27-10-2024

1803CJA101001240036 JM

PART-1 : PHYSICS

SECTION-I

1) Two sphere made of same substance have radii 1 m and 4 m and temperatures 4000 K and 2000 K
respectively. The ratio of power radiated by two spheres is :-

(A)

(B)

(C) 4
(D) 1

2) The plots of intensity vs. wavelength for three black bodies at temperatures T1, T2 and T3

respectively are as shown. Their temperatures are such that :

(A) T1 > T2 > T3

(B) T1 > T3 > T2
(C) T2 > T3 > T1
(D) T3 > T2 > T1

3) Newton's law of cooling is a special case of

(A) Stefan's law

(B) Kirchhoff's law
(C) Wien's law
(D) Planck's law

4) Good absorber is good emitter is explained by–

(A) Stefan’s law

(B) Kirchoff’s law
(C) Newton’s law of cooling
(D) Wein’s displacement law

5) A sphere and cube of same material and same volume are heated upto the same temperature and
allowed to cool in the same surroundings. The ratio of the amounts of radiations emitted will be
(A) 1 : 1

(B)

(C)
:1

(D)

6) A black body calorimeter filled with hot water cools from 60°C to 50°C in 4 min and 40°C to 30°C
in 8 min. The approximate temperature of surrounding is :

(A) 10°C
(B) 15°C
(C) 20°C
(D) 25°C

7) A spherical body of area A, and emissivity e = 0.8 is kept inside a black body. What is the rate at
which energy is radiated per second at temperature T.

(A)
(B)
(C)
(D)

8) A block of ice at –10°C is placed in a room which has temperature of 27°C. Then the ice

(A) Does not emit any radiation

(B) Emits some radiation but absorbs an equal amount of radiation
(C) Absorb more radiation than it emits
(D) Emits more radiation than it absorbs

9) An ideal body is liberating radiation at temperature T1, If the rate of release of energy at T2 is 16
times as that when temperature was T1 then :-

(A) T2 = 16T1
(B) T2 = 8T1
(C) T2 = 4T1
(D) T2 = 2T1

10) When the temperature of a black body increases, it is observed that the wavelength
corresponding to maximum energy changes from 2λ to λ. Find ratio of temperature of body
respectively.

(A) 1

(B)
(C)

(D)

11) You have two closed containers of equal volume. One is full of helium gas. The other holds an
equal mass of nitrogen gas. Both gases have the same pressure. How does the temperature of the
helium compare to the temperature of nitrogen ? (Assume gases to be have as ideal gas)

(A) Thelium > Tnitrogen

(B) Thelium = Tnitrogen
(C) Thelium < Tnitrogen
(D) cannot be compared

12) The correct order of most probable speed (Vmp), root mean square speed (Vrms) and average speed
(Vav) of molecules in an ideal gas is :

(A) Vav > Vmp > Vrms

(B) Vrms > Vmp > Vav
(C) Vmp > Vrms > Vav
(D) Vrms > Vav > Vmp

13) The rms speed of helium gas at 27°C and 1 atm pressure is 900 ms–1. Then the rms speed of
helium molecules at temperature 27°C and 2 atm pressure is :-

(A) 450 m/s

(B) 900 m/s
(C) 1800 m/s
(D) 750 m/s

14) An ideal gas is initially at temperature T and volume V. Its volume is increased by ΔV due to an

increase in temperature ΔT, pressure remaining constant. The quantity (say δ) varies with
temperature as :-

(A)

(B)
(C)

(D)

15) Vrms of O2 gas molecule at 27°C is v1 and Vrms of N2 gas molecule at 427°C is v2. The ratio is:

(A)

(B)

(C)

(D)

16) Heat is supplied to a diatomic gas at constant pressure, with the usual notation the ratio ΔQ : ΔU
: ΔW is

(A) 5 : 2 : 2
(B) 5 : 2 : 3
(C) 7 : 5 : 2
(D) 7 : 2 : 5

17) 2 moles of an ideal monoatomic gas occupying volume V is adiabatically expanded from
temperature 300K to a volume of 2 V. Then the final temperature & change in internal energy are
respectively (R = 8.3)

(A) 150 K, – 3735 J

(B) 140 K, – 3735 J
(C) 150 K, – 3537 J
(D) 140 K, – 3537 J

18) If a given mass of an ideal gas taken through the process VT = constant, then which of the
following graph is correct for the process.
(A)

(B)

(C)

(D)

19) A polyatomic gas with six degrees of freedom does 25 J of work when it is expanded at constant
pressure. The heat given to the gas is :-

(A) 100 J
(B) 150 J
(C) 200 J
(D) 250 J

20) One mole of an ideal gas at temperature T1 expends according to the law = a (constant). The
work done by the gas till temperature of gas becomes T2 is :

(A)
R(T2 – T1)

(B)
R(T2 – T1)

(C)
R(T2 – T1)

(D)
R(T2 – T1)

SECTION-II

1) A diatomic gas is undergoing a process such that 9 dQ = 14 dW where dQ is heat absorbed by gas
and dw is work done by gas. Find x if its specific heat is xR.
2) Assume that the total surface area of a human body is 1.6 m2 and that it radiates with e = 1/2. If
steady state temperature of body is 37 °C and surrounding temperature is 27 °C then rate at which
heat is produced in human body will be xσ × 106 J/sec. Find value of x.

3) A cup of tea cools from 80°C to 60°C in one minute. The ambient temperature is 30°C. In cooling
from 60°C to 50°C. It will take time (in sec) :

4) A gas mixture consists of 3 moles of oxygen and 5 moles of argon at temperature T. Considering
only translational and rotational modes, the total internal energy of the system is x R T. find x

5) One kg of a diatomic gas is at a pressure of 8 x 104 N/m2. The density of the gas is 4 kg/m3. If the
energy of the gas due to its thermal motion is n × 104 J. Find n

PART-2 : CHEMISTRY

SECTION-I

1) Which one is the most acidic compound?

(A)

(B)

(C)

(D)
2) Which of the following compound does not react with

(A)

(B)

(C)

(D)

3) Which of the following C-H bonds participate in hyperconjugation ?

(A) I and II
(B) I and IV
(C) I and III
(D) III and IV

4) The correct order of increasing basic nature for the bases NH3, CH2NH2 and (CH3)2NH is-

(A) CH3NH2 < NH3 < (CH3)2NH

(B) (CH3)2NH < NH3 < CH3NH2
(C) NH3 < CH3NH2 < (CH3)2NH
(D) CH3NH2 < (CH3)2NH < NH
5) Which compound does not show G.I. –

(A)

(B)

(C)

(D) None of these

6) Which of the following compounds will show geometrical isomerism.

(A)

(B)

(C)

(D)

7) Which is the most stable conformation :

(A)

(B)
(C)

(D)

8) Which one of the following is a Z isomer ?

(A)

(B)

(C)

(D)

9) C6H5–CH=CH–CH=CH–CH=CH–CH=CH–CH3 ; How may geometrical isomers are possible :

(A) 10
(B) 16
(C) 32
(D) 20

10) Which of the following conformations will be the most stable ?

(A)
(B)

(C)

(D)

11) Identify the most stable conformer of cyclohexane :

(A) Chair form

(B) Boat form
(C) Half Chair form
(D) Twist boat form

12) Which is a pair of geometrical isomers :-

(I) (II) (III) (IV)

(A) I and II (B) I and III (C) II and IV (D) III and IV
(A) A
(B) B
(C) C
(D) D

13) Which of the following conformers for ethylene glycol is most stable :-

(A)
(B)

(C)

(D)

14) The IUPAC name of the following compounds is :

(A) (Z) – 5 hepten – 3 – yne

(B) (Z) – 2 hepten – 4 – yne
(C) (E) – 5 hepten – 3 – yne
(D) (E) – 2 hepten – 4 – yne

15) In the following structure, the double bonds are marked as I, II, III and IV

Geometrical isomerism is not possible at site(s)

(A) III
(B) I
(C) III and IV
(D) I and III

16) Which of the following compounds is not chiral ?

(A) DCH2CH2CH2Cl
(B) CH3CHDCH2Cl
(C) CH3CHClCH2D
(D) CH3CH2CHDCl

17) The compound which has maximum number of chiral centres is

(A)

(B)

(C)
(D)

18) Which of the following represent correct matching ?

(A) Metamer

(B) Position isomer

(C) H3C - CH2 - CH2 - NH2 & H3C - CH2 - NH - CH3 Functional isomer

(D) Chain isomer

(A) A, B, C only
(B) B, C, D only
(C) A, C, D only
(D) A, B, D only

19) Which of the following pairs of compounds is a ring-chain isomer?

(A)
and

(B)
and
and
(C)

(D)
and

20) C7H7Cl shows how many benzenoid aromatic isomers ?

(A) 4
(B) 3
(C) 5
(D) 6

SECTION-II

1) How many number of monoanionic resonating structures are possible for given anion .

2) Find total number of H replaced by deuterium when below compound is kept in /D2O solution
for long time ?

3) Number of compound which can show geometrical isomerism

4) How many sp2 carbons are present in following compound :

5) How many pairs are correct?

 functional isomer

metamers

metamers

functional isomers

& homologous

& chain isomer

PART-3 : MATHEMATICS

SECTION-I

1) The length of transverse axis of is

(A) 8
(B) 10
(C) 12
(D) 14
2) The eccentricity of hyperbola is

(A)

(B)

(C)

(D)

3) If touches the ellipse then the eccentric angle of the point of

contact is :

(A)

(B)

(C)

(D)

4) The eccentricity of an ellipse, with its centre at origin is . If one of the directrices is x = 4 then
the equation of the ellipse is

(A) 3x2 + 4y2 = 1

(B) 3x2 + 4y2 = 12
(C) 4x2 + 3y2 = 12
(D) 4x2 + 3y2 = 1

5) If F1 = (3, 0), F2 = (–3, 0) and P is any point on the curve 16x2 + 25y2 = 400, then PF1+ PF2 equals
:

(A) 8
(B) 6
(C) 10
(D) 12

6) In an ellipse, the distance between its foci is 6 and minor axis is 8. Then its eccentricity is-

(A)

(B)
(C)

(D)

7) On the ellipse 4x2 + 9y2 = 1, the points at which the tangents are parallel to the line 9y = 8x are :

(A)

(B)

(C)

(D)

8) If the line 2x + y + K = 0 is a normal to the parabola, y2 + 8x = 0 then K =

(A) –16
(B) –8
(C) –24
(D) 24

9) The equation of common tangent to the parabolas y2 = 2x and x2 = 16y is-

(A) x + 2y + 1 = 0
(B) x + 2y + 2 = 0
(C) 2x + y + 1 = 0
(D) None of these

10) The value of λ for which the equation (10x – 5)2 + (10y – 7)2 = λ (5x + 12y + 7)2 represents the
parabola is

(A)

(B)

(C)

(D) None of these

11) If (t2, 2t) is one end of a focal chord of the parabola y2 = 4x then the length of the focal chord will
be-

(A)
(B)

(C)

(D) None of these

12) If line 3x + y = 8 meets parabola (y – 2)2 = 4(x – 1) at A and B, then the point of intersection of
tangents drawn at A and B lies on line

(A) x = –1

(B)
x=
(C) x = 0
(D) None of these

13) If (2, –8) is one end of a focal chord of the parabola y2 = 32x, then the other end of the focal
chord, is-

(A) (32, 32)

(B) (32, –32)
(C) (–2, 8)
(D) (2, 8)

14) If two normals to the parabola intersect at right angles then the chord
joining their feet passes through a fixed point whose
co-ordinates are :

(A) (- 2, 2)
(B) (- 6, 0)
(C) (- 6, 2)
(D) (0,- 2)

15) If two tangents drawn from a point P to the parabola are at right angles, then the locus
of P is

(A)
(B)
(C)
(D) x = 1

16) The focal chord to y2 = 64x is tangent to (x – 4)2 + (y – 2)2 = 4, then the possible values of the
slope of this chord is -

(A)
(B)

(C)

(D)

17) Find the equation of the radical axis of the circle and

(A) x + 2y =2
(B) x + 2y =1
(C) 2x + y = 2
(D) 2x + y = 1

18) For the circle x2 + y2 – 2x – 10y – 1 = 0 which of the following is/are true-

(A) x intercept of the circle is

(B)
y intercept of the circle is
(C) line x + y = 6 is diameter of the circle
(D) All of these

19) The circle having minimum radius and passes through the points (1, –2) and (3, –4) is :-

(A) x2 + y2 – x – y – 11 = 0
(B) x2 + y2 – 4x – 2y + 1 = 0
(C) x2 + y2 – 4x + 6y + 11 = 0
(D) x2 + y2 + 2x – 3y = 0

20) Length of common chord of two circles of radii 3 and 4 which intersect orthogonally is ℓ, then
is

(A) 3
(B) 2
(C) 5
(D) 7

SECTION-II

1) If equation ax2+by2+(a+b–6)xy+6x+12y–12=0 represents a circle then radius of that circle will be

:
2) If L1 and L2 are the length of the segments of any focal chord of the parabola y2 = x, then
is equal to :

3) The line x = 8 is the directrix of the ellipse with the corresponding focus (2, 0). If

the tangent to E at the point P in the first quadrant passes through the point and
intersects the x-axis at Q, then (3PQ)2 is equal to

4) Let the tangents at the points P and Q on the ellipse meet at the point

. If S is the focus of the ellipse on its negative major axis, then is equal
to

5) The number of distinct normal lines that can be drawn to ellipse from the point P(0,
6) is ___.
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D B A B C B C C D B C D B C A C A A A C

SECTION-II

Q. 21 22 23 24 25
A. 7 864 48 15 5

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C A B C B D A A B A A C C D B A C B C A

SECTION-II

Q. 46 47 48 49 50
A. 5 9 6 9 4

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A C A B C D D D B D A C A C B A A D C C

SECTION-II

Q. 71 72 73 74 75
A. 3 4 39 13 3
 SOLUTIONS

PART-1 : PHYSICS

2)

Theory

5)
Vsphere = Vcube

substituting the volue of a in eqn (1)

6)

7)

11) T = pV/nR. Pressure and volume are the same, but n differs. The number of moles in mass
M is n = M/Mmol. Helium, with the smaller molar mass, has a larger number of moles and
thus a lower temperature.]

12) vrms > vav > vmp

13)

14) PV = nRT ....(i)

PΔV = nRΔT ....(ii) (P = constant)
(ii)/(i)

So
So graph will be rectangular hyper
15)

17)

18)

19) ΔW = 25 = nRΔT
ΔU = 3nRΔT = 75

20)

PV–2 = constant = .

21)
dQ = dU + dw

dQ = dU +

dQ =

22)

24) U = (f1/2)n1RT + (f2/2)n2RT

U = (5/2)(3RT) + (3/2)(5RT)
U = 15RT

25) The thermal energy or internal energy is for diatomic gases, (degree of freedom for
 diatomic gas = 5)
But PV = RT
V = mass/density = 1kg/(4 kg/m3) = (1/4)m3
P = 8 x 104 N/m2
U = (5/2) x 8 x l04 x 1/4 = 5 x 104J

PART-2 : CHEMISTRY

26) Magnitude of -M groups increases the acidic nature of phenol

27) is a weak acid as compared to H2CO3 and so does not produce CO2 with
NaHCO3 Option (A) is Answer.

28) I and IV are only α–H.

29) ∴ when R = – CH3 then order of basic strength

⇒ 2º > 1º > 3º > 0º

30)
31)

32) In (1) both groups are at equatorial position. So, least repulsion. Hence, more stable.

34) When number of double bonds are even with different ends formula is 2n where n is the
number of double bond, so 24 = 16

35) Conformation has lowest vanderwaal and torsional strain. Hence it must be
most stable.

36)

Stability order ⇒ Chair form > Twist boat form > Boat form > Half chair
⇒ Due to least Torsional strain & Steric strain, chair form is most stable conformer of
cyclohexane.

37) Pair of geometrical isomers

Option II & IV are geometrical isomers.

38)
Most stable conformer of ethylene glycol

Gauche form is most stable due to presence of H-Bonding.

39)

40) In 'I' identical groups are present on one side of double bond, so no geometrical
isomerism.

41) In ‘A’ there is no chiral carbon present.

42)
43) Functional

44)

45) C7H7 – Cl

where m ⇒ no. of mono valent atoms

t ⇒ no. of trivalent atoms

=
Benzoidal isomers
46)

47)

48)

49)

sp2 carbon
⇒ 2σ + 1π bond

50)

Conceptual
PART-3 : MATHEMATICS

53)

Equation of tangent is

....(1)
Equation of tangent at the point
is

...(2)
Compare (1) and (2)

54) e = & = 4 ⇒ a = 2
b2 = a2(1 – e2)

b2 = 4 ⇒ b2 = 3

3x2 + 4y2 = 12

55) The equaion of the ellipse can be written as =1

Here a2 = 25, b2 = 16
but b2 = a2(1 – e2)
⇒ 16 = 25 (1 – e2) ⇒ e = 3/5
So that focii of the ellipse are (± ae, 0) i.e. (±3, 0) or F1 and F2
By definition of the ellipse, since P is any point on the ellipse
PF1 + PF2 = 2a = 2 × 5 = 10

56) 2ae = 6
ae = 3
2b = 8 ⇒ b = 4
b2 = a2(1 – e2)
b2 = a2 – ae2
16 = a2 – 9
a2 = 25

⇒
Option (D) is correct.
57)
Tangent at (x1, y1)
4xx1 + 9yy1 = 1
+ =1

solving, we get ,

58) m = – 2, a = – 2
∴ equation of normal
y = – 2x – 2(–2)(–2) – (–2)(–2)3
2x + y + 24 = 0
∴ k = 24

59) Any tangent to parabola x2 = 16y is y = mx – 4m2

If this is also tangent for parabola y2 = 2x

then ⇒ – 4m2 = ⇒ m3 = – ⇒ m = –
Hence equation of common tangent is

y=– ⇒ 2y = – x – 2 Þ x + 2y + 2 = 0

60)

61) y2 = 4x
a =1
here end point focal chord

Now

PQ

=
option (A) is correct.
62) (y – 2)2 = 4(x – 1)
vertex : (1, 2)
focus : (a + h, k) = (2, 2)
L : 3x + y = 8
This line shows that it passes through focus

63)

(at2, 2at) one end then another end.

16t = – 8 ⇒ t = –1/2
∴ Another end (32, 32)

64) If the normal intersect at right angles then their corresponding tangents will also intersect
at right angles hence the chord joining their feet must be a focal chord]

65) We know that the locus of perpendicular tangents is directrix i.e.,

66) Equation of focal chord is y = m(x – 16)

∴
⇒ 4(1 + m2) = (–12m – 2)2

67)

Equation of radical axis

S1 – S2 = 0

68)

(A)

69) Points will be ends of diameter for the circle

(x – 1)(x – 3) + (y + 2)(y + 4) = 0
x2 + y2 – 4x + 6y + 11 = 0

70)
ℓ = 2(4sinθ)

71) a = b = 3
x2 + y2 + 2x + 4y – 4 = 0
r=

72) Any point on the parabola is P(at2, 2at) where a = 1/4. S(a, 0) is the focus of the parabola.

So L1 = SP = = a(t2 + 1)
If PQ is a focal chord, then Q(a/t2, –2a/t)

So that L2 = SQ = a =

and =4

73) ____(1)
ae = 2 …….(2)

8e =

a=4
b2 = a2(1 – e2)

= 12

θ = 30°
(3PQ)2 = 39

74) ;
Chord of contact is

solving with ellipse

75)