Stainless Steel Technical Guide
Effects of Alloying Elements and Impurities in
Stainless Steels and High Strength Heat-Resisting
Alloys
Aluminum (AI)                                                                         Nitrogen (N)
     A strong ferrite former. Added to type 405 12% straight chrome weld metal to        A strong austenite former
     make it non-hardening (ferritic)                                                    Used to minimize grain grown in high chromium straight chromium steels at high
     Used to improve high temperature scaling resistance                                 temperatures
     Added with titanium to some high strength alloys for age hardening effects          Adversely affects weld metal toughness at cryogenic temperatures
     Strong nitride former                                                               Raises strength
Carbon (C)                                                                            Nickel (Ni)
     A strong austenite former                                                           An austenite former
     Added to some high strength alloys for hardening and strengthening effects          Used to improve the general corrosion resistance against non-oxidizing liquids
     Adversely affects weld metal corrosion resistance and toughness at low              Sometimes added in small amounts to straight chromium grades to improve the
     temperatures                                                                        mechanical properties
                                                                                         Generally improves weld metal toughness
Columbium (Niobium) Cb(Nb)
                                                                                      Phosphorus (P) Sulphur (S) Selenium (Se)
     A strong carbide former. Used to stabilize austenitic stainless steels against
     precipitation of chromium carbides in the range of 800- 1600°F                      One of these three elements is occasionally added to stainless steels in
     Moderate ferrite former                                                             conjunction with a small amount of Molybdenum or Zirconium to improve
     Added to some high strength alloys for hardening and strengthening effects          machinability of the steel
     Added to some martensitic straight chromium stainless steels to tie up the          All three promote cracking in weld metal
     carbon and reduce the hardening tendency of the steels
Cobolt (Co)                                                                            Silicon (Si)
   Added to various alloys to impart strength and creep resistance at high                 A ferrite former
   temperatures                                                                            Used to increase the corrosion resistance of austenitic steels
                                                                                           Used to improve high temperature scaling resistance
Chromium (Cr)                                                                              Used to improve resistance of high temperature steels to carburization
   A ferrite and carbide former                                                        Titanium (Ti)
   Primary contributor to scaling and corrosion resistance
   In the stainless steels, this element has little or no effect on high temperature       A strong carbide and nitride former. Used to stabilize austenitic stainless steels
   strength and creep strength                                                             against precipitation of chromium carbides in the range of 800-1600°F
                                                                                           A strong ferrite former
Copper (Cu)                                                                                Added to some high strength heat resisting alloys for its hardening and
                                                                                           strengthening effects
   Used to improve corrosion resistance of stainless steel in many liquids which           Added with aluminum to some high strength heat resisting alloys for age
   are reducing rather than oxidizing                                                      hardening effects
Molybdenum (Mo)                                                                        Tungsten (W)
   A ferrite and carbide former                                                            Improves the high temperature strength and creep resistance of some high
   Used to improve high temperature strength and creep resistance                          temperature alloys
   Used to improve general corrosion resistance of steels in non-oxidizing media,          A strong ferrite former
   and the resistance to pitting corrosion in all media                                    Stainless Steel Covered Electrodes
                                                                                           Electrode Identification
Manganese (Mn)                                                                             Commercial stainless electrodes are imprinted with the AWS grade and,
                                                                                           frequently, a lot number
   Austenite former
   Improves weld metal crack resistance in fully austenitic alloys