Sec: JR.

IIT _*CO-SC(MODEL-A) Date: 15-10-23

Time: 3 Hrs Max. Marks: 198
15-10-23_JR.IIT_STAR CO-SC(MODEL-A) _JEE ADV_WAT-24_SYLLABUS
MATHEMATICS: 100% COMPLETE CONTINUITY AND DIFFERENTIABILITY
PHYSICS: PRESENT WEEK (80%): Surface Tension: Definition of surface
tension, Force required to lift objects from surface of liquids, Surface
energy, relation between surface tension and surface energy, Capillarity,
Angle of contact, rising of liquid in a capillary tube, excess pressure
inside a liquid drop, soap bubble,Surface tension, Experiment: Surface
tension of water by capillary rise and effect of detergents
PREVIOUS WEEK (20%): Elasticity & Viscosity: Elastic behaviour,
stress-strain relationship,Hooke's Law,Young's modulus,bulk modulus,
Elasticity experiment: Young's modulus of elastisity of the material of a
metallic wire Viscosity: Viscus force between two layers,stoke's law
terminal velocity, Rynolds number & Critical Velocity, Experiment:
Young’s modulus - elasticity of the material (Exclude: thermal stess)
CHEMISTRY: PRESENT WEEK (80%): Group 14: Electronic configuration ,general
trends in physical and chemical properties,allotropes of carbon,
Reactivity towards water halogen acid & alkali, Preparation , properties
and uses of CO, CO2, Silicon dioxides, Silicones, Silicates, Zeolites
(Exclude: Compounds of Sn & Pb)
PREVIOUS WEEK (20%): Group 13: Electronic configuration and
general trends in physical and chemical properties of elements across
the periods and down the groups; unique behaviour Boron, Reactions of
Boron and Aluminium with air, water, acids, alkali and halogen, uses of
Boron and Aluminium, Preparation, properties of diborane. Boron
halides- Lewis acid strength, Hydrolysis- Preparation , properties and
uses of Boron trifloride Preparation , properties and uses of Orthoboric
acid, Borax, Aluminium chloride, alums (Exclude: Isolation of B,
extraction of Al)
Narayana IIT Academy 15-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-24_QP
TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 198

PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 6) Questions with Single Correct Options +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 7 – 12) +4 -2 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 13 – 18) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +4 0 6 24
27.30)
Total 18 66

CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 19 – 24) Questions with Single Correct Options +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 25 – 30) +4 -2 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 31 – 36) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +4 0 6 24
127.30)
Total 18 66

MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 37 – 42) Questions with Single Correct Options +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 43 – 48) +4 -2 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 49 – 54) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +4 0 6 24
127.30)
Total 18 66

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Narayana IIT Academy 15-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-24_QP
MATHEMATICS MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
1. A function f(x) is defined as

 1
 1 , x  n ,n  I  I is the set of integers 
n

f : R  R, f  x    2

 0, otherwise

Then which of the following statement(s) is/are true?

A) f  x   f  2x  is continuous at x = 0

B) f(x) + f(2x) is continuous at x = 0

C) f(x) + f(4x) is continuous at x = 0

D) f(x) is continuous at x = 2

2. Let f  x   x  1  1 and g  x   max f  t  ;x  t  x  1, x  R  . The number of points

of non-differentiability of g(x) is

A) 7 B) 8 C) 9 D) 5

3. If f : R  R is a continuous function satisfying

f  0   1 and f  2x   f  x   x  x  R and

  x 
lim  f  x   f  n    P  x  then the value of P  3 is
n 
 2 

A) 2 B) 3 C) 1 D) none of these

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Narayana IIT Academy 15-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-24_QP
4. For every pair of continuous functions f ,g : 0,1  such that

max f  x  : x 0,1  max g  x  : x 0,1,

Consider the following statements.

S1:  f  c    3f  c    g  c    3g  c  for some c 0,1

2 2

S2:  f  c    f  c    g  c    3g  c  for some c 0,1

2 2

S3:  f  c    3f  c    g  c    g  c  for some c 0,1

2 2

S4:  f  c     g  c   for some c 0,1

2 2

Number of statements that are surely correct is:

A) 2 B) 3 C) 1 D) 0

5. Let y  f  x  be a function defined for all realx and is discontinuous at some points. Let

h  x    x 3  3x  1  f  x  be a function such that h(x) is continuous everywhere.

Then f  x  is discontinuous at ‘k’ number of points. Maximum value of k can be

A) 1 B) 2 C) 3 D) more than 3

6. Let f ,g : D  R be two functions and D  . Suppose c is an interior point of D such

that g(x) and f  x   g  x  be differentiable at x  c . Consider the statements P and Q.

P: If f(x) is not differentiable at x  c , then g(c) = 0.

Q: If g(c)  0 then f(x) must be differentiable at x  c .

Which of the following is correct?

A) Both P and Q are true B) Both P and Q are false

C) P is true but Q is false D) Q is true but P is false

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Narayana IIT Academy 15-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-24_QP
SECTION - 2 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
 2 1
 x  sin   ; if x  0
7. Consider the function ‘  ’ defined in [0,1] as   x    x .
 0 if x  0
 ;

Which of the following option(s) is/are correct?

A)   x  has a right derivative at x = 0

B)    x  is discontinuous at x = 0

C)    x  is continuous at x = 0

D)    x  is differentiable at x = 0

8. Let f be a twice differentiable function (meaning f   x  exists for all x) and

f x
 , x0
f  0   0,f   0   0. Define a function g by g  x    x
 0, x0


Then which of the following statement(s) is/areCORRECT?

A) g is continuous at x = 0

B) g has a first derivative at x = 0

C) The first derivative of g must be continuous at x = 0

D) g must have a second derivative at x = 0

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Narayana IIT Academy 15-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-24_QP
 2 
 x cos if x  0
9. Consider the function, f  x    2x
 if x  0
 0

Which of the following statement(s) is/are correct?

A) f is continuous at x  0
1
B) f is differentiable at x 
3
C) f is non-differentiable at infinite number ofpoints.
1
D) f is non-differentiable at x 
5
 1  1
 x   , x  ,n  N

Let f  x     x   n
10. then,
 1
 0, x 
 n

(Where  denotes greatest integer function)

A) f is differentiable at every value of x where it is defined

B) f is continuous at every value of x where it is defined

C) f is periodic

D) f is not an odd function

 5 1   x   1 where  represents the greatest integer

11. Let f : 0,    ,3 such that f  x   
 2 2  x  1
function and  represents the fractional part of x, then which of the following is/are
true?
A) f(x) is injective discontinuous function.
B) f(x) is surjective non-differentiable function.

 
C) min lim f  x  , lim f  x   f 1
x 1 x 1

D) max  lim f  x  , lim f  x    f  2 

x 2 x 2 

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Narayana IIT Academy 15-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-24_QP
12. For the function f :  0,1  R,f  x    2n x   2m x ,  n,m  N,n  m  , the number of

points of discontinuity of the function can be (where  x ,x represent G.I.F. and

fractional part respectively)

A) 24 B) 28 C) 26 D) 496

SECTION - 3 (Maximum Marks : 24)

This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
13. Number of points where f  x   x   x  sin x   sgn  x 2
 1 , x   6,6  is
discontinuous is ____ (where  denotes greatest integer function and  is fractional
part function, sgn(x) is signum function)
14. If x  R  and n  N, we can uniquely write x  mn  r where m  W and 0  r  n .
We defined x mod n = r for example 10.3 mod 3 =1.3. The number of points of
discontinuity of the function f  x    x mod 2    x mod 4  in the interval 0  x  9 is
2

Number of functions f(x) satisfying  f  x    x 2 x  R and continuous on R is

2
15.

 x 2  2x  3; x   2,0 

16. Let f  x    x 3  x 2  2; x   0,2 , then number of points of discontinuity of
 3  2x; x  (2,6]

f  f  x   in  2,6 is

17. For the function f  x   lim

 
ln 1  9x 2   9n x 2n cos  9x 2 
number of points of
n  1  9n x 2n
discontinuity in  3,3 is (where,  denotes G.I.F)

18. Let f : R  R and g : R  R be respectively given by f  x   x  1 and g  x   x 2  1 .

max.f  x  ,g  x  if x  0,
Define h : R  R by h  x   
 min.f  x  ,g  x  if x  0.

The number of points at which h(x) is not differentiable is

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Narayana IIT Academy 15-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-24_QP
PHYSICS MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
19. Water is filled upto a height h in a beaker of radius R as shown in the figure. The
density of water is  , the surface tension of water is T and the atmospheric pressure is
P0 . Consider a vertical section ABCD of the water column through a diameter of the
beaker. The force on water on one side of this section by water

A)  2 P0 Rh   R 2  gh  2 RT  B)  2 P0 Rh  R  gh 2  2 RT 

C)  P0 R 2  R  gh 2  2 RT  D)  P0 R 2  R  gh 2  2 RT 

20. Water in a clean aquarium cuboidal shapewith open topforms a meniscus as shown in
figure. Taking surface tension of the water as ‘T”, and density of water being ‘d’
determine the height difference h between the centre and edge of the meniscus (g =
acceleration due to gravity)(Assume angle of contact to be zero).

T 2T T T
A) B) C) D) 2
dg dg 2dg dg

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Narayana IIT Academy 15-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-24_QP
21. A glass capillary tube is of the shape of truncated cone with an apex angle ‘  ’ so that its
two ends have cross sections of different radii. When dipped in water vertically, water
rises in it to a height h,where the radius of its cross section is b. If the surface tension of
water is S, its density is ‘  ’ and its contact angle with glass is ‘  ’, the value of h will
be (g is the acceleration due to gravity)

2S 2S
A) .cos     B) .cos    
b g b g

2S     2S    
C) .cos       D) .cos      
b g   2  b g   2 

22. There is a horizontal film of soap solution. On it a thread is placed in the form of a loop.
The film is punctured inside the loop and the thread becomes a circular loop of radius R.
If the surface tension of the soap solution is T, then tension in the thread will be

 R2
A) B)  2 R 2T C) 2 RT D) 2RT
T

23. A cube with mass 20g floats on the surface of water. Each face of the cube is 3 cm long.
Surface tension of water is 70 dyne/cm. The distance of the lower face of the cube from
the surface of water is  g  980 cms 2   Angle of contact  00 

A) 2.13 cm B) 1.6 cm C) 2.7 cm D) 0.7 cm

24. A drop of water of volume V is pressed between the two glass plates so as to spread to
an area A. If T is the surface tension, the normal force required to separate the glass
plates is (gap between the plates is very small compared to A)

TA2 2TA2 4TA2 TA2

A) B) C) D)
V V V 2V

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Narayana IIT Academy 15-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-24_QP
SECTION - 2 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
25. A uniform rod of length L, area of cross section A and mass M is pulled horizontally on
a smooth surface with a force F. Identify the correct option (s)

Fl
A) elongation of the rod is
2YA
F
B) the strain produced in the wire is
2YA
F 2L
C) elastic potential energy in the string is
6YA
F 2L
D)elastic potential energy in the string is
4YA
26. When liquid medicine of density  is to be put in the eye, it is done with the help of a
dropper. As the bulb on the top of the dropper is pressed, a drop forms at the opening of
the dropper. We wish to estimate the size of the drop. We first assume that the drop
formed at the opening is spherical because that requires a minimum increase in its
surface energy. To determine the size, we calculate the net vertical force due to the
surface tension T when the radius of the drop is R. When this force becomes smaller than
the weight of the drop, the drop gets detached from the dropper.
Identify the correct option(s)
A) If the radius of the opening of the dropper is r, the vertical force due to the surface
2 r 2T
tension on the drop of radius R (assuming r << R) is
R

B) If the radius of the opening of the dropper is r, the vertical force due to the surface
 r 2T
tension on the drop of radius R (assuming r << R) is
R

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Narayana IIT Academy 15-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-24_QP

C) If r  5 104 m,   103 kgm3 , g  10ms 2 , T  0.11Nm1 , the radius of the drop when it
detaches from the dropper is approximately 1.4 103 m

D) If r  5 104 m,   103 kgm3 , g  10ms 2 , T  0.11Nm1 , the radius of the drop when it
3
detaches from the dropper is approximately 2.4 10 m

27. Pick out the wrong statement(s) from the following:

A) viscosityof a liquiddepends upon the nature of the liquids

B) generally viscosity of liquids is more than that of gases

C) in case of gases, viscosity decreases with increase of temperature

D) in case of liquids, viscosity decreases with increase of temperature

28. For vulcanized rubber stress – strain curve is shown. The rubber is used as vibration
absorbers. Choose the correct statement (s)

A) After one complete cycle, compression in rubber is zero.

B) The Young`s modulus of rubber is not constant for the given range of strain in the
figure
C) Work done by external agent is transformed into internal energy.
D) The temperature of rubber rises in every complete cycle.
29. A uniform capillary tube of inner radius ‘r’ is dipped vertically into a beaker filled with
water. The water rises to a height ‘h’ in the capillary tube above the water surface in the
beaker. The surface tension of water is  . The angle of contact between water and wall
of the capillary tube is  . Ignore the mass of water in the meniscus. Which of the
following statement is (are) true?
A) For a given material of the capillary tube, h decreases with increase in r.
B) For a given material of the capillary tube, h is independent of  .
C) if this experiment is performed in a lift, going up with a constant acceleration, then h
decreases.
D) h is proportional to contact angle  .
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Narayana IIT Academy 15-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-24_QP
30. Regarding figures (A) and (B) which of the following statements are correct.

A) The figure A shows water droplet on lotus leaf and angle of contact is obtuse

B) In figure B, Water spreads on clean plastic plate and angle contact is acute

C) The figure A shows water droplet on lotus leaf and angle of contact is acute

D) In figure B, Water spreads on clean plastic plate and angle of contact is obtuse

SECTION - 3 (Maximum Marks : 24)

This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
31. When a film of soap solution is created inside a loop formed by rectangular wire frame
and an inextensible light thread AB of length l , the thread assumes shape of a
semicircle. By pulling the midpoint of the thread with a force F, the thread can be given
shape of two semicircles as shown in the figure. Surface tension of the soap solution is
F
 . Find x
xl

32. A long capillary tube of radius 0.1 cm open at both ends is filled with water and placed
vertically. What could be maximum height of the column of water (in cm) left in the
capillary? (Given surface tension of water = 72 dyne/cm and density of water = 1
gm/cc. g  9.8 m / s 2 ,Angle of contact = 00 )

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Narayana IIT Academy 15-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-24_QP
33. When water is filled carefully in a glass, one can fill it to a height ‘h’ above the rim of
the glass due to the surface tension of water. To calculate ‘h’ just before water starts
flowing, model the shape of the water above the rim as a disc of thickness ‘h’ having
semicircular edges, as shown schematically in the figure. When the pressure of water at
the bottom of this disc exceeds what can be withstood due to the surface tension, the
water surface breaks near the rim and water starts flowing from there. If the density of
water, its surface tension and acceleration due to gravity are 103 kg / m3 ; 0.07 N / m and
10 m / s 2 , respectively, the value of ‘h’ (in mm) is

34. A circular wire, 10cm in diameter, with a slider wire on it, is in a horizontal plane. A
soap film is formed, bounded by the wires, on the left side of the slider, as shown. The
surface tension of the liquid is 100 103 N / m . An applied force F, perpendicular to the
slider, maintains the film in equilibrium. Ignore the sag in the film. In figure, when the
x
slider is 9cm from point P, the applied force is x 103 N . is equal to
6

35. A soap bubble is being blown on a tube of radius 1 cm. The surface tension of the soap
solution is 0.05 N/m and the bubble makes 600 with the tube as shown in the figure. The
excess of pressure over the atmosphere pressure in the tube is 2  Pa . Find the value of


36. The mass of water that rises in capillary tube of radius R is M. The mass of water that
rises in the tube of radius 2R is nM. What is the value of n?  angle of contact   00 

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Narayana IIT Academy 15-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-24_QP
CHEMISTRY MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
37. Which one is correct:

A) Density(G-13): B > Al > Ga

B) Density (G-14): Diamond > graphite < Lead

C) Electronegativity: Th >Carbon

D) Stability : T 
T 3

38. Which among the following are possible/feasible reactions ?

I) ZnO  C  Zn  CO

II) Cr2O3  2 Al  Al2O3  2Cr

III) Al2O3  2Cr  Cr2O3  2 Al

A) I, III B) II, III C) I, II D) I, II, III

39. Which among the facts, is false for diborane ?

A) It is highly reactive towards oxygen

B) It is having a maximum of Six atoms in the plane

C) It is not an electron deficient compound as it has sp 3 hybridized boron atoms

D) It can form boric acid upon reaction

40. An inorganic compound (x) obtained by the two most occurring elements into the earth
crust, has a polymeric tetrahedral network structure. (x) produces a toxic gas (y) with
carbon which is the most stable diatomic molecule. (x) & (y) are :

A) SiO2 , N 2 B) SiO2 , CO2 C) SiC, CO D) SiO2 , CO

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Narayana IIT Academy 15-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-24_QP
41. Which of the below is true, relative to silicones ?
A) RSiCl3 units are used to provided the cross linking among the silicone chain, making
if softer.
B) Silicone has very low dielectric strength
C) R3 SiCl units are called silicone chain stopping/terminatingunits.
D) Silicones can be decomposed very easily upon heating
42. Standard Carbogen(95% Oxygen, 5% Carbondioxide) is allowed to effuse out via an
44
orifice. The mole fraction of O2 in effusion mixture is : [Take  1.17 ]
32

A) 0.900 B) 0.980 C) 0.957 D) 0.998

SECTION - 2 (Maximum Marks : 24)

This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
43. Which of the following are not true ?
A) SiO exists at room temperature.
B) Tin decomposes water to form dioxide and hydrogen gas.
C) GeCl62 doesn’t exist.
D) SiCl62 doesn’t exist.
44. Identify the correct statement(s):
A) One of the man-made silicate is glass
B) Cations such as Na  , K  or Ca 2 are used to balance the negative charge of
aluminosilicates
C) Soccer shaped carbon allotrope has aromatic character
D) Fullerenes have smooth structures with dangling bonds

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Narayana IIT Academy 15-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-24_QP
45. Correct statement(s) is/are :
A) Si, Ge, Sn & diamond are isostructural.
B) I 2O5 is used in quantitative estimation of CO (g).
C) Keiselghur is a crystalline form of silica, used in filtration plants.
D) Silicones are biocompatible.
46. Identify A,B,C and D in the following reaction sequence

Si  CH 3Cl 
Cu powder
570K
 A 
H O
  B
2

O2 Polymerization

 C    D
Excess coke
Silicone
Electric arc

A) The compound A is  CH3 2 SiCl2

B) The compound C and D are SiO2 and SiC respectively

C) The compound B is  CH3 2 Si  OH 2

D) The compound B is  CH3 2 Si  O

47. Final products in the reaction is/are ?

3B2 H6  6NH3 

Low temperature
  x  

(y)  (z,gas)
 excess 

A) H 2O B) The gas z is diamagnetic

C) Borazole D) Borazon

48. Which of the following is/are correct:

A) Aluminium is a bright silvery-white metal, with high tensile strength.

B) I.E.1: Pb >Sn

C) Melting point: Ga > lead

D) Electrical resistivity: Si>Pb

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Narayana IIT Academy 15-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-24_QP
SECTION - 3 (Maximum Marks : 24)
This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
49. Average number of oxygen atoms shared per tetrahedral unit, in amphibole silicates are :

50. In Bucky(Soccer) ball :

No.of pentagons = x

No.of hexagons = y

No.of  bonds = z

Find x. y  z

51. Find the total number of incorrect statements:

A) Alum is a double salt which consists M  and M 3 types of cation only

B) Branched silicones can be formed by the hydrolysis of R 2SiCl2

C) Borax gives boric acid on hydrolysis in basic medium

D) Silicones are used in shoe polish due to water repelling nature of its alkyl group

E) Borax 
HCl
this reaction can result in product containing sp2 hybridized boron

F) In diborane, all B.A.s are equal

G) Carbon suboxide is a linear structure

H) Silicon can not react with nitrogen gas at any temperature

52. In an anion of pyrosilicate

Total number of Si atoms = x

Total number of O atoms = y

Magnitude of charge on one unit = z

x. y
Find
z

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Narayana IIT Academy 15-10-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_WAT-24_QP
53. Total number of neutral oxides among the following:

CO,CO2 ,GeO,SiO2 ,C3O2 ,B2O3

54. Find the mass of Al 3 ions, in gm. Required to neutralize 0.25 mole of the given cyclic
silicate
[Al = 27 g.mol-1]

JR.IIT_*CO-SC Page. No. 18