Lodhi Tutorials

Date : 09-11-2024 STD 11 Science Chemistry Total Marks : 25

Time : 1 Hour Organic

* Choose The Right Answer From The Given Options.[1 Marks Each] [6]

1. What is the correct IUPAC name of the following?

(A) 3-ethyl-1,1-dimethylcyclohexane. (B) 1-ethyl-3,3-dimethylcyclohexane.

(C) 1,1-dimethyl-3-ethylcyclohexane. (D) None of the above.

SIR
Ans. :
a. 3-ethyl-1,1-dimethylcyclohexane.
Explanation:
The correct IUPAC name of the following structure is
SH
EE

2. Hyperconjugation involves delocalisation of ___________.

(A) Electrons of carbon-hydrogen σ bond of an alkyl group directly attached to an
JN

atom of unsaturated system.

(B) Electrons of carbon-hydrogen σ bond of alkyl group directly attached to the
RA

positively charged carbon atom.

(C) π-Electrons of carbon-carbon bond.
(D) Lone pair of electrons.
Ans. :
a. Electrons of carbon-hydrogen σ bond of an alkyl group directly attached
to an atom of unsaturated system.
b. Electrons of carbon-hydrogen σ bond of alkyl group directly attached to
the positively charged carbon atom.
Explanation:
Hyperconjugation, also known as sigma-pi conjugation, is the delocalization of sigma
electrons. Presence of -H with respect to double bond, triple bond or carbon

Page 1
 containing positive charge (in carbonium ion) or unpaired electron (in free radical) is
a condition required for hyperconjugation.
H H H
⊕
| H | |

⊖ ⊖
⊕
H − C − CH = CH2 ↔ H − C = CH− C H2 ↔ H C = CH− C H2 ↔ H

− C − CH− C H2

| |

⊕
| H

H H H

3. The correct way(s) of representing 2-bromobutane is/ are:

(A) CH3CHBrCH2CH3

SIR
(B)

SH
(C)
EE

(D) All of the above

JN

Ans. :
d. All of the above
4. Homologous series is____________.
RA

(A) A series of compounds in which the same functional group substitutes for
hydrogen in a carbon chain.
(B) A series of compounds in which different functional group substitutes for
hydrogen in a carbon chain.
(C) A series of compounds with same molecular formula and different structural
formulae.
(D) A series of compounds with same molecular formula but different functional
groups.

Ans. :
a. A series of compounds in which the same functional group substitutes
for hydrogen in a carbon chain.

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 Explanation:
Homologous series is a series of compounds in which the same functional group
substitutes for hydrogen in a carbon chain. The chemical properties of the
compounds are very similar.
Example of a homologous series: CH 3​OH,C2 ​H 5​OH,C3 ​H 7 ​OH,C4 ​H 9 ​OH.

5. Covalent bond can undergo fission in two different ways. The correct
representation involving a heterolytic fission of CH3—Br is:
(A) (B)

(C) (D)

SIR
Ans. :
b.
SH
Explanation:
Arrow denotes the direction of movement of electrons
EE

Since, Br is more electronegative than carbon, hence heterolytic fission occurs in

JN

such a.

6. The bond that consist of an upper and a lower sharing of electron orbitals is
RA

called as:
(A) A pi bond (B) A sigma bond
(C) A hydrogen bond (D) An ionic bond

Ans. :
a. A pi bond
Explanation:
The bond that consist of an upper and a lower sharing of electron orbitals is called as
a pi bond.
A pi bond is formed by lateral (side ways) overlap.
For example, two 2pz​ orbitals of two C atoms laterally overlap to for pi bond in
ethene CH 2 ​= CH 2​.

Page 3
 [10]
* Given Section consists of questions of 2 marks each.

7. Write the product of the following reactions:

i.

AlCl 3

ii. CH3 − CH2 − CH2 − CH3 −−−→

Δ

Ans. :
i.

SIR
AlCl 3

ii. CH3 − CH2 − CH2 − CH3 −−−→ CH3 − CH − CH3

Δ

CH3
SH
8. Classify each of the following carbon intermediates:
i. (CH3 )C
∙

ii. CH3 − C H − CH3

EE

iii. CH2 = CH− C H2

iv. : CCl2
JN

Ans. :
i. Free radical.
ii. Carbanion.
RA

iii. Carbocation.
iv. Carbene.
9. Give IUPAC names of the following structures.
i.

ii.

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 iii.

iv.

SIR
SH
Ans. :
i. 4-ethyl-3-propylhept-1-ene.
ii. 3-chloro-4-cyclopropyl-1,2 cyclobutandiol.
iii. Butan-2, 3-diol.
EE

10. Write all the possible isomers of aromatic compound C8H10.

Ans. :
JN
RA

11. Name the compounds whose line formulae are given below:
 Ans. :

* Given Section consists of questions of 3 marks each. [9]

SIR
12. i. Draw cis and trans-structures for Hex-2-ene. Which isomer will have
higher boiling point and why?
ii.
SH
Ans. :
i.
EE
JN

cis-Hex-2-ene has higher dipole moment and therefore, it has higher boiling point.
ii.
RA

is not aromatic, Due to the presence of sp3

carbon (carbon 3), the system is not planar, Futher, it contains only four n electsons.
Hence, it is not aromatic because it does not contain planar delocalised cloud with
(4n + 2)π electrons.

13. i. Write IUPAC name of the following:

 ii. CH2 CH2 CHO and CH3 C − CH3

||

iii. Draw the structure of 3-oxopentanal.

Ans. :
i.

ii. Functional isomerism.

iii. O

CH3 − CH2 − C − CH2 − C − H

SIR
∥

is structive of 3-oxo pentanal.

14. i. Write IUPAC name of the following:

SH
CH3 CHCH ≡ CH

CH = CH2

ii. Draw the structure of Pent-4-en-2-ol.

EE

iii. What is nucleophile? Give one example.

Ans. :
JN

3 4 5

i. CH, − CH − CH≡CH

CH = CH2
RA

2 1

3-methyl pent-1-en-4yne

1 2 3 4 5

ii. CH3 − CH − CH − CH=CH2

OH

iii. Nucleophile is a species which is either negatively charged or has lone

pair of electron.
----- All the best -----