Rayat Shikshan Sanstha’s

Karmaveer Bhaurao Patil College, Vashi, Navi Mumbai

(Empowered Autonomous)

[University of Mumbai]

Syllabus for Approval

Sr. Heading Particulars

No.

1 Title of Course S.Y.B.Sc. Chemistry

2 Eligibility for Admission F.Y.B.Sc. [of any recognized

University]

3 Passing marks 40%

4 Ordinances/Regulations

(if any)

5 No. of Years / Semesters One Year / Two Semesters

6 Level U.G.

7 Pattern Semester

8 Status New (NEP 2020)

9 To be implemented from Academic 2024-2025

year
 AC - / / 2024

Item No –

Rayat Shikshan Sanstha’s

KARMAVEER BHAURAO PATIL COLLEGE, VASHI.NAVI MUMBAI
Sector-15- A, Vashi, Navi Mumbai - 400 703

(Empowered Autonomous)

Program: B.Sc.
Syllabus for S.Y.B.Sc. In Chemistry
Course: S.Y.B.Sc. Chemistry

Under NEP 2020

with effect from the academic year

2024‐2025
Preamble of the Syllabus:

Bachelor of Science (B.Sc.) in Chemistry is an undergraduate program of the Department of

Chemistry, Karmaveer Bhaurao Patil College Vashi, Navi Mumbai. The revised syllabus in
Chemistry as per the NEP 2020 structure for S.Y.B.Sc. The course will be implemented from the
academic year 2024-2025.

The NEP 2020 to be implemented through this curriculum would allow students to motivate and
encourage learners to understand basic concepts in chemistry and to develop the experimental skills
that will provide a strong foundation.
The learners pursuing this course would have to enrich their knowledge through critical/analytical
thinking and reasoning abilities, numerical problem solving, hands-on activities, study tours,
industrial visits, mini projects etc.
The learner would have to familiarize with the recent scientific and technological advancements and
in turn to develop critical and analytical abilities towards understanding of real world problems.

Rayat Shikshan Sanstha’s

 Karmaveer Bhaurao Patil College Vashi, Navi Mumbai
Name of the Faculty: Science and Technology
Name of the Program: Bachelor in Science (B. Sc.)
S. Y. B. Sc. Chemistry
Program Outcomes
PO-1 Disciplinary Knowledge:
Understand the basic concepts, fundamental principles, theoretical formulations and
experimental findings and the scientific theories related to Physics, Chemistry,
Mathematics, Microbiology, Computer Science, Biotechnology, Information Technology
and its other fields related to the program.
PO-2 Communication Skills: Develop various communication skills such as reading, listening
and speaking skills to express ideas and views clearly and effectively.
PO-3 Critical Thinking: Propose novel ideas in explaining the scientific data, facts and figures
related to science and technology.
PO-4 Analytical Reasoning and Problem Solving: Hypothesize, analyze, formulate and
interpret the data systematically and solve theoretical and numerical problems in the diverse
areas of science and technology.
PO-5 Sense of Inquiry: Curiously ask relevant questions for better understanding of fundamental
concepts and principles, scientific theories and applications related to the study.

PO-6 Use of Modern Tools: Operate modern tools, equipments, instruments and laboratory
techniques to perform the experiments and write the programs in different languages
(software).
PO-7 Research Skills: Understand to design, collect, analyze, interpret and evaluate
information/data that is relevant to science and technology.
PO-8 Application of Knowledge: Develop scientific outlook and apply the knowledge with
respect to subject.
PO-9 Ethical Awareness: Imbibe ethical, moral and social values and exercise it in day-to-day
life.
PO-10 Teamwork: Work collectively and participate to take initiative for various field-based
situations related to science, technology and society at large.
PO-11 Environment and Sustainability: Create social awareness about environment and develop
sustainability for betterment of future.
PO-12 Lifelong Learning: Ability of self-driven to explore, learn and gain knowledge and new
skills to improve the quality of life and sense of self-worth by paying attention to the ideas
and goals throughout the life.
Name of the Specific Program: BSc Chemistry Program Specific Outcomes (PSO)
PSO-1 Enable students to develop scientific skills by applying the principles of organic, inorganic,
physical chemistry and analytical chemistry.
PSO-2 To develop ability and to acquire the knowledge of terms, facts, concepts and processes
techniques of Chemistry.
PSO-3 To inculcate the ethical, Human, environmental, Social Values and responsibilities in the
context of learning Chemistry.
PSO-4 To expose the students to a breadth of experimental techniques, skills required in chemistry,
proper handling of apparatus and chemicals using modern instrumentation.
SYLLABUS (UNDER NEP 2020) FOR S. Y. B. Sc. CHEMISTRY

(THEORY & PRACTICAL)

SEMESTER – III (MAJOR & MINOR)

Course Title Credits
Code
CHE201 Physical and Inorganic Chemistry 03

CHE202 Organic and Inorganic Chemistry 03

CHE203 Analytical Chemistry 03

CHEP201 Practicals 01

CHEP202 Practicals 01

CHEP203 Practicals 01

Total = 12

SEMESTER – IV (MAJOR & MINOR)

CHE251 Physical and Inorganic Chemistry 03
CHE252 Organic and Inorganic Chemistry 03
CHE253 Analytical Chemistry 03
CHEP251 Practicals 01
CHEP252 Practicals 01
CHEP253 Practicals 01
Total = 12

SCHEME OF THEORY (SEE) EXAMINATION (SEM- III & IV)

I. Theory: Semester End Examination: 60 % Weightage
Each theory course shall be of TWO hours in duration.
Each course shall consist of FOUR questions, one on each Unit.
All questions are compulsory and will have internal options.
Choice in question papers is 2 times.

Q–I : From Unit – I (12 Marks) Total Marks

(45M )

Q – II : From Unit – II (12 Marks)

Q – III : From Unit – III (12 Marks)

Q – IV : From Unit – I, II & III (09 Marks)

II. Theory: Continuous Internal Assessment: 40 % Weightage Total Marks

1. Online Test (MCQ type) of 20 marks of 20 minutes duration. 40 reduced to
2. Evaluation Method (I) : 10 marks (30 Marks)
3. Evaluation Method (II): 10 marks

SCHEME OF PRACTICAL EXAMINATION (SEM- III & IV)

III. Practical: Semester End Examination: 25 marks

CHEP201 1. One Experiment (20 marks and 2 hrs duration) Total Marks
(Major) 2. Certified Journal and Viva-Voce: 05 marks (25 Marks)

CHEP202 1. One Experiment (20 marks and 2 hrs duration) Total Marks
(Major ) 2. Certified Journal and Viva-Voce: 05 marks (25 Marks)

CHEP203 1. One Experiment (20 marks and 2 hrs duration) Total Marks
(Minor) 2. Certified Journal and Viva-Voce: 05 marks (25 Marks)

SEMESTER - III
Course Code Title of the Courses Credits

CHE201 Physical and Inorganic Chemistry 3P+1P = 04

CHE202 Organic and Inorganic Chemistry 3T+1P = 04

 CHE203 Analytical Chemistry 3T+1P = 04

Vertical 1 -Major Course ‐ 1:

Course Code: CHE201: (45 Lectures Theory + 30 Hrs Practicals, Total Credits = 04)
Unit – Chemical Thermodynamics-II, Electrochemistry (10 L)
1: 1.1 Chemical Thermodynamics-II (5L)
 1.1.1 Free Energy Functions: Helmholtz Free Energy, Gibb's Free
Energy, Variation of Gibb's free energy with Pressure and Temperature.
 1.1.2 Gibbs-Helmholtz equation, Van't Hoff reaction isotherm and Van't
Hoff reaction isochore.(Numericals expected).
1.2 Electrochemistry: (5L)
 1.2.1 Conductivity, equivalent and molar conductivity and their
variation with dilution For weak and strong electrolytes.
 1.2.2 Kohlrausch law of independent migration of ions.
 1.2.3 Applications of conductance measurements: determination of
degree of Ionization and ionization constant of weak electrolyte,
solubility and solubility product of sparingly soluble salts, ionic product
of water. (Numericals expected).
Unit – Chemical Kinetics-II, Solutions (10 L)
2: 2.1 Chemical Kinetics-II (5L)
 2.1.2 Effect of temperature on the rate of reaction, Arrhenius equation,
Concept of energy of activation (Ea). (Numericals expected).
 2.1.3 Theories of reaction rates: Collision theory and activated complex
theory of bimolecular reactions. Comparison between the two theories
(Qualitative treatment only)
2.2 Solutions: (5 L)
 2.2.1 Thermodynamics of ideal solutions: Ideal solutions and Raoult’s
law, deviations from Raoult’s law–non-ideal solutions. Vapour pressure-
composition and temperature-composition curves of ideal and non-ideal
solutions.
 2.2.2 Partial miscibility of liquids: Critical solution temperature; effect of
impurity on partial miscibility of liquids with respect to Phenol-Water,
Triethanolamine – Water and Nicotine – Water systems
 2.2.4 Nernst distribution law and its applications, solvent extraction.
Selected topics on p-block elements
Unit – 3.1 Chemistry of Boron Compounds (02) (10 L)
3: 1. Preparation of simple boranes like diborane and tetraborane.
2. Structure and bonding in diborane and tetraborane (2e-3c bonds)
3. Synthesis and applications of Borax.
3.2 Chemistry of Silicon and Germanium (03)
1. Silicon compounds: Occurrence, Structure and inertness of SiO2
2. Preparation of structure of SiCl4
3. Occurrence and extraction of Germanium
4. Preparation of extra pure Silicon and Germanium
 3.3 Chemistry of Nitrogen family (05)
1. Trends in chemical reactivity - Formation of hydrides, halides,
oxides with special reference to oxides of nitrogen.
2. Oxides of nitrogen with respect to preparation and structure of NO,
NO2, N2O and N2O4.
3. Synthesis of ammonia by Bosch – Haber process.

Reference Books:
1. Barrow, G.M. Physical Chemistry Tata McGraw‐Hill (2007).
2. Castellan, G.W. Physical Chemistry 4th Ed. Narosa (2004).
3. Kotz, J.C., Treichel, P.M. & Townsend, J.R. General Chemistry CengageLearning
India Pvt.Ltd., New Delhi (2009).
4. Mahan, B.H. University Chemistry 3rd Ed. Narosa (1998).
5. Petrucci, R.H. General Chemistry 5th Ed. Macmillan Publishing Co., NewYork (1985).
6. K.L.Kapoor A textbook of Physical Chemistry3rd Ed. vol.1,2Macmillan Publishing
Co., NewDelhi(2001)
7. Practical Inorganic Chemistry by G. Marr and B. W. Rockett van Nostrand Reinhold
Company (1972)
8. Inorganic Chemistry – Gary Wulfsberg, Viva Book, First Indian Edition 2002
9. Quantitative Analysis – R.A.Day, A.L. Underwood, sixth edition
10. Vogel’s Textbook of Quantitative Chemical Analysis – J Mendham, R C Denny, J D
Barnes, M Thomas, B Sivasankar
11. Bruce H. Mahan, University Chemistry, Narosa publishing house pg. 611 to 683.
12. R. Gopalan , Universities Press India Pvt.Ltd. Inorganic Chemistry for Undergraduates.
13. Chemistry of Transition Elements Pg.- 608 – 679.14. J. D. Lee, 4th Edn., Concise
Inorganic Chemistry, ELBS, The group III elements Pg. 359- 648.

Vertical -1- Major Course ‐ 2:

Course Code: CHE202: (45 Lectures Theory + 30 Hrs Practicals, Total Credits = 04)

Unit – Carbonyl Compounds (10 L)

1:
1.1 Carbonyl Compounds and their Reactivity: [10L]
1.1 Nomenclature of aliphatic, alicyclic and aromatic carbonyl compounds.
Structure, reactivity of aldehydes and ketones and methods of preparation;
Oxidation of primary and secondary alcohols using PCC, hydration of alkynes,
action of Grignard reagent on esters, Rosenmund reduction, Gattermann –
Koch formylation and Friedel Craft acylation of arenes, Riemer-Tiemann
Reaction, Vilsmeier Haack reaction
1.2 General mechanism of nucleophilic addition, and acid catalyzed
nucleophilic addition reactions.
 1.3 Reactions of aldehydes and ketones with NaHSO3, HCN, RMgX, alcohol,
amine, phenylhydrazine, 2,4-Dinitrophenyl hydrazine, LiAlH4 and NaBH4.
1.4 Mechanisms of following reactions: Aldol condensation, Knoevenagel
condensation, Claisen-Schmidt and Cannizzaro reaction.
1.5 Keto-enol tautomerism: Mechanism of acid and base catalyzed enolization
1.6 Active methylene compounds: Acetylacetone, ethyl acetoacetate diethyl
malonate, stabilized enols. Reactions of Acetylacetone and ethyl acetoacetate
(alkylation, conversion to ketone, mono- and dicarboxylic acid)
Reactions and reactivity of halogenated hydrocarbons, alcohols, phenols
Unit – and epoxides, (10 L)
2: 2.1. Reactions and reactivity of hydrocarbons:

2.1.2. Aromatic Nucleophilic Substitution [5L]

Reactivity of aryl halides towards nucleophilic substitution reactions.
Nucleophilic aromatic substitution (SNAr) addition-elimination mechanism
and benzyne mechanism. SN1 reactions (Sandmeyer reaction)

2.2 Reagents in Organic Synthesis: [5L]

2.2.1 Oxidizing & Reducing reagents [3L]
Oxidizing Agents (Preparation, reaction and application) PDC, PCC, Swern,
Jones regent oxidation, Oppenauer oxidation, Reducing Agents (Preparation,
reaction and application)
Clemmensen Reduction, Wolff- Kishner Reduction, Birch Reduction, MPV
reduction, Barnavont Blanc Reduction
2.2.2 Organomagnesium and organolithium compounds: [2L]

Nomenclature, nature, type and reactivity of carbon-metal bond. Preparation

using alkyl/aryl halide. Structure, stability and reactions with compounds
containing acidic hydrogen, carbonyl compounds, CO2, cyanides and
epoxides.

Unit – Chemical Bonding (10 L)

3:
Directional Bonding: Orbital Approach. (5L)
1. Covalent Bonding: The Valence Bond Theory- Introduction and basic
tenets. Interaction between two hydrogen atoms and the Potential energy
diagram of the resultant system. Corrections applied to the system of two
hydrogen atoms- Formation of H2.
2. Homonuclear diatomic molecules from He2 to Ne2. Resonance and the
concept of Formal Charge; Rules for Resonance or Canonical
structures.Bonding in Polyatomic Species: The role of Hybridization.
Types of hybridization involving d orbitals.dsp2, sp3d, sp3d2 and sp3d3.
3. Equivalent and Non-Equivalent hybrid orbitals.
4. Contribution of a given atomic orbital to the hybrid orbitals (with reference
to sp3 hybridization as in CH4, NH3 and H2O and series like NH3, PH3,
AsH3, BiH3)
 2. Molecular Orbital Theory (5L)
1. Comparing Atomic Orbitals and Molecular Orbitals.Linear combination
of atomic orbitals to give molecular orbitals (LCAO- MO approach for
diatomic homonuclear molecules).Wave mechanical treatment for
molecular orbitals (H2+ and H2).Molecular orbital Theory and Bond Order
and magnetic property: with reference to O2,O2+ O2-,O22- (Problems and
numerical problems expected wherever possible)

Reference Books:
1. Barrow, G.M. Physical Chemistry Tata McGraw‐Hill (2007).
2. Castellan, G.W. Physical Chemistry 4th Ed. Narosa (2004).
3. Kotz, J.C., Treichel, P.M. & Townsend, J.R. General Chemistry CengageLearning
India Pvt.Ltd., New Delhi (2009).
4. Mahan, B.H. University Chemistry 3rd Ed. Narosa (1998).
5. Petrucci, R.H. General Chemistry 5th Ed. Macmillan Publishing Co., NewYork (1985).
6. K.L.Kapoor A textbook of Physical Chemistry3rd Ed. vol.1,2Macmillan Publishing
Co., NewDelhi(2001)
7. Practical Inorganic Chemistry by G. Marr and B. W. Rockett van Nostrand
Reinhold Company (1972)
8. Inorganic Chemistry – Gary Wulfsberg, Viva Book, First Indian Edition 2002
9. Quantitative Analysis – R.A.Day, A.L. Underwood, sixth edition
10. Vogel’s Textbook of Quantitative Chemical Analysis – J Mendham, R C Denny,
J D Barnes, M Thomas, B Sivasankar
11. Bruce H. Mahan, University Chemistry, Narosa publishing house pg. 611 to 683.
12. R. Gopalan , Universities Press India Pvt.Ltd. Inorganic Chemistry for Undergraduates.
13. Chemistry of Transition Elements Pg.- 608 – 679 .
14. J. D. Lee, 4th Edn., Concise Inorganic Chemistry, ELBS, The group III elements
Pg. 359- 648.

Vertical 2-Analytical Chemistry(Minor) Code-CHE203

Unit – Treatment of analytical data and sampling (10 L)

1:
1. Sampling (05L)
 Definition and purpose of Sampling, Types of Sampling,
 Sampling of liquids: Homogeneous (Static), Heterogeneous (Static
immiscible) and flowing liquids.
2. Sampling of solids: Sample size, size reduction, Different sampling
equipment.
3. Treatment of Analytical Data (05L)
 Types of errors, Precision and Accuracy in Analysis, Corrections for
Determinate Errors
4. Concept of Confidence limits and confidence interval and its
computation using
 Population standard deviation, Student’s test, Range
Unit – Unit - Classical Methods of Analysis (10 L)
2:
1. Gravimetric analysis (05L)

General Introduction to Gravimetry. Types of Gravimetric Methods,

Precipitation Gravimetry, Steps involved in gravimetric analysis, Role of
Digestion, Filtration, Washing, Drying Ignition of precipitate.

2. Methods of separation: Solvent extraction (05 L)

Introduction, Nernst distribution Law, Distribution Ratio, Partition

Coefficient, Single-step and multi-step extraction, Percentage extraction for
single-step and Multistep extraction. Batch and continuous extraction

(Numericals are expected)

Modern Approach Chemical Industrial

Unit – 1. Basic Approach to Chemical Industry (10 L)
3: Introduction, basic requirements of chemical industries, chemical production,
raw materials, unit process and unit operations, Quality control, quality
assurance, process control, research and development, pollution control, human
resource, safety measures, classification of chemical reactions, batch and
continuous process, Conversion, selectivity and yield, copyright act, patent act,
trademarks
2. Fermentation Industry: (05)
Introduction, importance, the Basic requirement of the fermentation process,
Manufacture of industrial alcohol from molasses, fruits, food grains, & ethylene,
Manufacturing of wine, beer, whisky, and rum from molasses.
References: 1. Instrumental Methods of Chemical Analysis by Gurdeep R. Chatwal , Sham K.
Anandpp2.107-2.148.
2. Principles of Instrumental Analysis by Skoog, Holler, Nieman, 5 th Edition pp143-172.
3. Instrumental Methods of Analysis by Willard, Merritt, Dean, Settle 7th Edition pp118-181.
4. Instrumental Analysis by Douglas A. Skoog,F. James Holler, Stanley R.Crouch
5. Instrumental methods of analysis by Willard, H.H.; Merritt, L.L. Jr.; Dean, J.A.; Settle,7thEdition
6. Fundamental of Analytical Chemistry by Douglas A. Skoog, West, F. James Holler, S. R. Crouch
Modern Analytical Chemistry by David Harvey, McGraw-Hill Higher Education
7. Skoog et al. “Fundamentals of Analytical chemistry" Cengage Learning, Eight Edition, chapter
13, 14 and 15
8. Day and Underwood, “Quantitative analysis" prentice hall 1991, chapter3
9. S.M. Khopkar, “Basic Concepts of Analytical Chemistry”, II nd Edition NewAge International
Publisher
10. Gary D. Christan,” Analytical Chemistry”, VIth Edition, Wiley Students Edition, Chapter
No8,9,10
11. Fundamental of Analytical Chemistry by Douglas A. Skoog, West, F. James Holler, S. R.
Crouch
12. Modern Analytical Chemistry , David Harvey ( page numbers 232-265)
13. Handbook of Industrial Chemistry by Cory Simmons
14. Industrial Chemistry by Dr. Darshan V Chaudhary
15. Fundamentals of Industrial Chemistry by John A. Tyrell
 16. Industrial Inorganic Chemistry by Mark Anthony Benvenuto
17. Organic Chemistry Principles and Industrial Practice by Mark M. Green, Harold A.
Wittcoff
18. Industrial Chemistry by Mr Ravi S Tank

Practical Laboratory Course (CHEP201and CHEP202)

List of Experiments: 08 (Min. 06 to be completed)

Chemistry Practicals:

I- Physical Chemistry

1. To verify Ostwald’s dilution law for weak acid conductometrically.

2. To determine the dissociation constant of weak acid conductometrically.

3. To determine the critical solution temperature (CST) of phenol - WaterSystem.

4. Determination of energy of activation of acid-catalyzed hydrolysis of methyl acetate.

5. To investigate the reaction between K2S2O8 and KI with equal initial concentrations of the
reactants.

6. To determine the solubility of sparingly soluble salts (any two) conductometrically.

II-Inorganic Chemistry

1. Identification of cations in a given mixture and Analytically separating them [From a mixture
containing not more than two of the following: Pb(II), Ba(II), Ca(II), Sr (II), Cu(II), Cd(II), Mg(II),
Zn(II), Fe(II), Fe(III), Ni(II), Co(II) Al(III), Cr(III)]

2. Crystallisation of potassium iodate and to estimate its purity before and after the separation.

3. Estimation of total hardness

4. Investigation of the raction between Copper supfate and Sodium Hydroxide (Standard EDTA
solution to be provided to the learner).

III-Organic Chemistry

Purify the product by recrystallization. Report theoretical yield, percentage yield and melting point
of the purified product. Preparation of:

1. Cyclohexanone oxime from cyclohexanone.

2. Glucosazone from dextrose or fructose

3. Tribromoaniline from aniline.

4. β-Naphthylbenzoate

5. m-Dinitrobenzene from nitrobenzene

6. Phthalic anhydride from phthalic acid by sublimation

7. Acetanilide from aniline

8. p-Bromoacetanilide from acetanilide.

9. Iodoform from acetone (Any eight preparations)

A minimum 06 experiments for EACH course from the list should be completed in SEM – III and
to be reported in the journal. A certified journal is a must to be eligible to appear for the semester-
end practical examination. For practical examinations, the learner will be examined for ONE
experiment in each course. The scheme of examination for the revised course in Chemistry at the
Second Year B.Sc. Semester end examination will be as mentioned above. The duration of the
practical examination will be of 2 hrs for each course.

The questions on slips for the same should be framed in such a way that candidate will be able to
complete the task and should be evaluated for its skill and understanding of the subject.

Reference Books for Practicals:

Unit I: 1. Khosla B.D., Garg V.C. and Gulati A., Senior Practical Physical Chemistry, R. Chand and
Co., New Delhi (2011).

2. Garland C. W., Nibler J.W. and Shoemaker D.P., Experiments in Physical Chemistry, 8th Ed.,
McGraw-Hill, New York (2003).

3. Halpern A.M. and McBane G.C., Experimental Physical Chemistry, 3rd Ed., W.H. Freeman and
Co., New York (2003).

4. Athawale V.D. and Mathur P., Experimental Physical Chemistry, New Age International, New
Delhi (2001)

Unit II: 1. Practical Inorganic Chemistry by G. Marr and B. W. Rockett van Nostrand Reinhold
Company (1972)

Unit III: 1. Mann, F.G. & Saunders, B.C. Practical Organic Chemistry, Pearson Education (2009)

2. Ahluwalia, V.K. & Aggarwal, R. Comprehensive Practical Organic Chemistry: Preparation and
Quantitative Analysis, University Press (2000). Mann, F.G. & Saunders, B.C. Practical Organic
Chemistry, Pearson Education (2009)

3. Furniss, B.S.; Hannaford, A.J.; Smith, P.W.G.; Tatchell, A.R. Practical Organic th Chemistry, 5
Ed., Pearson (2012)

4. Vogel, A.I., Tatchell, A.R., Furnis, B.S., Hannaford, A.J. & Smith, P.W.G., Textbook of Practical
Organic Chemistry, Prentice-Hall, 5th edition, 1996
 CHEP203 Practical in Basics in Analytical Chemistry

1. Tools of Analytical Chemistry-I:

a) Analytical glass wares like burettes, pipettes, Standard flasks, Separating funnels.

b) Weighing tools such as two pan balance and mono pan balance, digital balances:

c) Incineration devices: Burners, Electrical Incinerators, Muffle Furnace,

d) Drying Devices: Hot Air Oven, microwave oven, Desiccators, Vacuum desiccators

e) Monochromators, Filters, Sample holders, Prisms, Diffraction Gratings, Photoemissive cells,

Photomultiplier tubes (The learner should draw diagrams and write-ups providing uses, care and
maintenance of the items mentioned in (a)and principle, construction and uses of items(b)to (e)in his
journal.

2. Gravimetric estimation of Nickel (II) as Ni-DMG and calculation of % error.(The learner is

expected to know the role of the various reagents/chemicals used in the estimation, the various steps
involved. They should write the complete and Balanced chemical reaction for the formation of the
Ni(DMG)2 complex.

3. Colorimetric Determination of Copper Ions in a given Solution by using calibration curve method
and calculation of % error. (The learner is expected to learn the relation between concentration and
Absorbance, to draw a calibration curve, use the slope of the calibration curve and compare it with
the calculated slope. They are also expected to state the error estimate of their results).

4. Determination of buffer capacity of acid buffer and basic buffer. (The learner is expected to learn
the use pH meter, standardization of pH meter, use of Henderson’s equation and calculation of buffer
capacity)

5. Estimation of Aspirin

6. Gravimetric estimation of barium ions using K2CrO4 as precipitant. Calculation of % error. (The
learner is expected to learn the skills of using the counterpoise technique used in this gravimetric
estimation; Using counterpoise method whatman No.42 for filtration. In such a case no incineration
or use of silica crucible is required. They are also expected to state the error estimate of their results)

Vertical 3- OPEN ELECTIVE (OE) -Course - 4

Course Code: CHE204: (30 Hrs Practicals, Total Credits = 02 credits)

Learning Outcome:

After successful completion of the course, students will be able to:

● The adulteration of common foods and their adverse impact on health
● Comprehend certain basic skills of detecting adulteration in common foods.
● Extend their knowledge of detecting other kinds of adulteration.
 CO-PO-PSO Mapping
Semester-III

Open Elective Course: Fundamentals of Food Adulteration

After successful completion of course in cosmetic chemistry a learner should be able to:
CO-1 To understand chemistry behind food adulteration. [2] *
CO-2 To evaluate the amount of adulteration in given beverage product. [4]
CO-3 To describe various methods to detect adulteration. [2]
CO-4 To understand the health hazards of different adulterant materials in food materials [2]

ICT Tools: Videos, PPT, Smart Board

Students Centric Methods: Experimental, Participative, Problem Solving
The CO-PO Mapping Matrix
CO\ PO PO1 PO2 PO3 PO4 PO5 PO6 PO7 P O8 PO9 PO10 PO11 PO12 PSO1 PSO2 PSO3 PSO4
CO-1 2 - - 2 2 - - - - - - - 2 2 - -
CO-2 2 1 2 - - - - - - - - - - 2 - -
CO-3 1 2 - - - - - - - - - - - 2 1
CO-4 1 - - - 2 - - - - - - - 1 - - -
*Note: [1]: Remembering, [2]: Understanding, [3]: Applying, [4]: Analyzing, [5]: Evaluating,
[6]: Creating

Fundamentals of Food Adulteration

Food Adulteration Practices Laboratory Practicals (2credits)

Adulteration-Definition; types-Intentional, incidental, metallic, and packaging hazard. Causes

and methods of food adulteration. General Impact on Human Health. Detection and Prevention
of Food Adulteration. Mitigation measures for addressing food adulteration.
Food additives- Definition, classification, role of additives in processed foods. Safe levels of
additive uses and the institutions involved in the process.
Explanation to be followed by practicals
Adulteration of Common Foods and Methods of their Detection

1. Composition and adulterant detection in the following Foods- Milk, Edible Oil, Sugar,
Spices, honey, flours, Ghee Beverages- Alcoholic and Non-Alcoholic. (one method of
detection for each food item).
2. To detect the adulterants like paraffin wax/hydrocarbons, dyes and argemone in the fats,
oils and ghee.
3. To detect the presence of adulterants like water, proteins, urea, formalin, detergent, sugar
 and starch in the milk.
4. To detect the adulteration of insoluble substance, chalk powder and washing soda in
sugar.
5. To detect the adulteration of red lead salts/brick powder in chili powder, yellow lead
salts/ colored saw dust in turmeric and dried papaya seeds in pepper.
6. To detect sugar as an adulterant in honey.

Reference books:
1. A first course in Food Analysis, A.Y. Sathe, New Age International (P) Ltd., 1999.
2. Food Safety, case studies – R. V. Bhat, NIN, 1992.
3. DART- Detect adulteration with rapid test. FASSAI, Imprinting Trust, assuring safe and
nutritious food, Ministry of Health and Family Welfare, Government of India.
4. Rapid detection of food adulterants and contaminants Theory and Practice, S. N. Jh, 2016,
Kindle Edition.
5. Domestic Tests for Food Adulterations, H. G. Christian, Forgotten books.
6. A Laboratory Manual of Food Analysis, S. Sehgal, Wiley Publishers.

Food Safety and Standards Act, 2006. Bare ACT, November 2020, Commercial law publishers

Vertical -4-Vocational Skill Course (VSC) -course 5:

Course Code: CHE205: (60 Hrs Practicals, Total Credits = 02 credits)

Course Name :Forensic Chemistry

Course Outcomes (COs): After completing this course, the students should be able to …
“Forensic Chemistry"

Course Outcomes:
1. To understand the basic principles and applications of forensic chemistry
2. To learn various analytical techniques used in forensic chemistry
3. To acquire practical skills in handling and analyzing forensic samples
4. To develop critical thinking and problem-solving abilities in forensic chemistry
5. To appreciate the ethical and legal aspects of forensic chemistry
 Syllabus-Theory & Practical
Name of the Course: Value Added Certificate course in Applied Forensic Chemistry

Theory

Unit I : Forensic Toxicology (10 lectures)

1.1 Introduction and Concept Of Forensic Toxicological Examination And Its Significance.
1.2 Forensic Pharmacology and Forensic Toxicology, Drugs and Poisons, Pharmacokinetics,
Absorption, Distribution, Metabolism and Elimination.
1.3 Pharmacodynamics, Identification of drugs in the body, Immunoassay techniques
1.4 Forensic Toxicology of Ethyl Alcohol, Pharmacokinetics of Ethanol, Analysis of Alcohol in
Breath

Unit II: Fires and Explosives (10 lectures)

2.1 Introduction to Fire and Explosives and Case Study

2.2 Conditions for a fire, Types of fires, analysis of fire scene residue evidence
23 Analysis of Fire Scene Accelerant Residues by Gas Chromatography, Interpretation and
Association of Fire Scene Evidence.
2.4 Effects of Explosives, Types of Explosives, High and Low order Explosives, Explosive Trains,
Analysis of Explosives.
Unit-II: Project /field visit/Practical (10 Lecture)

Reference
1. Introduction to Forensic Science in Crime Investigation By Dr.(Mrs.) Rukmani Krishnamurthy
2. Henry Lee’s Crime Scene Handbook by Henry C Lee
3. Forensic Biology by Shrikant H. Lade
4. Crime Scene Processing and Laboratory Work Book by Patric Jones
5. Forensic Science: An Introduction to Scientific and Investigative Techniques 3rd ed. by
Stuart H. James
6. Fundamentals of Forensic Science by Max M. Houck, Jay A. Siegel

Vertical :5-– (IKS) INDIAN KNOWLEDGE SYSTEM (IKS) -Course 6:

Course Code: CHE206: (30 Lectures Theory, Total Credits = 02 credits)

Course Outcomes (COs): After completing this course, the students should be able to …
CO - 1: The core ideas behind Indian Knowledge Systems.

CO - 2: To think critically and compare old Indian science with modern science,
understanding how different kinds of knowledge connect.
CO - 3: To know how ancient India approached environmental care.

CO - 4: To understand how ancient Indian knowledge can enhance modern science,

especially in Chemistry.
IKS Induction Program Module for Chemistry and Metallurgy (2 credits)
Unit 1: ( 15L)
Introduction to IKS in general; introduction to a few terms along with the IAST transliteration
scheme with diacritic marks.( IAST- International Alphabet of Sanskrit Transliteration)
Outline of the contributions of ancient and medieval Indians in the area of chemistry and metallurgy
as gleaned from archaeological artifacts, temple icons and other such tangible objects like the Delhi
Iron Pillar that have survived the test of time.
Specific use, processing, and finishing of 6 metals since the Vedic times and how the knowledge
constantly evolved to incorporate other metals like mercury and zinc at later periods
Unit 2: (15L)
Chemistry of dyes, pigments, and other coloring materials used in paintings, fabrics, beads, and other
day-to-day utilities since ancient times and their constant evolution through different periods.
Chemistry in Ayurvedic texts as well as in Ayurveda practice. A few case studies on the preparation,
quality control, and delivery of herbs-mineral drug formulations. Introduction to select original texts
about chemistry and metallurgy like the Rasāṛṇava and Rasaratnasamuccaya; dwelling on the style
of writing a technical subject as well as on the content that are in vogue in contemporary chemistry.

References Text Books:

1. R.M. Pujari, Pradeep Kolhe, N. R. Kumar, ‘Pride of India: A Glimpse into India's Scientific
Heritage’, Samskrita Bharati Publication.
2. ‘Indian Contribution to science’, compiled by Vijnana Bharati.
3. ‘Knowledge traditions and practices of India’, Kapil Kapoor, Michel Danino, CBSE, India.
Reference Books:
1. Dr. Subhash Kak , Computation in Ancient India,Mount, Meru Publishing (2016)
2. Dharampal, Indian Science and Technology in the Eighteenth Century, Academy of Gandhian
Studies, Hyderabad, 1971, republ. Other India Bookstore, Goa, 2000
3. Robert Kanigel, The Man Who Knew Infinity: A Life of the Genius Ramanujan, Abacus, London,
1999
4. Alok Kumar, Sciences of the Ancient Hindus: Unlocking Nature in the Pursuit of Salvation,
CreateSpace Independent Publishing, 2014
5. B.V. Subbarayappa, Science in India: A Historical Perspective, Rupa, New Delhi, 2013
6. S. Balachandra Rao, Indian Mathematics and Astronomy: Some Landmarks, Jnana Deep
Publications, Bangalore, 3rd edn, 2004
7. S. Balachandra Rao, Vedic Mathematics and Science In Vedas, Navakarnataka Publications,
Bengaluru, 2019
8. Bibhutibhushan Datta, Ancient Hindu Geometry: The Science of the Śulba, 1932, repr. Cosmo
Publications, New Delhi, 1993
9. Bibhutibhushan Datta & Avadhesh Narayan Singh, History of Hindu Mathematics, 1935, repr.
Bharatiya Kala Prakashan, Delhi, 2004
. George Gheverghese Joseph, The Crest of the Peacock, Penguin Books, London & New Delhi,
2000
11. J. McKim Malville & Lalit M. Gujral, Ancient Cities, Sacred Skies: Cosmic Geometries and
City Planning in Ancient India, IGNCA & Aryan Books International, New Delhi, 2000).
12. Clemency Montelle, Chasing Shadows: Mathematics, Astronomy and the Early History of
Eclipse Reckoning, Johns Hopkins University Press, 2011
13. Anisha Shekhar Mukherji, Jantar Mantar: Maharaja Sawai Jai Singh’s Observatory in Delhi,
AMBI Knowledge Resources, New Delhi, 2010
14. Thanu Padmanabhan, (ed.), Astronomy in India: A Historical Perspective, Indian National
Science Academy, New Delhi & Springer (India), 2010
15. Acharya Prafulla Chandra Ray, A History of Hindu Chemistry, 1902, republ., Shaibya Prakashan
Bibhag, centenary edition, Kolkata, 2002
16. R. Balasubramaniam, Delhi Iron Pillar: New Insights, Indian Institute of Advance Study, Shimla
& Aryan Books International, New Delhi, 2002
17. R. Balasubramaniam, Marvels of Indian Iron through the Ages, Rupa & Infinity Foundation,
New Delhi, 2008 11 Guidelines for Training/ Orientation of Faculty on IKS
18. Anil Agarwal & Sunita Narain, (eds), Dying Wisdom: Rise, Fall and Potential of India’s
Traditional Water-Harvesting Systems, Centre for Science and Environment, New Delhi, 1997
19. Fredrick W. Bunce: The Iconography of Water: Well and Tank Forms of the Indian
Subcontinent, DK Printworld, New Delhi, 2013 12

Vertical :6- (FP) FIELD PROJECTS (FP) – Course -7:

Course Code: CHE207: (120 Hrs, Total Credits = 04 credits)

SEMESTER - IV

Vertical Course Code Title of the Courses Credits

Vertical 1 CHE251 Physical and Inorganic Chemistry 3P+1P = 04

Major

CHE252 Organic and Inorganic Chemistry 3T+1P = 04

Vertical 2 CHE253 Analytical Chemistry 3T+1P = 04

 Minor

Vertical:1- Major Course -1-Physical and Inorganic Chemistry

Course code :CHE251 (Credits-3T+1P) (45 Lectures Theory + 30 Hrs Practicals, Total
Credits = 04
1.1.Electrochemistry-II: (5L)
Unit – 1: Electrochemical conventions, Reversible and irreversible cells. (10 L)
Nernst equation and its importance, Types of electrodes, Standard
electrode potential, Electrochemical series (Numericals expected).
Thermodynamics of a reversible cell, calculation of thermodynamic
properties: ΔG, ΔH and ΔS from EMF data. (Numericals expected)
1.2 Phase Equilibria: (5L)
Phases, components and degrees of freedom of a system, criteria of
phase equilibrium. Gibbs Phase Rule and its thermodynamic
derivation. Phase diagrams of one-component systems (water and
sulphur).Two-component systems involving eutectics, congruent
and incongruent melting points (lead-silver system). Three-
component System –Introduction with diagrammatic
representation.
Solid-State Chemistry and Catalysis
Unit – 2: 2.1 Solid State Chemistry: (5 L) (10 L)
Recapitulation of laws of crystallography and types of
crystals, Characteristics of simple cubic, face-centered cubic and
body-centered cubic systems, interplanar distance in the cubic
lattice (only expression for the ratio of interplanar distances are
expected. Use of X-rays in the study of crystal structure, Bragg’s
equation (derivation expected), X-rays diffraction method of
studying crystal lattice structure, structure of NaCl and KCl.
Determination of Avogadro’s number (Numericals expected)
2.2 Catalysis: (5 L)
Types of catalysis, catalytic activity, specificity and selectivity,
inhibitors, catalyst poisoning and deactivation.Mechanisms and
kinetics of acid-base catalyzed reactions, effect of pH. Mechanisms
and kinetics of enzyme-catalyzed reactions (Michaelis-Menten
equation).Effect of particle size and efficiency of nanoparticles as
catalyst.
Comparative Chemistry of the Transition Metals and
Unit – 3: Coordination Chemistry (5L (10 L)
Comparative Chemistry of the transition metals
Origin of color for transition metals and their compounds: such as
reflectivity, surface coatings, particle size, packing density for
metals and nature of d-orbitals, number of electrons in the d-
orbitals, geometry, and ability for charge transfer).Magnetic
properties of transition metal compounds: Origin of magnetism-
spin and orbital motion of electrons; equation for spin only and
 spin-orbital magnetism in terms of Bohr magnetons (No derivation
of relevant equations expected) Reasons for quenching of orbital
moments.
2. Coordination Chemistry : (5 L)
Introduction to Chemistry of Coordination Compounds
1. Historical perspectives: Early ideas on coordination compounds
Basic terms and nomenclature.Types of ligands,4. Isomerism:
Types of Structural Isomerism. Evidence for the formation of
coordination compounds.
2.Theories of coordination compounds: Werner’s Theory of
coordination compounds, Effective atomic number rule. Nature of
the Metal-Ligand Bond:Valence Bond Theory; Hybridization of the
central metal orbitals- sd3/d3s sp3d2/d2sp3, sp2d.Inner and outer
orbital complexes of (suitable examples of Mn(II) Fe(II), Fe(III),
Co(II)/Co(III), Ni(II), Cu(II) Zn(II) complexes with ligands like
aqua, ammonia CN- and halides may be used)
 Limitations of V.B.T

Major Course ‐ 2: Organic and Inorganic Chemistry

Course Code: CHE252: (45 Lectures Theory + 30 Hrs Practicals, Total Credits = 04)

1.1 Carboxylic Acids and their Derivatives: ( 10 L)

Unit – 1: (10 L)
Nomenclature, structure and physical properties, acidity of
carboxylic acids, effects of substituents on acid strength of aliphatic
and aromatic carboxylic acids. Preparation of carboxylic acids:
oxidation of alcohols and alkyl benzene, carbonation of Grignard
and hydrolysis of nitriles. Reactions: Acidity, salt formation,
decarboxylation, Reduction of carboxylic acids
with LiAlH4, diborane, Hell- Volhard-Zelinsky reaction,
Conversion of carboxylic acid to acid chlorides, esters, amides and
acid anhydrides and their relative reactivity. Mechanism of
nucleophilic acyl substitution and acid-catalyzed nucleophilic
acyl substitution. Interconversion of acid derivatives by
nucleophilic acyl substitution.. Mechanism of Claisen condensation
and Dieckmann condensation.

Unit – 2: Unit II: Amines, dizonium salts :Nitrogen containing compounds (10 L)

2.1 Amines: (5 L)

 Nomenclature, the effect of substituent on the basicity of

aliphatic and aromatic amines; Preparation: Reduction of
aromatic nitro compounds using catalytic hydrogenation,
chemical reduction using Fe-HCI, Sn-HCl, Zn-acetic acid,
reduction of nitriles, ammonolysis of halides, reductive
amination, Hofmann bromamide reaction.
  Reactions- Salt Formation, N-acylation, N-alkylation,
Hofmann’s exhaustive methylation (HEM), Hofmann-
elimination reaction, reaction with nitrous acid, carbylamine
reaction, Electrophilic substitution in aromatic amines:
bromination, nitration and sulphonation.

2.2.Diazonium Salts: (5 L)

 Preparation and their reactions/synthetic application -

Sandmeyer reaction, Gattermann reaction, Gomberg reaction,
Replacement of diazo group by -H,-OH. Azo coupling with
phenols, naphthols and aromatic amines, reduction of
diazonium salt to aryl hydrazine and hydroazobenzene.

1. Ions in aqueous medium (08 L)

Unit – 3: (10 L)
Acidity of Cations and Basicity of Anions
 Hydration of Cations; Hydrolysis of Cations predicting
degree of hydrolysis of Cations-effect of Charge and Radius.
 Latimer Equation. Relationship between pKa, acidity and
z2/r ratios of metal ions graphical Presentation
 Classification of cations on the basis of acidity category –
Non acidic, Moderately acidic, strongly acidic, very strongly
acidic with pKa values range and examples
 Hydration of Anions; Effect of Charge and Radius;
Hydration of anions-concept, diagram classification
on the basis of basicity

2. Uses and Environmental Chemistry of volatile Oxides and

oxo-acids (02 L)
 Physical properties of concentrated oxo-acids like sulfuric,
Nitric and Phosphoric acid
 Uses and environments aspects of these acids

Reference Books:
1. Morrison, R. T. and Boyd, R. N. Organic Chemistry, Dorling Kindersley (India) Pvt. Ltd.
2. (Pearson Education).2012
3. Finar, I. L. Organic Chemistry (Volume 1), Dorling Kindersley (India) Pvt. Ltd. (Pearson
4. Education).
5. Finar, I. L. Organic Chemistry (Volume 2: Stereochemistry and the Chemistry of Natural
6. Products), Dorling Kindersley (India) Pvt. Ltd. (Pearson Education)
7. Mc Murry, J.E. Fundamentals of Organic Chemistry, 7 th Ed. Cengage Learning India
8. Edition, 2013.
9. Clayden, J.; Greeves, N.; Warren, S.; Wothers, P.; Organic Chemistry, Oxford University
10. Press.
11. Graham Solomons, T.W. Organic Chemistry, John Wiley & Sons, Inc.
12. Comprehensive Organic Chemistry- The synthesis and reactions of Organic Compounds,
13. Derek barton ,W. David Ollis.
 14. Kalsi, P. S. Textbook of Organic Chemistry 1 st Ed., New Age International (P) Ltd. Pub.
15. Eliel, E. L. and Wilen, S. H. Stereochemistry of Organic Compounds, Wiley: London,
16. 1994.
17. Kalsi, P. S. Stereochemistry Conformation and Mechanism, New Age International, 2005

Vertical:2- Minor- Course -3 Course name- Analytical Chemistry

Course code-CHE253 -(Credits-3T+1P)

(45 Lectures Theory + 30 Hrs Practicals, Total Credits = 04

Basic Concepts in Instrumental methods

Unit – 1.1. Optical methods. (10 L)
1:
 Statement of Beer’s Law and Lambert’s Law,
Combined Mathematical Expression of Beer -Lambert’s
Law, Deviations from Beer-Lambert’s Law (Real deviations,
Instrumental deviations and Chemical deviations) (Numerical
problems based on Beer-Lambert’s Law)Block Diagrams for Single
beam Colorimeter, and Spectrophotometer (Construction and
working-Details of Components expected)
1.2. Potentiometry:
 Principle.:Role of Reference and indicator electrodes
1.3. pH metry:
Principle, Construction Working of Combined Glass electrode
1.4 Conductometry:
Principle, Conductivity cell and its construction, Applications in
Neutralization Titrimetry with respect to Strong Acid-Strong
Base,Strong Acid-Weak Base,Strong Base-weak Acid

Miscellaneous methods and environmental (05)

Unit – 2.1 Thermal methods (10 L)
2:  Introduction, Different thermal events, and classification based on
different interactions. Principle, instrumentation and applications of
 Thermogravimetric Analysis (TGA) Differential Thermal Analysis
(DTA)
2.2 Environmental analysis (05)
(Basic relations and formulae are expected)
 Soil analysis, important parameters of soil testing namely,
i) Cation exchange capacity (CEC), ii) Organic matter, iii) SAR
(Sodium Absorption Ratio), iv) Soil pH v) EC (Electrical
Conductivity)
 Water analysis,
i) pH ii) Total Dissolved Solids (TDS) iii) Hardness iv) Biological
Oxygen Demand (BOD) v) Chemical Oxygen Demand (COD) vi)
E. Coli (Escherichia coli)
 Industrial Chemistry (10 L)
Unit – 1. Operation -Distillation (05L) (10 L)
3:  Introduction ,Fractional distillation ,Azeotropic distillation
Vaccum distillation,Extractive distillation
2. Petrochemicals and eco-friendly fuels (05L)
 Introduction, occurrence, composition of petroleum, resources,
processing of petroleum, calorific value of fuel, cracking, octane
rating (octane number), cetane number, flash point, and
petroleum refineries, applications of petrochemicals, synthetic
petroleum, lubricating oils & additives.Fuels and eco-friendly
fuels: liquid, gaseous fuel (LPG, CNG), fossil fuels, diesel,Bio-
diesel, gasoline, aviation fuels. Use of solar energy for power
generation.

References
1. Instrumental Methods of Chemical Analysis by Gurdeep R. Chatwal , Sham K. Anandpp2.107-
2.148.
2. Principles of Instrumental Analysis by Skoog, Holler, Nieman, 5 th Edition pp143-172.
3. Instrumental Methods of Analysis by Willard, Merritt, Dean, Settle 7th Edition pp118-181.
4. Instrumental Analysis by Douglas A. Skoog,F. James Holler, Stanley R.Crouch
5. Instrumental methods of analysis by Willard, H.H.; Merritt, L.L. Jr.; Dean, J.A.; Settle,7thEdition
6. Fundamental of Analytical Chemistry by Douglas A. Skoog, West, F. James Holler, S. R.
Crouch.
7.Modern Analytical Chemistry by David Harvey, McGraw-Hill Higher Education
8.Skoog et al. “Fundamentals of Analytical chemistry" Cengage Learning, Eight Edition,
9;Day and Underwood, “Quantitative analysis" prentice hall 1991, chapter3
10. S.M. Khopkar, “Basic Concepts of Analytical Chemistry”, II nd Edition NewAge International
Publisher
11. Gary D. Christan,” Analytical Chemistry”, VIth Edition, Wiley Students Edition, Chapter
No8,9,10
12. Fundamental of Analytical Chemistry by Douglas A. Skoog, West, F. James Holler, S. R.
Crouch
13. Modern Analytical Chemistry , David Harvey ( page numbers 232-265)
14. Handbook of Industrial Chemistry by Cory Simmons
15. Industrial Chemistry by Dr. Darshan V Chaudhary
16. Fundamentals of Industrial Chemistry by John A. Tyrell
17. Industrial Inorganic Chemistry by Mark Anthony Benvenuto
18. Organic Chemistry Principles and Industrial Practice by Mark M. Green, Harold A. Wittcoff
19. Industrial Chemistry by Mr Ravi S Tank

Practical Laboratory Course

(Major- CHEP251and CHEP252)

I-Physical Chemistry
1. To determine standard EMF and the standard free energy change of Daniel cell
potentiometrically.

2. To determine the amount of HCl in the given sample potentiometrically.

3. Compare the strengths of HCl and H2SO4 by studying kinetics of acid hydrolysis of methyl
acetate.

6. Industrial visit report.

II- Inorganic Chemistry

1. Inorganic preparation – Nickel dimethyl glyoxime using microscale method.

2. Complex cation – Tris (ethylene diamine) nickel (II) thiosulphate.

3. Complex anion – Sodium Hexanitrocobaltate (III) The aim of this experiment is to understand
the preparation of a soluble cation (sodium)and a large anion hexanitrocobaltate (III) and its use to
precipitate a large cation (potassium)

4. Inorganic salt – Calcium or magnesium oxalate using PFHS technique

III -Organic Chemistry

Qualitative Analysis of bi-functional organic compounds on the basis of

1. Prelimenary examination

2. Solubility profile

3. Detection of elements C, H, (O), N, S, X.

4. Detection of functional groups

5. Determination of physical constants (M.P/B.P) Solid or liquid Compounds containing not more
than two functional groups from among the following classes may be given for analysis to be
given: Carboxylic acids, phenol, carbohydrates, aldehydes, ketones, ester, amides, nitro, anilides,
amines, alkyl and aryl halides. Students are expected to write balanced chemical reactions
wherever necessary. (Minimum 6 compounds to be analyzed)

A minimum 06 experiments for EACH course from the list should be completed in SEM – III and
to be reported in the journal. A certified journal is a must to be eligible to appear for the semester-
end practical examination.

For practical examinations, the learner will be examined for ONE experiment in each course. The
scheme of examination for the revised course in Chemistry at the Second Year B.Sc. Semester end
examination will be as mentioned above. The duration of the practical examination will be of 2 hrs
for each course.

The questions on slips for the same should be framed in such a way that candidate will be able to
complete the task and should be evaluated for its skill and understanding of the subject.
Practical for Minor course (Basics in Analytical Chemistry)

1. Demostration to Tools of Analytical Chemistry

a. Filtration Flasks, Funnels, Separating Funnels, Distillation apparatus, Vacuum Distillation

assembly, Centrifuge machine, Electrophoresis apparatus.

b. Development chamber for chromatography

c. Electrodes like Reference Electrodes and Indicator Electrodes (with respect to care and
maintenance.)

d. Conductivity cell (with respect to care and maintenance.)

e. Combined Glass electrode (with respect to care and maintenance.)

f. Types of Salt Bridges and preparation of anyone or use of a salt bridge, its effect on the
potential of a given electrode/cell (The learner should draw diagrams and write-ups providing uses
of the items mentioned in (a and b) and Principle, Construction care and Uses of items (c) to (f) in
his journal.)

2. Paper chromatography: Separation of cations like Fe (III), Ni (II) and Cu (II) in a sample. 3.
Separation of a solute between two immiscible solvents to determine the distribution ratio and/or
extraction efficiency. (Solutes could be as their aqueous solutions and the organic solvent ethyl
acetate) Suggested solute for the distribution study: Fe (III) in aqueous solutions. (The learner is
expected to learn the technique of solvent extraction by using a separating funnel, method to
estimate the concentrations of the solute distributed in the two immiscible phases, determination of
the extraction efficiency)

4. Estimation of concentration of Iron from a given sample calorimetrically by using 1,10

phenanthroline.(The learner is expected to learn the handling of the colorimeter).

5. Estimation of Fe (II) in the given solution by titrating against K2Cr2O7 potentiometrically and
calculation of % error. (The learner is expected to learn the handling of the potentiometer, use of
Platinum electrode and reference electrode like SCE. They will learn to determine endpoint by
plotting a graph. They are also expected to state the error estimate of their results).

6. Gravimetric estimation of Sulfate as BaSO4 and calculation of % error. (The learner is expected
to write a balanced chemical reaction, need for digestion of the precipitate and the skill required to
carry out the incineration and to estimate the% error.) (The learner is expected to write a balanced
chemical reaction, need for digestion of the precipitate and the skill required to carry out the
incineration and to estimate the % error.)

REFERENCES:

1. D.A. Skoog, D.M. West, F.J. Holler, and S.R. Crouch, Analytical Chemistry: An
Introduction,7th ed., Chapter 15, pp. 345-381.

2. A.I. Vogel.“Text book of Quantitative Inorganic Analysis”, Longman, London (1961).

3. R.V. Dilts.“Analytical Chemistry. Methods of Separation”, van Nostrand, N.Y.(1974).

4. Some Experiments for B. Tech in Chemistry & Chemical Technology compiled by Prof. J.B.
BARUAH, Mrs. Abhilasha Mohan Baruah and Mr. Parikshit Gogoi

Vertical :3- OPEN ELECTIVE (OE)

Course - 4: Course Name -Chemistry in Agrochemicals

Course Code: CHE254: (30 Hrs Practicals, Total Credits = 02 credits)

Course Outcomes (COs): After completing this course, the students should be able to …

Objective: Conventional insecticides are synthetic chemicals used for quick killing and effective
control of insect populations. Biopesticides tend to be highly targeted to specific pests while
conventional insecticides allow farmers to control numerous pests with one agrochemical only.

Course Learning Outcomes: Students will be able to learn about the various types of synthetic
pesticides available in the market and their selective mode of action on insect populations They can
promote the future use of insecticides as metabolic inhibitors in insect physiological research. As a
result both the pesticides and the plant sciences get a boost

Theory (1 credit- 15L)

1.1.General introduction and scope, meaning, and examples of insecticides, herbicides,
fungicides, rodenticides, pesticides, and plant growth regulators.
1.2. Advantages and disadvantages of agrochemicals
1.3. Synthesis and applications of IAA(Indole Acetic acid) and Endosulphan.
1.4. Biopesticides-Neem oil and Karanj Oil
1.5. Organochlorine Insecticides: Synthesis, nomenclature, structure activity relationship
(SAR), mode of action, benefits and adverse effects of the following Organochlorines:
DDT, Gammaxene, Chloridane, Hptachlor, Aldrin and Endosulfan.

Practical: (1 credit)
1. To carry out a market survey of potent pesticides (five or more) with details as follows:
a) Name of pesticide
b) Chemical name, class and structure of pesticides
c) Type of formulation available and Manufacturer’s name
d) Useful information on the label of packaging regarding Toxicity, LD50 (“Lethal Dose, 50%”),
Side effects and Antidotes.
2. Preparation of simple Organochlorine pesticides.
3. To calculate acidity/alkalinity in a given sample of pesticide formulation as per BIS
specifications.
 5. Data collection : Agrochemicals and their impact on human health:
References:
1. Insecticides in Agriculture and Environment, Perry, A.S., Yamamoto, I., Shaaya, I., Perry,
R., Narora Publishing House.
2. Carbamate Insecticides, Chemistry, Biochemistry and Toxicology, Kuhr, R.J., Derough,
H.W., CRC Press.
3. Insecticide, Action and Metabolism, O’Brien, R.D., Academic Press, New York and
London.
4. Chemical Pesticides: Mode of Action and Toxicology, Stenersen, J., CRC, 2004. Practical:
5. Agrochemicals preparation and mode of action, Cremlyn, R.J.W
6. https://www.mcgill.ca/pfss/files/pfss/agrochemicals_and_their_impact_on_human_health.pdf

Vertical:4-VSC- Course Name: Chemistry of Perfumes:

Vocational Skill Course (VSC) - 5:

Course Code: CHE255: (60 Hrs Practicals, Total Credits = 02 credits)

Course Outcomes (COs): After completing this course, the students should be able to

Perfumes are a mixture of fragrant essential oils or aroma compounds (fragrances), fixatives and
solvents, usually in liquid form, used to give the human body, animals, food, objects, and living
spaces a pleasant scent.

Perfumes are essentially a blend of complementary ingredients and essential oils. Therefore,
perfumes are complex combinations of natural and/or man-made substances that are added to
many consumer products to give them a distinctive smell. The salient feature of this program is the
emphasis being laid on the overall development of student with a major focus on application and
filed work.

Perfume Chemistry, Learning of analytical techniques used in cosmetic and perfume industries etc.
Students will get many opportunities interactions with experts in these fields during the course
tenure. The students can gain hands-on experience in the field while doing internships in
industries/research institutes/health sectors etc. Course Objectives: To provide the learner with
knowledge of cosmetics and perfumes with respect to the types of formulations, evaluation and
regulatory aspects.

Course Outcome: Upon completion of the course, the learner shall be able to:

1. Discuss the various raw materials for cosmetics and perfumes.

2. Understand the toxicological aspects.

3. Discuss the various cosmetics products w.r.t. raw materials, large scale manufacture. and
functional and physiochemical evaluation.

4. Know the regulatory guidelines and sensorial assessment for cosmetics

Unit I

Content Introduction, history, classifications and sources of cosmetics and perfumes Surfactants and
their types; Additives (thickeners, foam stabilizers, pearlescent agents, conditioning agents, etc.) Oil
componcnts; Waxes, Silhcone Chemistry oils; Cream bases; Emulsifiers; Humectants; Acrosol
Propcllants. and production of essential oils with special reference to the following, Eugenol,
Geraniol, Sandalwood oil, cucalyptus oil, rosce oil, Jasmone, Civet one, Muscone.

Psychological benefits, fragrance and mood, aromatic substances, types of aromatic substances,
chemical constituents of aromatic substances, odours of substances from vegetable, animal and
artificial origin

Suggested Continuous Evaluation Methods: Students can be evaluated on the basis of score obtained
in a mid-term exam, together with the performance of other activities which can inchude short
exams, in-class or online tests, home assignments, group discussions or oral presentations.

Unit II

Essential Oils fixatives - Sandal wood, lemon, cinnamon, patchouli oil, Phenyl acetaldehyde,
vanillin. d. Synthetics fixatives Diethyl phthalate Benzyl- Benzoate, alcohols Acetophenone, musk-
ketone, musk- Ambrette, Heliotropin, hydroxy citronellal, indole

Suggested Readings:

1. Earnest Guenther, "The Essential Oils" vol. I Robert E. Kreiger Publishing Co. Huntington,
New York, 1972.

2. M.S. Balsem, S.D. Genshon, M.M. Rieger, E. Sagarin, S.J. Strianase, "Cosmetics, Science and
Technology, Vol. I, II and II, Wiley-Interscience, A Division of John Wiley and Sons., Inc., New
York, London, Sydney, Toronto, 1972, Ed. By M.S. Balsam and M.S. Sagarin.

3. Paul Z. Bedoukian, "Perfumery and Flavouring Synthetics" II Edn, Elsevier Publishing Co.,
Amsterdam, London, New York, 1967.

4. J. Stephan Jellinick," Formulation and Functions of Cosmetics", Wiley Interscience, a Division

of John Wiley & Sons., Inc.
5. Mareel IBillot, F.V. Wells," Perfumery Technology" Ellis Harwood Ltd., Halrted Press, a
Division of John Wiley & Sons., Inc. New York, London. 1975.

Practical
Preparation of Standard solutions: 1 Normal, I Molar, % w/v solution, % v/v solution.
Standardization of volumetric apparatus.
Analysis of heavy metals- Lead and Mercury.
Determination of chlorides and sulphates.

Paper and Thin Layer Chromatography

Vertical 5:INDIAN KNOWLEDGE SYSTEM (IKS) – Course 6:

Course Code: CHE256: (30 Lectures Theory, Total Credits = 02 credits)

Course Outcomes (COs): After completing this course, the students should be able to …

CO - 1: The core ideas behind Indian Knowledge Systems.

CO - 2: To think critically and compare old Indian science with modern science,
understanding how different kinds of knowledge connect.

CO - 3: To know how ancient India approached environmental care.

CO - 4: To understand how ancient Indian knowledge can enhance modern science,

especially in Chemistry.

Chemistry in India Vatsyayana, Nagarjuna, Khanda, Al-Biruni, Vagbhaṭa –building of the ras-
shala (laboratory), working arrangements of ras-shala, material and equipment, Yaśodhara Bhaṭṭa-
process of distillation, apparatus, saranasamskara, saranataila.

Ancient Indian Chemistry Course type: IKS No. of Credits: 2

Course Outcomes After the completion of this course, students will be able to
CO1: know the Indian Knowledge System, Indian Knowledge system, Chemistry in India,
Chemical in Practical Arts and Contribution of Indians.
CO2: understand the Indian Knowledge System and ancient Indian Chemistry.
CO3: relate the various concepts of ancient Chemistry with modern Chemistry.
CO4: describe the concepts of ancient Indians Chemistry.
CO5: justify the role of Indians in the development of Chemistry.
CO6: summarize the Ancient Indian Chemistry.

Course Content

Chapter 1: Introduction to the Indian Knowledge System [10hours]

Part 1 – Indian Knowledge System:

An Introduction: Indian Knowledge System: An Overview, The Vedic Corpus Philosophical

Systems, Wisdom through the Ages

Part 2: Concepts of Science and Technology:

Linguistics, Number System and Units of Measurement, Knowledge: Framework and

Classification

Chapter -2: Chemistry in India [10 hours]

Introduction,

Pre-Vedic period, The Vedic age and Post-Vedic period and the Classical age, Alchemy, Indian
Alchemy and its characteristics, possible origin of Indian Alchemy, Laboratory and Apparatus, the
Chemical Laboratory at Presidency College, the Institutional Home of the Indian School of
Chemistry, the School of Indian Chemistry

Chapter -3: Chemical in Practical Arts [10 hours]

Introduction, Metallurgy and working of metals: Zinc (Zn), Mercury(Hg), Gold (Au), Silver (Ag),
Copper (Cu), Bronze and Brass, and iron (Fe), Tinning and alloying, enameling, recovery of gold
(Au) from wastage of gold(Au) working, gunpowder, saltpeter, mineral acid, alum and green
vitriol, paper, ink, soap, cosmetics and perfumery.
References-
1. The Positive Sciences of the Ancient Hindus; Brijendra Nath Seal; 4th Edition; 2016
2.Fine Arts & Technical Sciences in Ancient India with special reference to Someśvara’s
Mānasollāsa; Dr. Shiv Shekhar Mishra, Krishnadas Academy, Varanasi 1982
3. Mints and Minting in India; Upendra Thakur; Chowkhanba Publication; 1972
4. Science and Technology in Medieval India - A Bibliography of Source Materials in
Sanskrit, Arabic and Persian by A Rahman, M A Alvi, S A Khan Ghori and K V Samba
Murthy; 1982.
5. Science and Technological Exchanges between India and Soviet Central Asia (Medieval
Period), ed B V Subbarayappa;1985.

Vertical: 6 Course -7- (Field project-FP/ Community Engagement program-CEP)

Course Code: CHE257: (120 Hrs, Total Credits = 04 credits)