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           Physics
                                                                                      Vanier
                                                                                     Tomescu
         The Quantum Physics of Atomic Frequency Standards: Recent
         Developments covers advances in atomic frequency standards
         (atomic clocks) from the last several decades. It explains the use of
         various techniques, such as laser optical pumping, coherent population
         trapping, laser cooling, and electromagnetic and optical trapping, in the
         implementation of classical microwave and optical atomic frequency
         standards.
         Features
            • Describes the basic physics, including quantum mechanics,
               behind the operation of atomic clocks
            • Explores new frequency standards that provide better stability
               and accuracy than older, more conventional standards
            • Discusses the importance of the field in the general context
               of physics
            • Gives an extensive list of the most important references in
               the field
                                                                 K16759
                                                          ISBN: 978-1-4665-7695-7
                                                                           90000
9 781466 576957
         Jacques Vanier
Université de Montréal, Montréal, Canada
       Cipriana Tomescu
Université de Montréal, Montréal, Canada
CRC Press
Taylor & Francis Group
6000 Broken Sound Parkway NW, Suite 300
Boca Raton, FL 33487-2742
© 2016 by Taylor & Francis Group, LLC
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Contents
Preface.................................................................................................................... xiii
Introduction ............................................................................................................xvii
Authors ....................................................................................................................xix
                                                                                                                              v
vi                                                                                              Contents
                                                                                      xiii
xiv                                                                            Preface
stored in optical lattice traps in order to reduce their thermal motion. Laser cooling
has also been used in the mono-ion trap to implement optical frequency standards. In
that case, a single ion, say Sr+ or Yb+, is maintained in a Paul or Penning trap and its
motion within the trap is damped by laser cooling. Clocks at optical frequencies have
been implemented as laboratory units with unsurpassed accuracy and frequency sta-
bility reaching the 10−16 to 10−18 range. In both cases, the clock frequency is derived
from a transition between the ground S state of the atom and an excited metastable
state with a lifetime of the order of 1 second or more leading to a very narrow
resonance line. The clock transition is detected by means of monitoring changes in
the fluorescence level created by the cooling radiation when the clock transition is
excited.
    The large gap in frequency between the microwave and the optical range has
always been an roadblock in the use of optical frequencies in various applications
such as frequency standards or still high precision spectroscopy and fundamental
research. The reason is mainly due to the fact that gaps between available optical
frequencies for the realization of clocks are very large. It is extremely difficult to
connect those frequencies to the microwave range. This connection is required
because most of the applications are in the low frequency range of the spectrum and,
furthermore, because the SI (International System of Units) definition of the second
is based on a microwave hyperfine transition in Cs, in the X band. We have given in
Volume 2 of QPAFS examples of the conventional method used to make that connec-
tion. That method comprises frequency- and phase-locking together banks of lasers
with appropriate heterodyning in several steps in order to interconnect various opti-
cal frequencies to reach finally the microwave range. The connection has to be done
over a large number of steps and involves tremendous investment of space and time
to finally measure what very often happens to be just a single frequency. Such a task
has been reduced considerably by the invention of the so-called optical comb, which
comprises locking the repetition rate of a femtosecond laser to a stable atomic fre-
quency standard of high spectral purity, such as an H maser referenced in frequency
to a primary Cs atomic clock. When observed by means of a nonlinear optical fibre,
the resulting laser spectrum consists of a spectrum of sharp lines, themselves called
the teeth of the comb, which covers a frequency range of the order of 1 octave.
Frequencies over a broad range are then measured essentially in a single step on an
optical table, resulting in a considerable reduction in work and size as compared to
the previous heterodyning technique, which required entire rooms filled with lasers.
    This volume covers those subjects in some detail. It is divided into five chapters.
Chapter 1 is an introduction, presenting a review of recent developments made on
the improvement of conventional atomic frequency standards described in the two
volumes of QPAFS. It highlights the main limitations of those frequency standards
and the physical basis of those limitations and outlines the progress made during the
last 25 years. Chapter 2 is a description of recent advances in atomic physics, theory
and applications, that opened new avenues. Chapter 3 is concerned with research
and development done in the development of new microwave frequency standards.
Chapter 4 describes research and development done in the optical range to implement
optical frequency standards based on new results in atomic physics as described in
Chapter 2. Chapter 5 summarizes the results in frequency stability and accuracy
Preface                                                                              xv
achieved with those new frequency standards and outlines selected applications.
A short reflection is included giving some insight into future work.
    Such a text cannot be written without significant help from experts in the field.
We wish to recognize the contribution and collaboration of many scientists. In particu-
lar, we wish to recognize the invaluable help of André Clairon, who has read the whole
manuscript and helped in improving its exactness and completeness. We also show our
gratitude to the following scientists who helped us through their encouragement, sup-
plied original figures or material, and contributed by means of comments on various sec-
tions of the text: C. Affolderbach, A. Bauch, S. Bize, J. Camparo, C. Cohen-Tannoudji,
E. De Clercq, A. Godone, D. Goujon, S. Guérandel, P. Laurent, T. Lee, S. Micalizio,
G. Mileti, J. Morel, W.D. Phillips, P. Rochat, P. Thomann, R.F.C. Vessot, and S. Weyers.
                                                                     Jacques Vanier
                                                                                 and
                                                                 Cipriana Tomescu
                                                               University of Montreal
This page intentionally left blank
Introduction
This book is about recent developments in the field of atomic frequency standards,
developments that took place after the publication in 1989 of the first two volumes
with the same title. Atomic frequency standards are systems providing an electri-
cal signal at a cardinal frequency of, say, 10 MHz, a signal generated usually by
a quartz crystal oscillator locked in phase or in frequency to a quantum transition
inside an atom. The atom is selected for its properties such as easy detection of the
particular quantum transition chosen and relative independence of its frequency of
the environment. In early work, those conditions limited development around hydro-
gen and alkali atoms, which have transitions in the microwave range and could be
manipulated easily as beams or atomic vapour with the techniques available at that
time. Progress in the development of lasers and their stabilization extended that
work to the optical range. A major task encountered in the early development of
microwave standards has always been the elimination of Doppler effect. Atoms at
room temperature travel at speeds of several hundred metres per second and, conse-
quently, Doppler effect causes frequency shifts and line broadening of the resonance
signal. This effect is generally eliminated by means of various storage techniques
based on Dicke effect, or still beam techniques using the Ramsey double-arm cavity
approach. These techniques are not well adapted to optical frequencies because of
the shorter wavelengths involved. However, progress in the understanding of inter-
actions between atoms and electromagnetic interactions has provided new means
of reducing the velocity of atoms and reducing, if not eliminating, the constraints
introduced by Doppler effect.
    An atomic frequency standard that is operated continuously becomes an atomic
clock. The operation is essentially a process of integration and the date set as the
constant of integration provides the basis for implementing a timescale. This is the
origin of atomic timescales, in particular the one maintained by the International
Bureau of Weights and Measures. Various systems in operation have their own
timescale, for example, the global positioning system (GPS) of the United States,
the Russian Glonass system, the Chinese Beidou system, and the European Galileo
systems under development, all playing an important role in navigation on or near
the surface of the earth.
    Although time is central to physics and is used in our day-to-day life, it is a con-
cept that is difficult to grasp, let alone to define. We use it without questioning its
origin and its exact nature. It is basic in physics for describing the dynamics of sys-
tems and ensembles of systems by means of equations that model the evolution of
objects forming our universe. The concept is used as such without questioning much
its exact nature and origin. In Newtonian mechanics, objects evolve in space and
their behaviour is described by means of differential equations and functions of time
and space. Both space and time are independent and in common language they are
said to be absolute. In that context, time is not a function of space and space is not a
function of time. However, in attempts to relate mechanics and electromagnetism by
                                                                                    xvii
xviii                                                                     Introduction
space and time transformations, a difficulty arose. This is due to the finiteness and
invariability of the speed of light, made explicit in Maxwell’s equations, whatever
the motion of the frame of reference in which it is generated and measured. In this
context, with Einstein, Poincaré, Lorentz, Minkowski, and others, time and space
become entangled and functions of each other. There is no such thing as an absolute
space in which objects evolve in an absolute time framework, both independent of
each other. Time and space form a single four-dimensional framework and cannot be
treated independently. This concept forms the basis of the theory of relativity. This
theory has been shown to be valid through multiple experiments and verifications to
a level that raises its validity to a high degree. It should be pointed out that the most
accurate verifications were done with atomic clocks, the instruments that are the
content of this book. There is another question also often raised regarding the nature
of time: Could it be discrete? If so what would be the size of its smallest quantity,
the time quantum? Could it be that Planck’s time is the smallest time entity? This
is a totally unknown subject and appears to be a roadblock to in the development of
a sustainable quantum theory that includes the concepts elaborated in the theory of
general relativity.
    Although we may feel somewhat uncomfortable in the context of such questions,
time remains the most basic concept in physics, is fundamental, and is the quantity
that is measured with the greatest precision. Current atomic clocks can commonly
keep time to an accuracy of 1 s in a million years, or in other words are stable to
better than 1 ms in a year. For example, the timescale generated by the GPS satellites
for navigation, based on atomic frequency standards on satellites and on ground,
is stable after appropriate processing and filtering to about 1 ns/day. On the other
hand, on the basis of our inability to measure time by astronomical means with such
accuracy, it was decided in 1967 to replace the astronomical definition of the second
by one in terms of a particular atomic hyperfine transition in the Cs atom. The fre-
quency of that transition is set at 9,192,631,770 Hz. Furthermore, since now the speed
of light is defined exactly as 299,792,458 m/s, providing at the same time a definition
of the metre, the mechanical units of the SI become essentially determined by the
basic time unit, the second. The concept of unifying all SI units in terms of a single
quantity goes further due to the Josephson effect phenomenon, which relates voltage
to frequency in a most fundamental expression, 2e/ℏ, involving only fundamental
constants. This is the subject that will be described in Chapter 5.
    From this discussion, it is evident that time plays a most important role in physics
and technology and the realization of the highest accuracy and precision of the SI
unit, the second, has remained one of the most active preoccupations of several labo-
ratories and institutes over the past 50 years. Starting with tremendous improvements
in the realization of the second within the microwave range, work has extended to
the optical range with proven increase in frequency stability and accuracy by several
orders of magnitude. These achievements were possible mainly through a better
understanding of the interactions between electromagnetic radiation and atoms, pro-
viding a means of altering the properties of atoms. This book is about those improve-
ments that have taken place mainly during the past 25 years, on the realization of
stable and accurate frequency standards.
Authors
Jacques Vanier completed his undergraduate studies in
physics at the University of Montreal, Québec, Canada,
before moving to McGill University to undertake his gradu-
ate studies. During his career he has worked in various
industries (Varian, Hewlett-Packard); taught physics; and
carried out research at Laval University, Montreal, Québec,
Canada, and has also been an active member of the National
Research Council of Canada, in Ottawa, Ontario, Canada.
His research work is oriented towards the understanding
and the application of the quantum electronics phenomena
and he has been a consultant for several companies engaged in the development of
atomic clocks. Jacques has also been very active on the academic circuit, giving lec-
tures and presenting at numerous conferences in universities, national institutes, and
summer schools around the world. He has written more than 120 journal articles and
proceedings papers and is the author of review articles and books on masers, lasers,
and atomic clocks. His book The Quantum Physics of Atomic Frequency Standards,
written with C. Audoin, is recognized as a main reference in the field. He is the author
of The Universe: A Challenge to the Mind published by Imperial College Press/
World Scientific. Jacques is a fellow of the Royal Society of Canada, the American
Physical Society, and the Institute of Electrical and Electronic Engineers. He has
received several awards for his contributions to the field of measurement science. He
is currently an adjunct professor in the Physics Department, University of Montreal,
Québec, Canada.
                                                                                    xix
xx                                                                            Authors
At the end of the 1980s, atomic frequency standards reached a level of refinement
that made it the envy of many other fields of physics. The accuracy of primary cae-
sium (Cs) standards maintained in operation at national institutes reached a level
better that 10−13 and the frequency stability of the hydrogen (H) maser in the medium
term was better than 10−14. These characteristics made possible the verification to
great accuracy of basic physics predictions such as those resulting from the theory of
relativity and made possible the maintenance of a timescale to an unsurpassed stabil-
ity. It also opened the use of such devices in many applications. The time unit, the
second, became the most accurate unit of the International System of Units (SI), with
consequences for the implementation of other units such as the metre, the volt, and
the ohm. On the other hand, Rb standards had reached a level of development that
made them an excellent support of digital communication systems with improved
reliability and also made them appropriate for navigation systems using satellites
requiring medium frequency stability and small size.
    There has been extensive research on the possibility of using other atoms as the basis
for new types of frequency standards. However, those systems are still under study in lab-
oratories; Cs, H, and Rb therefore remain the atoms at the heart of atomic frequency stan-
dards used at large either as references in basic research or in practical systems requiring
precise and accurate timing. Although the Cs standard in its original beam implemen-
tation using magnetic state selection has been dethroned as the most accurate primary
standard with the introduction of optical pumping and laser cooling, it still remains in
many laboratories the work horse for implementing a local timescale, for confirming the
accuracy of other standards, and, to a limited extent, for reliable reporting to the BIPM
(Bureau International des Poids et Mesures) in the maintenance of the second.
    In this chapter, we recall the physical construction and the characteristics of
those frequency standards based on Cs, H, and Rb, as well as of some selected other
types of microwave frequency standards, which still show promise regarding pos-
sible specific applications. We examine the physics at the heart of the operation of
those standards and behind their limitations relative to size, accuracy, and frequency
stability. We also see that those limitations were overcome to some extent, showing
that, with some imagination, improvements could still be made on instruments that
had already attained a very high level of maturity.
                                                                                          1
2                            The Quantum Physics of Atomic Frequency Standards
              2.0                                                             4
                                                                              3
    E/hνhf                                                                    2
                                                                              1
              1.5                                                             0
                                                                             −1
                                                                             −2
                                                                             −3
              1.0
F=4 0.5
0.0
F = 3 −0.5
             −1.0
                                                                             −4
                                                                             −3
                                                                             −2
             −1.5                                                            −1
                                                                              0
                                                                              1
                                                                              2
             −2.0                                                             3
                 0.0      0.2         0.4            0.6       0.8         1.0
                                            B (T )
FIGURE 1.1 Ground state energy level manifold of the caesium atom as a function of the
magnetic induction B in tesla.
and in a low magnetic field the structure consists of two manifolds of 7 and 9 energy
levels, respectively. This ground state is shown in Figure 1.1 as a function of the
magnetic induction B.
                                                                   Modulation,
                                                               synchronous detector,
                               Microwave generator
                                                                and frequency lock
                                                                      system
                                                                Hot wire
                                                                detector       Electron
                                                                               multiplier
                                 Ramsey cavity
Cs oven
                                                                                  Signal out
                                                        Bo
                                                                            Signal out
             Magnet A                                      Magnet B
           state selector     Magnetic shields             analyzer
FIGURE 1.2 Simplified conceptual diagram of the Cs beam frequency standard using magnetic
state selection. The inset shows the shape of the resonant signal observed when the frequency-
lock loop is open and the microwave frequency is scanned slowly over the atomic hyperfine
resonance. Although in the figure the magnetic induction is shown parallel to the beam direc-
tion, in practice it is very often made perpendicular to the beam. (Data from Vanier, J. and
Audoin, C., Metrologia, 42, S31, 2005. Copyright Bureau International des Poids et Mesures.
Reproduced by kind permission of IOP Publishing. All rights reserved.)
beam composition is done by the combination of magnet B, called the analyzer, and
a hot wire ionizer followed by a counter usually assisted by an electron multiplier. In
their transit through the Ramsey cavity, the atoms are submitted to an electromag-
netic field of angular frequency ω in the two arms of the cavity called the interaction
regions. In the first arm of the cavity, atoms are excited into a Rabi oscillation that
puts them into a quantum superposition of the two hyperfine levels F = 4, mF = 0
and F = 3, mF = 0 of the ground state. We define τ, the time of transit of an atom at
speed v inside that first arm of length l. The power fed into the cavity is adjusted to
such a value as to make the electromagnetic radiation appear as a π/2 pulse, that is to
say a microwave pulse that puts the atoms in an exact superposition state of the two
hyperfine levels when they exit that first arm at the most probable speed. The atoms
are subsequently left to drift unperturbed in the space within the double arm cavity.
A uniform magnetic induction Bo provides an axis of quantization and the atoms
remain in the same state. They then penetrate inside the second arm at distance L
from the first arm. We call T the time of transit between the two arms of the cavity.
If v is the speed of a given atom, then T is simply L/v and is affected the spread in v.
In that second arm, the atoms are again submitted to a field of the same intensity and
same frequency as in the first arm. Atoms having the same speed as in the first arm
are, thus, submitted again to a π/2 pulse. The atoms at the exit of the second arm find
themselves in the lower state F = 3, mF = 0 and the transition is complete as if they
had been submitted to a π pulse. If the frequency applied to the cavity is not exactly
the resonance frequency of the atoms, the phase of the field in the second arm is not
Microwave Atomic Frequency Standards                                                  5
coherent with the phase of the magnetic moment of the entering atoms and interference
takes place. The total effect of the radiation inside the two arms is smaller than that
of a π pulse and the transition is not complete. The probability of the transition is
not a maximum and upon detection some atoms appear as having made the transi-
tion to the lower state and some not. The actual state of affairs is analyzed by means
of a second Stern–Gerlach filter that selects only atoms having made the transition
and orients them towards the detector. That detector is made of a hot wire of tung-
sten or other material that ionizes the atoms reaching it. The resulting ion current is
measured either directly (usual in laboratory standards) or by means of an electron
multiplier (usual in commercial standards). If the frequency of the radiation fed to
the cavity is swept over a certain range, a kind of interference pattern is observed at
the output of the detector as shown in the inset of Figure 1.2. It is worth mentioning
that the role of atoms in level F = 4, mF = 0 and of atoms in level F = 3, mF = 0 can
be inverted without affecting the operation of the system.
    This type of signal is called Ramsey fringes (Ramsey 1956). A complete calcula-
tion of the shape of that signal is done in QPAFS, Volume 2 (QPAFS 1989).
    Since the central peak, being the resonance peak, is the signal of interest we con-
centrate on it. For a given atomic velocity v leading to a transit time τ in each arm
of the cavity, the shape of the central fringe signal can be represented approximately
by the following equation (for ease in reading, we import into the present text a few
important equations from QPAFS 1989):
                            1 2
                  P (τ) =     sin bτ 1 + cos ( ΩoT + φ )    | Ωo| << b        (1.1)
                            2
where:
  τ is the time of interaction of the atom with the microwave field in each interac-
         tion region
  T is the time spent by the atom between the interaction regions
  ϕ is the phase difference that exists between the microwave fields in the two arms
         of the cavity, including the effect of asymmetries and cavity losses
  Ωο is the difference between ω, the angular frequency of the microwave radia-
         tion in the Ramsey cavity, and ωo, the resonance angular frequency of the
         atom:
Ωo = ω − ωo (1.2)
The parameter b is the Rabi angular frequency in the interaction region and is a
measure of the amplitude of the microwave induction Bmw. It is defined by the equa-
tion (our definition of b is different from that used by Ramsey (1956) by a factor
of 2, consistent with the notation used in QPAFS 1989):
                                               µB
                                          b=      Bmw                             (1.3)
                                                
where:
  μB is the Bohr magneton
  ℏ is the Planck’s constant h over 2π
6                              The Quantum Physics of Atomic Frequency Standards
Assuming ϕ = 0 or π, the full width at half maximum of the central fringe as given
by Equation 1.1 is readily calculated as:
                                                     π
                                           W=                                               (1.4)
                                                     T
If the resonance signal was observed with a single cavity (Rabi resonance), its line
width would be π/τ. With the double arm cavity the width of the signal is reduced by
the factor, L/l = T/τ, which could be very large in laboratory units designed with a
large distance L between the two arms of the Ramsey cavity of individual lengths l.
In those units, L/l may be in practice of the order of 100 or more.
    We note that Equation 1.1 is valid under the assumption that | Ωo | << b. A better
approximation to the central fringe is obtained by means of a first-order expansion of
the full Ramsey fringe equation as developed in QPAFS, Volume 2 (QPAFS 1989):
                  1 2                             2Ω o          1                    
        P (τ) =     sin bτ 1 + cos ( ΩoT + Φ ) −            tan 2 bτ sin ( Ω0T + Φ )    (1.5)
                  2                               b                                  
Equation 1.1, however, is an excellent approximation of the central fringe shape and
is used in most calculations concerned with frequency shifts introduced by various
phenomena. The third term in Equation 1.5 introduces a correction that amounts in
some cases to a few percent of the biases calculated and is sometimes used for better
precision in the evaluation of various effects (Makdissi and de Clercq 2001).
   The above calculation was done under the assumption that the atoms in the beam
have all the same velocity and spend the same time in the two arms of the cavity. In
practice, the beam is composed of atoms travelling at thermal velocities. In a gas,
atomic velocities are spread according to a Maxwell distribution. However, in the
case of a collimated beam and state selection by magnets, this distribution is greatly
altered. If f(τ) is the resulting distribution of interaction times τ in each arm of the
cavity, then an average of the probability P over this distribution must be made:
                                           ∞
                                      P=
                                           ∫ f (τ)P(τ)d τ
                                           0
                                                                                            (1.6)
where the following relations between speed v and interaction time distributions hold:
                                  ∞             ∞
                                  ∫ f (τ)d τ = ∫ p(v)dv =1
                                  0              0
                                                                                            (1.7)
                                                 l l
                                      f (τ) =      p                                        (1.8)
                                                τ2  v 
The fringe pattern is smeared out to some extent by the velocity spread. It turns out,
however, that the central fringe is not much affected by the averaging, if the velocity
distribution is made sufficiently narrow as is done in some implementation (Becker
1976). A typical experimental result is shown in Figure 1.3 for two scan widths.
Microwave Atomic Frequency Standards                                                   7
1.6 kHz 40 Hz
(a) (b)
FIGURE 1.3 Ramsey fringes observed experimentally in the NRC Cs VI standard. (Data
from Mungall, A.G. et al., Metrologia, 17, 123, 1981. Copyright Bureau International des
Poids et Mesures. Reproduced by permission of IOP Publishing. All rights reserved.)
The field applied may be of the order of 50 to 100 × 10−7 Tesla (50 to 100 mG) and
the displacement of the resonance peak is several parts in 1010. This is the most
important shift in the frequency standard and must be determined with an accuracy
compatible with the accuracy desired in the final evaluation. It is obvious that field
fluctuations must be minimized for reasons of frequency stability. This constraint
forces the use of a rather stable current source supplying the device that creates the
field. This device may be rods or a solenoid. On the other hand, efficient magnetic
shielding is used to prevent environment field fluctuations from reaching the region
of interaction, the Ramsey cavity. This is generally done by means of several lay-
ers of mu-metal or high permeability metallic cylinders surrounding the region of
interaction.
1.1.1.2.1.2 Second-Order Doppler Effect This shift originates from the time
dilation phenomenon of special relativity. For an atom at speed v, the second-order
Doppler effect frequency shift ΔνD2 is given by the equation (QPAFS 1989, Volume 1)
                                          ∆ν D2    v2
                                                =− 2                                   (1.10)
                                           ν hf   2c
where:
  c is the speed of light
In the beam, the velocities are spread over a relatively large range and this shift must
be averaged over the velocity distribution. The average transition probability is given
by Equation 1.6. Since the various shifts to be considered are expected to be small,
we may consider them as independent of each other. When the second-order Doppler
shift alone is taken into account, then the transition probability at the exit of the sec-
ond selector magnet is given by:
                         ∞
                    1                                         v2   
                 P=
                    2    ∫0
                              f (τ)sin 2 bτ 1 + cos ω − ωo  1 − 2   T  d τ
                                                          2c   
                                                                                       (1.11)
This expression may be used directly by proper adjustment and normalization to obtain
the intensity of the beam reaching the detector. We may, thus, write the beam intensity as:
                              ∞
                         1                                     v2       
              I = Ib +
                         2     ∫
                           I o f (τ)sin 2 bτ 1 + cos ω − ωo  1 − 2
                               0                           2c
                                                                            T  dτ
                                                                            
                                                                                       (1.12)
where:
  Ib is the background atomic flux reaching the detector, which, for example, is
         composed of atoms in a wrong state and do not contribute to the signal
The resonance frequency of the standard is identified with the maximum of the
central Ramsey fringe signal, which is simply the maximum of the beam intensity
I reaching the detector. The value of that frequency is obtained by differentiating
Equation 1.12 with respect to ω (see Appendix 1.A). Hence, we obtain:
Microwave Atomic Frequency Standards                                                      9
                          ωD − ωo
                                  =−
                                        ∫0
                                                v2T 2 f (τ)sin 2 b τ d τ
                                                    ∞
                                                                                     (1.13)
                            ωo
                                       2c 2
                                                ∫0
                                                        T 2 f (τ)sin 2 b τ d τ
where:
  ωD is the frequency of the maximum of the central Ramsey fringe
In order to evaluate the resulting shift, one needs to know the interaction time dis-
tribution function f(τ) or the speed distribution. In the 1960s, in the field of atomic
beam resonance spectroscopy, a Maxwellian distribution of atomic velocities in the
beam was assumed (Harrach 1966, 1967). With magnets as state selectors, the distri-
bution may be very different from a Maxwell’s distribution. In early developments of
Cs primary standards, it was assumed that the distribution was Maxwellian, but with
low and high speeds cutoff (Mungall 1971). It was then verified by numerical analy-
sis that the velocity spectrum with its chosen width and cutoff frequencies, using
Equation 1.6, reproduces the observed Ramsey fringe pattern to a good approxima-
tion. However, such an approach is rather empirical. We now outline more advanced
methods for evaluating f(τ) and recent developments that have allowed the evaluation
of velocity-dependent shifts to a very satisfying accuracy.
                                                   φ
                                       ∆ν φ = −                                     (1.14)
                                                  2πT
For example, an asymmetry to the extent of 10−4 m between the lengths of the two
arms of the Ramsey cavity may cause a frequency shift of the order of 10−13 depend-
ing on the electrical losses of the waveguide used. The frequency shift changes sign
upon reversal of the velocity. It can thus be determined experimentally by reversing
the direction of the beam. However, due to the presence of a phase shift that varies
with position in the cavity, called generally distributed phase shift, and due to the fact
that the beam does not necessarily retrace the same path upon reversal, the accuracy of
determination of this shift is limited. In short commercial instruments, the frequency
shift is larger since T is smaller than in laboratory standards. It may reach 1 × 10−12.
   We have provided in QPAFS, Volume 2 (QPAFS 1989), a detailed analysis of the
effect of this shift. Let us recall the main points of that analysis. The equations to be
used are Equations 1.1 and 1.6. Converting to beam intensity, we obtain:
                             ∞
                        1
                        2    ∫                {                         }
                I = Ib + Io f ( τ) sin 2 bτ 1 + cos ( ω − ωo ) T + φ  d τ       (1.15)
                              0
We emphasize the difference between this type of bias and that introduced by the
second-order Doppler effect. The second-order Doppler shift affects directly the fre-
quency of the atoms while the phase shift is introduced through the cavity and is con-
sidered as a step in the time evolution of the atoms. To obtain the frequency where
beam intensity I is maximum, we need to do as in the case of second-order Doppler
effect, that is, differentiate with respect to ω and set ∂I/∂ω = 0 (see Appendix 1.B).
Using the relation T = L/v, the result is:
                                          ∞
                                          ∫ (1 v) f (τ)sin bτ d τ
                                                           2
                                     φ
                         ωφ − ωo = −     ∞
                                          0
                                                                                    (1.16)
                                     L
                                         ∫ (1 v ) f (τ)sin bτ d τ
                                                  2            2
An important consideration follows from that analysis: the shift as measured from
the maximum of the Ramsey pattern is a function of the velocity distribution and
depends on the value of b, thus on the power fed to the cavity. This is the same thing
Microwave Atomic Frequency Standards                                                  11
as in the case of second order Doppler effect, as calculated through Equation 1.13.
We now return to this point and see how recent advances in understanding the phase
shift effect has resulted in its reduction by means of a new type of cavity.
1.1.1.2.2.2 Cavity Pulling The cavity tuning influences the position of the reso-
nance maximum. The effect is small due to the fact that the cavity Q is low resulting
in weak stimulated emission in the cavity since the number of atoms in interaction is
small. In short, Cs beam frequency standards where the resonance is less selective,
the effect may be significant. However, in laboratory standards where the cavity Q
is intentionally made small and the atomic gain is low, this shift is generally under
control and does not cause a problem. For example, for a cavity Q of 500, a line Q
of 1.5 × 108 corresponding to a line width of 60 Hz as realized in the best standards
shown in tables provided hereunder, a detuning of the cavity by 1 MHz would pro-
duce a fractional frequency shift of 6 × 10−15. Full details of the calculation are given
in QPAFS, Volume 2 (1989). On the other hand, it may be mentioned that cavity
detuning may introduce another frequency shift when square wave modulation of the
microwave interrogating frequency is used. The effect appears because the fields at
the two frequencies resulting from the modulation may not have the same amplitude
if the cavity is not tuned exactly to atomic resonance.
1.1.1.2.2.4 Majorana Transitions If the constant magnetic field along the atomic
beam is inhomogeneous, transitions of random nature can be caused between mF
sublevels of the two manifolds F = 3 and F = 4. These are called Majorana transi-
tions (Majorana 1932). It has been shown that these transitions can cause a shift of
the resonance frequency of the central ΔmF = 0 transition (Ramsey 1956). Since in
the classical approach permanent magnets are used for state selection and detec-
tion, it is possible that stray inhomogeneous fields created by those magnets excite
Majorana transitions with a resultant frequency shift. This effect is absent in opti-
cally pumped beam tubes in which no selector magnets are used and where the mag-
netic field can be made very homogeneous all along the beam path.
1.1.1.2.2.5 Rabi and Ramsey Frequency Pulling This is an effect that is partly
inherent to the atoms and partly introduced by the technique of detection of the reso-
nance. A shift is introduced by the overlapping of the symmetrically situated field
dependent Rabi pedestals with the central fringe of the ΔF = 1, ΔmF = 0 resonance
line (De Marchi et al. 1984; De Marchi 1987). When these pedestals have different
amplitudes, which is the case for magnetic state selection, a small distortion of the
12                            The Quantum Physics of Atomic Frequency Standards
central fringe is created by the tails of the field dependent Rabi pedestals, causing a
frequency shift of the central fringe. Furthermore, the microwave field in the cavity
may contain a small perpendicular component causing transitions ΔF = 1, ΔmF = ±1
that are connected to the resonant transition of interest (the ΔmF = 0 transition) by a
common energy level. These transitions may also distort the central fringe and cause
a small frequency shift. This is called Ramsey pulling (Cutler et al. 1991). These
shifts are a function of beam design and depend to some extent on the microwave
power applied to detect the resonance. The effect is function of the applied mag-
netic field and is small when the resonance line is narrow. Consequently, these effects
are much reduced in laboratory standards and in general are small. A considerable
amount of theoretical analysis has been made on these effects (Shirley et al. 1995;
Lee et al. 2003).
                                        ∆ν gr gh
                                             ≅ 2                                      (1.17)
                                         ν    c
where:
  g is the acceleration due to gravity at the location of the clock
  c is the speed of light (Ashby et al. 2007)
  The altitude h is assumed to be small relative to the earth’s radius
The fractional effect on the frequency is about 10−16 m–1. The height above the geoid
is difficult to determine to an accuracy of the order of 10 cm. This corresponds to an
accuracy in clock frequency to the order of 10−17. Consequently, since, as we will see in
Chapter 4, it is possible that optical clock accuracies could reach a level of 10−18 soon, it
should be possible to find a very useful application of atomic clocks in precision geodesy.
Microwave Atomic Frequency Standards                                                     13
                                                       Servo frequency,
   Amplitude of                                       symmetrical line A
     fringe
                                                            Servo frequency,
                                                           asymmetrical line B
                      A
                                                                  B
                              −ωm      ωo         +ωm
                              −ω′m          ω′o     +ω′m
FIGURE 1.4 Illustration of the effect on the actual measured frequency of using square
wave modulation for detecting an asymmetrical fringe. A is a symmetrical fringe while B is a
fringe that is made asymmetrical by a bias such as second-order Doppler effect that depends
on the velocity of the atoms.
14                           The Quantum Physics of Atomic Frequency Standards
velocity-dependent shift. In that case it is shown that the measured frequency called
ω′D is different from ωD and is given by (see Appendix 1.C) (Audoin et al. 1974):
                     ω′D − ωo
                              =
                                     ∫      0
                                             ∞
                                                 v f (τ)sin 2 bτ sin ωmTd τ
                                                                                    (1.18)
                        ωo
                                     ∫           (1 v) f (τ)sin 2 bτ sin ωmTd τ
                                    2
                                  2c
                                            0
A similar expression is obtained for the shift introduced by a residual phase shift
between the two arms of the Ramsey cavity:
                                      ∫ f (τ)sin bτ sin ω Td τ
                                                            2
                               φ                                     m
                   ωφ − ωo = −                   0
                                                 ∞                                  (1.19)
                               L
                                   2c
                                      ∫ (1 v) f (τ)sin bτ sin ω Td τ
                                        2
                                                0
                                                                2
                                                                          m
Consequently, it is clearly seen from these expressions that the locking frequency
of the servo system depends on both the amplitude of the microwave field, b, in the
interaction regions and the amplitude of the frequency modulation, ωm. In conclu-
sion, extreme care needs to be taken in order to evaluate the appropriate corrections
for the bias effects mentioned above that are velocity sensitive and distort the central
Ramsey fringe. The reader is referred to QPAFS, Volume 2 (QPAFS 1989), for more
details on this subject.
1.1.1.2.3.4 Frequency Control Loop Finite dc gain in the control loop and volt-
age offsets can cause frequency offsets in the frequency lock loop. In state-of-the-art
designs, digital servo loops are used and such offsets are eliminated (Garvey 1982;
Nakadan and Koga 1985; Rabian and Rochat 1988; Sing et al. 1990).
   The size of the various offsets described above is summarized in Table 1.1 along
with the present state-of-the-art accuracy in the determination of these offsets. The
table is given without reference to particular systems implemented and is given
solely as a guide to the reader making explicit the relative importance of a given
shift and how accurately it can be determined in the best experimental conditions.
At present, it appears that the biggest shift is the magnetic field offset. However, it is
felt that the accuracy with which it is determined does not cause a major problem if
care is taken in the design of the magnetic environment around the clock. The great-
est cause of inaccuracy is probably still the cavity distributed phase shift limiting
the accuracy to which phase asymmetry in the Ramsey cavity can be determined.
Microwave Atomic Frequency Standards                                                                   15
TABLE 1.1
Approximate Size of Biases or Offsets Present in Laboratory Cs Beam
Frequency Standarda
                                                                                   Typical Smallest
                                             Typical Size in                    Evaluation Uncertainty
                                          Laboratory Standards                         Achieved
                                             (parts in 1015)                        (parts in 1015)
Magnetic field                        >100,000                                  0.1
Second-order Doppler effect           Depends on construction > −50             1
Black Body radiation                  ~20                                       0.3
Spin–exchange interactions            Unknown                                   Expected ≤1
Cavity phase shift                    Depends on construction >100              1 to 10
Cavity pulling                        ~5 to 10                                  0.6
Bloch–Siegert effect                  ~1                                        Expected ≤0.3
Majorana transitions                  ~2                                        <1.3
Rabi and Ramsey pulling               <2                                        0.02
Microwave spectrum                    <1                                        0.1
Electronics, modulation,              1                                         1
 demodulation, etc.
Microwave leakage                     Depends on construction                   <1
Gravitation                           Depends on location                       <0.1
Microwave spectrum                    <1                                        0.1
Fluorescence light shift in           <2                                        <0.5
 optically pumped standards
Source: Vanier, J. and Audoin, C., Metrologia, 42, S31, 2005. Copyright Bureau International des Poids
         et Mesures. Reproduced by kind permission of IOP Publishing. All rights reserved.
a The uncertainty given is that achieved in best circumstances and is given as a reference to the accuracy
                                                     k′
                                       σ(τ) =                                                      (1.20)
                                                Ql (S N )τ1/ 2
where:
  Ql is the atomic line Q
  S/N is the signal-to-noise ratio essentially limited by shot noise at the detector
  k′ is a factor close to unity
16                           The Quantum Physics of Atomic Frequency Standards
The range of application of this equation depends on the servo loop, integrating
filter type and bandwidth. As an example, in some well-designed laboratory stan-
dards using magnetic state selection, a frequency stability of 5 × 10−12 τ −1/2 over a
range extending to 40 days has been measured, in general agreement with the above
expression (Bauch et al. 1999). In the case of optically pumped standards, a better
signal-to-noise ratio (S/N) can be obtained and a frequency stability better than that
just mentioned by an order of magnitude can be realized (3.5 × 10−13 τ −1/2) (Makdissi
and de Clercq 2001).
    The long-term frequency stability of the Cs beam frequency standards depends
on the stability of the various frequency shifts and offsets enumerated above. Con-
sequently, the frequency of a unit is dependent to a certain extent on its environment.
Depending on construction type, temperature, humidity, atmospheric pressure, and
magnetic field play a role to various degrees in determining long-term frequency
stability. Temperature fluctuations appear to have the most important effect acting
through some of the shifts enumerated above. In general, best results are obtained in
a temperature controlled environment.
    Fluctuations of unknown origins generally limit the frequency stability in the
very long term. When the averaging time τ is increased, frequency stability, as given
by Equation 1.20, improves and reaches a plateau called the flicker floor. The level
of this flicker floor is generally a function of unknown parameters. In practice it is
found that better quality in construction and design lowers this flicker floor to nearly
undetectable levels.
    Several national institutes and laboratories have been very active during the
period 1970–1990, in developing Cs beam frequency standards using the classical
approach. Those standards reached a high level of maturity. That stage was attained
through intensive research and development, sophistication of the units, better under-
standing of the fundamental phenomena taking place and collaboration between the
institutions. Table 1.2 is a compilation of the main characteristics of several selected
laboratory units that have been developed during that period. They have played and,
in some cases, still play an important role in the accuracy of TAI (Temps Atomique
International) maintained by the BIPM. Most of them have been influential in the
design of classical primary Cs standards implemented later.
Source: Vanier, J. and Audoin, C., Metrologia, 42, S31, 2005. Copyright Bureau International des Poids et Mesures. Reproduced by kind permission of IOP Publishing.
        All rights reserved.
                                                                                                                                                                                17
18                           The Quantum Physics of Atomic Frequency Standards
that are functions of velocity can be computed more easily. Furthermore, those same
laser diodes allowed the mechanical manipulation of atoms such as reducing their
speed to such limits that it became possible to create small atomic ensembles of
atoms, essentially small balls of the order of a cm or so in diameter, characterized
by a very low temperature. The old dream of the atomic fountain clock, called in the
early days as Fallotron, proposed by Zacharias in the 1950s, could be realized (see
Forman 1985).
    Nevertheless, some institutions continued the refinement of their classic Cs beam
standards, sometimes even in parallel with developments in the new avenues, opti-
cal pumping state selection and atomic fountain just mentioned. Those refined fre-
quency standards using the classical approach reached a level of accuracy such that
it proved the high degree of understanding reached in the physics involved by those
who persisted in improving them. It left no doubts on the quality of the work that was
performed. Some of those standards, at the time of writing of this book, are still used
in some cases in the implementation of the atomic timescale (TAI). They are also
used as reference to check, within their own limits, the reliability and absolute accu-
racy of the standards of the new wave. However, it is clear that their contribution as
a primary standard is limited by their accuracy. An examination of all the work pub-
lished during that period makes evident that the goal was that of breaking the 10−14
barrier as far as accuracy is concerned. It was only achieved after extensive work.
    The Cs and Rb fountains are now the workhorse in many primary standards labo-
ratories and have reached a level of accuracy in the 10−15 and better. However, it is
worth examining the physics behind the work that was done in the improvement of
the classical Cs frequency standards using magnetic state selection since their under-
standing is essential to the success of the optical pumping and fountain approaches.
We hence review in the following paragraphs some of those refinements that were
accomplished during the last two decades and have provided the scientific commu-
nity with some of the most reliable frequency standards.
    As readily observed from Table 1.1, the largest frequency biases, which are observed
in classical Cs beam standards using magnetic state selection and which need to be
evaluated as accurately as possible, are the magnetic field and its homogeneity, the
second-order Doppler effect, and the cavity phase shifts, either nominal between
the two interaction regions or distributed within each region. Black Body radiation,
cavity pulling, Majorana transitions, and Rabi–Ramsey pulling cause shifts much
smaller, less than 10−14, but have also been carefully re-examined in order to certify
that they do not introduce inadvertently any important bias in the measurements.
50 to 100 × 10−7 T (50–100 mG). This gives a Zeeman frequency of the order of 25 to
50 kHz for transitions between field-dependent levels. It provides enough separation
between the field dependent Rabi pedestals to guarantee little effect from overlap.
Thus, the applied field is quite large. The displacement ΔνB of the central fringe of
the Ramsey pattern is obtained from Equation 1.9 as:
where:
  B is in Tesla
That relation applies within the upper states manifold F = 4. In another design, the
field is created by means of a long solenoid enveloping the whole Ramsey cavity
with small end coils used for trimming the field at both ends (Bauch et al. 1996). The
whole structure is enveloped in all cases in multilayer high permeability material
such as mu-metal or moly-permalloy. In that approach, as mentioned in the article
cited, one main cause of instability is temperature affecting the length of the sole-
noid support, causing a change in actual solenoid dimensions with a resulting fluc-
tuation of the magnetic field. Temperature regulation is thus required.
    Nevertheless, as reported in Table 1.1, it appears that the task of creating a field of
sufficient homogeneity and stability for implementing a clock with accuracy in the
10−15 range is not insurmountable. Actually, even at this high magnetic field, an accu-
racy in magnetic field bias determination of 10−15 has been realized in Physikalisch-
Technische Bundesanstalt (PTB) CS1 (Bauch et al. 2000a, 2000b). The question
of the magnetic field bias is thus not a major problem in the construction of such
a device although it must be implemented with great care, particularly regarding
homogeneity. The main reason of this requirement is that what is measured by means
20                           The Quantum Physics of Atomic Frequency Standards
of the Zeeman frequency of ΔmF transitions is the actual value of the field along the
beam while the bias frequency of the clock transition is proportional to the average
of the field squared. In general, <B2> is not equal to <B>2. In practice, the effect
may be evaluated from the position of the Ramsey resonance on top of the Rabi
pedestal (Bauch et al. 1996).
   It should, however, be recalled that the Ramsey cavity design approach intro-
duces a desirable property regarding frequency shifts introduced by magnetic field
inhomogeneities. For example, the magnetic field may be different in the two inter-
action regions and may be different from the field in the drift region. The resulting
frequency shift of the central Ramsey fringe, for a drift region L long compared to
the interaction region l, is the sum of the shifts multiplied by the ratio l/L. The actual
shift is given by the equation (QPAFS 1989):
            ω − ωo l  ω′o − ωo ω′′o − ωo 
                  =           +
                                               ∫0
                                                       τ f (τ)(1 − cos bτ)sin bτ d τ
                                                                                       (1.23)
              ωo   L  ωo           ωo                   ∞
                                                       ∫ 0
                                                               bτ2 f (τ)sin 2 bτ d τ
where:
  ω ο′ and ωο″ are the resonance frequencies in the two interacting regions, respectively
  ωο is the resonance frequency in the drift region
For a laboratory standard with a 1 m long cavity, a frequency shift of the order of
10−4 Hz may thus be reduced by a factor of 100 and made negligible.
to be a proper avenue for calculating a bias affecting the accuracy of a primary stan-
dard. We now outline regarding how the question of determining the velocity distri-
bution to evaluate carefully the frequency bias caused by the second-order Doppler
effect as well as by cavity phase shift bias was addressed.
(ABA) (ABA)
(a)
ABA
ABA
(b)
FIGURE 1.5 Schematic representation of the two usual implementations of the Ramsey
cavity. In (a) ABA stands for atomic beam axis. The coupling to the cavity is made through an
E-plane T-junction and the cavity is bent in the E-plane; (b) the coupling is done through an
H-plane T-junction. The magnetic field is represented by dotted lines. In the implementations
chosen, in (a) the atomic beam passes close to the end while in (b), it passes at a so-called anti-
node (1/2)λg from the short circuit end. (Data from Bauch, A. et al., IEEE T. Instrum. Meas.,
IM-34, 136, 1985; Mungall, A.G. et al., Metrologia, 9, 113, 1973.)
This is illustrated in Figures 1.6c and d. Let us examine the phase of the microwave
standing wave along the direction travelled called the zg direction. If we call z′g as the
distance within the guide from the nearest antinode point identified by the number
p = 0, 1, 2 …, then the phase is given by:
                                       1                             2π z′g
                           φ ( z′g ) =  pα g λ g + α g z′g + rm  tan                      (1.24)
                                       2                              λg
                        Short circuit
                                                                         Short circuit
           H                                             H
                                          zg                                             zg
                       0          λg/2                               0            λg/2
     (a)                                           (c)
                                              zg                                         zg
                       0         λg/2                                    0        λg/2
     (b)                                           (d)
FIGURE 1.6 Schematic representations of the amplitude of the magnetic field H and the
phase of H at the first antinode(s) near the end of the arms of the Ramsey cavity. (a) and
(b): case where the walls of the waveguide are perfect conductors. (c) and (d): case where the
walls of the waveguide have finite electrical conductivity. (Data from Bauch, A. et al., IEEE
T. Instrum. Meas., IM-34, 136, 1985.)
on the right represents absorption along the waveguide characterized by the absorption
coefficient αg due to the extra length travelled by the wave upon its reflection to reach
the antinode point (1/2) pλg. The second term is of the same nature but represents
the same effect as a function of distance close to an antinode with z′g being a small
distance from the antinode centre. The last term, rm, represents the effect of the finite
conductivity of the cavity termination on the actual reflection of the wave at that
short circuit. The parameter rm is the real part of the surface impedance of the short-
circuit material normalized to the waveguide impedance. Hereunder, we provide the
value of the various parameters for a copper waveguide WR 90
We recall that p is an integer with value 0 at the short circuit and 1 at the first antinode
close to the short circuit, which in some implementation is the point where the beam is
oriented as in Figure 1.5b. Because of the electrical losses, two effects result. If the arms
do not have exactly the same length, that is, the T feeding the cavity is not well centred,
the phase is different in the two arms. As a first approximation, neglecting the small
effect of reflection less than unity at the short circuit, rm can be neglected relative to the
other terms in Equation 1.24 and the phase shift ϕ between the two arms is calculated as:
                                              2πα g Lo ∆Lo
                                         φ=                                              (1.25)
                                                  λg
24                             The Quantum Physics of Atomic Frequency Standards
where:
  L o is the mean value of the length of each of the two arms
  ΔL o is the difference between their lengths caused by an inexact centring of the T
          feeding the cavity
For convenience, the results are shown in Figure 1.7, partly replicated from QPAFS
(1989) and for the value of the parameters given above for a WR 90 copper wave-
guide. The variation of the phase along the other axis xg′ perpendicular to the beam
direction for the case of Figure 1.5b, that is in the direction of the larger transverse
dimension, a, of the waveguide, is calculated in the same manner. Those results are
also shown in Figure 1.7.
   In practice, the measured gradient of the distributed phase shift may be as large as
10−4 rad/mm, slightly larger than that calculated above (as reported for PTB’s CS2,
Bauch et al. 1987). On the other hand, in a particular design, the precision of the
retrace upon beam reversal and after great experimental care was found to be of the
order of 0.13 mm (Bauch et al. 1993). This would thus correspond to a possible error
of 1.3 × 10−5 rad in the evaluation of the phase shift. Using Equation 1.9, for a cavity
structure 1 m long and a mean atomic beam speed of 100 m/s, this would corre-
spond to a fractional frequency shift of the order of 2 × 10−14. As can be seen, it thus
appears that the phase shift, although great care is taken in evaluating it by means of
beam reversal, limits the accuracy of the clock. Furthermore, the beam trajectory is
affected by the earth’s gravitational field (QPAFS 1989). A simple calculation shows
Microwave Atomic Frequency Standards                                                         25
ϕ1 (10−4 rad.)
6 b
2 a
                                                                     c
                                                                    Distance (cm)
−2
−4
FIGURE 1.7 Variation of the phase as a function of the transverse direction across the
beam. Curve b is for a beam traversing the waveguide at an antinode point situated at λg/2
from the short circuit while curve a is for the beam traversing the waveguide close to the short
circuit. Curve c is for the ring cavity studied below. The dotted line curve is for direction x,
perpendicular to the direction of propagation as explained in the text.
that for a 1 m long structure and even with an average atomic beam speed of 100 m/s,
the atoms fall by 0.5 mm during the traversal of the cavity. This number varies with
the speed of the individual atoms forming the beam. This effect of course creates a
real challenge in mechanical design and adjustment to reproduce reliably the beam
path upon reversal. With such an error in path reproducibility, the corresponding shift
could be nearly 10−13 for the case above. For this reason, some systems using slow
atoms have been constructed vertically. However, the particular approach used was
abandoned due to other difficulties encountered in connection to several other detri-
mental effects in particular with magnetic shielding (A. Bauch 2012, pers. comm.).
    As is readily observed in Equation 1.26, if the odd terms could be eliminated by
means of a different cavity configuration, the phase shift could be reduced. This can
be accomplished by means of a so-called ring cavity (De Marchi 1986). Such a cav-
ity is shown in Figure 1.8.
    In that configuration, the cavity resonant at 9.192 GHz is excited by means of
a rectangular waveguide, and waves are generated symmetrically around the ring.
A standing wave is thus excited in the structure. In the configuration shown, at
the entrance through the tee, the wave separates into two waves travelling to the
right and to the left with amplitudes b1 and b 2, or since we are interested in the
magnetic field components of the wave as H10 and H20. We assume that the struc-
ture is characterized by a propagation vector γ = α + iβ, where α is the absorption
26                           The Quantum Physics of Atomic Frequency Standards
             T-junction
                                                                                          b3   a3
a1 a2
b1 b2
                                                               Cs beam
             Cs beam                                         entrance hole                          z′
           entrance hole
     (a)                                               (b)
FIGURE 1.8 Ring cavity used in some of the recently implemented Cs atomic beam
frequency standards. (a) 3D view, (b) Identification of the various field components.
                                                    − iω t − γ ( l 2+ z ′ )
                                 H1( z′) = H1e
                                                                                                              (1.27)
                                                     − iω t − γ ( l 2 − z ′ )
                                 H 2 ( z′) = H 2e
                                                        (
                           H ( z′) = H oeiω t − γ l 2 e − γ z′ + e + γ z′       )                             (1.28)
By using trigonometric relations (see Appendix 1.D), it is then shown that the phase
of H close to the beam axis is given approximately by:
φ = αβ z′2 (1.29)
What are the advantages of such a cavity in comparison to the standard one using
short circuits? This question can be addressed by comparing the result just obtained
to that of Equation 1.26 for the standard approach using a cavity terminated with
short circuits. Its first advantage is that the value of phase shift is independent of
the antinode chosen for the interaction. The second advantage is that, since there is
no short circuit used to terminate the cavity, there is no reflected wave and thus the
phase shift does not depend on the attenuation caused by partial reflection at such
a short circuit. For example, for a displacement of the beam along z′ we have the
following result for the phase shift, assuming the same characteristics as those used
previously for the waveguide:
Microwave Atomic Frequency Standards                                                   27
The distributed phase shift thus appears to be reduced somewhat in the ring cavity
compared to the standard short-circuit approach. However, asymmetries in the ring
may have an effect on the phase shift and position of the antinode. Asymmetries can
be of two types. A phase shift may be introduced in construction through a mechani-
cal asymmetry, a tilt angle of the T-junction, for example. The resulting effect is an
imbalance of the two counter-propagating waves excited in the cavity (De Marchi
et al. 1988). In such a case, the asymmetry may cause a small displacement of the
antinode relative to its position when the structure is symmetrical. It is evaluated
that a tilt angle of 50 mrad can produce a frequency shift of the order of 3 × 10−15 .
A similar effect may result from an asymmetry of the propagation constant γ in the
two halves of the cavity. It is calculated that if the asymmetry, in terms of Δγ/γ, is
less than 10−2, the displacement of the antinode is then less than 0.2 mm, which is
negligible in the present context.
   The ring cavity was used in a few recent implementations of laboratory primary
standards (Bauch et al. 1998, 1999a, 1999b). It was also used in some units where
optical pumping was used for state selection (Shirley et al. 2001; Hasegawa et al.
2004). It was found that the distributed phase shift was reduced to some extent when
compared to the short-circuit approach. In the case of PTB’s CS1 refurbished with
ring cavities, it was concluded that the phase gradient could be as large as 20 μrad/
mm although using the analysis presented above the phase over the beam diameter
of 3 mm should not vary more than approximately 4 μrad. It is concluded, however,
that this is much better than the 94 μrad/mm expected in their case for the standard
cavity using short-circuit terminations (Bauch et al. 1998). We note that in order
to evaluate correctly the effect of the phase shift, we must evaluate it by means of
Equation 1.19 and that the velocity distribution or interaction time distribution must
be established for the particular device used. This is what we examine next.
using Fourier transform techniques to analyze the observed Ramsey fringes was
introduced early in the development of laboratory standards (Kramer 1973; A.
Bauch 2012, pers. comm.). The technique was used in various ways and has been
an important factor in improving accuracy. It was outlined in QPAFS, Volume 2
(1989). Let us recall that technique and address the question in the more gen-
eral context of the control of atomic velocities in laboratory Cs beam frequency
standards.
   The need of knowing accurately the velocity distribution, or the interaction
time distribution, arises in the evaluation of both the second-order Doppler effect
and the cavity phase shift. These are given by Equations 1.13 and 1.16. In those
equations, it is observed that although the shifts are functions of velocity, they are
rather small, being of the order of parts in 1013. Consequently, although producing
a measurable frequency shift, the effect on the shape of the Ramsey fringes them-
selves arising from those shifts is very small. The shape of the signal detected, as
given by Equations 1.12 and 1.15 with the term v2/2c2 and ϕ neglected can then
be used as an excellent representation of the Ramsey line shape, which remains a
function of velocity through the function f(τ). In that context, those expressions
become:
                                  ∞
                            1
                            2     ∫
                    I = Ib + Io f ( τ) sin 2 bτ 1 + cos ( ω − ωo ) T  d τ
                                  0
                                                                                      (1.30)
However, this equation can be rearranged. We remove the constant term Ib not con-
tributing to the useful signal and hence obtain:
                      ∞                          ∞
                  1                         1
             I=
                  2   ∫
                      0
                                            2    ∫
                    Io f ( τ) sin 2 bτ d τ + Io f ( τ ) sin 2 bτ cos ( ω − ωo ) d τ
                                                 0
                                                                                      (1.31)
This equation relies on the approximation made earlier that (ω − ωο) is much smaller
than bτ. The first term is independent of ω and is simply the maximum of the Rabi
pedestal. The second term is the Ramsey modulation of that pedestal. This expres-
sion contains the effect of the atoms' velocity distribution on the Ramsey fringes.
The Rabi pedestal being broad with a flat top, a simple approach consists in looking
only at the second term as a good representation of the effect of the velocity spec-
trum on the signal observed. It is readily seen that the expression is a cosine trans-
form of the term f(τ) sin2 bτ. Consequently, with a knowledge of the Rabi frequency
b in the cavity, f(τ) can in principle be obtained through an inverse Fourier transform
of the measured Ramsey pattern (Kramer 1973; Daams 1974).
   A particular approach in applying such a technique consists in setting ω = ωο,
and measuring the signal amplitude as a function of the field intensity b in the cavity
(Boulanger 1986). Let us now recall the general idea. For ω = ωο, the expression for
the Ramsey fringe amplitude becomes:
                                          ∞
                                          ∫
                                   I = Io f ( τ) sin 2 bτ d τ
                                          0
                                                                                      (1.32)
Microwave Atomic Frequency Standards                                                 29
In that case, the second term is the cosine transform of f(τ) that we call F(b). An
experimental plot of I against b gives F(b) and its inverse transform gives:
                                          ∞
                                        4
                               f ( τ) =
                                        π ∫
                                          F( b) cos 2bτ db
                                           0
                                                                                  (1.34)
                          R(Ωo) =
                                    ∫ f (τ) sin bτ cos ( Ω τ) d τ
                                                    2
                                                              o                   (1.35)
                                     0
The function f (τ)sin 2 bτ, called F(τ), can then be obtained from the data recorded as
a function of Ωo by means of an inverse transform (Shirley 1997):
                                                    ∞
                                               4
                   F( τ) = f ( τ) sin 2 bτ =
                                               π ∫
                                                 R ( Ωo ) cos ( Ωo τ ) d Ωo
                                                    0
                                                                                 (1.36)
  Where a distance rod is used, as on the rear axle, both ends are
attached by shackles.
  3. The three quarter elliptic, Fig. 3, always used as a suspension
for the rear axle. This form gives more flexibility than a half elliptic,
and is still stiffer so far as side motion is concerned, than the
following type.
   4. The full elliptic, Fig. 4, was formerly used much more than at
the present time.
   There are also in use springs comprising a combination of half
elliptic, or three quarter elliptic, on each axle, in which the front end
is shackled to the frame, and the rear ends connected by shackles to
another half elliptic spring, the center of which is fastened to the
frame.
  Fore and Aft Motion. Provision must be made, in all cases, for the
fore and aft movement of the car body which takes place in stopping
or starting, and, particularly when the wheels strike an obstruction.
   Flues. Fig. 5 shows a side view of a car, in which the dotted lines
indicate the position of the body, relative to the normal, when the
wheels strike an obstacle.
   Lateral Motion. In like manner when the car swings around a
corner, or is traveling along a hill-side, the springs must hold the
body from swinging too far. Fig. 6 illustrates, by means of the dotted
lines, the side movement. It is obvious, therefore, that the springs
have a duty to perform in addition to that of merely giving flexibility
to the body.
                           Fig. 6. Lateral
                              Motion.
   3. Full floating axles carry the full weight of the car, and the
differential bevel gear teeth pressure with the housing, so that the
axle shafts carry no load but only the torsional stress.
    Both full and semi-floating constructions are applied to rear axles
only. The front wheels are now universally applied to knuckles, which
swing on vertical pivot pins at the ends of the dead axles.
    Wheels.—Wheels are now in a transition state. The ultimate wheel
has not yet appeared; but whatever its form or construction, certain
things are essential.
    Flexibility.—In the ordinary wagon or carriage wheel, there is but
little, if any, flexibility; but in automobiles, where speed is a
consideration, elasticity, either in the rim, or in some other part of
the wheel, is necessary.
    One of the reasons for this is, that on account of tire expense,
motor wheels are smaller than carriage wheels. Making them
smaller, however, produces certain disadvantages. One is that in
going over the inequalities of the road, the axle on the small wheel
has a greater vertical movement than on a large wheel, and the jar
on striking an obstruction is more pronounced, also. These
disadvantages, however, are more than counterbalanced by the
elasticity of the invention.
    Large vs. Small Wheels.—Fig. 9 shows a large wheel A, passing over
a depression B. The large arc of the wheel does not permit the rim
to go to the bottom. On the other hand, the small wheel C goes to
the bottom of the depression, and the vertical distance which the
axle of this wheel must travel, is three times as far as in the case of
the wheel A.
    In Fig. 10, where the large wheel strikes an obstruction D, the
angle of its upward movement, as designated by the line E, is much
less than the impact force of the small wheel, as shown by the
greater slope or incline of the line F.
            Fig. 9. Crossing          Fig. 10. Striking
              Depression.               Obstruction.
  The solid tires are used on heavy trucks, where weight and not
speed must be provided for.
  Cushion tires are sometimes employed on cars and trucks of
medium weight.
  Pneumatic tires, in which air is used, are universally used in
automobiles for all other purposes.
                          Fig. 12. Single
                               Tube.
   Various ways are provided for holding the shoe to the rim of the
wheel; but in the different types shown by the illustrations, Figs. 13
and 14, the shoe has a flange which is held within channels on the
rim, or by some form of fastening device.
   The inner tube is usually of thin elastic rubber, so made that when
properly inflated it will fit the outer tube or casing. The outer part,
which can be made of a different rubber compound, and is better
adapted to stand wear, whereas, the inner tube, which is made of
the best, and more costly material is protected.
   Advantage of Double Tube.—The great advantage of the double tube
is due to the positive means of fastening it to the rim of the wheel,
so as to prevent creeping.
   In the single tire construction the latter is liable to roll out of its
bed where quick turns are made, but with the double tube this is not
possible.
               Fig. 14. Illustrating Tire-removing
                               Tool.
                              Fig. 15.
                             Vulcanizer.
                Fig. 23.
              Contracting               Fig. 24.
                Brake.              Expanding Brake.
  The gears which make up the train are usually put into a suitable
casing, as illustrated in Fig. 31, which gives a good example of the
construction. The housing A is fixed to the side of a large bevel gear
B, this gear being designed to receive power from the motor through
a bevel pinion C. One part of the axle D passes through the gear B,
and is fixed to a bevel gear E within the housing, and the other part
of the axle F passes through the housing and is fixed to a bevel gear
G, the same size as gear E.
  Intermediate the two gears is a pair of bevel pinions H, H, and
these latter are mounted on pivots I, I, projecting inwardly from the
housing.
  The fact that the pinions are attached to housing has the effect of
complicating the matter, so that it may be well to show the relative
arrangement of the gears without the housing.