Safety Data Sheet

According to regulation (EC) No. 1907/2006 (REACH)

64004 Firebrake® ZB
Page 1
Revised edition: 01.12.2016 Version: 4 Printed: 06.02.2017
1. Identification of the Substance/Mixture and of the Company/Undertaking
1. 1. Product Identifier
Product Name: Firebrake® ZB
Article No.: 64004
1. 2. Relevant identified Uses of the Substance or Mixture and Uses advised against
Identified uses:
Flame retardant
Anticorrosive adhesion polymer
Anti tracking in polymers
Corrosion inhibitors and anti-scaling agents
Uses advised against:
1. 3. Details of the Supplier of the Safety Data Sheet (Producer/Importer)
Company: Kremer Pigmente GmbH & Co. KG
Address: Hauptstr. 41-47, 88317 Aichstetten, Germany
Tel./Fax.: Tel +49 7565 914480, Fax +49 7565 1606
Internet: www.kremer-pigmente.de
EMail: [email protected]
Importer: --
1. 4. Emergency No.
Emergency No.: +49 7565 914480 (Mon-Fri 8:00 - 17:00)
2. Hazards Identification
2. 1. Classification of the Substance or Mixture
Classification according to Regulation
(EC) No. 1272/2008 (CLP/GHS)
Reproductive toxicity, hazard category 2
Acute aquatic toxicity, hazard category 1
Chronic aquatic toxicity, hazard category 2
H361d Suspected of damaging the unborn child.
Cat.: 2
H400 Very toxic to aquatic life.
Cat.: 1
H411 Toxic to aquatic life with long lasting effects.
Cat.: 2
Classification according to Directive No.
67/548/EC or No. 1999/45/EC
Hazardous to the R50 Very toxic to aquatic organisms.
environment (N)
Hazardous to the R51 Toxic to aquatic organisms.
environment (N)
R53 May cause long-term adverse effects in the aquatic environment.
Safety Phrases:
Possible Environmental Effects:
Label Elements
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According to regulation (EC) No. 1907/2006 (REACH)

64004 Firebrake® ZB
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Revised edition: 01.12.2016 Version: 4 Printed: 06.02.2017
2. 2.
Classification according to Regulation
(EC) No. 1272/2008 (CLP/GHS)
Hazard designation:

GHS08

GHS09-1

Signal word:
Warning
Hazard designation:
H361d Suspected of damaging the unborn child.
H400 Very toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
Safety designation:
P202 Do not handle until all safety precautions have been read and
understood.
P273 Avoid release to the environment.
P308+P313 If exposed or concerned: Get medical advice/attention.
P501 Dispose of contents/ container according to regional, national and
international regulations.
Hazardous components for labelling:
2. 3. Other Hazards
3. Composition/Information on Ingredients
3. 1. Substance
3. 2. Mixture
Chemical Characterization: Dodecaboron tetrazinc docosaoxide heptahydrate. CAS No. 138265-
88-0; EINECS 235-804-2. REACH Reg. No. 01-2119691658-19-0000
Information on Components / Hazardous
Ingredients:
Zinc Borate (N; R50-50/53; Repr.2, H361d-400- > 98.8 % CAS-Nr: 138265-88-0
410); REACH Reg. No. 01-2119691658-19-0000) EINECS-Nr: 235-804-2
EC-Nr:

Additional information:
4. First Aid Measures
4. 1. Description of the First Aid Measures
General information:
Seek medical attention in case of complaints.
After inhalation:
Supply fresh air. next page: 3
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In case of complaints consult a physician.
After skin contact:
This product is in general not irritating to the skin.
After eye contact:
Rinse open eye for several minutes under running water. Should
irritation continue, seek medical advice.
After ingestion:
No hazards for healthy adults expected when small amounts (a
teaspoon) are swallowed.
Rinse mouth with water and drink plenty of water.
If symptoms persist consult physician.
4. 2. Most important Symptoms and Effects, both Acute and Delayed
Symptoms:
Prolonged/repeated intake or contact of inorganic borate salts may
cause following symptoms: nausea, vomiting, diarrhea, anemia,
skin redness, scaling of the skin.
Effects:
No further information available.
4. 3. Indication of any Immediate Medical Attention and special Treatment needed
Treatment:
Note to physicians: Supportive care only is required for adult
ingestion of less than a few grams of the product.
For ingestion of larger amounts, maintain fluid and electrolyte
balance and maintain adequate kidney funktion. Gastric lavage is
only recommended for heavily exposed, symptomatic patients in
whom emesis has not emptied the stomach.
Hemodialysis should be reserved for patients with massive acute
absortion, especially for patients with compromised renal function.
Boron analyses of urine and blood are only useful for verifying
exposure and are not useful for evaluating severity of poisoning or
as a guide in treatment.
5. Fire-Fighting Measures
5. 1. Extinguishing Media
Suitable extinguishing media:
Product itself does not burn.
Use extinguishing media for surrounding fire.
Unsuitable extinguishing media:
None known.
5. 2. Special Hazards arising from the Substance or Mixture
Special hazards:
None. The product is not flammable, combustible or explosive.
5. 3. Advice for Firefighters
Protective equipment:
No special measures required.
Further information:
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Not applicable: the product itself is a flame retardant.
6. Accidential Release Measures
6. 1. Personal Precautions, Protective Equipment and Emergency Procedures
Personal precautions:
Do not inhale dust.
Avoid contact with eyes.
6. 2. Environmental Precautions
Environmental precautions:
Prevent contamination of soils, drains and surface water.
Contact local authorities if product pollutes soil or vegetation.
6. 3. Methods and Material for Containment and Cleaning Up
Methods and material:
Take up mechanically and collect in suitable containers for
disposal.
6. 4. Reference to other Sections
For information for safe handling see Section 7.
Protective clothing, see Section 8.
See Section 13 for information on disposal.
7. Handling and Storage
7. 1. Precautions for Safe Handling
Instructions on safe handling:
Avoid formation of dust. Do not inhale dust.
Hygienic measures:
Keep away from foodstuffs and drinks. Do not eat, drink or smoke
during work. Wash hands before breaks and at the end of work.
Take off contaminated clothing immediately. Store working clothes
separately.
7. 2. Conditions for Safe Storage, including any Incompatibilities
Storage conditions:
Store in a cool and dry place.
Protect against humidity.
Requirements for storage areas and
containers:
Store product in closed containers.
Information on fire and explosion
protection:
No special measures necessary.
Storage class (VCI):
13; Non combustible solids
Further Information:
7. 3. Specific End Use(s)
Further information:
No information available.
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According to regulation (EC) No. 1907/2006 (REACH)

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8. Exposure Controls/Personal Protection

8. 1. Parameters to be Controlled
Parameters to be controlled (DE):
none known
Parameters to be controlled:
OEL: 1 mg B/m3 (recommended value)
Derived No-Effect Level (DNEL):
Zinc Borate:
25.7 mg/m3 (worker, inhalation, chronic effects - systemic)
1814 mg/kg/D (worker, skin contact, chronic effects - systemic)
2.8 mg/kg/D (consumer, swallowing, chronic effects - systemic)
9.5 mg/m3 (consumer, inhalation, chronic effects - systemic)
1379 mg/kg/D (consumer, skin contact, chronic effects - systemic)
Predicted No-Effect Concentration
(PNEC):
Zinc ion:
Fresh water sediment: 1000 mg/l
Seawater: 6.1 µg/l
Fresh water sediment: 117.8 mg/kg
Intermittent release: 0.61 mg/l
Soil: 107 mg/kg
Sewage treatment system (STP): 100 µg/l
Boron:
Fresh water / Seawater: 2900 µg/l
Water, intermittent: 13700 µl
Soil: 5.7 mg/kg
Sewage treatment system (STP): 10 mg/l
Additional Information:
8. 2. Exposure Controls
Technical protective measures:
Use local exhaust ventilation in case of dust and/or fume
formation.
Personal Protection
General protective measures:
Wash hands before breaks and after work.
Respiratory protection:
None required under normal operating conditions.
Hand protection:
Protective gloves (EN 374)
Protective glove material:
Butyl or nitrile rubber.
Natural latex.
Suitability and durability of a glove is dependent on usage, e.g.
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frequency and duration of contact, chemical resistance of glove
material and dexterity. Always seek advice from glove suppliers.
Eye protection:
Safety glasses (EN 166)
Body protection:
Protective clothing.
Environmental precautions:
Avoid contamination of sewage system, open water ways and
ground water.
9. Physical and Chemical Properties
9. 1. Information on Basic Physical and Chemical Properties
Form: powder
Color: white
Odor: odorless
Odor threshold:
No information available.
pH-Value: 6.8 - 7.5 (20°C)
Melting temperature: > 300°C
Boiling temperature:
not determined
Flash point:
not applicable
Evaporation rate:
not applicable
Flammability (solid, gas):
not flammable
Upper explosion limit:
not determined
Lower explosion limit:
not determined
Vapor pressure:
not applicable
Vapor density:
No information available.
Density: 2.6 g/cm3 (20°C)
Solubility in water: < 0.28 % (25°C)
Coefficient of variation (n-
Octanol/Water):
not determined
Auto-ignition temperature:
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No information available.
Decomposition temperature:
not determined
Viscosity, dynamic:
not applicable
Explosive properties:
Product does not present an explosion hazard.
Oxidizing properties:
none
Bulk density:
not determined
9. 2. Further Information
Solubility in solvents:
Viscosity, kinematic
Burning class:
Solvent content:
Solid content:
Particle size:
Other information:
No further information.
10. Stability and Reactivity
10.1. Reactivity
Stable if used according to specifications.
10.2. Chemical Stability
Stable at room temperature.
10.3. Possibility of Hazardous Reactions
Reacts with strong reducing agents, e.g. metal hydrides or
alkalimetals (development of hydrogen: explosion risk)
10.4. Conditions to Avoid
Conditions to avoid:
No further information available.
Thermal decomposition:
No further information available.
10.5. Imcompatible Materials
Strong reducing agents.
10.6. Hazardous Decomposition Products
None if handled according to specifications.
10.7. Further Information
11. Toxicological Information
11. 1. Information on Toxicological Effects
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Acute Toxicity
LD50, oral: > 10000 mg/kg (rat)
Zinc borate: 2335 /kg (50 % w/v formulation in corn oil; rat; OECD
401)
LD50, dermal: > 10000 mg/kg (rabbit)
Zinc borate: 2335 /kg (rabbit)
LC50, inhalation:
Zinc borate: > 4.95 mg/l (rat; OECD 403)
Primary effects
Irritant effect on skin:
Non irritating (rabbit)
Dosage: 500 mg; Route of exposure: dermal
Irritant effect on eyes:
Non-irritating to eyes (rabbit)
Dosage: 100 mg; Route of exposure: eyes
Inhalation:
No information available.
Ingestion:
No information available
Sensitization:
Zinc borate (hydrate; 0.4 g): no sensitizing effects known (guinea
pig; OECD 406).
Mutagenicity:
Zinc borate hydrate: 0.001-0.075 mg/ml (1 - 75 ppm); mouse
(lymphoma cells; in-vitro): not mutagenic (Ames-Test; OECD 476)
Reproductive toxicity:
Zinc borate hydrate: NOAEL (Oral) 100 mg/kg bw (0, 50, 100, 200,
375 mg Zinc borate hydrate / kg/Tag); rat (90-Day Oral Toxicity
Study; OECD 408)
Zinc borate hydrate: NOAEL (Oral) < 100 mg/kg bw (0, 100, 125,
150 mg zink borate hydrate / kg bw); rat (Prenatal Development
Toxicity Study; OECD 414). Classification: Reproductive Toxicity
Category 2 (Hazard Statement: H361d: Suspected of damaging
the unborn child).
Boron: A subset of workers was exposed to 125 mg B/day
(combined oral ingestion and inhalation): No adverse fertility
effects in male workers. Epidemiological studies of human
developmental effects have shown an absence of effects in
exposed borate workers and populations living in areas with high
environmental levels of boron.
(Method: Occupational studies of evaluating sensitive sperm
parameters in highly exposed borate workers. Epidemiological
studies evaluating high environmental exposures to boron and
developmental effects in humans have been conducted).
Cancerogenity:
No experimental test data on zinc borate.
Results: Zinc borate disassociates to zinc hydroxide and boric acid
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in the low pH environment of the stomach. No carcinogenic effects
observed in chronic carcinogenicity studies of boric acid conducted
in rats and mice, and no evidence of carcinogenic effects in zinc
borate breakdown products.
Based on the available data, the classification criteria are not met.
Teratogenicity:
No information available.
Specific target organ toxicity (STOT):
Single exposure: no target organ has been identified in humans.
Repeated exposure: Subacute toxicity (oral): NOAEL: 150 mg/kg
KG/day (rat; 28 days; OECD 407), not considered to represent
severe damage to the health of animals. At doses above 105
mg/kg/day, haematological changes indicative of anaemia was
observed. Based on the available data, the classification criteria
were not met.
Additional toxicological information:
Aspiration hazard: not applicable
Toxicokinetics: Following a single dose (1000 mg/kg) of zinc
borate hydrate, zinc and boron appeared in rat plasma and tissue
samples, indicating the hydrolysis of zinc borate in the
gastrointestinal tract and subsequent systemic absorption of zinc
and boron. In plasma, Tmax occured between 5 and 6h after
administration. Concentrations decreased to background levels by
72h post-dose; T1/2 ranged from 5 to 7.7h (zinc and boron, resp.).
Information on the likely routes of exposure: Inhalation is the most
significant route of exposure in occupational and other settings.
Dermal exposure is not usually a concern because the product is
poorly absorbed through the intact skin. Product is not intended for
ingestion.
Symptoms: Not expected to be irritating to eyes, nose, throat or
skin in normal industrial use. Occasional mild irritation effects to
the nose and throat may occur from inhalation of dust levels
greater than 10 mg/m3. Products containing zinc borate are not
intended for ingestion. Zinc borate has a low acute toxicity. Small
amounts (e.g. a teaspoon) swallowed accidentally are not likely to
cause effect; swallowing amounts larger than that may cause
gastrointestinal symptoms.
Epidemiological studies in humans did not show any significant
increase in lung diseases in professionals who are chronically
exposed to boric acid and sodium borate dust. Epidemiological
studies in humans did not show a signifant effect on the fertility in
professionals who are chronically exposed to borate dust and does
not show any adverse effects in the general population at a high
environmental exposition to borates.
12. Ecological Information
12. 1. Aquatic Toxicity
Data values are expressed as zinc ion or boron equivalents. To
convert to this product, divide the zinc equivalent by 0.301 and
divide the boron equivalent by 0.149. Studies judged to be
unreliable or with insufficient information to evaluate are not
included.
Fish toxicity:
Freshwater (Chronic study): Zinc: 0.044 mg Zn/l (Joranella
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floridae) to 0.530 mg Zn/l (Salvenius fontinalis)
Freshwater (Chronic studies): Boron (Fish): 6.3 mg B/l (Danio
rerio) to 36.8 mg B/l (Micropterus salmoides); Boron (Amphibian):
9.4 mg B/l (Xenopus laevis) to 69.6 mg B/l (Bufo fowleri)
Freshwater (Acute study): Zinc: 0.169 mg Zn/l (Oncorhynchus
mykiss) to 1.16 mg Zn/l (Oncorhynchus kisutch)
Freshwater (Acute study): Boron: 79.7 mg B/l (Pimephales
promelas)
Marine and Estuarine Data (Chronic study): Zinc: 0.025 mg Zn/l
(Clupea harengus)
Marine and Estuarine Data (Acute study): Zinc: see freshwater
acute data and marine chronic data.
Marine and Estuarine Data (Acute study): Boron: 74.0 mg B/l
(Limanda limanda)
Daphnia toxicity:
Freshwater (Chronic study): Zinc: 0.037 mg Zn/l (Ceriodaphnia
dubia) to 0.137 mg Zn/l (Chironomus tentans)
Freshwater (Chronic study): Boron: 6.3 mg B/l (Hyalella azteca) to
30.0 mg B/l (Lampsilis silliquoidea)
Freshwater (Acute study): Zinc: 0.147 mg Zn/l (Ceriodaphnia
dubia) to 1.05 mg Zn/l (Daphnia magna)
Freshwater (Acute study): Boron: 112.9 mg B/l (Ceriodaphnia,
dubia) bis > 544 mg B/l (Megalonaias nervosa)
Marine and Estuarine Data (Chronic study): Zinc: 0.010 mg Zn/l
(Arbacia lixula, Sphaerechinus granularis) to 0.900 mg Zn/l (Mya
arenia)
Marine and Estuarine Data (Chronic study): Boron: 16.6 mg B/l
(Americamysis bahia)
Marine and Estuarine Data (Acute study): Zinc: see freshwater
acute data and marine chronic data.
Marine and Estuarine Data (Chronic study): Boron: 130 mg B/l
(Litopenaeus vannamei)
Sediment: Boron: 37.7 mg B/kg sediment TG (Chironomus
riparius)
Bacteria toxicity:
Terrestrial Data (Chronic Studies):
Zinc: Plant: 32 mg Zn/kg TG (Trifolium pratense, Vicia sativa) to
5855 mg Zn/kg TG (Triticum aestivum); Invertebrates: 14.6 mg
Zn/kg TG (Folsomia candida) to 1634 mg Zn/kg TG (Lumbricus
terrestris); Soil micro-organisms: 17 mg Zn/kg TG (soil respiration)
to 2623 mg Zn/kg TG (phosphatase)
Boron: Plant: 7.2 mg B/kg dw (Zea mays) to 56 mg B/kg dw (Allium
cepa); Invertebrates: 15.4 mg B/kg dw (Folsomia candida) to 86.7
mg B/kg dw (Caenorhabditis elegans); Soil micro-organisms: 41.3
mg B/kg dw (Substrate-induced nitrification) to 48.1 mg B/kg dw
(soil nitrogen transformation test)
Sediment toxicity data:
Zinc: Crustacean: 0.146 mg Zn/kg TG (Gammarus pulex) to 0.529
mg Zn/kg TG (Hyalella azteca); ; Insects: 0.164 mg Zn/kg TG
(Ephoron virgo) to 0.696 mg Zn/kg TG (Chironomus tentans);
Worms: 0.878 mg Zn/kg TG (Lumbriculus variegates) to 1.101 mg
Zn/kg TG (Tubifex tubifex)
Sewage plant (STP) Zinc (Microbial process): > 0.1 Zn/l
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(nitrification)
Boron: Active Sludge: > 17.5 mg B/l to 1000 mg B/l; Microbes: 10
mg B/l (Opercularia bimarginata) to 20 mg B/l (Paramecium
caudatum)
Algae toxicity:
Freshwater (Chronic studies): Zinc (Algae): 0.,019 mg Zn/l
(Pseudokirchneriella subcapitata) to 0.048 mg Zn/l (Chlorella sp.);
Zinc (Higher plants): 0.060 mg Zn/l (Cladophora glomerata) to >
0.65 mg Zn/l (Elodea nuttalli, Callitrische platycarpa, Spirodella
polyrhiza, Lemna gibba, L. minor, L. pauciscostata)
Freshwater (Chronic study): Boron (Algae): 17.5 mg B/l
(Pseudokirchneriella subcapitata); Boron (Higher plants): 6.0 mg
B/l (Spirodella polyrhiza)
Freshwater (Acute study): Zinc: 0.142 mg Zn/l
(Pseudokirchneriella subcapitata)
Freshwater (Acute study): Bor: 52.4 mg B/l (Pseudokirchneriella
subcapitata)
Marine and Estuarine Data (Chronic studies): Zinc (microscopic
algae): 0.011 mg Zn/l (Chaetoceros compressum) to 0.066 mg Zn/l
(Nitzschia closterium); Zinc (macroscopic algae): 0.008 mg Zn/l
(Ceranium tenuicore) to 0.671 mg Zn/l (Pelvetia canaliculata)
Marine and Estuarine Data (Chronic study): Boron: 27.9 mg B/l
(Phaedactylum tricornutum)
Marine and Estuarine Data (Acute study): Zinc: see freshwater
acute data and marine chronic data.
Marine and Estuarine Data (Acute study): Boron: 66.0 mg B/l
(Pseudokirchneriella subcapitata)
12. 2. Persistency and Degradability
Inorganic substance. Biological degradability is not affected.
12. 3. Bioaccumulation
Zinc borate will hydrolyse under environmental conditions to boric
acid and zinc hydroxide via zinc oxide. Boric acid will not
biomagnify through the food chain. The solubility of zinc hydroxide
is low under neutral and basic conditions (pH). The rate of
hydrolysis depends on the initial loading and pH value. Zinc is,
however, an essential element which is actively regulated by
organisms. Bioaccumulation is thus not considered to be relevant.
12. 4. Mobility
Zinc borate hydrolyses into boric acid and zinc hydroxide. The
absorption of boric acid in soils or sediments is minimal. The
absorption of zinc ions is described by the partition coefficient.
Partition coefficient for boric acid: 2.19 l/kg (soil), 2.8 l/kg
(sediment)
Partition coefficient for zinc: 159 l/kg (soil), 73000 l/kg (sediment),
6010 l/kg (seawater sediment)
12. 5. Results of PBT- und vPvP Assessment
Inorganic substance: does not comply with the criteria for the
classification as PBT or vPvB.
12. 6. Other Adverse Effects
Water hazard class:
Do not let product contaminate ground water, waterways or
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sewage system.
Behaviour in sewage systems:
Further ecological effects:
AOX Value:
13. Disposal Considerations
13. 1. Waste Treatment Methods
Product:
Must not be disposed together with household garbage.
This product is classified as toxic to reproduction (Repr. 2) and as
dangerous for the environment (Env.Acute 1) and falls within the
scope of Directive 2008/98/EC as hazardous waste (H10 and H14,
respectively). Tonnage quantities of product should, if possible, be
used for an appropriate application. Final disposal must be made
in a registered landfill site according to the local authorities.
Zinc borate has a reportable quantity (RQ) of 454 kg (1000 lbs).
European Waste Code (EWC):
Uncleaned packaging:
Dispose of according to official local regulations.
Waste Code No.:
14. Transport Information
14. 1. UN Number
ADR, IMDG, IATA 3077
14. 2. UN Proper Shipping Name
ADR/RID: UMWELTGEFÄHRDENDER STOFF, FEST, N.A.G. (Zinkborat)
IMDG/IATA: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(Zinc borate)
14. 3. Transport Hazard Classes
ADR Class: 9
Hazard no.: 9
Classification code: M7
Tunnel restriction code: E
IMDG Class (sea): 9
Hazard no.: 9
EmS No.: F-A,S-F
IATA Class: 9
Hazard no.: 9
14. 4. Packaging Group
ADR/RID: III
IMDG: III
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IATA: III
14. 5. Environmental Hazards
Labelling according 5.2.1.8 ADR/RID: fish and tree
Labelling according 5.2.1.6.3 IMDG: fish and tree
Labelled with "P" according 2.10 IMDG: yes
14. 6. Special Precautions for User
Warning: various dangerous materials and products.
14. 7. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code
not applicable
14. 8. Further Information
15. Regulatory Information
15. 1. Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture
Water hazard class:
2, hazardous for water (German Regulation)
Local regulations on chemical accidents:
Employment restrictions:
Restriction and prohibition of application:
Restricted to professional users!
Technical instructions on air quality:
15. 2. Chemical Safety Assessment
A Chemical Safety Assessment has been carried out for this
product.
15. 3. Further Information
EINECS (235-804-2), TSCA (US; 1332-07-6), DSL/INV (CA; 1332-
07-6), METI (JP; (1)-73), KECI (KR; KE-18394), IECSC (CN;
138265-88-0)
Regulation (EC) 2037/2000 - Substances that Deplete the Ozone
Layer: does not contain any ozondepleting substances of group I
and II nor are any used for the manufacture.
Clean Air Act (Montreal Protocol) - Substances that Deplete the
Ozone Layer: does not contain any ozondepleting substances of
group I and II nor are any used for the manufacture.
Regulation (EC) 689/2008 concerning the export and import of
dangerous chemicals: not regulated / not applicable
16. Other Information
This product should be stored, handled and used in accordance
with good hygiene practices and in conformity with any legal
regulations. This information contained herein is based on the
present state of knowledge and is intended to describe our product
from the point of view of safety requirements. It should be
therefore not be construed as guaranteeing specific properties.