?
A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined
A. Many solids dissolve more quickly in a cold solvent than in warm solvent.
34. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base? B. Gases are generally more soluble in water at low temperature.
C. Aqueous solution is a mixture containing the solute soluble in water as a solvent.
A.F- B. BF3 C. BF4- D. none of them is correct
D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute
35. For an exothermic dissolution process, the increasing of the temperature causes: surface is increased.
A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct 49. All of them are correct except:
36. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature, A. An ionic compound at solid state does not conduct electric current.
what would be the value of that constant for the reverse reaction at the same condition? B. Alloy is a mixture the atoms of two or more metals are uniformly mixed.
A. 0.05 B. 0.1 C. 10 D. 5 C. The Brownian motion is a motion due to collision rapidly moving molecules.
D. HCl does not soluble in water.
37. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct?
50. The solution that contains the precisely known concentration of a solute is known as:
A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous.
A. saturated solution B. dilute solution C. standard solution D. buffer solution
C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous.
38. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O
fast :N2O+H2 →N2+H2O which of the following is correct ?
A. R=k[NO][H2]
C. the reaction order is second
B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O
D. Both (A+C) are correct
X
39. While mixing a small quantity of water with a large quantity of ethanol, water considered as :-
A. solvent B. solute C. solution D. none of them
40. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is
called:
A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat
 Kurdistan Region – Iraq 0025 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
Y 15. The energy required to raise the reactant to the level of the activated complex is:
A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction
SN: 6000105 16. The rate of the slow reaction increases by :
(science)
Answer the following questions : ( two marks for each right choice ) A. the addition of a catalyst. B. increasing activation energy
C. increasing concentration. D. Both (A+C) are correct
1. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base?
17. The net ionic equation for the precipitation Nickel ( II )sulfide is :
A.F- B. BF3 C. BF4- D. none of them is correct A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s)
2. Which of the following solutions with the same concentrations has lower [H3O+]? C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water.
A. HCl B. H2O C. NH3 D. HF 18. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat
3. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the is 0.449J/g.K?
concentration of both reactants is doubled? A. 202kJ B.27.83J C.1002J D. 202J
A. the reaction rate remains the same. B. the reaction rate increases by a factor of two. 19. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the
C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight. right ?
4. A substance that formed when a strong acid has lost a proton A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure
A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations 20. When barium chloride solution is mixed with sodium nitrate:
5. Adding NH4Cl to NH3 solution leads to: A. sodium chloride precipitates B. barium nitrate precipitates
A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+] C. precipitation does not occur D. Both ( A + B ) are correct
6. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for 21. The entropy increases at:
transition interval is (3.1- 4.4): A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct
A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH 22. Which of the following is the equilibrium constant for an anion hydrolysis reaction?
[HB][OH− ] [B− ] [HB] [B− ][OH− ]
7. The strength of an acid does not depend on: A. B. C. D.
[B− ] [HB][OH− ] [B− ][OH− ] [HB]
A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy
C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct 23. Which of the following is a binary acid?
A. H2S B.H2CO3 C. H2O2 D. all of them are correct
8. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct?
A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound. 24. Which of the following is homogenous mixture?
C. a liquid is polar molecular compound. D. none of them A. milk B. 24-karat gold C. tap water D. oil and water
9. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M 25. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is
the value of the equilibrium constant equals: called:
A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84 A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat
10. The dilute aqueous solution of a weak acid contains: 26. All of them are correct except:
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct A. An ionic compound at solid state does not conduct electric current.
B. Alloy is a mixture the atoms of two or more metals are uniformly mixed.
11. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ?
C. The Brownian motion is a motion due to collision rapidly moving molecules.
A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol
D. HCl does not soluble in water.
12. While mixing a small quantity of water with a large quantity of ethanol, water considered as :-
27. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :-
A. solvent B. solute C. solution D. none of them
A. 3.1 B. 3.7 C. 10.9 D. 10.3
13. Which of the following ions hydrolyze in aqueous solution?
28. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal
A.NO3- B. CO32- C. SO42- D. none of them is correct
50kJ/mol ,the activation energy for reverse reaction is equal to
14. When polar compound ionizes completely in water the compound is:
A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol
A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte.
29. The common-ion causes: 41. The solution that contains the precisely known concentration of a solute is known as:
A. increasing precipitation. B. decreasing ionization. A. saturated solution B. dilute solution C. standard solution D. buffer solution
C. shifting equilibrium to left. D. all of them are correct. 42. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion?
30. The boiling point of a solution is higher than that of a pure solvent because :- A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol
A. Vapor-pressure lowering B. Freezing- point heightening
43. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is:
C. Vapor-pressure heightening D. none of them
A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2
31. All of the following statements are true about the collision theory except:
44. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if :
A. all collisions between particles of reactant leads to the occurrence of the chemical reaction
A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined
B. the reaction rate is directly proportional with the number of effective collision.
C. in order for chemical reaction to occur, the reacting particles must collide 45. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of
D. the particles of reactants must have enough energy to initiate the reaction. solution?
32. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is; A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M
A. SO42- B. Al+3 C. H3O+ D. all of them are correct. 46. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are
33. A substance that can react as an acid or a base : contained per 250g of water?
A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol
A. SO42- B. HSO3- C.CH3COO- D. NH4+
47. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the
34. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature, concentration of carbonate ions is:
what would be the value of that constant for the reverse reaction at the same condition? A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M
A. 0.05 B. 0.1 C. 10 D. 5
48. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O
35. Aqueous solution of NH3 is an Arrhenius base because: fast :N2O+H2 →N2+H2O which of the following is correct ?
A. it is proton accepter. B. it increases the concentration of hydronium ion. A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O
C.it is an electron pair donor. D.it increases the concentration of hydroxide ion. C. the reaction order is second D. Both (A+C) are correct
36. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true 49. For an exothermic dissolution process, the increasing of the temperature causes:
about the reaction ? A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct
A. The reaction is always spontaneous. B. The reaction is never spontaneous. 50. Which of the following represents the formation equation?
C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature. A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2
37. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals :
-
A. 184.6kJ/mol B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol

38. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct?
A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous.
Y
C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous.
39. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a
nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant?
A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
40. Which one of the following statements is incorrect?
A. Many solids dissolve more quickly in a cold solvent than in warm solvent.
B. Gases are generally more soluble in water at low temperature.
C. Aqueous solution is a mixture containing the solute soluble in water as a solvent.
D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute
surface is increased.
 Kurdistan Region – Iraq 0026 In the Name of Allah Name: _ _ _ _ _ _ _ _ _ _ _ _ _
High Committee for General Examinations
General exams for preparatory stage
Subject: Chemistry Time: 3:30 Hours
91285
For the Academic year (2020-2021) Second attempt
Z 13. A solution made from ethanol ,C2H5OH,and water is 1.76m in ethanol .How many moles of ethanol are
contained per 250g of water?
A. 0.142mol B. 0.44mol C. 20.24mol D. 7.04mol
SN: 6000106
(science)
Answer the following questions : ( two marks for each right choice ) 14. In the following reaction :( 2HCl(g)+184.6kJ →H2(g)+Cl2(g) ), the standard formation enthalpy of HCl equals :
-
1. The common-ion causes: A. 184.6kJ/mol B. -184.6kJ/mol C. -92.3kJ/mol D. 92.3kJ/mol
A. increasing precipitation. B. decreasing ionization. 15. How much energy would be absorbed as heat by 75g of iron when heated from 295K to 301K if its specific heat
C. shifting equilibrium to left. D. all of them are correct. is 0.449J/g.K?
2. The solubility product of cadmium carbonate, CdCO3 , is 1.0x10-12 .In a saturated solution of this salt, the A. 202kJ B.27.83J C.1002J D. 202J
concentration of carbonate ions is: 16. When polar compound ionizes completely in water the compound is:
A. 5x10-13 M B. 3x10-6 M C. 1x10-6 M D. 5x10-7 M A. ionic electrolyte. B. weak electrolyte. C. non-electrolyte molecular. D. strong molecular electrolyte.
3. The following reaction :(2A+B →A2B) is occur by one step mechanism the rate law for the reaction is: 17. The entropy increases at:
A. R=k[A][B] B. R=k[A2B] C. R=k[A]2[B] D. R=k[A][B]2 A. evaporating of liquid B. temperature raising. C. increase pressure D. both(A+B) are correct
4. In the following an exothermic gaseous reaction :( 2CO+O2 →2CO2 ) , which of the following statements is true 18. Which of the following ions hydrolyze in aqueous solution?
about the reaction ? A.NO3- B. CO32- C. SO42- D. none of them is correct
A. The reaction is always spontaneous. B. The reaction is never spontaneous.
19. Unknown liquid miscible with toluene and immiscible with water which of the following statements is correct?
C. The reaction is spontaneous at low temperature. D. The reaction is spontaneous at high temperature.
A. an aqueous solution for the liquid conducts electric current. B. a liquid is nonpolar molecular compound.
5. The pH of an aqueous solution composed 2x10-4 mol of H3O+ ions in 250 mL of its solution is equal to :- C. a liquid is polar molecular compound. D. none of them
A. 3.1 B. 3.7 C. 10.9 D. 10.3
20. The enthalpy change that occurs during the complete combustion of one mole of an element or compound is
6. All of them are correct except: called:
A. An ionic compound at solid state does not conduct electric current. A. Enthalpy of formation. B. Enthalpy of solution. C. Enthalpy of combustion. D. Specific Heat
B. Alloy is a mixture the atoms of two or more metals are uniformly mixed.
C. The Brownian motion is a motion due to collision rapidly moving molecules. 21. Adding NH4Cl to NH3 solution leads to:
A. decrease [NH3] B. increase [OH-] C. increase ionization of NH3 D. increase [H3O+]
D. HCl does not soluble in water.
22. Which of the following represents the formation equation?
7. Which of the following solutions with the same concentrations has lower [H3O+]?
A. N2+O2 →2NO B. C(graphite) +O2 → CO2 C. CO+1/2 O2 →CO2 D. CO 2 →C(graphite) +O2
A. HCl B. H2O C. NH3 D. HF
23. How many moles of ammonium sulfate must be dissociate to produce 0.4 mol of sulfate ion?
8. The net ionic equation for the precipitation Nickel ( II )sulfide is :
A. NiS(s) → Ni+2(aq) +S-2(aq) B. 2Ni+2(aq) +2S-2(aq) → Ni2S2(s) A. 0.2 mol B. 0.4 mol C. 0.6 mol D. 0.8 mol
C. Ni+2(aq) +S-2(aq) → NiS(s) D. it does not have precipitate equation because it is soluble in water. 24. Which of the following is a binary acid?
9. For an exothermic dissolution process, the increasing of the temperature causes: A. H2S B.H2CO3 C. H2O2 D. all of them are correct
A. increasing dissolution B. decreasing dissolution C. decreasing crystallization D. Both (A+C) are correct 25. The value of equilibrium constant for this gaseous reaction :(N2O4 2NO2) is 0.1 at a specified temperature,
10. A substance that can react as an acid or a base : what would be the value of that constant for the reverse reaction at the same condition?
A. 0.05 B. 0.1 C. 10 D. 5
A. SO42- B. HSO3- C.CH3COO- D. NH4+
11. The boiling point of a solution is higher than that of a pure solvent because :- 26. A proposed mechanism for the reaction is:- slow :2NO+H2 →N2O+H2O
A. Vapor-pressure lowering B. Freezing- point heightening fast :N2O+H2 →N2+H2O which of the following is correct ?
C. Vapor-pressure heightening D. none of them A. R=k[NO][H2] B. overall balanced equation for the reaction is :2NO+2H2 →N2+2H2O
C. the reaction order is second D. Both (A+C) are correct
12. In the following gaseous reaction:(N2+3H2 2NH3) it was found the [NH3]=0.62 M ,[H2]=0.14 M, [N2]=0.45 M
the value of the equilibrium constant equals: 27. A substance that formed when a strong acid has lost a proton
A. 3.2x10-3 B. 3.11x102 C. 3.11x10-2 D. 9.84 A. strong conjugate base B. weak conjugate acid C. weak conjugate base D. cations
28. The solution that contains the precisely known concentration of a solute is known as: 43. When barium chloride solution is mixed with sodium nitrate:
A. saturated solution B. dilute solution C. standard solution D. buffer solution A. sodium chloride precipitates B. barium nitrate precipitates
29. In the following hypothetical reaction :(A2+B2 →2AB+30kJ), the activation energy for the forward reaction equal C. precipitation does not occur D. Both ( A + B ) are correct
50kJ/mol ,the activation energy for reverse reaction is equal to 44. The methyl orange is used to determine the equivalence point in one of the following titration: If the pH range for
A.20kJ/mol B. 80kJ/mol C. -80kJ/mol D.10kJ/mol transition interval is (3.1- 4.4):
A. HCl, NH3 B. CH3COOH,NaOH C. HNO3,NaOH D.NH3,CH3COOH
30. The strength of an acid does not depend on:
A. The polarity of the bond between hydrogen and the element it is bonded. B. the bond energy 45. All of the following statements are true about the collision theory except:
C. the number of hydrogen atoms in the chemical acid formula. D. both (A+B) are correct A. all collisions between particles of reactant leads to the occurrence of the chemical reaction
B. the reaction rate is directly proportional with the number of effective collision.
31. The rate of the slow reaction increases by :
C. in order for chemical reaction to occur, the reacting particles must collide
A. the addition of a catalyst. B. increasing activation energy
D. the particles of reactants must have enough energy to initiate the reaction.
C. increasing concentration. D. Both (A+C) are correct
46. Aqueous solution of NH3 is an Arrhenius base because:
32. In aqueous solution contains, Ca+2,SO42- ions, CaSO4 precipitates if :
A. it is proton accepter. B. it increases the concentration of hydronium ion.
A. [Ca+2][SO42-]=Ksp B. [Ca+2][SO42-] >Ksp C. [Ca+2][SO42-] < Ksp D. can not be determined
C.it is an electron pair donor. D.it increases the concentration of hydroxide ion.
33. While mixing a small quantity of water with a large quantity of ethanol, water considered as :-
47. The rate law of the following reaction: A+2B →AB2 ,is R=k[B] 2 , what happens to the reaction rate when the
A. solvent B. solute C. solution D. none of them
concentration of both reactants is doubled?
34. the spectator ion in the following reaction (Al(S) +H2SO4(aq) → ), is; A. the reaction rate remains the same. B. the reaction rate increases by a factor of two.
A. SO42- B. Al+3 C. H3O+ D. all of them are correct. C. the reaction rate increases by a factor of four. D. the reaction rate increases by a factor eight.
35. Which of the following is the equilibrium constant for an anion hydrolysis reaction? 48. Which one of the following statements is incorrect?
[HB][OH− ] [B− ] [HB] [B− ][OH− ] A. Many solids dissolve more quickly in a cold solvent than in warm solvent.
A. B. C. D.
[B− ] [HB][OH− ] [B− ][OH− ] [HB]
B. Gases are generally more soluble in water at low temperature.
36. In the following reaction :( BF3(aq) +F-(aq) → BF4-(aq) ) which of the following is Lewis base? C. Aqueous solution is a mixture containing the solute soluble in water as a solvent.
D. The effect of stirring is similar to that of crushing a solid – contact between the solvent and the solute
A.F- B. BF3 C. BF4- D. none of them is correct surface is increased.
37. A reaction has ∆H=-74.8kJ/mol , ∆S=-0.081kJ/mol.K at 27oC which of the following is correct? 49. Calculate the moles of NaOH if 100 mL of its solution neutralized with 200 mL of 0.01M HBr ?
A. ∆G= 50.5 kJ/mol , nonspontaneous . B. ∆G= -72.8 kJ/mol , spontaneous. A. 0.01mol B. 0.002mol C. 0.001mol D. 0.02mol
C. ∆G= 72.8 kJ/mol , nonspontaneous D. ∆G= -50.5 kJ/mol , spontaneous. 50. In equilibrium gaseous reaction: 2NO+Cl2 2NOCl +energy, which of the following shift the reaction to the
38. The energy required to raise the reactant to the level of the activated complex is: right ?
A. Activation energy B. Free energy C. Kinetic energy D. Energy of reaction A. adding catalyst B. decreasing system volume C. increasing temperature D. decreasing pressure
39. The dilute aqueous solution of a weak acid contains:
A. hydronium ions. B. acid molecules. C. anions. D. all of them are correct
40. The boiling-point elevation of a solvent is 2.4oC, when the concentration of the solution containing a
nonelectrolyte solute is 3.1m, what is the value of molal boiling-point constant?
Z
A. 1.29oC/m B. -0.77oC/m C. 7.44oC/m D. 0.77oC/m
41. Which of the following is homogenous mixture?
A. milk B. 24-karat gold C. tap water D. oil and water
42. The concentration of H3O+ ions in aqueous solution of Ba(OH)2 is 1x10-11 M, what is the molar concentration of
solution?
A. 1x10-3 M B. 2x10-4 M C. 2x10-3 M D. 5x10-4 M