Ql Q2 Q3 Q4 Qs Q6 Q7 Qs Q9 Q.10 Qu Qi2 Q13 Qld Qs EXERCISE # SINGLE CORRECT Inthe precipitation ofthe iron group in qualitative analysis, ammonium chloride is added before adding ammonium hydroxideto (A) decrease concentration of OH— ions. _(B) prevent interference by phosphate ions, (C)inerease concentration of CI ions, (D)None of these salt gives violet vapours when treated with conc. H,SO,, it contains (cr (B)I- (Br (D) NOs ‘The acidic solution of a salt produceda deep blue colour with starch iodide solution. The salt may be (A) chloride (B)nitrite (C)acetate (D) bromide Whena mixture of solid NaCl, solid KCr,O, is heated with cone. H,SO,, orange red vapours are obtained. These are of the compound (A) chromous chloride (B)chromyl chloride (C) chromic chloride (D)chromic sulphate Nessler's reagent is (A)K,Hel, (B)K,Hgl,+KOH (C)K,Hgl,+KOH (D) K,Hgl, + KI When bismuth chloride is poured into a large volume of water the white precipitate produced is (A)BiOH), (B)Bi,0, (CBiocl (D)Bi,OCI, Ferric ion formsa prussian blue coloured ppt of (A) K,[Fe(CN),] (B) Fe,[Fe(CN)], (C)KMnO, (D) Fe(OH), A mixture, on heating with cone. H,SO, and MnO, librates brown vapour of (A)Br, (B) NO, (C)HBr (yl, Atthe occasion of marriage, the fire works are used, which of the following gives green flame? (A) Ba (B)K (C)Be (D)Na Nitrate is confirmed by ring test. The brown colour of the ring is due to formation of (A) ferrous nitrite (B)nitroso ferrous sulphate (C) ferrous nitrate (D) FeSO,NO, Fe(OH); can be separated from Al(OH), by addition of (A)dil. HCL (B) NaCl solution (C)NaOHsolution — (D) NH,Cl and NH,OH IfNaQH isadded oan aqueous solution of zine ions a white ppt appears and on adding excess NaOH, the pptdissolves. In this solution zine exist in the (A) cationic part (B)anionic part (C)both incationic and anionic parts (D) there is no zine ion in the solution Mark the compound whichis soluble in hot water. (A) Lead chloride (B)Mercurous chloride (C)Stronsium sulphate (D)Silverchloride Colour of nickel chloride solution is (A) pink (B) black (C)colourless (D)green Sometimes yellow turbidity appears while passing H,S gas even in the absence of Il group radicals. This isbecause of (A) sulphur is present in the mixture as impurity. (B)IV group radicals are precipitated as sulphides. (C)the oxidation of H,S gas by some acid radicals. (D) Ill group radicals are precipitated as hydroxidesQ6 Qi7 Qs Qu9 Q.20 Q2i Q2 Q23 Q.24 Q25 Q.26 Q27 Q28 Q29 Q30 ‘The ion that cannot be precipitated by H,S in presence of dilute HCl is (A) Poe (B)Cu* (ag (DN CuSO, decolourises on addition of excess KCN, the product is (A)[Cu(CN),F. ——(B) Cu get reduced to form [Cu(CN), (C) Cu(CN), (D)CuCN Which of the following cations is detected by the flame test? (A) NHY (B)K* (CMe (part Which one among the following pairs of ons cannot be separated by H,S in dilute HCI? (A) BP*, Sn** (B)AP*, He (C)Zn**, Cu ‘A metal salt solution givesa yellow ppt with silver nitrate. The ppt dissolves in dil nitric acid as well as in ammonium hydroxide, The solution contains (A) bromide (B)iodide (C)phosphate (D) chromate A metal saltsolution forms a yellow ppt with potassium chromate in acetic acid, a white ppt with dilute sulphuric acid, but gives no ppt with sodium chloride or iodide, itis: (A) leadcarbonate _(B) basic lead carbonate (C) barium nitrate (D) strontium nitrate Which is soluble in NH,OH? (A)PbCl, (B)AgCl (©) PbsO, (D) Caco, Which of the following combines with Fe({l) ions to forma brown complex (A) NO (B)NO (C)N,0, (D) NO, Nessler’s reagent is used to detect (A) Crop (B) POY (C) MnO; (D) NH} Prussian blue is formed when (A) ferrous sulphate reacts with FeCl, (B) ferric sulphate reacts with K,[Fe(CN),] (C)Ammonium sulphate reacts with FeCl, (D) ferrousammonium sulphate reacts with FeCl, What product is formed by mixing the solution of K,[Fe(CN),] with the solution of FeC,? (A) Ferro-ferricyanide (B)Ferri-ferrocyanide (C)Ferri-ferricyanide (D)None of these Which of te following will not give positive chromyl chloride test? (A) Copperchloride, CuCl, (B) Mercurie chloride, HgCl, (C)Zine chloride, ZnCl, (D)Anillinium chloride, C,H,NH,Cl A blue colouration isnot obtained when (A) ammonium hydroxide dissolves in coppersulphate (B) copper sulphate solution reacts with K,[Fe(CN),] (C) ferric chloride reacts with sodium ferrocyanide. (D) anhydrous white CuSO, is dissolved in water. AgCI dissolves inammonia solution giving (A)Ag*, NHjandCI- (B)Ag(NH,)* and CI- (C)Ag,(NH,)*-and CI- (D)Ag(NH)$ and CI- crystalline substance dissolves in water On passing H,S gas in this solution, a black ppt is sd. The black ppt dissolves completely in hot HNO, Onaddinga few drops of conc. H,SO,, White pptis obtained. This ppt isthat of (A) BaSO, (B) SSO, (C) Pbso, (D) Caso,Q31 Q32 Q33 Q34 Q.35 Q36 Q37 Q38 Q39 Q40 Q4l Q.42 Qa Q44 Q4s When excess of SnCl is added toa solution of HgCI,, a white ppt turing grey is obtained, The grey colour is dueto the formation of (A)He,Cl, (B)SnCl, (c)Sn (Hg Aqueous solution ofA gives the green precipitate with NaOH solution but gives deep blue colour of the solution with excess NH,OH Identify A (A) Pb? (B)Ni? (C) Ca? (Bi? When chlorine water is added to an aqueous solution of potassium halide in presence of chloroform, a violet colouris obtained. On adding more of chlorine water, the violet colour disappears, and colourless. solution is obtained. This test confirms the presence of the following inaqueous solution (A) lodide (B)Bromide (C)Chloride (D) odide and bromide Anaqueous solution of colourless metal sulphate M, givesa white ppt, withNH,OH. This was soluble in excess of NH,OH. On passing H,S through this solution a white ppt is formed. The metal M in the salt is (A)Ca (B)Ba (CAL (@)Zn When AgNO, is strongly heated, the products formed are (A)NO and NO, (B)NO,andO, — (C)NO, and N,O_—_(D) NO and 0, A substance on treatment with dil. H,SO, liberates a colourless gas which produces (i) turbidity with baryta water and (ii) turns acidified dichromate solution green. The reaction indicates the presence of (A) Coe (B)S* (©) so} (D) Ni When copper nitrate is strongly heated, itis converted into (A)Cumetal (B) cupric oxide (C)cuprousoxide — (D) coppernitrate Apale green crystalline metal salt of M dissolves freely in water. On standing it gives a brown ppton addition of aqueous NaOH. The metal salt solution also gives a black ppt on bubbling H,S in basic ‘medium. Anaqueous solution ofthe metal salt decolourizes the pink colour ofthe permanganate solution ‘The metal in the metal salt solution is (A) copper (B)aluminium (C)lead (D)iron On the addition ofa solution containing Cro} obtained first will be of (A) Caro, (B) SrCrO, (C) BaCrO, (D)amixture ofall the three Tumbull'sblue isacompound (A) ferricyanide (B)ferroferricyanide (C) ferrouseyanide —_ (D) ferrferrocyanide Sodium borate on reaction with conc. H,SO, and C,H,OH gives a compound A which bums with a green edged flame. The compound A is ions to the solution of Ba*, Sr* and Ca?* ions, the ppt (A)H,B,0, (B)(C,H,);B,0, _ (C) HBO, (D)(C,H,);BO, When K,Cr,0, crystals are heated with cone. HCI, the gas evolved is (A)0, (B)Cl, (C) Cr0,Cl, (my HCI Which is most soluble in water? (A)AgCl (B)AgBr (C)Agl (D)AgF On passing H1,S gas in II group sometimes the solution tums milky. It indicates the presence of (Ajo agent (B)acidie salt ()thiosulphate (D) reducing agent. Dimethyl glyoxime ina suitable solvent was refluxed for 10 minutes with pure pieces of nickel sheet, it will resultin (A) Red ppt (B) Blue ppt (C) Yellow ppt. (D)No ppt.Q46 Q47 Q48 Q49 Q.50 Qsi Qs2 Q33 Qs4 Q55 Q56 Q57 Qs8 Amixture of chlorides of copper, cadmium, chromium, iron and aluminium was dissolved in water acidified with HCI and hydrogen sulphide gas was passed for sufficient time. It was filtered, boiled and afew drops of nitric acid were added while boiling To this solution ammonium chloride and sodium hydroxide were added in excess and filtered. The filtrate shall give test for (A) sodium and iron ion (B) sodium, chromium and aluminium ion (C) aluminium and iron ion (D) sodium, iron, cadmium and aluminium ion Solution of chemical compound X reacts with AgNO, solution to form a white ppt Y, which dissolves in NIH,O11to giveacomplexZ, When Z is reated with dil IINO,, Y reappears. The chemical compound X canbe (A)NaCl (B)CH,CI (C)NaBr (D) Nal Awhite ppt obtained in a analysis of a mixture becomes black on treatment with NH,OH. It may be (A)Pocl, (B)Agcl (OHeCl, ()He,Cl, A salt on treatment with dil. HCI gives a pungent smelling gasand a yellow precipitate. The salt gives green flame when tested, The solution gives a yellow precipitate with potassium chromate, The salt is (A)NiSO, (B) BaS,O, (C) Pbs,0, (D)Cuso, ‘Which compound does not dissolve in hot dilute HNO,? (A) Hgs (B)Pbs (C)CuS (Dy cds Anaqueoussolution of FeSO,,Al,(SO,); and chrome alum isheated withexcess of Na,O, and filtered. The materials obtained are: (A)acolourless filtrate and agreen residue, _(B) ayellow filtrate and a green residue (Cayellow filtrateanda brown residue. __(D)agreen filtrate anda brown residue Which of the following compound on reaction with NaOH and Na,O, gives yellow colour? (ACOH), (B)Zn(OH), (C)AKOH), (D) None of these Cr0, dissolves in aqueous NaOH to give (A) Choy (B) Cro (C)Cr(OH), (D) Cr(OH), Clear solution Salt A+ S,0,2° —> white ppt 3,0 PPt | ag SO Bk which of following metal salt A does not give this test (A)Ag. (B)Pb (C)Bi (D)Zn An aqueous solution ofa substance gives a white ppt.on treatment with dil, HCI, which dissolves on heating. ‘When hydrogen sulphide is passed through the hot acidic solution, ablack ppt. isobtained The substance isa (A) Hg* salt (B) Cu salt (C)Agr salt (D)Pb* salt Which one of the following does not produce metallic sulphide with H,S? (A)ZnCl, (B) CaCl, (C)CoCl, (oy cucl, ‘Apale yellowerystalline solid insoluble in water but soluble in CS, isallowed toreact with nitric oxide to give X and Y. X isacolourless gas with pungent odour X is further allowed to react in aqueous medium with nitric oxide to yield Z and T. Compounds X, Zand are (A) SO,, H,SO,, N,0 (B) SO,, H,SO,, NO (©)Si0,, H,S0,,N, (D) SO}, H,SO;, Ny Which metal salt gives a violet coloured bead in the borax bead test? (A) Fe* (B)Ne* (C) Co (D)Mn**Q59 Q.60 Qol Q02 Q63 Q64 Q65 Q.66 Q67 Q68 Q69 Q70 Q7 Qn Q73 Which of the following gives a precipitate with Pb(NO,), but not with Ba(NO,),? (A)Sodium chloride (B)Sodiumacetate (C)Sodium nitrate (D) Sodium hydrogen phosphate Which ofthe following is soluble in yellowammonium sulphide? (A) Cus, (B) Cas (C)SnS (D) PbS chloride dissolves appreciably in cold water. When placed on a platinum wire in Bunsen flame no distinctive colour is noticed, the cation would be: (A) Mg** (B) Ba* (C) Pb (D) Ca®* A white salt is readily soluble in water and gives a colourless solution with a pH ofabout 9. The salt could be: (A) NH,NO, (B)CH,COONa = (C) CH,COONH, ~—(D) CaCO, Anclement (X) forms compounds of the formula XCI,, X,0, and Ca,X,, but does not form XCl,. Which of the following isthe element X? (A)B (B)Al (ON (DP A white sodium salt dissolves readily in water to give solution which is neutral to litmus. When silver nitrate solution isadded to the solution, a white precipitate is obtained which does not dissolve in dil HNO, The anion could be: (a) coe (B)cr (©) soz" (D) S* A mixture of two salts is not water soluble but dissolves completely in dil HC! to form a colourless solution. The mixture could be (A)AgNO, and KBr (B)BaCO,andZnS (C) FeCl, and CaCO, (D) Mn(NO,), and MgSO, ‘Three separate samples ofa solution ofa single salt gave these results. One formed a white precipitate ‘with excess of ammonia solution, one formed a white precipitate with dil NaCl solution and one formed ablack precipitate with H,S. The salt could be: (A) AgNO, (B) PL(NO,), (C) Hg(NO,), (D) MSO, ‘Which one of the following ionic species will impart colour toan aqueous solution? (A) Ti* (B)Cut (C)Zn* (Dycr+ Whenasubstance A reacts with water it produces a combustible gas B and a solution of substance C in water. When another substance D reacts with this solution of C, it also produces the same gas B on ‘warming but D can produce gas B on reaction with dilute sulphuric acid at room temperature. A imparts adeep golden yellow colour a smokeless flame to Bunsen bummer. A, B, Cand D respectively are (A) Na, H,, NaOH, Zn (B)K, H,, KOH, Al (C) Ca, H, Ca(OH), Sn (D) CaC;, CH, Ca(OH), Fe Which s not dissolved by dil HCI? (A) ZnS (B) MnS (C) BaSO, (D) BaSO, ‘The brown ring test for NO; and NO} is due to the formation of complex ion with formula: (A) [Fe(H,0),P* (B) [Fe(NO)(CN),P- (C) [Fe(H,0),(NO)P* (D) [Fe(H,0\(NO),}* InNessler’s reagents, the ion present is: (A)Hgt (8) Hgl}- (C)Hg* (Dy Hg ‘The ations present inslightly acidic solution are Fe, Zn?* and Cu®*. The reagent which when added in excess to this solution would identify and separte Fe* in one step is: (A)2MHCI (B)6 MNH, (C)6MNaOH (D)H,S gas Which of the following leaves no residue on heating? (A) PO(NO,), (B) NH,NO, (C) Cu(NO,),, (D) NaNO,Q7m4 Q75 Q76 Q7 QB Q79 Q.80 Qsi Q.82 Q83 Q.ss Q.85 Q.86 Q87 Q88 ‘When |, is passed through KCI, KF, KBr: (A)Cl, and Br, are evolved (B)Cl, isevolved (C)Cl,, F, and Br, are evolved (D)None of these In the separation of Cu* and Ca in 2 group qualitative analysis of cations tetrammine copper (Il) sulphate and tetrammine cadmium (I) sulphate react with KCN to form the corresponding cyano complexes. Which one of the following pairs of the complexes and their relative stability enables the separation of Cu** and Cd"? (A)K[Cu(CN),] more stable and K,{Cd(CN), ] less stable. (B) K,[Cu(CN),] less stable and K,[Cd(CN),] more stable. (C)K[Cu(CN),] more stable and K,{Ca(CN),] less stable. (D)K,[Cu(CN),] less stable and K,{Cd(CN),] more stable. Which one has the minimum solubility product?” (A)AgCl (AICI, (C)BaCl, (D)NH,CI Which of te following sulphate is insoluble in water? (A) CusO, (B) CdsO, (C) PSO, (D)BifSO,), Ametal X on heating in nitrogen gas gives ¥.¥. on treatment with HO givesa colourless gas which when passed through CuSO, solution givesa blue colour Y is: (A) Mg(NO,), (B)Mg,N, (C) NH, (D)MgO Which ofthe following gives blood red colour with KCNS? (A) Cu* (B) Fe* (cya (D)Zn* ‘Which of the followings insoluble in excess of NaOH? (A)AIOH), (8)Cr(OH), (C) Fe(OH), (D)Zn(0H), In the borax bead test of Co*, the blue colour of bead is due to the formation of: (A)B,0, (B)Co;B, (C) Co(BO,), (D) CoO ‘Mercurous ion is represented as: (A) Hg3* (B) Hg (C) Hg+ Hg (D) Hg} ‘The metal ion whichis precipitated when HS is passed with HCI: (A)Zn** (B)N#* (c) ca (D) Mn* Which of the following is not a preliminary test used to detect ions: (A) borax bead test (B) flame test (C)brownringtest (D) cobalt nitrate test Which one of the following metal sulphides has maximum solubility in water? (A) HgS, K,,=10* (B) CdS, K,=10 (C) FeS, K,, =10 (D) ZnS, K,= ‘The compound formed in the borax bead test of Cu* ion in oxidising flame is: (ayCu (B)CuBO, (C)Cu(BO,), (D) None of these Read of the following statements and choose the correct code wrt true(T) and false(F) (1) manganese salts give a violet borax bead test in reducing flame (Il) from amixed precipitate of AgC! and Agl, ammonia solution dissolves only AgCI (Ill) ferric ions give a deep green precipitate, on adding potassium ferrocyanide solution (IV) on boiling the solution having K*, Ca°* and HCO,” we geta precipitate of K,Ca(CO,), (D) TIF y-22 (A)TTFF (B) FTFT (C)FTFF Identify the correct order of solubility of Na,S, CuS and ZnS in aqueous medium is: (A) CuS > ZnS > Na,S (B) ZnS > Na,S >CuS (C)Na,$ > CuS > ZnS (D)Na,S > ZnS > CuSQ.89 Q90 Qa Q92 Q93 Q.94 Q95 Q.96 ‘When H,S gas is passed through the HCI containing aqueous solution of CuCl, HgCl, BiCl, and, CoCl,, itdoes not precipitate out: (A) CuS (B) Hes (OBI. ‘Mark the correct statement (A) group basic radicals precipitate as chlorides (B)IV group basic radicals precipitates as sulphides. (C)V group basic radicals precipitates as carbonates. (D)All the above statement are correct. Potassium chromate solution is added to an aqueous solution of a metal chloride. The precipitate thus obtained are insoluble in acetic acid. These are subjected to flame test, the colour of the flame is: (A) Lilac (B) Apple green (C)Crimson red —_(D) Goldenyellow ‘MgSO, on reaction with NH,OH and Na, HPO, forms a white crystalline precipitate. What is its formula? (A)Mg(NH,)PO, —(B) Mg,(PO,),,(C)MgClyMgSO, _(D) MgSO, ASSERTION REASON Statement-1: On passing CO, gas through lime water, the solution turns milky. because Statement-2: Acid-Base (neutralisation) reaction takes place. (A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1 (B) Statement-I istrue, statement-2 is true and statement-2 is NOT the correct explanation for statement-1. (C) Statement-1 is true, statement-2 is false. (D) Statement| is false, statement-2 is true. (D) CoS Statement-1: NO} ion can not be detected by brown ring test in presence of NO; ion Statement-2: Both NO} and NO; ionsare confirmed by brown ring test (A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1, (B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1. (C)Statement-1 is rue, statement-2 is false. (D) Statement-1 is false, statement-2 is true. Statement-1. : _‘S' onreactionwith NaOH, produces H,S first as one of the product. Statement-2: —_H,S isacidic innature to produce Na,S as final product. (A) Statement-1 istrue,statement-2 is true and statement-2 is correct explanation for statement-1 (B) Statement-1 is true, statement-2is true and statement-2 is NOT the correct explanation for statement-1 (C)Statement-1 is rue, statement-2 is false. (D) Statement-| is false, statement-2 is true. Statement-1_: Conc. HNO, can bestored in Al-container Statement-2__: Alrreacts with conc. HNO, forming AI,O, which makes impervious coating on itand does not dissolve any more. (A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-I. (B) Statement-1 is true, statement-2 is trueand statement-2 is NOT the correct explanation forstatement-1 (C) Statement-1 istrue, statement-2 is false. (D)Statement-1is false, statement-2 is true.Q97 Statement-1 : _Diluteaqueoussolution of CuCl, is Blue in colour but on evapouration becomes. green. Statement-2. : —__ Intheresulting solution after evapouration [Cu(H,0),]* and [CuCl,]*-both are present together, (A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1. (B) Statement-| is true, statement-2 is trueand statement-2 is NOT the correct explanation forstatement-1 (C)Statement-1 istrue, statement-2 is false (D) Statement-1 is false, statement-2 is true. COMPREHENSION: Question No. 98 to 100 (3 questions) Compound'A' —*-> Initially swelled = Amorphous powder song hesing \_— Lita tame nthe Name test Compound'A' —"20H_, 1B No change in colour) 25 'C' (Yellow solution) (inaq solution) Q.98 Compound'A' is having water of crystallization by the numberof (A)10 (B)20 (C) 24 (D) 36 Q.99 Thecompound'B ishaving oxidation state of (A)zero (B)II (ol (D)IV Q.100 The hybridization ofcompound'C is (A)sp3 (B)sp'd (C) &sp? ()d’s Question No. 101 to 103 (3 questions) Awhite solid A reacts with dilute H,SO, to produce a colourless gas B and a colourless solution C, The reaction between Band acidified dichromate yields green solution and aslightly coloured precipitate D. The substance D, when burnt in air, gives a gas E which reacts wih B to yield D and a colourless liquids. Anhydrous copper sulphate tums blue with this colourless liquid. The addition of aqueous NH, ‘or NaOH to C produces a precipitate that dissolves in an excess of the reagent to form aclear solution. Answer the following questions based on above passage. Q.101 Which of the following gases are Band E respectively? (A)CO, and SO, —(B)SO,and HS (C)H,S and SO, (1D) CO, and 11,8 Q.102. What would appear if the gas B is passed through an aqueous solution of Pb(NO,),? (A) white precipitate soluble in hot dilute HNO, (B)Ablack precipitate soluble in hot dilute HNO, (C)Ablack precipitate insoluble in hot dilute HNO, (D)Ayellow precipitate soluble in hot concentrated HNO, Q.103 Suppose the solution obtained by the treatment of the solution C with an excess of NaOH is acidified with acetic acid and the gas B is passed through it. Which of the following will obtained? (A) Colourlesssolution (B) Yellow precipitate (©)Black precipitate (D) White precipitate MORE THAN ONE MAY BE CORRECT Q.104 The colour of KMnO, is discharged by which of the following gases (AyNO (B) NO, (C)N,0 (D) NO, Q.105 Which one among the following pairs of ions cannot be separated by H,S indilute hydrochloric acid? (A) B?*, Sn** (B)AP*, Hg (C)Zn?*, Cur (D) Sb, As*Q.106 AP* and Cr** can be distinguished by which of following reagent. (A)NaOH (B) NH,OH + NH,Cl (C) Excess NH,OH (D)(NH)),S Q.107 Which of the following radical(s) on reaction with dil HCl liberate(s) gas which decolourize(s) acidified KMn0, solution (A) 8,05- (B) NOZ (CBr (D) HCO; Q.108. Which of the following metal produces N,O gas with 20% HNO, (A)Fe (B)Cu (C)Zn (D)Sn MATCH THE COLUMN : Q.109 Column Column It (A) Amphoteric metal oxide @) Pb (B) Metal acetate —*-+ acetone + metal carbonate Q a (C) Metal carbonate —*» metal oxide +CO,t (RNa (D) Metal nitrate 4-5 metal oxide+NO,1+0,7 (Ss) Li Q.110. Which of anions in the Column-I shows one or more observations from the column lI Column Column It (A) sb (2) White ppt. withAgNo, (8) NO; (Q __ Evolution of pungent smell gas with (Al+cone. NaOH) (© soz (R)__ Brown fumes with cone, H,SO, (hot) (©) CH,CoO" (S)__Decolourises acidified KMnO,