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100% found this document useful (1 vote)
72 views26 pages

PTM-14 Q.paper

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kammedi34435s
Copyright
© © All Rights Reserved
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Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI


A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_NUCLEUS&STERLING_BT JEE-MAIN Date: 16-11-2024
Time: 09.00Am to 12.00Pm RPTM-14/18 Max. Marks: 300
IMPORTANT INSTRUCTION:
1. Immediately fill in the Admission number on this page of the Test Booklet with Blue/Black Ball Point Pen
only.
2. The candidates should not write their Admission Number anywhere (except in the specified space) on the
Test Booklet/ Answer Sheet.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 90 questions. The maximum marks are 300.
5. There are three parts in the question paper 1,2,3 consisting of Physics, Chemistry and Mathematics having
30 questions in each subject and subject having two sections.
(I) Section –I contains 20 multiple choice questions with only one correct option.
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
(II) Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only, if more than 5
questions attempted, First 5 attempted questions will be considered.
∎ The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer
value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and
less than 11 round off is 11).
To cancel any attempted question bubble on the question number box.
For example: To cancel attempted question 21. Bubble on 21 as shown belo w

.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use of pencil is
strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone any electron
device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in the Hall.
However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet
Name of the Candidate (in Capital): ________________________________________________

Admission Number:
Candidate’s Signature:________________ Invigilator’s Signature: ________________
SRI CHAITANYA IIT ACADEMY, INDIA 16-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-14/18_Q.P
16-11-2024_Sr.Super60_ NUCLEUS & STERLING_BT _ Jee-Main_RPTM-14/18_Test Syllabus
PHYSICS : Fluid statics & Dynamics: Pressure in a fluid; Pascal’s law; Buoyancy, Streamline flow, equation
of continuity, Bernoulli’s theorem and its applications.
COMPLETE RPTM-14 SYLLABUS (Except MAINS Deleted Topics) (20Q RPTM14+10Q CUMULATIVE)

CHEMISTRY : Chemical Equilibrium: Introduction,Equilibrium in physical processes, Equilibrium in chemical


processes, Law of mass action and equilibrium constant, Types of equilibrium constant,Effect of
temperature on the equilibrium constant, Applications of equilibrium constant, Relationship
between equilibrium constant K and Reaction Quotient Q, and Gibbs energy G
lonic equilibrium : Introduction,Concepts of acids and bases, Classification of solvents, Arrhenius
theory , Bronsted and Lowry theory, Lewis acid and base theory, lonisation of acids and
bases,Ostwald's Dilution Law,lonisation of water,The pH Scale Common ion effect in the ionisation
of acids and bases,Di and polybasic acids and Di-and polyacidic bases , Buffer solutions, Hydrolysis
of salts and the pH of their solutions,Indicators , titration curves, Solubility of sparingly soluble
salts and solubility product, common ion effect , Solubility of sparingly soluble salts
COMPLETE RPTM-14 SYLLABUS (Except MAINS Deleted Topics) (20Q RPTM14+10Q CUMULATIVE)

MATHEMATICS : Progressions and Sets and Relations


COMPLETE RPTM-14 SYLLABUS (Except MAINS Deleted Topics) (20Q RPTM14+10Q CUMULATIVE)

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SRI CHAITANYA IIT ACADEMY, INDIA 16-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-14/18_Q.P
PHYSICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Given below are two statements: One is labeled as Assertion (A) and the other is labeled as
Reason( R).
Assertion (A): Pascal’s law is the working principle of hydraulic lift.
Thrust
Reason (R): Pressure=
Area
In the light of the above statements, choose the most appropriate answer from the options
given below.
1) Both A and R are correct and R is the correct explanation of A
2) Both A and R are correct but R is NOT the correct explanation of A
3) A is true but R is false
4) Both A and R are true
2. A water barrel having water up to depth ‘d’ is placed on a table of height ‘h’. A small hole is
made on the wall of the barrel at its bottom. If the stream of water coming out of the hole
falls on the ground at a horizontal distance R from the barrel, then the value of ‘d’ is:

d=dpeth of water
in barrel

h=height of table

Horizontal distance on ground


4h 2 R2 h
1) 2 2) 4hR 3) 4)
R 4h 4 R2
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3. A sphere of relative density  and diameter D has concentric cavity of diameter d. The ratio
D
of .If it just floats on water in a tank is:
d
1 1 1 1
  3    1 3    1 3   2 3
1)   2)   3)   4)  
  1   1    2
 r2 
4. Consider a solid sphere of radius R and mass density   r   20  1  2  ,0  r  R .The
 R 
minimum density of a liquid in which it will float is:
 4 2 2
1) 0 2) 0 3) 0 4) 0
3 5 5 3
5. Two liquids of densities 1and 2  2  31  are filled up behind a square wall of side 10 m
as shown in figure. Each liquid has a height of 5m.The ratio of the forces due to these liquids
exerted on upper part MN to that at the lower part NO is (Assume that the liquids are not
mixing)
M

O
1)1/5 2)2/3 3)1/3 4)1/4
6. Correct Bernoulli’s equation is (symbols have their usual meaning):
1 2 1
1) P  mgh  2 mv  constant 2) P  gh  v 2  constant
2
1 1
3) P  gh  v 2  constant 4) P  gh  v 2  constant
2 2
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7. Three particles are thrown with same speed from top of towers of same height as shown in
the figure. Which option is correct for the final speed of ball just before reaching the ground.

(1) (2) (3)

1) V1  V2  V3 2) V2  V3  V1 3) V1  V2  V3 4) V3  V2  V1
8. A piece of ice having a stone frozen in it floats in a glass vessel filled with water. When the
ice melt the level of water in the vessel
1) Decreases 2) Increases 3) remain same 4) increases then decreases.
9. Given below are two statements: One is labeled as Assertion (A) and the other is labeled as
Reason (R)
Assertion (A): In an uniform magnetic field, speed and kinetic energy remains the same for a
moving charged particle.
Reason(R): Moving charged particle experiences magnetic force parallel to its direction of
motion.
1) Both (A) and (R) are true and (R) is the correct explanation of (A).
2) Both (A) and (R) are true but (R) is NOT the correct explanation of (A)
3) (A) is true but (R) is false
4) (A) is false but (R) is true.
10. A target object is placed at the bottom of a tank of depth 20m,and filled with a liquid of
density 500 gm/cc. Another object of density 100gm/cc is dropped onto it, from a height of
45m from the upper surface of the liquid.(Take g= m/s 2)
Choose incorrect statement.

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1) The second object does not collide with the target.


2) The second object does collide with the target.
3) The least separation between object and target is 8.75 m
4) The retardation of the object in the liquid is 40ms-2
11. A body floats in a liquid contained in a beaker. The whole system shown in figure is falling
under gravity. The up thrust on the body due to liquid is:

1) Zero
2) equal to weight of liquid displaced
3) Equal to weight of the body in air
4) equal to weight of the immersed body
12. Four charged particle,   q, m  ,  3q,4 m  ,   q, m  and  2 q, m  enter in uniform magnetic

field (in inward direction) with same kinetic energy as shown in figure. Inside the magnetic
field their paths are shown. Match the following two columns.

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Column-I Column-II
a)particle   q, m  (p) 

b)Particle  3q,4m  (q) x

c)Particle   q, m  (r) y

d)Particle  2 q, m  (s) z

1) a  r; b  s; c  q; d  p 2) a  s; b  r; c  q; d  p
3) a  s; b  r; c  p; d  q 4) a  r; b  s; c  p; d  q
13. In the figure shown find velocity of efflux

H

2H 2
v

1) 2 gH 2) 3 gH 3) 6gH 4) 5gH

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SRI CHAITANYA IIT ACADEMY, INDIA 16-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-14/18_Q.P
14. Two connecting vessels contain mercury. The diameter of one vessel is n times larger than
the diameter of the other. A column of water of height h is poured into the left vessel. The
mercury level will rise in the right-hand vessel by
(s= relative density of mercury and   density of water)

water

Mercury

n2 h h h h
1) 2) 3) 4)
 n  12 s n 2
1 s  n  12 s n2 s
15. Equal masses of three liquids are kept in three identical cylindrical vessels. A,B and C. The
densities are  A ,  B , C with  A   B  C .the force on the base will be
1) maximum in vessel A 2) maximum in vessel B
3) maximum in vessel C 4) equal in all vessels.
16. An open water tanker on a horizontal straight road has a cubical block of cork floating over
its surface. If the tanker has an acceleration of a as shown, The acceleration of the cork w.r.t
container is____

a2 a
1)Zero 2) 3) g 2  a2 4) a
g y

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SRI CHAITANYA IIT ACADEMY, INDIA 16-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-14/18_Q.P
17. Statement-1: Cross-sectional area of the water stream pouring out of a tap decreases as the
height from the ground decreases.(in steady state)
Statement-2: Work done by gravity is equal to increase in the kinetic energy of the fluid and
thus reduces the cross-sectional area.
1) Statement-1 is true, statement-2 is true; Statement-2 is a correct explanation for statement-
1
2) Statement-1 is true, statement-2 is true; statement-2 in Not a correct explanation for
statement-1
3) Statement-1 is true, statement-2 is false
4) Statement-1 is false, statement-2 is true
18. Which one of the following cannot be explained on the basis of Bernoulli’s theorem?
1)Blowing off of light roofs when strong winds blow
2)Curved path followed by a spinning ball
3)Working of perfume bottle
4)None
19. A container is filled with fluid of density  and 2 as shown in the figure. When it is
rotated with constant angular velocity  . Find PA  P0 .
 B A
O

 2

l l
32l 2
1) 2) 62l 2 3) 3.52l 2 4) 82l 2
2

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SRI CHAITANYA IIT ACADEMY, INDIA 16-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-14/18_Q.P
20. Statement-1: A point particle of mass m moving with speed v collides with stationary point
1 
particle of mass M. If the maximum energy loss possible is given as d   mv 2  then
2 
 m 
d  
M m
Statement-2: Maximum energy loss occurs when the particles get stuck together as a result
of the collision
1) Statement-1 is true, statement-2 is true; Statement-2 is a correct explanation for statement-
1
2) Statement-1 is true, statement-2 is true; statement-2 in Not a correct explanation for
statement-1
3) Statement-1 is true, statement-2 is false
4) Statement-1 is false, statement-2 is true
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
21. The water is filled upto height of 12 m in a tank having vertical sidewalls. A hole is made in
one of the walls at a depth ‘h’ below the water level. The value of ‘h’ for which the
emerging stream of water strikes the ground at the maximum range is____ m

22. A liquid of density 750kgm 3 flows smoothly through a horizontal pipe that tapers in cross-

A1
sectional area from A1  1.2  10 2 m 2 to A2  .The pressure difference between the wide
2
and narrow sections of the pipe is 4500Pa.The rate of flow of liquid is ___ 10 3 m3 s 1 .

23. The surface of water in a water tank of area of cross section 600cm2 on the

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top of a house is h m above the tap level. The speed of water coming out through the tap of
dh
cross-section area 150 mm2 is 40cm/s. At that instant is x  10 3 m / s , then the value of
dt
x____

24. A rod of mass M and length L is lying on a horizontal frictionless surface. A particle of mass
‘m’ travelling along the surface hits at one end of the rod with a velocity ‘u’ in a direction
perpendicular to the rod. The collision is completely elastic. After collision, particle comes
m y
to rest. The ratio of masses   is .The value of ‘x+y’ will be_____
M  x

25. A copper piece of mass 10 g is suspended by a vertical spring. The spring elongates 1 cm
over its natural length to keep the piece in equilibrium. A beaker containing water is now
placed below the piece so as to immerse the piece completely in water.(Density of copper
=9000 kg / m3 ,g=10 m / s 2 ). The elongation of the spring is x  102 m . x=_______

26. In Young’s double slit experiment, two slits S1 and S2 are ‘d’ distance apart and the
separation from slits to screen is D(as shown in figure).Now if two transparent slabs of equal
thickness 0.1 mm but refractive index 1.60 and 1.52 are introduced in the path of beam
 0
   4000 A  from S1 and S2 respectively. The central bright fringe spot will shift by_____
 
number of fringes.

1.52 P
S1

0.1mm
d 1.60 screen

S2 D

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27. The radius of 2 orbit of He of Bohr’s model is r1 and that of third orbit of Be3 is
nd 

r1
represented as r2 .Now the ratio is x:y. The value of x+y is_______
r2

28. A system of 10 balls each of mass 2 kg are connected via massless and unstretchable string.
The system is allowed to slip over the edge of a smooth table as shown in figure. Tension on
the string between the 6th and 7th ball is_____ N when 3rd ball just leaves the table.

10th ball

1st ball

29. A particle of mass 2 kg is initially at rest. A force starts acting on it in one direction whose
magnitude changes with time. The force time graph is shown in figure. Find the velocity of
the particle (m/s) at the end of 10 s.

30. A bullet of mass 10 3 kg strikes an obstacle and moves at 600 to its original direction. If its
speed also changes from 20 m/s to 10m/s.The magnitude of impulse acting on the bullet is
x  102 N  s . x is……..

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SRI CHAITANYA IIT ACADEMY, INDIA 16-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-14/18_Q.P
CHEMISTRY Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
31.
OH

NH 2

O 
2

Br / NaOH

product: The product of this Hoffmann bromide reaction is:


O
OH
Ph  CH
Ph  C  CH 3 NH 2
1) 2) Ph  CHO 3) 4) Ph  CH 2  NH 2

MeO 
C 

OMe


32. Ph
The reaction proceds through
1) Bimolecular basic hydrolysis with acyl-oxygen heterolysis
2) Bimolecular basic hydrolysis with alkyl-oxygen heterolysis
3) Unimolecular basic hydrolysis with acyl-oxygen heterolysis
4) Unimolecular basic hydrolysis with alkyl-oxygen heterolysis.
33. The correct order of melting point is......
1) C  Si  Ge  Sn  Pb 2) C  Si  Ge  Sn  Pb
3) C  Si  Ge  Pb  Sn 4) C  Si  Pb  Sn  Ge

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34. Column-I Column-II
H3C CH3
C C C
oldKMnO4
 
H H
a) p) Racemic mixture
CH3 CH3
CC B
r2.CCl4
 
H H
b) q)Erythro
CH3 H
CC C
FC
3 OH
(
) 
3
H /H2O
H CH3
c) r)Threo
CH3 H
CC C
l2.CCl4
 
H CH3
d) s)Meso compound
1) a  qs; b  pr; c  qr; d  qs 2) a  qr; b  pr; c  qs; d  qr
3) a  qs; b  pr; c  qs; d  qs 4) a  qs; b  ps; c  qs; d  qr
35. In water  H  O  H  bond angle is 1050 .The distance between  O  H  is 0.94 A0 .
 of H 2O  1.85D . Determine the magnitude of the charge on the oxygen atom and
hydrogen atom in water molecule  cos52.50  0.609 
1) 3.2  1010 esu,1.6  1010 esu 2) 32  1010 esu,16  1010 esu
3) 3.2  109 esu,1.6  109 esu 4) 32  109 esu,16  109 esu
36. What is the ratio of nodal planes presented in  2* p and  1s* molecular orbitals?
1)0 2)  3)2 4)1
37. The structure of the product formed in the reaction given below is____

H

OH OH
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1) 2) O

3) O 4) O

38. The combustion of one mole of benzene takes place at 298 k and 1 atm. After combustion,
CO2  g  and H 2O  l  are produced and 3267.0kJ/mol of heat is liberated calculate the

standard enthalpies of formation  f H   of benzene. Standard enthalpies of formation of


CO2  g  and H 2O  l  are 393.5 kJ / mol and  285.83 kJ / mol respectively

1) 48.51kJ / mol 2) 58.51kJ / mol


3) 48.51kJ / mol 4) 58.51kJ / mol
39. Given below are two statements.
Statement-I: The gas liberated on warming a salt with dil . H 2 SO4 turns a piece of paper
dipped in potassium dichromate paper acidified with dil. H 2 SO4 into green, It is a
confirmatory test for sulphite ion.
Statement-II: In statement-I the colour of paper turns green because of formation of
chromium sulphate.
In the light of the above statements. Choose the most appropriate answer from options given
below.
1) Both statement -I and statement II are false
2) Statement I is false but statement II is true
3) Statement I is true but statement II is false
4) Both statement I and statement II are true.
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H
40. Calculate the P of the following mixture of strong acids & strong bases.8g of NaOH+680
ml of 1M HCl +10 ml of H 2 SO4 (specific gravity 1.2, 49% H 2 SO4 by mass).The total
volume of the solution was mole to 1 L with water.
1)0.22 2)0.44 3)0.66 4)0.88
41. The following equilibrium are given

N 2  3H 2 
 2 NH 3 ; k1 
 2 NO ; k2
N 2  O2 

1   H 2O ; k3
H 2  O2  
2
The equilibrium constant of the reaction
5   2 NO  3H 2O in terms of k1, k2 and k3 is
2 NH 3  O2  
2
2
k1k3 k1k2 k2 k33
1) 2) 3) k1k2 k3 4)
k2 k3 k1
42. The k sp for bismuth sulphide  Bi2 S3  is 1.08  10 58 .the solubility of Bi2 S3 in mol / L at
298k is_____
1) 2.7  10 12 2) 1.0  10 12 3) 3.2  10 10 4) 1.0  10 15
43. The equilibrium reaction that is not influenced by volume change at constant temperature
is___

 2 HI
1) H 2 g   I 2 g  
 
2) N 2 g   3 H 2 g    2 NH 3

g g

 2 NO2
3) N 2O4 g  
 
 2 NO2
4) 2 NO g   O2 g  

g g
44. For the following Assertion(A) and Reason (R) the correct option is..
Assertion(A): The ionization of hydrogen sulphide in water is low in the presence of
hydrochloric acid.
Reason(R): Hydrogen sulphide is a weak acid
1) Both A and R are true and R is correct explanation of A
2) Both A and R true but R is not correct explanation of A
3) A is true but R is false
4) Both A and R false

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45. At equilibrium the concentrations of
N2  3.0 103 M , O2  4.2  103 M and NO  2.8  103 M in a sealed vessel at 800k.What

 2 NO
will be kC for the reaction. N 2 g   O2 g  
 g
1)0.622 2)0.644 3)0.602 4)0.604
46. The correct formula to calculate the hydroxyl ion concentration of an aqueous solution of
NH 4 NO3 is____
c  kw kw  kb c  kw k a  kw
1) 2) 3) 4)
kb c ka c
47. The standard Gibbs energy change at 300 k for the reaction 2 A   B  C is 2494 .2J .

1 1
At a give time the composition the reaction mixture is  A  2  B   and C   .The
2 2
reaction proceeds in the _____  R  8.314 J / k / mol 10 0.434  0.37 
1) Forward direction because Q  K c 2) Reverse direction because Q  K c
3) Forward direction because Q  K c 4) Reverse direction because Q  K c

X 
 2Y 
Z 
P Q
48. For the reactions and
Occuring at two different pressure P1and P2 respectively.The ratio of the two pressures is
4:3.What will be the ratio of equilibrium constant, if the degree of dissociation of X and Z
are equal
1)1:36 2)16:3 3)16:9 4)1:12
49. Assertion(A): solution containing a mixture or
Assertion (A) : A solution containing a mixture of acetic acid and sodium acetate maintains
a constant value of pH on addition of small amounts of acid or alkali
Reason(R): A solution containing mixture of acetic acid and sodium acetate acts as a
buffer solution having pH around 4.75
1) A is false R is true
2) Both A and R is false
3) Both A and R is true but R is not the correct explanation for A
4) Both A and R is true but R is the correct explanation for A
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50. Consider the following statements for a given reaction

Fe3( aq )  SCN aq 


[ Fe( SCN )]2( aq )

(Yellow) (colourless) (deep red)


[ Fe( SCN )( aq ) ]2
I. The equilibrium constant K c 
[ Fe3( aq ) ][ SCN ( aq ) ]

II. A reddish colour appears on adding two drops at 0.002M potassium thiocynate solution to
1 ml of 0.2 M iron (III) nitrate solution due to the formation of [ Fe( SCN )]2 The intensity of
the red colour becomes constant on attaining equilibrium.
III. The equilibrium can be shifted in either forward (or) reverse directions depending on our
choice of adding a reactant or a product.
IV. The equilibrium can be shifted in the opposite direction by adding reagents that remove

Fe3 or SCN   ions.


Choose the correct statement(s)


1) Only I 2) I, III and IV 3) I and II 4) All of these
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

51. The P H of an aqueous solution containing 1M benzoic acid ( p ka  4.20) and 1M sodium
benzoate is 4.5. The volume of benzoic acid solution in 600ml of this buffer solution is
_________ mL.(Given: log2  0.3 )
52. At 298k , the solubility of silver chloride in water is 14.34  103 g / L. The value of
 log k sp for silver chloride is (given mass of Ag is 107.9 g / mol and mass of Cl is
35.5 g / mol )
53. Two salts A2 X and MX have the same value of solubility product of 2.56  10 10
S( A2 X )
The ratio of their molar solubilities i.e.  _____
S( MX )

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54. How many of the following are non electrolytes____
HCOONH 4 , CH 3COONa, C6 H 5CH 3 , C6 H12O6 , NH 4Cl, C6 H 6

0
55. The standard free energy change ( G 0 ) for 60% dissociation of N 2O4 into NO2 27 c and
1atm pressure is  x J / mol .The value of x is __________
(Nearest integer)[Given R  8.31 J / k  mol , log 2.25  0.35218 ln10  2.3 ]
56. The vapour density of the equilibrium mixture of the reaction:
 SO2  Cl2 is 50. The percent dissociation of SO2Cl2 is ______
SO2Cl2( g )  (g) (g)


57. No.of possible stereo isomers for Co  en 2  Cl 2  is....

58. How many of the following do not establish equilibrium when carried in closed vessel

 NaCl  H 2O
a) NaOH  HCl 


 AgCl  NaNO3
b) AgNO3  NaCl 


 CH 3COOH  C2 H 5OH
c) CH 3COOC2 H 5  H 2O 


 2 NH 3
d) N 2  3H 2 


 2 SO3
e) 2 SO2  O2 


 SnCl4  2 FeCl2
f) SnCl2  2 FeCl3 


 BaSO4  2 NaCl
g) BaCl2  Na2 SO4 

59. If the P Ka of acetic acid and P Kb of NH 4OH are 4.76 and 4.75 respectively. The P H of the
ammonium acetate solution will be_______(Round of the nearest integer)

60. The P H at which Mg  OH 2  K sp  1  10 13  begins to precipitate form a solution

containing 0.1 M Mg 2 ion is______

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SRI CHAITANYA IIT ACADEMY, INDIA 16-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-14/18_Q.P
MATHEMATICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
61. Statement 1: log10 x  log 3 x  log e x  log 2 x  x  0, x  1
Statement 2: If 0  x  1 then log x a  log x b  0  a  b
1) Statement I is true, Statement 2 is true
2) Statement I is true, Statement 2 is false
3) Statement I is false, Statement 2 is true
4) Statement I is false, Statement 2 is false
62. The area inside the parabola 5 x 2  y  0 but outside of the parabola 2 x 2  y  9  0 is
1) 12 3 sq. Units 2) 6 3 sq. Units
3) 8 3 sq. Units 4) 4 3 sq. Units
63. Match the following
Column-I Column-II
([.] denotes the greatest integer function)
a.  sin x   tan x   p) 198
lim  100  100
x0   x   x  
b.  x   tan x   q) 199
lim  100  100
x0   
sin x   x  
c.  sin 1 x   tan 1 x   r) 200
lim  100   100  
x 0  x x
   
d.  x   tan 1 x   s) 201
lim  100 1   100  
x 0   sin x  x
  
1) a  q; b  r; c  p; d  q. 2) a  q; b  r; c  q; d  p.
3) a  r; b  q; c  q; d  p. 4) a  p; b  r; c  q; d  r.
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1 2 3
64. The sum of the series 2 4
 2 4
  .... up to 20 terms is
1  3.1  1 1  3.2  2 1  3.32  34
200 210 220 230
1) 2) 3) 4)
419 419 419 419
65. Let 2 ,8 and 44 , terms of a non- constant A.P be respectively the 1st ,2nd and 3rd terms
nd th th

of G.P. If the first term of A.P is 1 then the sum of first 25 terms of A.P is equal to
1) 1525 2) 1550 3) 1575 4) 1625
1 1 1 1 1 1
66. If   ....   m and   .....   n,
1 2 2 3 99  100 1.2 2.3 99.100
Then the point (m,n) lies on the line
1) 11 x  1  100  y  2   0 2) 11x  100 y  0
3) 11 x  2   100  y  1  0 4) 11 x  1  100 y  0
67. Let R be a relation on , given by R  {( a, b ):3a  3b  7 is an irrational number}. Then
R is
1) Reflexive but neither symmetric nor transitive
2) Reflexive and transitive but not symmetric
3) Reflexive and symmetric but not transitive
4) An equivalence relation
68. In a group of 100 persons 75 speak English and 40 speak Hindi. Each person speaks at least
one of the two languages. If the number of persons who speak only English is  and the
Number of persons who speaks only Hindi is , then the eccentricity of the conic
25(2 x 2   2 y 2 )   22 is
1) 15/13 2) 12/11 3) 14/13 4) 13/12
69. Let the relations R1 and R2 on the set X  1, 2, 3,..., 20 be given by R1   x, y  : 2 x  3 y  2
and R2   x, y  : 5 x  4 y  0 If M and N be the minimum number of elements required to be
added in R1 and R2 respectively, in order to make the relations symmetric then length of
x2 y2
latus rectum of   1 is
M 2 N2

16
1) 2) 18 3) 6 4) 8
3
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70. In a town of 10,000 families, it was found that 40% families buy newspaper A, 20% buy
newspaper B and 10% buy newspaper C. Also, 5% families buy newspapers A and B, 3%
buy newspapers B and C and 4% buy newspapers A and C. If 2% families buy all the three
newspapers, then number of families which buy newspaper A only is
1) 3100 2) 3300 3) 2900 4)1400
71. If from a point P representing the complex number z1 on the curve z  2 two tangents are

drawn from P to the curve z  1 meeting at points Q  z2  and R  z3  , then which of the

following is FALSE
1) Complex number  z1  z2  z3  / 3 will be on the curve z  1

 4 1 1  4 1 1 
2)         9
 z1 z2 z3   z1 z2 z3 
z  
3) arg  2  
 z3  3
4) Orthocentre and circumcenter of PQR will coincide
S3n  Sn1
72. If S n denotes the sum of first n terms of an A.P and  31 then the value of n is
S2 n  S2 n1
1) 21 2) 15 3) 16 4) 19

73. Let ,  R . If ,  2 are the roots of quadratic equation x2  px  1  0 and  2 ,  is the


r
roots of quadratic equation x2  qx  8  0, then the value of r if is the arithmetic mean of
8
p and q is
1) 83/2 2) 83 3) 83/8 4) 83/4
74. Given a,b,c are in A.P.,b,c,d are in G.P., and c,d,e are in H.P. If a = 2 and e = 18 then the
sum of squares of all possible value of c is _________.
1) 0 2) 72 3) 16 4) 36

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117
1 p
75. Let S   when [.] denotes the greatest integer function and if S  , when p
r 1 2[ r ]  1 q
and q are co-prime the value of p  q is
1) 20 2) 76 3) 19 4) 69
76. Let AB be any chord of the circle x 2  y 2  4 x  4 y  4  0 which subtends an angle of 90º
at the point (2,3), then the locus of the midpoint of AB is circle whose centre is
 5  3  5
1) (1,5) 2)  1,  3)  1,  4)  2, 
 2  2  2
x2 y 2 x2 y2
77. A common tangent T to the curves C1 :   1 and C2 :   1 does not pass
4 9 42 143
through the fourth quadrant. If T touches C1 at  x1 , y1  and C2 at  x2 , y2  , then | 2 x1  x2 | is

equal to ____
1) 10 2) 20 3) 40 4) 60
a3 x2 a 2 x
78. The locus of the vertices of the family of parabolas y    2 a is_____
2 3
105 37 35 35
1) xy  2) xy  3) xy  4) xy 
64 54 52 16
79. Let f  x  be continuously differentiable on the interval  0,  such that f 1  1 , and

t 2 f  x   x2 f t 
lim  1 for each x > 0 , then f  3  is
tx tx
1) 55/9 2) 107/9 3) -1/9 4) 1/3
80. A and B are two non singular matrices such that A5  A1 and AB 2  BA  B  I  .A value of

K so that B K  B 1 is
1) 31 2) 32 3) 62 4) 63

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SRI CHAITANYA IIT ACADEMY, INDIA 16-11-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-14/18_Q.P
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

81. Let f ( x)  x5  2e x /4x  R consider a function g ( x) such that ( gof )( x)  x, x  R, then

1729 g1(2) is

0 

1 k
1  x7 dx 10
1
82. Let P  k k 1
, k  N , then the value of  7  P  1 is
 1  x 
1 7 k 1
dx k
0

83. 
The sum all elements in the set n   : n2  10n  19  6 is _________ 
84. Let 3, 7, 11, 15,....., 403 and 2, 5,8,11... 404 be two arithmetic progressions. Then the sum,
of the common terms in them, is equal to

85. If three successive terms of a G.P. with common ratio r  r  1 are the lengths of the sides of
a triangle and [ r ] denotes the greatest integer less than or equal to r, then 9[ r ]  [ r ] is equal
to:

86. Let the positive integers be written in the form:


1

2 3
4 5 6
7 8 9 10

If the kth row contains exactly k numbers for every natural number k, then the row in which
the number 5350 will be is___________

87. Consider a line L passing through the points P(1,2,1) and Q(2,1,-1). If the mirror image of
the point A(2,2,2) in the line L is  , ,   ,then 5      6 is equal to ____

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88. Let A  2,3,6,7 and B  4,5,6,8 .Let R be a relation defined on A  B by  a1, b1  R  a2 , b2 

if and only if a1  a2  b1  b2 .Then the number of elements in R is_______

89. Let A {1,2,3,4,5}, Let R be a relation on A define by xRy if and only if 4 x  5 y .Let m be
the number of elements in R and n be the minimum number of elements from A  A that are
required to be added to R to make it a symmetric relation. Then m +n is equal to

90. The number of relations, on the set {1,2,3} containing (1,2) and (2,3) which are reflexive
and transitive but not symmetric, is_____

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