SEC: JR_*CO-SC Date: 05-12-21

Time: 3 Hrs Max. Marks: 186

05-12-21_JR.IIT_STAR CO-SC (MODEL-A)_JEE ADV_WAT-30_SYLLABUS
PHYSICS: PRESENTWEEK (80%): Kinetic Theory of gases, gas laws and ideal
gas equation, Specific heat of gases
(Exclude: Q,U,W calculation, First & Second Law)
PREVIOUS WEEK (20%): Heat & Thermodynamics: Definition of
heat, Temperature, Scales of measurement of temperature, Thermal
Expansion of Solids & Liquids, Calorimety.

CHEMISTRY: PRESENTWEEK (80%): optical isomerism conversion of wedge dash,

sahworse newmann formula, optical isomerism chiral molecules
condition for chirality, specific rotation, optical rotation, optical
isomerism RS & DL, optical isomerism Calculation of stereoisomer's,
specific optical rotation
PREVIOUS WEEK (20%): STEREO ISOMERISM: Conformational

isomerism: Conformational isomerism of ethane, butane, derivatives

of ethane and cyclohexane

MATHEMATICS: PRESENTWEEK (80%): Maximum / Minimum values of a function

PREVIOUS WEEK (20%): Introduction Monotonicity, Increasing &
Decreasing functions, Rolle's theorem, Lagrange's mean value
theorem
Narayana IIT Academy 05-12-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-30_Q’P
TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 186

PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 4) Questions with Single Correct Options +3 -1 4 12
One of More Correct Options Type
Sec – II (Q.N : 5 – 12) +4 -1 8 32
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 13 – 18) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +3 0 6 18
27.30)
Total 18 62

CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 19 – 22) Questions with Single Correct Options +3 -1 4 12
One of More Correct Options Type
Sec – II (Q.N : 23 – 30) +4 -1 8 32
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 31 – 36) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +3 0 6 18
127.30)
Total 18 62

MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 37 – 40) Questions with Single Correct Options +3 -1 4 12
One of More Correct Options Type
Sec – II (Q.N : 41 – 48) +4 -1 8 32
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 49 – 54) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +3 0 6 18
127.30)
Total 18 62

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Narayana IIT Academy 05-12-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-30_Q’P
PHYSICS Max.Marks:62
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
1. N molecules each of mass ‘m’ of gas A and 2N molecules each of mass ‘2m’ of gas B
are contained in the same vessel which is maintained at temperature ‘T’. The mean
square velocity of the molecules of B type is denoted by v 2 and the mean square of
2
the x-component of the velocity of A type is denoted by  . Then the ratio 2 is
2

v
equal to

2 1 4
A) B) C) D) 1
3 3 3

2. The pressure of a gas kept in an isothermal container is 200 kPa. If half of the gas is
removed from it, the pressure will be

A) 100 kPa B) 200 kPa C) 400kPa D) 800 kPa

3. A vessel of volume V is evacuated by means of a piston air pump. One piston stroke
captures the volume ΔV. The number of strokes needed to reduce the pressure of the
1
gas in the vessel times is_____ (The process is assumed to take place at constant

temperature, assume ΔV is very small when compared to V)

ln ln ln ln

A) B) C) D)
 V   V   V   V 
ln 1   ln 1   ln 1   ln 1  
 V   2V   2V   V 

4. The temperature of one mole of an ideal gas varies with its volume ‘V’ according to
the equation T  T0   V 2 , where T0 and  are positive constants. The minimum
attainable pressure of the gas in this process is (R is universal gas constant)

R
A) 3R  T0 B) 2R  T0 C) R  T0 D)  T0
2

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Narayana IIT Academy 05-12-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-30_Q’P
SECTION – II
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -1 in all other cases.
5. A container holds 1026 molecules/m3, each of mass 3×10-27kg. Assume that 1/6th of the
molecules moves with velocity 2000ms-1 directly towards one wall of the container
while the remaining 5/6th of the molecules move either away from the wall or in
perpendicular direction and all the collisions made by the molecules with the walls of
the container are elastic. Then
1
A) Number of molecules hitting 1m2 of the wall every second is  1029
3
B) Number of molecules hitting 1m2 of the wall every second is 2  1029
C) Pressure exerted on the wall by molecules is 24  105 Nm 2
D) Pressure exerted on the wall by molecules is 4  105 Nm 2
6. A diathermic piston of mass M cross section area A separate the volume inside a
horizontal thermally insulated cylinder of length 2 0 into two equal parts. Each
chamber contains an ideal gas and pressure on each side is P. The piston can move
without friction and is attached with a spring of spring constant ‘K’ as shown. Initially
the piston is non-deformed. The piston is given a small displacement ‘x’ towards left.
Then

0 0

A) The pressure in the left chamber increases just after the displacement of the piston

B) The pressure in the right chamber decreases just after the displacement of the
piston
M 0
C) The piston oscillates with a time period 2
2PA   0 K

M 0
D) The piston oscillates with a time period 2
PA   0 K

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Narayana IIT Academy 05-12-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-30_Q’P
P2
7. During an experiment an ideal gas is found to obey a condition  constant , where ρ

is the density of the gas and P is its pressure. The gas is initially at temperature T,

pressure P and density  . The gas expands such that density changes to then
2

A) The pressure of the gas changes to 2P

B) The temperature of the gas changes to 2T

C) The graph of the above process on the P-T diagram is a parabola

D) The graph of the above process on the P-T diagram is a hyperbola

8. A light container having a diatomic gas enclosed with in, is moving with velocity .
Mass of the gas is ‘m’, number of moles is ‘n’. Then choose the correct options of the
following
3
A) KE of the gas with respect to centre of mass of the system is nRT
2
5
B) KE of the gas with respect to centre of mass of the system is nRT
2
5
C) KE of the gas with respect to the ground is nRT
2
5
D) KE of the gas with respect to the ground is greater than nRT
2
9. A cubical box of side 5m contains helium gas at a pressure 320Nm–2. During an
observation time 1second an atom travelling with rms speed parallel to one of the
sides of the cube was found to make 1000 hits with a particular wall without any
collision with the other atoms. (Given R=25/3 SI units). Then

A) The temperature of the gas is 16  103 K

B) The temperature of the gas is 8  103 K

C) The total mass of the helium gas in the box is 1.2 gram

D) The total mass of the helium gas in the box is 2.4 gram

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Narayana IIT Academy 05-12-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-30_Q’P
10. An ideal monoatomic gas undergoes a process in which P  3V 3 where P is pressure
and V is volume of the gas. Then

A) If volume increases then the temperature of the gas will also increase

B) If the temperature of the gas decreases, then pressure of the gas must also decrease

C) In order to increase the volume of the gas heat has to be supplied to gas

D) In order to increase the volume of the gas heat has to be removed from the gas

11. Two ideal gases A and B are kept in a closed container at room temperature. Consider
collisions take place between the molecules of A and B. Let K 'A and K 'B are the kinetic

energies of molecules A and B respectively after the collision and K A and K B are the
kinetic energies of molecules A and B respectively before collision. Then

A) If K A > K 'B then K B  K 'B B) If K A < K 'A then K B  K 'B

C) If K A > K 'A then K B  K 'B D) If K A < K 'A then K B  K 'B

12. A partition divides a container having insulated walls into two compartments I and II.
The same gas fills the two compartments whose initial parameters are as shown. The
partition is a conducting wall which can move freely without friction. Then pick out
the correct statements of the following with reference to the final equilibrium position

A) The pressures in the two compartments will be equal

B) Volume of compartment I is 3V/5

C) Volume of compartment II is 12V/5

D) Final pressure in the compartment I is 5P/3

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Narayana IIT Academy 05-12-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-30_Q’P
SECTION – III
(NUMERICAL VALUE ANSWER TYPE )
This section contains 6 questions. The answer to each question is a Numerical values comprising of positive
or negative decimal numbers (place value ranging from Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme : +3 for correct answer, 0 in all other cases.
13. A vertical cylinder closed from both the ends is equipped with a piston that can move
without friction dividing the volume into two parts. Each part contains one mole of air.
In equilibrium at T0  300K the volume of the upper part is   4 times the lower
part. Find the temperature (in kilo K) at which the volume of the upper part will be
  3 times the lower part?

14. A glass tube which is closed at one end is completely submerged with open end
downwards in a vessel of mercury so that air column of = 10 trapped in the tube.
To what height (in cm) must the upper end of the tube be raised above the level of
mercury in the vessel so that the level of the mercury in the tube coincides with that in
the vessel? (Round off the answer to second decimal, given the temperature of the gas
is constant and equal to 270C, area of the cross section of the tube is 1cm2,
atmospheric pressure 76cm of Hg or 1.013 × 10 and molecular weight of air is
29)

15. A horizontal cylinder closed from one end is rotated with constant angular velocity ω
about a vertical axis passing through the open end of the cylinder. The outside air
pressure and temperature are respectively P0 and T, the molar mass of air is M. The air
pressure as a function of the distance from the rotation axis is found out to be
1.25M 2 r 2
P0 e zRT
. Find the value of ?

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Narayana IIT Academy 05-12-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-30_Q’P
16. An ideal gas is kept in a long cylindrical vessel fitted with a frictionless piston of
cross-sectional area 10cm2 and weight 1kg as shown in the figure. The vessel itself is
kept in a big chamber containing air at atmospheric pressure 100kPa. The length of the
gas column is 20cm. If the chamber is now completely evacuated by an exhaust pump
what will be the length (in meters) of the gas column? (Assume the temperature of the
gas is constant throughout the process)

17. The following figure shows a cylindrical tube of length 30cm which is partitioned by a
tight -fitting separator. The separator is very weakly conducting and can freely slide
along the tube. Ideal gases are filled in the two parts of the vessel. In the beginning,
the temperatures in the parts A and B are 400K and 100K respectively. The separator
slides to a momentary equilibrium position shown in the figure. When the system
attains final equilibrium find the length (in cm) of the gas in the part A?

18. The variation of density (ρ) with temperature (T) of an ideal gas of molecular mass
(M) at constant pressure is plotted as shown in the figure. The pressure of the gas at
RT 2
state P is . Find the value of ‘z’? (Round off the answer to two decimals)
zM

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Narayana IIT Academy 05-12-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-30_Q’P
CHEMISTRY Max.Marks:62
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
19. Among the following, the most stable conformation of meso – 2, 3 – dibromobutane is

A) B)

C) D)

20. Among the following compounds, the pair of enantiomers is

A) I and IV B) I and III C) II and III D) III and IV

21. The optically active stereoisomer of the following compound is

A) B)

C) D)

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Narayana IIT Academy 05-12-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-30_Q’P
22. The structure of D-galactose is
CHO
H OH
HO H
HO H
H OH

CH2OH
Which one of these structures is L – galactose?

A) B)

C) D)

SECTION – II
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -1 in all other cases.
23. The diastereomeric pair(s) among the following option(s) is/are.

A) B)

C) D)

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Narayana IIT Academy 05-12-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-30_Q’P
24. Which of the following structure/s will show optical isomerism?

A) B)

C) D)

25. The correct statement (s) about the compound given below is (are)

A) The compound is optically active

B) The compound possesses centre is symmetry

C) The compound possesses plane of symmetry

D) The compound possesses axis of symmetry

26. In which structure/s Gauche form has less potential energy than antiform

A) B)

C) D)

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Narayana IIT Academy 05-12-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-30_Q’P
27. Which conformer(s) of butane is (are) chiral in the given form?

A) B)

C) D)

28. Which of the following compound can show geometrical isomerism as well as optical
isomerism?

A) B)

C) D)

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Narayana IIT Academy 05-12-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-30_Q’P
29. The incorrect sequence of relationship between the compounds of the following pairs
I-IV is

I) II)

III) IV)

A) Identical, enantiomers, diastereomers and structural isomers

B) enantiomers, identical, structural isomers and diastereomers

C) enantiomers, identical, diastereomers and structural isomers

D) identical, identical, diastereomers and structural isomers

30. Which of the following is/are optically active compound?

A) B)

C) D)

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Narayana IIT Academy 05-12-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-30_Q’P
SECTION – III
(NUMERICAL VALUE ANSWER TYPE )
This section contains 6 questions. The answer to each question is a Numerical values comprising of positive
or negative decimal numbers (place value ranging from Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme : +3 for correct answer, 0 in all other cases.
31. How many meso isomers are possible for the given structure?

Cl Cl
| |
CH 3  CH  CH  CH  CH  CH 3

32. How many diastereomers are possible for the given molecule?

33. How many stereoisomers are possible for the following compound?

34. The total number of pair of enantiomers possible with molecular formula C5 H12O is __.
35. Find the total number of configurational isomers of 1, 2-Dibromo – 3 – chlorocyclo
propane.
36. The number of optical isomers of camphor is __________

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Narayana IIT Academy 05-12-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-30_Q’P
MATHEMATICS Max.Marks:62
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
1 1 6
37. If maximum value of the function y   is , then its value at point of
1 x 1 x  a 5
local minima is
1 2
A) B) 1 C) D) 0
3 3
1
38. The function f  x   ln x  2x  x 2 , x  0 attains local maximum at x =
8
2 3 2 3 2 3 2 3
A) B) C) D)
2 2 4 4
6
 1  6 1 
 x     x  6   2
x 
If f  x   then absolute minimum value of f  x  in its
x
39. 3
 1  3 1 
 x     x  3 
x x
domain is
A) 3 B) 9 C) 12 D) 6
40. If f  x   2x 3  9ax 2  12a 2 x  1 (a  0) has local maximum at x1 and local minimum at
x 2 and if x12  x 2 , then value of a is:
1
A) 1 B) C) -1 D) 2
2
SECTION – II
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -1 in all other cases.
 x   x 1
41. Let f  x    x 1 x , where  x   greatest integer function and  x 
1  x   x
fractional part of x. Then which of the following is/are correct ?

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Narayana IIT Academy 05-12-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-30_Q’P
A) f  x   0 for x  (, 1]

B) f  x  has no real root for x  0,1

C) for x [0,1) , range of f  x  is (-2,-1]

D) for x [1,2),f  x  has exactly one local minima

ex
42. Let f  x   and g  x   f ' x  then
1  x2
A) g  x  has two local maxima and two local minima points
B) g(x) has exactly one local maxima and one local minima point
C) x =1 is a point of local maxima for g(x)

D) there is a point of local maxima for g(x) in the interval (-1,0)


 x 3  x 2  10x; 1  x  0

 
43. Let f  x    sin x; 0x then f(x) has
 2
 
 1  cos x; x
2
 
A) local maximum at x  B) local minimum at x 
2 2
C) absolute maximum at x = 0 D) absolute maximum at x = -1
44. Let f : R   0,  and g : R  R be twice differentiable functions such that f '' and g ''

are continuous functions on R. Suppose f ' 2  g  2  0 , f ''  2   0and g ''  2   0 . If

f  x g  x
lim  1 , then
x2 f ' x  g ' x 

A) f has local maximum at x = 2

B) f has local minimum at x = 2

C) f has neither maximum nor minimum at x = 2

D) f ( x)  f '' ( x)  0 for atleast one x  R

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Narayana IIT Academy 05-12-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-30_Q’P
 x2 
45.  
If   x   3f    f 3  x 2 , x  3,4 where f '' x   0, x  3,4 , then   x  is
 3

3   3 
A) increasing in  ,4 B) decreasing in  3, 
2   2

 3   3
C) increasing in  ,0 D) decreasing in  0, 
 2   2

46. Which of the following statement(s) is/are correct for f  x   x1/3  x  1 , x  R

1
A) has two points of inflection B) is strictly increasing for x 
4

 1  3
C) is concave down in   ,0 D) minimum value of f(x) is
 2  44/3

Let f  x    x 2  1  x 2  x  1 ,n  N then f  x  has local extremum at x  1, when

n
47.

A) n  2 B) n  3 C) n  4 D) n  6

   
48.
 2 2
 
Let the function g :  ,     ,  be given by g  u   2 tan 1 e u  . Then which
2

of the following statements is/are TRUE ?

A) g (u )  g (u ) u  R

B) g (u )   g (u ) u  R

C) g (u ) is strictly increasing in  , 

D) g (u ) is strictly decreasing in  , 

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Narayana IIT Academy 05-12-21_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-30_Q’P
SECTION – III
(NUMERICAL VALUE ANSWER TYPE )
This section contains 6 questions. The answer to each question is a Numerical values comprising of positive
or negative decimal numbers (place value ranging from Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme : +3 for correct answer, 0 in all other cases.
k
49. The function f ( x)  2 x  x  2  x  2  2 x has a local maximum at x  k then =
2

   
2 3
50. If f  x   4  x2  3  4  x 2  1 , then absolute maximum value of f  x  for all

N
permissible values of x is N then 
5

51. Let p( x) be a real polynomial of least degree which has a local maximum at x=1 and a
local minimum at x=3 . If p(1)  6 and p(3)  2 then p ' (0) is

52. Let A(1, 1) , B(4, 2) and C (9,3) be the vertices of the triangle ABC . A parallelogram
AFDE is drawn with the vertices D, E and F on the line segments BC , CA and AB

respectively, then the maximum area of the parallelogram AFDE is

53. One corner of a long rectangular sheet of paper of width 1 unit is folded over so as to

reach the opposite edge of the sheet, then the value of

 minimum length of crease formed 
3

54. A cylindrical container is to be made from certain solid material with following
constraints. It has a fixed inner volume of V mm3, has a 2mm thick solid wall and is
open at the top. The bottom of the container is a solid circular disc of thickness 2 mm
and is of radius equal to the outer radius of the container. If the volume of the material
used to make the container is minimum when the inner radius of the container is 10
V
mm then the value of is
250

Jr.IIT_*CO SC Page No: 18