VEDANTA

Subject : Che Thermodynamics Test paper Paper Set : 1

Standard : 11 Advance foundation Date : 10-11-2024
Total Mark : 40 Time : 0H:0M

............ Chemistry - Section A (MCQ) ............ (A) 163.7 (B) 850.2

(C) 1381.1 (D) 0
(1) For the reaction N2 + 3H2 ⇌ 2N H3 ; ∆H =? (8) Considering entropy (S) as a thermodynamic
(A) ∆E − RT (B) ∆E − 2RT parameter, the criterion for the spontaneity of
(C) ∆E + RT (D) ∆E + 2RT any process is
(2) If ∆H is the change in enthalpy and ∆E the (A) ∆Ssystem > 0 only
change in internal energy accompanying a (B) ∆Ssurroundings > 0 only
gaseous reaction
(C) ∆Ssystem + ∆Ssurroundings > 0
(A) ∆H is always greater than ∆E
(D) ∆Ssystem − ∆Ssurroundings > 0
(B) ∆H < ∆E only if the number of moles of the
products is greater than the number of the (9) The absolute enthalphy of neutralisation of the
reactants reaction
M gO(s) + 2HCl(aq) → M gCl2 (aq) + H2 O(l)will
(C) ∆H is always less than ∆E be
(D) ∆H < ∆E only if the number of moles of the (A) Less than −57.33 kJ mol−1
products is less than the number of moles of (B) −57.33 kJ mol−1
the reactants
(C) Greater than −57.33 kJ mol−1
(3) Which of the following is the correct equation
(A) ∆U = ∆Q − W (B) ∆W = ∆U + ∆Q (D) 57.33 kJ mol−1
(C) ∆U = ∆W + ∆Q (D) None of these (10) In an endothermic reaction, the value of ∆H is
(A) Zero (B) Positive
(4) For the
reaction,C3 H8 (g) + 5O2 (g) → 3CO2 (g) + 4H2 O(l) (C) Negative (D) Constant
at constant temperature, ∆H − ∆E is
(A) −RT (B) = +RT
(C) −3RT (D) +3RT
(5) The work done during the expansion of a gas
from a volume of 4 dm3 to 6 dm3 against a
constant external pressure of 3 atm is
(1 L atm = 101.32 J) ......J
(A) +304 (B) −304
(C) −6 (D) −608
(6) Which of the following pairs of a chemical
reaction is certain to result in spontaneous
reaction ?
(A) Exothermic and decreasing disorder
(B) Endothermic and increasing disorder
(C) Exothermic and increasing disorder
(D) Endothermic and decreasing disorder
(7) One mole of an ideal gas at 300 K is expanded
isothermally from an initial volume of 1 litre to 10
litres. The change in energy for this process
is.......cal (R = 2 cal mol−1 K −1 )

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 VEDANTA
Subject : Che Thermodynamics Test paper Paper Set : 1
Standard : 11 Advance foundation Date : 10-11-2024
Total Mark : 40 (Answer Key) Time : 0H:0M

Chemistry - Section A (MCQ)

1 - B 2 - D 3 - C 4 - C 5 - D 6 - C 7 - D 8 - C 9 - A 10 - B

2
 VEDANTA
Subject : Che Thermodynamics Test paper Paper Set : 1
Standard : 11 Advance foundation Date : 10-11-2024
Total Mark : 40 (Solutions) Time : 0H:0M

............ Chemistry - Section A (MCQ) ............

Solution:(Correct Answer:D)
(d)W = −p∆V ; W = −3 × (6 − 4)
(1) For the reaction N2 + 3H2 ⇌ 2N H3 ; ∆H =? W = −6 × 101.32 (∴ 1 L atm = 101.32 J)
(A) ∆E − RT (B) ∆E − 2RT W = −608 J
(C) ∆E + RT (D) ∆E + 2RT
(6) Which of the following pairs of a chemical
Solution:(Correct Answer:B) reaction is certain to result in spontaneous
(b)∆H = ∆E + ∆nRT reaction ?
Since ∆n = −2 (A) Exothermic and decreasing disorder
Than ∆H = ∆E − 2RT .
(B) Endothermic and increasing disorder
(2) If ∆H is the change in enthalpy and ∆E the
change in internal energy accompanying a (C) Exothermic and increasing disorder
gaseous reaction (D) Endothermic and decreasing disorder
(A) ∆H is always greater than ∆E
Solution:(Correct Answer:C)
(B) ∆H < ∆E only if the number of moles of the
(c) ∆G = ∆H − T ∆S
products is greater than the number of the
for spontaneous process ∆G should be negative
reactants
in option (3) ∆H = −ve and ∆S = +ve than
(C) ∆H is always less than ∆E ∆G = (−ve) − T (+ve) = − ve
(D) ∆H < ∆E only if the number of moles of the
products is less than the number of moles of (7) One mole of an ideal gas at 300 K is expanded
the reactants isothermally from an initial volume of 1 litre to 10
litres. The change in energy for this process
Solution:(Correct Answer:D)
is.......cal (R = 2 cal mol−1 K −1 )
(d)If ∆n = −ve than ∆H < ∆E. (A) 163.7 (B) 850.2
(3) Which of the following is the correct equation (C) 1381.1 (D) 0
(A) ∆U = ∆Q − W (B) ∆W = ∆U + ∆Q
(C) ∆U = ∆W + ∆Q (D) None of these Solution:(Correct Answer:D)
(d) For isothermal expansion of ideal gas, ∆E = 0.
Solution:(Correct Answer:C)
It’s obvious.
(8) Considering entropy (S) as a thermodynamic
(4) For the parameter, the criterion for the spontaneity of
reaction,C3 H8 (g) + 5O2 (g) → 3CO2 (g) + 4H2 O(l) any process is
at constant temperature, ∆H − ∆E is (A) ∆Ssystem > 0 only
(A) −RT (B) = +RT
(B) ∆Ssurroundings > 0 only
(C) −3RT (D) +3RT
(C) ∆Ssystem + ∆Ssurroundings > 0
Solution:(Correct Answer:C)
(D) ∆Ssystem − ∆Ssurroundings > 0
(c)∆H − ∆E = ∆nRT ; ∆n = −3
so, ∆H − ∆E = −3RT .
Solution:(Correct Answer:C)
(5) The work done during the expansion of a gas (c)∆Ssystem + ∆Ssurroundings > O(for spontaneity)
from a volume of 4 dm3 to 6 dm3 against a Because of ∆S = R ln VV12
constant external pressure of 3 atm is Here the volume of gas increase from V1 to V2 at
(1 L atm = 101.32 J) ......J constant temperature T .
(A) +304 (B) −304 The total increase in entropy of the system and its
(C) −6 (D) −608 surrounding during the spontaneous process of

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 ( )
expansion considered above is, thus R ln VV12
since V2 > V1 it is obvious that the spontaneous
(irreversible) isothermal expansion of a gas is
accompanied by an increase in the entropy of the
system and its surrounding considered together.
∆Ssystem + ∆Ssurroundings > 0.

(9) The absolute enthalphy of neutralisation of the

reaction
M gO(s) + 2HCl(aq) → M gCl2 (aq) + H2 O(l)will
be
(A) Less than −57.33 kJ mol−1
(B) −57.33 kJ mol−1
(C) Greater than −57.33 kJ mol−1
(D) 57.33 kJ mol−1

Solution:(Correct Answer:A)
(a)Heat of neutralisation will be less than
−57.33 kJ/mole because some amount of this
energy will be required for the dissociation of
weak base (M gO)

(10) In an endothermic reaction, the value of ∆H is

(A) Zero (B) Positive
(C) Negative (D) Constant
Solution:(Correct Answer:B)
(b)∆H = +ve for endothermic reaction.