3 CHM. 112 CONTINUOS ASSESSMENT QUESTIONS | Gas Laws 1,__ When do gas laws of Boyle, Charles and Gay Lussac break down? ~The lero of Bj, Charbes anc} ) Gay Lusac. breaks cfoun ot hugh Prodsure a low tenn pesatiers Dey; 16 got ©, and 28 g of Nz exert a pressure of 20 Nm? in an enclosed volume of 10 dm®. Calculate the pressure of oxygen. flass @ O02 = iby bo, = X03% Py é : of Numdoeco onstes Os B06 rere Pr = ble Xoo [lst meg mole = Wo toy, Cs Are oS HENS mes 6-6 Taras presvure, pre dom —— 2.0 g of an organic compound was vaporized at 150 °C in a container of volume dm?, If the pressure of the vapour is 0.2 atm, calculate the molecular weight. R = 0,082 atm.Mol* deg* ciples 9 Ms Ixo-082 x 423 Perepette tse'ct 9-7 Se 23K OLX O05 kee ae Contuiac= 0-95 enile Predbure op Unpouc= o-datin Me (BER Eglin rfren Poe Pi PM tal Me lab fy 3. 0.25happen to the volume of one mole of an ideal gas when the pressure is by a factor of four at constant temperature? [eS tomes PNt= Pa mer ts trobword by & faetor ef for Poe Pye Ne | ory Nr Pr Jrthe Rlabama yt wrerea ne by x faetar of fore 28 g of Nz gas and 80 g of O> gas at 27°C were mixed in an 8 litres container. Calculate the total pressure. R = 0,082 L.atm.mol"K? (0 = 16,N = 14). From Leet presto Pre BE (93) Pi = 90820300, 3-5 % > 6s *8. Nit 4 t Noe 9.5eb= 9-s8ded From Cho Lows Ne be Calculate the ratio of the effusion of helium and methane (He = 4, C= 12, H = 1) Lea Rie 2 9 Peery Pies Remy = 221 A sample of sulphur hexafluoride gas occupies a volume of 5.00 L at 198°C. Assuming the pressure is constant, what wil volume is decreased to 2.50L? S-wol — (gC ll be the final temperature in °C if the ~ Mh Ta NOY . PEON, 99% ves sf 9. Calculate the molecular weight of a substanc: ‘e whose density is 4.85 g/L at 99°C and 0.964 atm. (R = 0.0821 L.atm/K.mol) or 8.3143 molk?, Mz Me cheavty, d= 45510 alirular trerfuc = TSETI GU Bs Prdruce -0-164aD, es ten Fy= pS. =F = 372K Aka = HASKO-OFD [x 37L ~oteg 28344 3Real Gases e and —--- of : AY : The ‘a’ and "bh! jn van der Waal's equation are related to th or fee fain Von dhe Waals im —> Athactons poled Ww Ven dec Maelh rqustin — Excbsted Molar per tele ot 2. The pressure of a gas calculated assuming ideal gas behavior is ------- than that calculated using van der Waals equation due to ——-~-~ between the molecules. ing Tatot goo 6 behauary The peters ees codoraket assuming hs Healer thad frat Coleatated tring ton yc |nlacts eqtatton cle Altra fos factivun fia eelinilst 3, Calculate the pressure (ideal) and pressure (van der Waals) for 0.580 kg Cl gas held’ ina 15.0L container at 200°C (a= 6.49 atm. Umol®, b = 0.0562 L mol?, MAS = o-S¢0kq = Sk9 > POL Mad ter (taats: N plume = [5.0b-> 15d een Nan dre bbnals equsters “emperstine = deviet 973 = 473K (pamx)(v-nb) 2007 where ns Sf m 1 p tual): nin, SEG frm a ae preclestecsty) (is-8 169k 9-0 563) 15 m7 a £Y.L69x0-0F2x 475. Spon mente +495) (1454)> 316543 “i fe2-)2atm | 14: SHp t 27. 98ts = 3c 843 4 4S PH 300-54 5-97-9849 5- e Pp ISS & S35 Te5y tPF F928 Jatin puts =Kinetic Molecular Theory State five Roaster Bie tiieie molecular theory thre ae fore gf stration bejwun gaa menos ; ) Angas B Conrposet pitas tray and tdentiiat melevebss Thset ot ritstutt F ee me teen E 7 Ve datrrage Rais 0 ay bp tonal ten of Me Oroleseteres Sapp praltentss ove tn A ancl Conttane mation, Collrsbriy ely di y) Wee cabissins Blo ger moliutes core Penfeatty plastid ulth reds o Combeintatin f anirpy 2. Deduce the Graham's law of diffusion from the kinetic molecular theory equation for gases, Wn hs fle ONS Speast Moteete 5 +List four aracteristics of the molecular speed distribution curve. i eee pete Ne ont Sena er Specs at fa beamed TE finest Ren rote spats ce wit ty He CO foteys Tuy Vey pos meteentes hase fa ov ng ws Speeds 3 «-Conbegarcase Ps tace ep The os Cem ta) Ay B trereate> He mest Spud proits spuests = Re clastirtncts ofS pret betes bearer bet Hoe ettectiud Shape 0 (Oe Plage open pesetint . Ww) the prbatitity thore melete hes itr Sperct betirten any Ze98 week | B duun bytk aro ureter Hee Cumdt boeladen taste ee ota gfe 4. At what temperature will the molecules of nitrogen have the same root mean square velocity as molecules of oxygen? Fron Poot Maan tyme Melani f,,, < 28KONS _ 234K © BPE who Re © 31Gum met oe urns i (Me Molo moss DBxE 34x Tm ~| 3x6-31Gx275 | lee | ese | SREB ET, 4x 3191972 If a 5, Calculate the most probable and the arithmetic mean speed of oxygen molecules at- 20°C. (NY? =31.623g"? ms") = DORN IIE D5SK [ye Pnthereti Ouax Spent, Molomas gf Op. = 32glmot Ez eke an ly the Mote forest sped cpr DEE ze: = Cp = [Ons-3147 x93 emer S| = cles C= 12<74x 3-623 Che (treros% x31-623) els + GF Fo9mnbs J (pe 363ns! § 6ifthe mole fractions of glucose and water in a given solution at 25°C are 0.022 and 0.978, respectively, calculate the vapour pressure (v.P- ) lowering of water at 25°C. The vip of water at 25°C is 23.8 mmHg. Weens O.0990 | > Bp. Fovgrox 13% Male fractin of water 9.978 = O-SI3mmemly , Negev preddinns pnars ain ci fre Rewert Lemos Akep werty AP EXP ult Ap a Inet Xp stele ie Pre Mapere prene a 3. Give four examples of colligative property t) Baling pein Ebeuectini. b) Napewe prapec Povsuiay- we) Friagiag pow Beprennion ty) Openates, Prispart ya Selctibn * 4. Propanol has a boiling point of 56.2°C, 1.0 g of a non-volatile substance was dissolved in 10 g propanol. The solution boiled at 57.4°C, calculate the molar mass of the substance; Kb = 1.70Kmolar! | Brugia Hoare = 00g Frew , Bib = Fe [De x [yise ie | beast Bott Waly = 160g Petey = by rete searc Me se) ee Sh Mos KoxWh €to0o > texte tise | te Tom MA phen Bib x hy [->xto SSTHe Bere bite Ma £1 at C Ig lonsl Y 142gtmotThermodynamics Whats a state function? List five examples of an intensive property ian that ir. hs OClur ey “ye npn Papen ut the sgitem a te) Oem pesctie i vu Pressrnt, OY Benycry- © Baba, pee ©) Motor ttetteneDsctoas=a9ee £3 XESeesbx age) USD ~4x3-3npwig3 x395 SMSO -F4}op 5g “UI 54.9 ee enot® 211 Coe Tout? we Heaty Omburtin ot Conskent Prisiece ¢ MEI - [166 Lymel! 5. Forthereaction: * 02), ———> 250sq, the standard enthalpy is ~196.58 kJ at 25°C and the standard entropy change is -189 kimol, Calculate the standard Gibb's free energy change. Be = -tTC-S8ENS 196 St0009 Temperature (T= 96% F273 =0.98K Per AG*= Ay— TAS” AG’ =-196 Sees ~(244X~(64) = -1165%as - (-S£ 399) st HIICS ROK 4 56390 = ~ (10k TES = -(Core7ko -chefs:Energetic For the reaction Cj) + H20g— CO) + Hz) the standard enthalpy and entropy are + 131 kimo!” and +0.1336kJmol 7K’ respectively. At what temperature willthe reaction attain equilibrium? SHainatat patiratpy BUS AEDT : Stanclerd Larepy , O5°= +0- (33¢ [ere fem Cobbs free energy equation AG*> Au-- TAS° i At tgp ? AG'=o 2 = AH? -TAS* Att= of TSS Tas*= BH i Sete ti .. Ta 138k BS FO1386 EIT ~ EO a If the standard enthalpy change for the reaction Nop) + 3H2ip) = Z2NH3(q) is:92.38 kJ at 25°C, calculate the entropy change for the reaction and hence predict the spontaneity of the reaction at 25°C. ceVin ay Standed errretpy cheng Atl? = Ja. 35 19 Tempe ee = O5°CT 973 DER AS= Ar = 7-3F _o ayeant ape = TOES T —— whet AS= Vrondar} eadrepy herje at IFC Fhe rraslin wis be Spontentetnbecaute toe tactepy ertert eninny Chenpia pescbee:retest me is9.0x 107, ateuace sel cOHUDILDy this temperature in water.: Mg(OH) is a strong electrolyte and hasa solubility product of 8.9 x 1072, Calculate its. bility in water.List 4 examples of, Arrhenius Acid, 5 YySoq CSetphunis ast Tetra tphete (us) occ) WW ( tyctrchtase asia). : BD Mitts (Terotanchale W)aciy). %) AE C Wyonsiodic a oid) oF Calculate the K, of a0.05) M solution of acetic acid which is 10% ionized at 25°C Vay Kas C Wen ge Agree F Unigctecn, ra CE Conceapraticn ya tench Lge hyp s0-l hea = 0-12 9.95 sxut or” oq = S-sbuit Chemical Kinetics 4: State the factors that affect the fate of chemical reaction. D) anger ¥) Seatiger- Oy Guat sve S) Duqaor epset acta + +) Nocti. of rloctents YW Greenretiin a Metter PAELD Th Bere cre rractiley.2 clas wus? x aveuvee COPS 2 ote FBI X too. wi é e methods for determining the order of reaction? order reaction: A ———> products has ky = 2.2 x 105s at 400K. What ntofA isleftafter2 hours of reaction? ae Xda Ber Ge ; ; oie cO.%s3s5 +35 %h