SAFETY DATA SHEET

NALCO® EC1021A

Section: 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : NALCO® EC1021A

Other means of identification : Not applicable.

Recommended use : CORROSION INHIBITOR

Restrictions on use : Refer to available product literature or ask your local Sales Representative for
restrictions on use and dose limits.

Company : Nalco Company

1601 W. Diehl Road
Naperville, Illinois 60563-1198
USA
TEL: (630) 305-1000

Emergency telephone : (800) 424-9300 (24 Hours) CHEMTREC

number

Issuing date : 09/13/2021

Section: 2. HAZARDS IDENTIFICATION

GHS Classification
Flammable liquids : Category 4
Skin corrosion : Category 1B
Serious eye damage : Category 1
Carcinogenicity : Category 2
Aspiration hazard : Category 1

GHS Label element

Hazard pictograms :

Signal Word : Danger

Hazard Statements : Combustible liquid

May be fatal if swallowed and enters airways.
Causes severe skin burns and eye damage.
Suspected of causing cancer.

Precautionary Statements : Prevention:

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear
protective gloves/ protective clothing/ eye protection/ face protection.
Response:
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF
SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a
POISON CENTER or doctor/ physician. IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water/shower. IF
INHALED: Remove person to fresh air and keep comfortable for breathing.

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Immediately call a POISON CENTER/doctor. IF IN EYES: Rinse cautiously with

water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Immediately call a POISON CENTER or doctor/ physician.
Storage:
Store in a well-ventilated place.
Disposal:
Dispose of contents/ container to an approved waste disposal plant.

Other hazards : None known.

Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS

Pure substance/mixture : Mixture

Chemical Name CAS-No. Concentration: (%)

Heavy Aromatic Naphtha 64742-94-5 30 - 60
Imidazoline Derivative Proprietary 30 - 60
Naphthalene 91-20-3 5 - 10
1,2,4-Trimethylbenzene 95-63-6 1-5

Section: 4. FIRST AID MEASURES

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Get medical attention immediately.

In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Wash clothing
before reuse. Thoroughly clean shoes before reuse. Get medical attention
immediately.

If swallowed : Rinse mouth with water. Do NOT induce vomiting. Never give anything by
mouth to an unconscious person. Aspiration hazard if swallowed - can enter
lungs and cause damage. Get medical attention immediately.

If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention if symptoms
occur.

Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put
yourself at risk of injury. If in doubt, contact emergency responders. Use
personal protective equipment as required.

Notes to physician : Treat symptomatically.

Most important symptoms : See Section 11 for more detailed information on health effects and symptoms.
and effects, both acute and
delayed

Section: 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Foam

Carbon dioxide
Dry powder
Other extinguishing agent suitable for Class B fires

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For large fires, use water spray or fog, thoroughly drenching the burning
material.

Unsuitable extinguishing : None known.

media

Specific hazards during : Fire Hazard

firefighting Keep away from heat and sources of ignition.
Flash back possible over considerable distance.
Beware of vapours accumulating to form explosive concentrations. Vapours can
accumulate in low areas.
Empty product containers may contain product residue. Do not pressurize, cut,
heat, weld, or expose containers to flame or other sources of ignition.

Hazardous combustion : Decomposition products may include the following materials: Carbon oxides
products nitrogen oxides (NOx)

Special protective equipment : Use personal protective equipment.

for firefighters

Specific extinguishing : Use water spray to cool unopened containers. Collect contaminated fire
methods extinguishing water separately. This must not be discharged into drains. Fire
residues and contaminated fire extinguishing water must be disposed of in
accordance with local regulations. In the event of fire and/or explosion do not
breathe fumes.

Section: 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Ensure adequate ventilation. Remove all sources of ignition. Keep people away
protective equipment and from and upwind of spill/leak. Avoid inhalation, ingestion and contact with skin
emergency procedures and eyes. When workers are facing concentrations above the exposure limit
they must use appropriate certified respirators. Ensure clean-up is conducted by
trained personnel only. Refer to protective measures listed in sections 7 and 8.

Environmental precautions : Do not allow contact with soil, surface or ground water.

Methods and materials for : Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. Contain
containment and cleaning up spillage, and then collect with non-combustible absorbent material, (e.g. sand,
earth, diatomaceous earth, vermiculite) and place in container for disposal
according to local / national regulations (see section 13). For large spills, dike
spilled material or otherwise contain material to ensure runoff does not reach a
waterway.

Section: 7. HANDLING AND STORAGE

Advice on safe handling : Take necessary action to avoid static electricity discharge (which might cause
ignition of organic vapours). Do not ingest. Keep away from fire, sparks and
heated surfaces. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get
in eyes, on skin, or on clothing. Wash hands thoroughly after handling. Use only
with adequate ventilation.

Conditions for safe storage : Keep away from heat and sources of ignition. Keep in a cool, well-ventilated
place. Keep away from oxidizing agents. Keep out of reach of children. Keep
container tightly closed. Store in suitable labelled containers.

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Suitable material : The following compatibility data is suggested based on similar product data
and/or industry experience: Perfluoroelastomer, PTFE, FEP (encapsulated),
Carbon Steel C1018, Stainless Steel 304, Stainless Steel 316L, Surface-
modified HDPE (high density polyethylene)

Unsuitable material : The following compatibility data is suggested based on similar product data
and/or industry experience: Neoprene, MDPE (medium density polyethylene),
Nitrile, EPDM, TFE, HDPE (high density polyethylene), Fluoroelastomer,
Compatibility with Plastic Materials can vary; we therefore recommend that
compatibility is tested prior to use.

Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Form of exposure Permissible Basis

concentration
Heavy Aromatic Naphtha 64742-94-5 TWA 500 ppm OSHA Z1
2,000 mg/m3
TWA 200 mg/m3 (as ACGIH
total hydrocarbon
vapor)
Naphthalene 91-20-3 TWA 10 ppm ACGIH
TWA 10 ppm NIOSH REL
50 mg/m3
STEL 15 ppm NIOSH REL
75 mg/m3
TWA 10 ppm OSHA Z1
50 mg/m3
1,2,4-Trimethylbenzene 95-63-6 TWA 25 ppm NIOSH REL
125 mg/m3
TWA 25 ppm ACGIH

Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below
occupational exposure standards.

Personal protective equipment

Eye protection : Safety goggles

Face-shield

Hand protection : Wear impervious chemical-resistant gloves when handling this product.
The following glove types are recommended based on our review of glove
manufacturer information and/or other available sources.
Viton® gloves
Other glove types may be used for short term, incidental contact if determined
by testing to provide adequate worker protection.
Gloves should be discarded and replaced if there is any indication of
degradation or chemical breakthrough.

Skin protection : Personal protective equipment comprising: suitable protective gloves, safety
goggles and protective clothing

Respiratory protection : Use local exhaust ventilation or other engineering controls as necessary to

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control airborne vapour and mist.

Where concentrations in air may exceed the limits given in this section or when
significant vapours are generated, use an approved air purifying respirator fitted
with a gas and vapour cartridge.
Use a particulate pre-filter where operations generate significant mists or
aerosols.
Recommended gas and vapour cartridge:
Organic vapor cartridge.
In event of emergency or planned entry into unknown concentrations a positive
pressure, full-facepiece SCBA or supplied-air respirator should be used.

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove
and wash contaminated clothing before re-use. Wash face, hands and any
exposed skin thoroughly after handling. Provide suitable facilities for quick
drenching or flushing of the eyes and body in case of contact or splash hazard.

The Personal Protective Equipment (PPE) recommendations provided above have been made in good faith based
on typical expected conditions of use. PPE selection should always be completed in conjunction with a proper risk
assessment and in accordance with a PPE management program.

Section: 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Liquid
Colour : clear
Odour : hydrocarbon-like
Flash point : 71 °C, Method: ASTM D 93, Pensky-Martens closed cup
pH : no data available
Odour Threshold : no data available
Melting point/freezing point : POUR POINT: -25 °C
Initial boiling point and boiling : 180 °C
range
Evaporation rate : no data available
Flammability (solid, gas) : Not applicable.
Upper explosion limit : no data available
Lower explosion limit : no data available
Vapour pressure : < 0.5 mm Hg, (37.8 °C),
Relative vapour density : no data available
Relative density : 0.918, (15 °C),
Density : 7.83 lb/gal
Water solubility : no data available
Solubility in other solvents : no data available
Partition coefficient: n- : no data available
octanol/water
Auto-ignition temperature : no data available

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Thermal decomposition : no data available

Viscosity, dynamic : no data available
Viscosity, kinematic : 8 mm2/s (40 °C)
Molecular weight : no data available
VOC : no data available

Section: 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : Stable under normal conditions.

Possibility of hazardous : No dangerous reaction known under conditions of normal use.

reactions

Conditions to avoid : Heat, flames and sparks.

Incompatible materials : Strong oxidizing agents

Hazardous decomposition : In case of fire, hazardous decomposition products may be produced such as:
products Carbon oxides
nitrogen oxides (NOx)

Section: 11. TOXICOLOGICAL INFORMATION

Information on likely routes of : Inhalation, Eye contact, Skin contact

exposure

Potential Health Effects

Eyes : Causes serious eye damage.

Skin : Causes severe skin burns.

Ingestion : May be fatal if swallowed and enters airways. Causes digestive tract burns.

Inhalation : May cause nose, throat, and lung irritation.

Chronic Exposure : Suspected of causing cancer.

Experience with human exposure

Eye contact : Redness, Pain, Corrosion

Skin contact : Redness, Pain, Corrosion

Ingestion : Corrosion, Vomiting, Abdominal pain

Inhalation : Respiratory irritation, Cough

Toxicity

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Product
Acute oral toxicity : Acute toxicity estimate: 2,547 mg/kg
Acute inhalation toxicity : no data available
Acute dermal toxicity : Acute toxicity estimate: > 5,000 mg/kg
Skin corrosion/irritation : no data available
Serious eye damage/eye : no data available
irritation
Respiratory or skin : no data available
sensitization
Carcinogenicity
IARC Group 2B: Possibly carcinogenic to humans
Naphthalene 91-20-3

OSHA No component of this product present at levels greater than or equal to 0.1% is
on OSHA’s list of regulated carcinogens.

NTP Reasonably anticipated to be a human carcinogen

Naphthalene 91-20-3

Reproductive effects : no data available

Germ cell mutagenicity : no data available
Teratogenicity : no data available
STOT - single exposure : no data available
STOT - repeated exposure : no data available
Aspiration toxicity : no data available

Section: 12. ECOLOGICAL INFORMATION

Toxicity

Environmental Effects : Toxic to aquatic life.

Very toxic to aquatic life with long lasting effects.

Product
Toxicity to fish : LC50 Oncorhynchus mykiss (rainbow trout): 2.7 mg/l
Exposure time: 96 hrs
Test substance: Product

NOEC Oncorhynchus mykiss (rainbow trout): 1.5 mg/l

Exposure time: 96 hrs
Test substance: Product

Toxicity to daphnia and other : LC50 Daphnia magna (Water flea): 1.1 mg/l
aquatic invertebrates Exposure time: 48 hrs
Test substance: Product

EC50 Daphnia magna (Water flea): 1.1 mg/l

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Exposure time: 48 hrs

Test substance: Product

NOEC Daphnia magna (Water flea): 0.60 mg/l

Exposure time: 48 hrs
Test substance: Product

Components
Toxicity to algae : Imidazoline Derivative
EC50 : 0.084 mg/l
Exposure time: 72 h

Components
Toxicity to bacteria : Imidazoline Derivative
28 mg/l

Persistence and degradability

Chemical Oxygen Demand (COD): 2,200,000 mg/l

Mobility

no data available

Bioaccumulative potential

no data available

Other information

no data available

Section: 13. DISPOSAL CONSIDERATIONS

The information presented only applies to the material as supplied. The classification or waste code may not apply if
the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine
the toxicity and physical properties of the material generated at the time of disposal to determine the proper waste
identification and disposal methods in compliance with applicable regulations.

Disposal methods : The product should not be allowed to enter drains, water
courses or the soil. Where possible recycling is preferred to
disposal or incineration. If recycling is not practicable, dispose
of in compliance with local regulations. Dispose of wastes in
an approved waste disposal facility.

Disposal considerations : Dispose of as unused product. Empty containers should be

taken to an approved waste handling site for recycling or
disposal. Do not re-use empty containers.

Section: 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance
with the selected mode of transport.

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The presence of an RQ component (Reportable Quantity for U.S. DOT) in this product causes it to be regulated with
an additional description of RQ for road, or as Environmentally hazardous for road and air, ONLY when the net
weight in the package exceeds the calculated RQ for the product.

Land transport (DOT)

Proper shipping name : AMINES, LIQUID, CORROSIVE, N.O.S.
Technical name(s) : Imidazoline Derivative
UN/ID No. : UN 2735
Transport hazard class(es) : 8
Packing group : III
Reportable Quantity (per : 1,818 lbs
package)
RQ Component : Naphthalene

Air transport (IATA)

Proper shipping name : AMINES, LIQUID, CORROSIVE, N.O.S.
Technical name(s) : Imidazoline Derivative
UN/ID No. : UN 2735
Transport hazard class(es) : 8
Packing group : III
Reportable Quantity (per : 1,818 lbs
package)
RQ Component : Naphthalene

Sea transport (IMDG/IMO)

Proper shipping name : AMINES, LIQUID, CORROSIVE, N.O.S.
Technical name(s) : Imidazoline Derivative
UN/ID No. : UN 2735
Transport hazard class(es) : 8
Packing group : III

*Marine pollutant : Imidazoline Derivative

* Note: This product is regulated as a Marine Pollutant when shipped by Rail or Highway (in bulk quantities), and
when shipped by water in all quantities.

Section: 15. REGULATORY INFORMATION

TSCA list : No substances are subject to a Significant New Use Rule.

No substances are subject to TSCA 12(b) export notification

requirements.

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity

Components CAS-No. Component RQ (lbs) Calculated product RQ
(lbs)
Naphthalene 91-20-3 100 1818
SARA 304 Extremely Hazardous Substances Reportable Quantity

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This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)

Carcinogenicity
Aspiration hazard
Skin corrosion or irritation
Serious eye damage or eye irritation

SARA 302 : This material does not contain any components with a section 302
EHS TPQ.

SARA 313 : The following components are subject to reporting levels established
by SARA Title III, Section 313:
Naphthalene 91-20-3 5 - 10 %
1,2,4-Trimethylbenzene 95-63-6 1-5%

California Prop. 65
WARNING: Cancer - www.P65Warnings.ca.gov
Naphthalene 91-20-3

INTERNATIONAL CHEMICAL CONTROL LAWS :

United States TSCA Inventory

On or in compliance with the active portion of the TSCA inventory

Australia. Australian Industrial Chemicals Introduction Scheme (AICIS)

All substances in this product comply with the Australian Industrial Chemicals Introduction Scheme (AICIS)

Canadian Domestic Substances List (DSL)

The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL).

Japan. ENCS - Existing and New Chemical Substances Inventory

All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical
Substances and are listed on the Existing and New Chemical Substances list (ENCS).

Korea. Korean Existing Chemicals Inventory (KECI)

All substances in this product comply with the Chemical Control Act (CCA) and are listed on the Existing Chemicals
List (ECL)

Philippines Inventory of Chemicals and Chemical Substances (PICCS)

All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines
Inventory of Chemicals & Chemical Substances (PICCS).

China Inventory of Existing Chemical Substances

All substances in this product comply with the Provisions on the Environmental Administration of New Chemical
Substances and are listed on or exempt from the Inventory of Existing Chemical Substances China (IECSC).

New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand

All substances in this product comply with the Hazardous Substances and New Organisms (HSNO) Act 1996,and
are listed on or are exempt from the New Zealand Inventory of Chemicals.

Taiwan Chemical Substance Inventory

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All substances in this product comply with the Taiwan Existing Chemical Substances Inventory (ECSI).

Section: 16. OTHER INFORMATION

NFPA: HMIS III:

Flammability

HEALTH 3*
2
Instability
Health

3 0 FLAMMABILITY 2
PHYSICAL HAZARD 0

Special hazard. 0 = not significant, 1 = Slight,

2 = Moderate, 3 = High
4 = Extreme, * = Chronic

Revision Date : 09/13/2021

Version Number : 2.0
Prepared By : Regulatory Affairs

REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by
a bar in the left-hand margin of the SDS.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use,
processing, storage, transportation, disposal and release and is not to be considered a warranty or quality
specification. The information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified in the text.
For additional copies of an SDS visit www.nalco.com and request access.

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