Simona Ag Muovien Liimaus Opas Englanniksi
Simona Ag Muovien Liimaus Opas Englanniksi
info
Gluing
1 General 3
1.1 Definition of terms 3
1.2 Basics 4
1.3 Classification of adhesives 5
2 Setting mechanisms 7
2.1 Adhesion bonding 7
2.2 Diffusion bonding 7
3 Pretreatment 8
6 Safety measures 11
SIMONA worldwide 20
0 = cannot be glued, or difficult to glue and only after pretreatment, + = gluable, ++ = easy to glue
Epoxy resins
Rubbers
Acrylics
Polyurethanes
MS polymers/hybrid
Silicones
Elongation at break %
Figure 1: Relative classification of material properties of adhesives from the category of chemically setting adhesives
Water-based glue
Water-based glue is an adhesive dissolved in water and of
vegetable, animal or synthetic origin. The bond strength
required is only achieved if, during the setting process, water
is withdrawn from the glued joint by at least one of the parts
being joined.
Hot-melt adhesives
Hot-melt adhesives are mainly thermoplastics. To make them
adhere, they are melted and allowed to set by cooling down. If
the adhesive is reheated, it melts again.
Adhesive tapes
There are always two types available:
1. Base tapes/films coated with adhesive on one side or
both sides
2. Tapes with adhesive continuously integrated
The setting of adhesives is based either on physical processes 2.2 Diffusion bonding
or on chemical reactions.
In diffusion bonding, solvent molecules migrate into the
Physical processes: plastic and by means of swelling and dissolving effects they
Evaporation of solvents (in the case of solvent adhesives cause molecular movements that bring about connections
and contact adhesives) similar to welded joints. Owing to the modification of molec-
Release of water (in the case of water-based glues) ular structure, the mechanical properties may change, pos-
Solidification of a melt (in the case of hot-melt adhesives) sibly accompanied by stress cracking. The adhesive zone, i. e.
the glued part, can only be subjected to mechanical loads
Chemical reactions: when the solvents have completely evaporated from it.
Polymerisation (in the case of polyester resins, PMMA)
Polyaddition (in the case of epoxy resins, polyurethanes)
Polycondensation (in the case of phenolic resins, urea
resins and formaldehyde resins)
Adhesion zone
Transition zone
Adhesive
Cohesion zone
Transition zone
Adhesion zone
Thermal method
Burning off the surface with a gas flame in conjunction with
atmospheric oxygen (oxidisation of the surface) is a method
that is ideal for PE-HD, for example.
Double overlaps produce firm bonds at low cost. The target should be wall
thickness ratios of 1:2:1 for reasons of cost-effectiveness.
In the case of a straight flush (stepped) overlap the levels of seam strength are
inadequate and the cost of preparation is high.
A straight flush double butt strap joint requires considerable effort whilst seam
preparation has to be precise.
The butt joint can scarcely transfer forces because the area to be glued is
small. Only suitable in exceptional cases.
With parts subject to torsion (pipe connections), adhesive bonds with large are-
as are exposed to loads uniformly. High levels of strength can be expected.
Connection to be recommended
Not to be recommended
Connection to be recommended
Not to be recommended
Connection to be recommended
F
F
The following information is intentionally of a general nature and 10.2 SIMONA® PVC (rigid and foamed PVC)
is based on basic information from adhesive manufacturers and
our own experiments. This list is not exhaustive and does not PVCs can be joined to one another by means of diffusion bond-
provide any guarantee of successful adhesive bonding in a par- ing with solvent adhesives. Prior cleaning should be performed
ticular application. In all cases, the information and instructions with special cleaning agents or methylene chloride.
for use provided by the adhesive manufacturers must be com-
plied with. Examples:
Tangit PVC-U (Henkel, Düsseldorf)
The PVC-based adhesive with tetrahydrofuran as solvent is
10.1 SIMONA® PE and PP particularly suitable for non-positive connection of pres-
sure pipes. According to information from the adhesive
Without any backing it is difficult to make a non-positive con- manufacturer, this adhesive should not be used for adhe-
nection between these two groups of materials. To accomplish sive bonds between pipes that convey the following acids:
adhesive bonding between materials or with other materials, Sulphuric acid above 70 %
it is essential to conduct thorough preparation by means of Hydrochloric acid above 25 %
long-pile roughening or thermal, chemical or electrical pretreat- Nitric acid above 20 %
ment. However, there are also adhesives available that have Hydrofluoric acid any concentration
been specially developed for low-energy surfaces. Tangit Dytex (Henkel, Düsseldorf)
Its basis is post-chlorinated PVC, dissolved in methylene
Examples: chloride (under certain conditions also suitable for bonding
Acrylic-based 2-component structural adhesive, e. g. 3M™ PVC to other materials such as wood and concrete).
Scotch-Weld™ DP 8005 or WEICON Easy-Mix PE-PP 45. However, for bonding PVC to other materials 2-component
systems or contact adhesives should always be used.
Far better results can be achieved with surfaces that have COSMOFEN PLUS white (Weiss, Haiger)
one-sided backing where, for example, the stretch fabric is This solvent adhesive is dyed white. Among other things, it
pressed into the plastic (SIMONA® PP-H AlphaPlus® -SK). can be used as an adhesive for SIMONA® COPLAST-AS and
Composite structures are particularly important. They exploit as an edge sealant.
the high chemical and thermal resistance of thermoplastics,
combine it with the strength of other materials and make a
major contribution towards improving cost-effectiveness. The 10.3 SIMONA® CPVC
main fields of application involved are laboratory construction,
composite tank construction and interior linings. CPVCs can also be joined to one another by diffusion bonding
with solvent adhesives. Prior cleaning should be performed
From the range of 2-component adhesives the following are with special cleaning agents or methylene chloride. As
available for these uses: opposed to rigid PVC adhesives, a different solvent mixture is
PUR-forming adhesives, e. g. Icema R 101 with hardener 7 normally used in which CPVC is dissolved instead of PVC-U.
(H.B. Fuller GmbH, Munich)
Epoxy resin adhesives, e. g. Araldite (Huntsman, Salt Lake Example:
City (USA)), or WEVOPOX (Wevo-Chemie, Ostfildern-Kemnat) Tangit PVC-C (Henkel, Düsseldorf)
Polyester resins, e. g. Palatal (DSM Coating Resins, PVC-based CPVC adhesive with tetrahydrofuran and
Augusta (USA)) butanone as the principal constituents is especially suit
able for hot-water applications and for use with corrosive
media at high temperatures so it is used for plant con-
struction in the chemical and metal industries (e. g. hot
water, waste acids).
Solvent mixtures have proved successful for gluing SIMOLUX It is possible to glue SIMOWOOD. Owing to the large number of
products, e. g.: different adhesives and their options for bonding to various
42 % methyl ethyl ketone (MEK) + 42 % trichloroethylene + material surfaces, we recommend performing tests before-
16 % methylene chloride hand. Good results are to be expected with various makes of
85 % methylene chloride + 12 % trichloroethylene + 3 % adhesive that are suitable for rigid plastics (rigid PVC / PVC-U).
MEK These include, for example, STPU (Hybrid) and 1K- and 2K-PU /
90 % chloromethane + 10 % acetic acid PUR adhesives as well as polyester resins and epoxy resins.
For many adhesives it is also advisable to pretreat the sub-
By dissolving approx. 10 % SIMOLUX shavings in the solvent strate using a cleaning agent or primer.
the evaporation rate of the solvent adhesive can be substan-
tially reduced. In particular this leads to longer fixation times For gluing SIMOWOOD to various substrates we have been
for adhesive bonds over large surfaces. In addition, the risk of able to achieve good short-term results and good adhesion
white discoloration in the adhesive zone is reduced consider properties on, for example, SIMOWOOD, gypsum, concrete,
ably. PVC-U, steel, aluminium, tiles, wood and GRP. For other mate-
rial combinations, please consult your adhesive manufacturer
SIMOLUX products can also be joined using most commercial- or contact our Technical Service Centre ([email protected]).
ly available polyester adhesives and double-sided adhesive
tapes. In addition to information in the manufacturers' technical data-
sheets, the following points should be observed in adhesive
bonding, depending on the field of application:
10.5 SIMONA® PVDF, ECTFE and PFA Adhesive bonding before assembly
Application of pressure to the adhesive seam
Without backing: fluorinated plastics such as PVDF can only Hydrolysis resistance of the adhesive
be bonded with considerable cost and labour. One option is Application temperature
adhesion bonding with epoxy resin-based or cyanoacrylate- Pot life
based 2-component reaction adhesives. It is absolutely essen- Adhesive layer thickness
tial to pretreat the surfaces. For adhesive bonds with partially Clean surface devoid of dust and grease
fluorinated or fully fluorinated plastics it is explicitly advisable Priming and substrate pretreatment (e. g. roughening)
to perform a test and consult the adhesive manufacturer.
We are in close contact with other well-known adhesive manu-
With backing: The same systems can be used as those speci- facturers; this allows us to expand and verify our state of
fied for SIMONA® PP. If high temperatures occur (approx. 90°C knowledge about the adhesive bonding of SIMOWOOD. For
to 120°C), epoxy resins are preferable. other processing instructions and adhesive suggestions,
please refer to the tech.info SIMOWOOD made of Resysta®.
SIMONA® PE-HD / SIMONA® PVC- SIMONA® CPVC SIMOWOOD SIMOLUX / SIMOLIFE EVA
SIMONA® PE 100 / CAW / SIMONA® Corzan Industrial SIMOLIFE PETG
SIMONA® PP-H PVC-MZ COLOR / Grade
AlphaPlus®/ SIMONA®
SIMONA® PP-H COPLAST /
SIMOPOR
3MTM Scotch-WeldTM DP 8005 (3M) x
3MTM Scotch-WeldTM DP 8010 (3M) x
Easy-Mix PE-PP 45 (WEICON) x
Tangit PVC-U (Henkel) x x
Tangit PVC-C (Henkel) x
Tangit Dytex (Henkel) x x x
COSMOFEN PLUS weiß (Weiss) x x
COSMOFEN PLUS HV (Weiss) x
MR-AP 35, MR-AP 49 (Lorenz) x
Agomet F 347 (Huntsman) x x
ACRIFIX® 2R 1900 (Evonik) x
(for transparent adhesive bonds)
Dymax MD® 191-M (Dymax) x
(for the medical sector)
Dymax Ultra Light-Weld® 3094 x
(Dymax)
VHBTM Tape 4941 (3M) x x
ASXplus 7078 (tesa) x x
Siemapren 1309/60 (SIEMA) x
For other adhesive suggestions, please refer to the tech.info SIMOWOOD made of Resysta®.
Depending on the particular field of application, it is absolutely essential to obtain manufacturers' information and approvals.
Upon publication of a new edition all previous editions shall Our applied technical advice is given according to our best
become void. The authoritative version of this publication can knowledge and is based on the information you have provided
be found on our website at www.simona.de. and the state of the art known to us at the time such advice is
furnished. The advice shall not constitute a guarantee or war-
All information furnished in this publication reflects our cur- ranty of specific characteristics or qualities and shall not
rent scope of knowledge on the date of publication and is establish an independent contractual legal relationship.
designed to provide details of our products and potential
fields of application (errors and omissions excepted, including We shall only be liable for cases of intent or gross negligence.
typographical mistakes). This shall not be deemed as consti- Under no circumstances shall we be held liable for the correct-
tuting the provision of legally binding guarantees or warranties ness or completeness of information you have provided or the
as to specific properties of the products or their suitability for advisory/consulting services rendered by us on the basis of
specific areas of application. such information. Any information provided by us shall not
release you from your obligation to conduct your own assess-
We provide warranty for the faultless quality of our products ments and evaluations.
solely within the framework of our Standard Terms and
Conditions of Business and only within the scope specified We reserve the right to update information without notice as
therein. part of our continuous research and development programme.
We shall assume no liability for the application, utilisation, Our staff at the Technical Service Centre and Customer
processing or other use of this information or of our products. Service will be pleased to advise you on the processing and
Furthermore, we shall assume no liability for any consequenc- use of semi-finished thermoplastic products and the availabili-
es related thereto. The purchaser is obliged to examine the ty of our products.
quality and properties of these products; he shall be responsi-
ble in full for selecting, applying, utilising and processing said Technical Service Center
products as well as applying any information relating thereto, Phone +49 (0) 67 52 14-587
which shall also include all consequences associated with [email protected]
such actions. Third-party property rights shall be observed
accordingly. Customer Service
Phone +49 (0) 67 52 14-926
[email protected]
Upon publication of a new edition all previous editions shall become void. The authoritative version of this publication can be found on our website at www.simona.de.
All information furnished in this publication reflects our current scope of knowledge on the date of publication and is designed to provide details of our products and potential
fields of application (errors and omissions excepted, including typographical mistakes).
work.info – Gluing 08/2017 21
SIMONA AG
Teichweg 16
55606 Kirn
Germany